• Journal of Soil and Groundwater Environment
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• v.11 no.2
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• pp.22-37
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• 2006

The applicability of biobarrier or in situ microbial filter technology for the remediation of groundwater contaminated with chlorinated solvent was investigated through batch microcosm study. The efficiency and rates of reductive dechlorination of tetrachloroethylene (PCE) are known to be highly dependent on hydrogen concentration. In this study, the effect of electron donors on the reductive dechlorination of PCE was investigated using vermicompost (or worm casting) and peat as a biobarrier medium. The effect of organic acids (lactate, butyrate and benzoate), yeast extract and vitamin $B_{12}$ on the reductive dechlorination was investigated. In the absence of biobarrier medium (adsorbent), addition of electron donors stimulated the dechlorination rate of PCE compared to the control experiment (i.e., no electron donor added). Among the treatments, addition of lactate or lactate/benzoate as hydrogen donor exhibited the highest dechlorination rate ($k_1=0.0260{\sim}0.0266\;day^{-1}$). In case of using vermicompost as a biobarrier medium, amendment of lactate/benzoate exhibited the highest dechlorination rate following with a pseudo-first-order degradation rate constant of $k_1=0.0849\;day^{-1}$. In contrast, when Pahokee peat was used as a biobarrier medium, either butyrate or lactate addition exhibited the highest dechlorination rate with $k_1$ values of 0.1092 and $0.1067\;day^{-1}$, respectively. The results of this study showed the potential applicability of in situ biobarrier technology using vermicompost or peat as a barrier material for the remediation of groundwater contaminated with chlorinated solvent.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.12-20
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• 2003

This study presents a mathematical model for simulating the fate and transport of a reactive organic contaminant, TCE, degraded by cometabolism in dual-porosity soils during the installation of in situ biobarrier. To investigate the effect of dual-porosity on transport and biodegradation of organic hydrocarbons, a bimodal approach was incorporated into the model. Modified Monod kinetics and a microcolony concept were employed to represent the effects of biodegrading microbes on the transport and biodegradation of an organic contaminant. The effect of permeability reduction in biobarrier due to biomass accumulation on the flow field were examined in the simulation of a hypothetical field-scale in situ bioaugmentation. Simulation results indicate that the presence of the immobile region can decrease the bioavailability of biodegradable contaminants and that the placement of microbes and nutrients injection wells should be considered for an effective installation of biobarrier during in situ bioaugmentation scheme.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.3
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• pp.302-308
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• 2005

Nitrate is one of common contaminants frequently found in the bank filtrate. Biological autotrophic denitrification into permeable reactive barrier(PRB) system to reduce nitrate concentration in bank filtrate was implanted. The objectives of research are to investigate effect of inoculation, to evaluate alternative alkalinity sources, and to determine effect of hydraulic characteristics, such as retention time, flow rate on the performance of semi-pilot PRB system. Semi-pilot scale biological PRB system was installed using elemental sulfur and limestone/oyster shell as reactive materials near Nakdong River in Kyoungnam province, Korea. Nitrate concentration in bank filtrate was reduced by indigenous microorganisms in oyster shell as welt as by inoculating microorganisms isolated from the sludge of an anaerobic digester in a wastewater treatment plant. Oyster shell as well as limestone can be used as an alkalinity source. However, oyster shell resulted in suspended solids of effluent. As the flow rate in the system increased from 66 to 132 mL/min and accordingly the residence time decreased from 15 to 7.5 hours, nitrate concentration in effluent increased and nitrate removal efficiencies decreased from 75 to 58% at the fixed thickness of 80 cm of PRB.

• Journal of Soil and Groundwater Environment
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• v.12 no.2
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• pp.1-8
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• 2007

A series of batch and column experiments were conducted for the development of biobarrier technology which can be applied to containment and reduction of contaminants in soil and ground waters. The growth kinetic constants of Pseudomonas fluorescens on glucose or molasses were determined using batch experiments. The maximum specific growth rate (Vmax) of P. fluorescens at $23^{\circ}C$ on glucose or molasses were $0.246\;hr^{-1}$ and $0.073\;hr^{-1}$, respectively. However, molasses was selected as carbon source due largely to the absence of lag phase of P. fluorescens growth on molasses and economic reason. In constant head column experiments, the hydraulic conductivity of the column soil reduced by $6.8{\times}10^{-3}$ times from $4.1{\times}10^{-2}cm/sec$ to $2.8{\times}10^{-4}cm/sec$ after the inoculation of P. fluorescens and administration of carbon source and nutrients. The biomass concentration was observed highest in the column inlet. Measurements of carbon source and electron accepter (dissolved oxygen) concentration showed that the growth of P. fluorescence, which is the main reason for hydraulic conductivity reduction, was limited not by the concentration of carbon source but by the concentration of electron acceptor.

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 1999.04a
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• pp.5-8
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• 1999

동일부지내에 설치된 각 단동하우스에 무가온 상태 및 심야전력 전기히터, 온풍난방기를 각각 설치하여, 동절기 시설원예용 하우스의 온열환경, 난방방식별 에너지 소비특성, 난방효율에 대해서 검토하였다. 동절기 하우스의 벽체, 지붕을 통해 유출되는 관류열량을 정량적으로 계산하므로서, 하우스의 단열계획과 효율적 난방방식의 선정 및 난방에너지 절약을 유도할 수 있는 기초데이터를 제시하고자 한다. (중략)

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 1994.05a
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• pp.88-91
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• 1994

최근 국내에서도 시설원예가 급격하게 보급되고 있는 실정이다. 하지만, 시설원예가 에너지 소비형의 농경방식이라 지적되고 있는바 에너지절약형 온실의 개발이 필요할 것으로 판단되어, 본 실험실에서는 본 연구와 관련하여 비닐하우스의 벽체를 이중으로 하여 이중벽사이에 단열입자를 송풍기의 케이싱내로 직접 통하게하는 직송방식으로 충전ㆍ회수하는 실험을 실시한 바가 있으며, 그 결과 외기온의 평균이 -4.9$^{\circ}C$인 겨울철 야간에 입자를 충전한 이중비닐 하우스의 내부온도는 평균 9.8$^{\circ}C$로 단열성이 우수함을 알 수 있었다.(중략)

• Journal of Korean Society of Environmental Engineers
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• v.29 no.9
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• pp.1060-1068
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• 2007

Perchlorate contamination in aquatic system is a growing concern due to the human health and ecological risks associated with perchlorate exposure. In spite of potential risks associated with perchlorate, drinking water standard has not been established worldwide. Recently, US EPA has issued new protective guidance for cleaning up perchlorate contamination with a preliminary clean-up goal of 24.5 ppb. In Korea, the drinking water standard and discharge standard for perchlorate has not been established yet and little information is available to address perchlorate problems. Perchlorate treatment technologies include ion exchange, microbial reactor, carbon adsorption, composting, in situ bioremediation, permeable reactive barrier, phytoremediation, and membrane technology. The process description, capability, and advantage/disadvantages of each technology were described in detail in this review. One of recent trends in perchlorate treatment is the combination of available treatment options such as combined microbial reduction and permeable reactive burier. In this review, we provided a brief perspective on perchlorate treatment technology and to identify an efficient and cost-effective approach to manage perchlorate problem.

• Journal of Environmental Science International
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• v.16 no.10
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• pp.1147-1155
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• 2007

The applicability of in situ biobarrier or microbial filter technology for the remediation of groundwater contaminated with chlorinated solvent was investigated through column study. In this study, the effect of packing materials on the reductive dechlorination of PCE was investigated using Canadian peat, Pahokee peat, peat moss and vermicompost (or worm casting) as a biobarrier medium. Optimal conditions previously determined from a batch microcosm study was applied in this column study. Lactate/benzoate was amended as electron donors to stimulate reductive dechlorination of PCE. Hydraulic conductivity was approximately $6{\times}10^{-5}-8{\times}10^{-5}\;cm/sec$ and no difference was found among the packing materials. The transport and dispersion coefficients determined from the curve-fitting of the breakthrough curves of $Br^-$ using CXTFIT 2.1 showed no difference between single-region and two-region models. The reductive dechlorination of PCE was efficiently occurred in all columns. Among the columns, especially the column packed with vermicompost exhibited the highest reductive dechlorination efficiency. The results of this study showed the promising potential of in situ biobarrier technology using peat and vermicompost for the remediation of groundwater contaminated with chlorinated solvents.

• Economic and Environmental Geology
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• v.38 no.5 s.174
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• pp.525-534
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• 2005

Adsorption experiments for As(V) and As(III) onto the surfaces of aerobic Pseudomonas aeruginosa, which can be readily isolated from natural media, were conducted under nutrient-absent conditions. While a small amount of As(III) was adsorbed on the bacterial cell surfaces, As(V) was not effectively removed from the solution through adsorption. The result was likely due to the electrostatic repulsion between anionic compounds of aqueous As(V) and cell surfaces of f aeruginosa. However, the bacteria forming biofilm reduced a large amount of aqueous As(V) to As(III), which indicated that microorganisms in most oligotrophic, natural geologic settings can mediate the behavior of aqueous As. Biobarriers designed to remove the various heavy metals in contaminant plume may practically lead to the enhancement of toxicity and mobility of As.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.402-406
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• 2006

The physical and chemical characteristics of ALC were analyzed and showed 2.2 of specific gravity and 9.05 of pH. The results of leaching tests with standard method for soil and waste indicated heavy metals(Cu, Cd, Pb, $Cr^{6+}$) were under maximum concentration level. The anaerobic digestion sludge was attached in the surface of ALC within 90 hours. As the results of batch test, pH of the ALC and Bio-ALC were decreased from initial pH of ALC to 8.7 and 7.8 respectively Also, the concentration of heavy metals was rapidly eliminated in the solution with the batch test. The result of column experiment indicates that the removal efficiency of ALC was showed 66% of T-P, 60% of T-N, and 67% of CODcr. Also, removal efficiency of Bio-ALC was slightly higher than that of ALC in T-N (64%) and CODcr (74%).