• Title/Summary/Keyword: 상자성

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The Magnetic Relaxation Properties of DTPA-bis(4-carboxycyclohexyl) amide Paramagnetic Gd-chelates (DTPA-bis(4-carboxycyclohexyl)amide 상자성 복합체의 자기이완특성에 관한 연구)

  • Kim, In-Sung;Lee, Young-Ju;Lee, Jae-Jun;Kim, Ju-Hyun;Kim, Yoo-Kyung;Sujit, Dutta;Kim, Suk-Kyung;Kim, Tae-Jeong;Kang, Duk-Sik;Chang, Yong-Min
    • Investigative Magnetic Resonance Imaging
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    • v.10 no.1
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    • pp.20-25
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    • 2006
  • Purpose : To evaluate the NMR relaxation properties of newly developed high performance paramagnetic complexes. Materials and methods : 4-aminomethylcyclohexane carboxylic acid (0.63g, 4 mmol) was mixed with the suspension solution of DMF (15mL) and DTPA-bis-anhydride (0.71g, 2 mmol) to synthesize the ligand. The ligand was then mixed with Gd2O3 (0.18g, 0.5 mmol) to synthesize Gd-chelate. For the measurement of magnetic relaxivity of paramagnetic compounds, the compounds were diluted to 1mM and then the relaxation times were measured at 1.5T(64 MHz). Inversion-recovery pulse sequence was employed for T1 relaxation measurement and CPMG(Carr-Purcell-Meiboon-Gill) pulse sequence was employed for T2 relaxation measurement. Using MATLAB(Version 7.1) program, T1 magnetic relaxation map, R1 map, T2 magnetic relaxation map and R2 map were developed to represent magnetic relaxation time and magnetic relaxivity as image. Results : Compared to $R1=4.9mM^{-1}sec^{-1}$ and $R2=4.8mM^{-1}sec^{-1}$ of Omniscan (Gadodiamide), which is commercially available paramagnetic MR agent, R1 of SUK090(Gd-C32H74N5O24) was $12.46mM^{-1}sec^{-1}$ and R1 of SUK091(Gd-C34H78N5O24) was $12.77mM^{-1}sec^{-1}$. However, R1 of SUK092(Gd-C30H56N5O17) was decreased to $2.09mM^{-1}sec^{-1}$. In case of R2, SUK090(Gd-C32H74N5O24) was $8.76mM^{-1}sec^{-1}$ and SUK091(Gd-C34H78N5O24) was $7.60mM^{-}1sec^{-1}$ whereas SUK092(Gd-C30H56N5O17) was decreased to $1.82mM^{-1}sec^{-1}$. Conclusion : Among three new paramagnetic complexes, SUK090(Gd-C32H74N5O24) and SUK091(Gd-C34H78N5O24) showed higher T1, T2 magnetic relaxation rates than that of commercially available paramagnetic MR agent and thus expected to have more contrast enhancement effect.

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Polarization dependence on Cavity Ringdown Spectroscopy (공동 광자감쇠 분광학에서의 편광의존성)

  • 김재완;한재원
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.216-217
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    • 2000
  • 상자성을 갖는 분자에 대한 분광학 연구에서는 제만(Zeeman) 효과로 생기는 이색성을 이용한 magnetic rotation spectroscopy (MRS)가 널리 사용되고 있다.$^{(1)}$ MRS가 일반적인 흡수 분광법에 비해 더 민감한 측정을 할 수 있기는 하지만 사용하는 편광기의 extinction ratio에 의해 감도가 한정된다. MRS의 감도를 높이는 방법으로는 광경로를 길게 만드는 것을 고려할 수 있다. 일반적으로 공진기 광자감쇠 분광학(Cavity Ring-Down Spectroscopy, CRDS)은$^{(2)}$ 높은 반사율을 갖는 거울을 사용해서 수 km 이상의 광 경로를 만들기 때문에 감도가 높다. (중략)

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Analysis of Box Girder Bridge for Finte Element Method (유한요소법(有限要素法)에 의한 상자항교(箱子桁橋)의 해석(解析))

  • Jang, In Ho;Choi, We Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.9 no.2
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    • pp.11-22
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    • 1989
  • The finite element utilizing isoparametric plate element is applied for the elastic analysis of straight box girder bridges. A continuous box girder is analyzed as an example to verify the validity and accuracy of this method. It is indicated that the deflections and longitudinal stresses obtained by this method agree well with those from the orther methods. This theory may, therefore, be directly used as an efficient tool to analyze and design box girder bridges subjected to arbitrary loading and boundary conditions.

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Pulsed NMR Study of $CuF_{2}.2H_{2}O$ ($CuF_{2}.2H_{2}O$의 펄스 핵자기공명 연구)

  • Lee, C.E.;Yoon, E.H.;Lee, C.H.;Kim, K.;Jeon, S.J.
    • Journal of the Korean Magnetics Society
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    • v.3 no.1
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    • pp.13-17
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    • 1993
  • We have studied $CuF_{2}.2H_{2}O$ using $^{1}H$ and $^{19}F$ pulsed nuclear magnetic resonance at 30 MHz. From the data of lineshapes, the spin-lattice relaxation times ($T_1$) and the spin echo decay times, lattice dynamics in the structure is investigated. $T_1$ data from both $^{1}H$ and $^{19}F$ NMR indicate that spin-lattice relaxation is dominated by the paramagnetic ion centers at the Cu sites. The lineshapes at room temperature appear to be strongly affected by exchange narrowing and motional narrowing.

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Freshness Extension of ‘Fuji’Apple to Packaging materials (포장재가 ‘후지’사과의 신선도에 미치는 영향)

  • 박형우;박종대;김동만;최주섭
    • Food Science and Preservation
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    • v.8 no.4
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    • pp.345-350
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    • 2001
  • This study was measured weight loss, total ascorbic acid, titratable acidity, and soluble solids content to investigate the effect of EPS(expanded polystyrene foam, foaming rate 55 times V/W) box, LDPE film pouches and double wall corrugated fiberboard box during storage at 20$\^{C}$. Weight loss of apple packed with corrugated paperboard box after 40 days storage was 5.7%, arid those of LDPE, CE(zeolited coated film) film and EPS box were 0.2-0.5%. Ascorbic acid content of apple packed with LDPE, CE, EPS was higher than that of control. Titratable acidity and total soluble solid content of control were changed 40% and 10%, but the EPS were changed 27% and 4%, respectively. Overall appearances of ‘Fuji’apple packed with LDPE, CE and EPS were better than that of control.

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Research Trend and Prospect in Ferromagnetic Superconductor (강자성 초전도체의 연구동향과 전망)

  • Han, Sang-Wook
    • Journal of the Korean Magnetics Society
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    • v.22 no.2
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    • pp.66-72
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    • 2012
  • The findings of ferromagnetic superconductor have attracted much attention not only for fundamental research to investigate how the antagonistic properties of ferromagnetism and superconductivity coexist peacefully but also for potential technological applications. Firstly, in order to help for understanding the ferromagnetic superconductor, I have explained the orbital and paramagnetic pair-breaking effects of magnetic field, which breaks the superconducting Cooper pairs. In addition to such effects of magnetic field, the singlet Cooper pairs become unstable upon going through the ferromagnetic materials by the proximity effect. The proximity effect occurs at the interface of thin films composing of superconductor and ferromagnet and leads to have very short penetration depth of Cooper pairs. However, a type of odd-frequency triplet in comparison with the singlet could be very stable and has a longer effective depth. It needs to be explored for the innovative spintronic devices. Finally, various ferromagnetic superconductors coexist and the lower-dimensional materials under the Quantum confinement effect have been introduced.

Development of Structural Design and Standards for Fishery Containers during Distribution Process (수송용 어상자 포장용기 규격 및 구조설계에 대한 연구)

  • Lee, Myung-Hoon;Son, Ki-Ju;Kim, Jai-Neung
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.8 no.2
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    • pp.32-38
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    • 2002
  • In order to improve the transportability and safety of fishery products during distribution process, we developed new containers made of polyethylene polypropylene copolymers. Two types are developed; two color type and bar type. As the result, the stacking efficiency improved by 27.6% while providing great transportability and decreasing sanitation problems.

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Corrugated Paperboard Box Laminated Functional MA Film for Freshness Extension of Tomato (기능성 골판지 상자에 포장된 토마토의 신선도)

  • Park, Hyung-Woo;Kang, Jin-Kyung;Park, Jong-Dae;Kim, Dong-Man;Kim, Kee-Jeong
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.7 no.2
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    • pp.1-5
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    • 2001
  • This study was measured weight loss, total ascorbic acid, titratable acidity, and soluble solids content and overall appearances to investigate the effect of FC(corrugated fiberboard box laminated with functional MA film)box, LDPE film, CE(functional MA film)pouches and double wall corrugated fiberboard box during storage at $20^{\circ}C$. Weight loss of tomato packed with control, LDPE, CE and FC box at $25^{\circ}C$ after 7 days were 5.3%, 1.5%, 1.3%, and 1.5%, respectively. Weight loss of control was 3.8% higher than that of FC box. Total ascorbic acid content(TAA) of tomato after 7. days, control was 6.89 mg%, LDPE was 8.62 and CE was 8.53mg%, FC was 8.42mg%. TAA of LDPE, CE and FC was higher than that of control. Titratable acidity of tomato packed with LDPE, FC and CE was higher than that of control. Overall appearances of tomato packed with LDPE, CE and FC was better than that of control. Functional MA film laminated in corrugated paperboard box(FC) showed to be able to used as a packaging box of tomato.

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An Experimental Study of Strength Evaluation in Frozen Soils according to Direct Shear Box Systems (직접전단상자 시스템에 따른 동결토의 강도 평가에 관한 실험적 연구)

  • Kim, Sang Yeob;Kim, YoungSeok;Lee, Jangguen;Lee, Jong-Sub
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.3
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    • pp.5-14
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    • 2017
  • Experimental study on strength characteristics of frozen soils is necessary for the safety evaluation of design and construction in cold region. The objective of this study is to evaluate the direct shear strength of frozen soils obtained from traditional system (Type-1), system with roller on the upper shear box (Type-2), and system with fixed upper shear box separated from bottom shear box (Type-3). Specimens mixed with sand, silt, and water are frozen to $-5^{\circ}C$, and then direct shear tests are conducted under the normal stress of 5, 10, 25, and 50 kPa. Experimental results show that the upper shear box of Type-1 touches the bottom shear box due to the rotation of the upper shear box. The shear strength obtained from Type-2 is overestimated because the preventing rotation force is added to shear force. Type-3 may acquire the only strength of the specimen, and shear strain at peak shear strength is similar to that at the beginning of vertical displacement occurrence. In addition, internal friction angle and cohesion at both peak and residual stresses in Type-3 are smaller than those of Type-2. This study shows that high strength specimens including frozen soils can be effectively evaluated using improved shear box system such as Type-3.

Ergonomic Evaluation of a Powered Rail Trolley in a Tomato Greenhouse (토마토 온실 내 레일 전동 작업차의 인간공학적 작업 부하 평가)

  • Jeong, Eun Seong;Yang, Myongkyoon;Son, Daesik;Cho, Seong In
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.143-143
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    • 2017
  • 산업이 고도화됨에 따라 자동화 기계 및 로봇에 의해 대량 생산 되는 품목과 달리, 작업 절차의 비정형성, 비연속성 등으로 인해 여전히 농업에 많은 인력이 투입되고 있다. 국제노동기구에 따르면, 세계 인력의 절반이 농업 인력에 해당하고 작업 중 부상이나 사망 등으로 인해 가장 위험한 직업군 중 하나에 해당하는 것으로 나타났다. 시설 재배 농업의 경우, 노동집약적인 온실 내 작업 특성상 잘못된 자세로 작업하거나 지나친 작업량 등으로 인해 작업자에게 근골격계 질환이 발생할 수 있다. 근골격계 질환으로 인해 작업효율이 감소하거나 생산비용의 증가로 이어질 수 있으며, 농가 수익에 손실이 발생할 수 있다. 이에 본 연구에서는 현행 시설 재배 농업에서 사용되는 레일 전동 작업차를 이용하여 작업자가 토마토를 수확할 때의 신체에 대한 농작업의 부하를 평가하고자 하였다. 작업차를 이용한 주요 작업 절차는 작물로부터 과실 수확, 과실 상자에 과실 투입, 빈 과실 상자와 가득 찬 과실 상자의 교대, 작업차 위의 과실 상자를 운반용 파레트에 하역하는 순서로 이루어지는 것을 확인하였다. 비디오장비로 촬영된 일련의 농작업 과정을 OWAS, RULA, REBA와 같은 체크리스트형 인간공학적 작업 부하 평가 도구를 이용하여 평가한 결과, 기존 레일 전동 작업차를 이용한 농작업의 근골격계 질환 유발 가능성을 확인하였다. 동작별 위험성을 토대로 근골격계 질환 유발 가능성이 높아 개선이 필요한 농작업 동작을 선정하였다. 선정된 동작은 실험실 내 환경에서 피실험자를 통한 모의 동작의 생체 신호 계측을 통해 신체 부하 정도를 정량적으로 측정할 수 있으며, 보조가 필요한 신체 부위를 특정하거나 안전성 확보가 필요한 동작에 대한 증거가 될 수 있다. 본 연구를 통해 향후 토마토 온실 내 신선도 유지를 위한 레일 전동 작업차의 개발에 작업자의 안전과 효율성 향상을 위한 인간공학적 설계를 적용할 수 있을 것으로 기대한다.

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