• Title/Summary/Keyword: 상대구조계수

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ta-C 후막코팅을 이용한 비철금속가공용 절삭 공구류의 수명향상에 관한 연구

  • Jang, Yeong-Jun;Gang, Yong-Jin;Kim, Dong-Sik;Lee, Ui-Yeong;Kim, Jong-Guk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.132-132
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    • 2016
  • 기계 가공품의 정밀화, 경량화 요구로 난색재로 분류되는 비철분야 및 복합재 가공용 공구개발에 대한 수요가 급증하고 있으나, 기존 난삭재 가공 시 절삭공구의 마모가 빠르고, 상대재의 융착 불량 등이 공구 수명 감소의 주요 영향으로 보고된다. 상기문제를 해결하기 위해 절삭가공 공정 중 과다한 절삭유의 사용에 따른 가공비용, 에너지소모 증가, 환경오염 등으로 절삭유의 최소화 또는 절삭유를 사용하지 않는 표면처리기술등의 친환경 가공기술의 개발이 필요하다. 내융착 및 내마모 특성 향상을 위한 표면코팅 방법으로 수소가 포함되지 않은 고경도 비정질 카본 (ta-C)이 있으나, ta-C 코팅 막은 경도 30 - 80 GPa, 잔류응력 3 - 10 GPa 범위로 일반 경질 코팅 막 (AlTiN, TiSiCrN : 평균 3 GPa)에 비해 높고 산업적 활용이 가능한 0.5 - 1.5 um 두께 수준의 후막화가 힘들어 매우 우수한 절삭공구용 코팅 막 특성에도 불구하고 적용사례가 매우 적다. 따라서, 본 연구에서는 아크플라즈마 방식 (Filtered Cathode Vacuum Arc Plasma, FCVA)을 활용한 고경도/무수소 카본 코팅 막을 후막형태로 증착하여 비철금속가공용 절삭 공구류의 수명향상 기법을 제시하고자 한다. ta-C 코팅 막의 기초 공정개발 단계에서는 바이어스 전압, 공정시간을 달리하여 ta-C 코팅 막의 기계적 물성(경도: $50{\pm}3GPa$, 잔류응력: $6{\pm}1GPa$, 밀착력: 30N 이상 및 트라이볼로지 특성: 마찰계수 0.1 이하, 마멸량: $1.85{\times}10-14mm^3$)을 확보하여 절삭공구로의 공정실용화 적용검토를 실시하였다. ta-C 코팅 막은 (1) WC 공구 및 기존 상용품인 (2) TiAlN/TiN/WC 구조에 대해 증착을 실시하였으며 코팅 막의 두께 변화에 따른 실제 절삭환경에서의 내수명 관측을 진행하였다. 시험결과, ta-C/WC의 단일막 구조인 절삭공구의 경우, 실제 절삭환경에서 쉽게 박리가 발생하여 코팅 막으로서의 효과를 나타내지 못하였다. 이는, 기초 공정개발 단계에서의 밀착력 기준이 실제 환경과 부합하지 않는 것을 의미하며 추후 공정개선을 통해 극복하고자 한다. 반면에, 상용품인 (2) TiAlN/TiN/WC 구조의 절삭공구 대비 ta-C/TiAlN/TiN/WC 구조에서 내수명 증가는 약 2.5배 (기존 300회, 코팅 후 800회)로 증가하였으며 ta-C 코팅 막의 두께가 $0.6-0.8{\mu}m$일 때 최대치를 취한 후 감소하였다. 이를 통해, 절삭공구로의 ta-C 코팅 막 효과는 최외각 층의 두께 범위와 모재 강도보강을 할 수 있는 적절한 중간층 막 (TiN/TiAlN 층)이 혼합되어 나타난 것으로 사료되며 현재 산업계로의 적용을 위한 대량생산용 코팅장비의 개발 및 비용절감을 위한 공정개발이 진행 중이다.

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Structural and Microwave Dielectric Properties of $La(Mg_{1/2}Ti_{1/2})O_3$ Ceramics ($La(Mg_{1/2}Ti_{1/2})O_3$ 세라믹스의 구조 및 고주파 유전 특성 연구)

  • Yeo, Jae-Hyun;Baek, Jong-Hu;Nham, Sahn;Lee, Hwack-Joo;Park, Hyun-Min;Byun, Jae-Dong
    • Korean Journal of Materials Research
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    • v.9 no.9
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    • pp.943-947
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    • 1999
  • The crystal structure and the microwave dielectric properties of $La(Mg_{1/2}Ti_{1/2})O_3$ ceramics have been investigated. $La(Mg_{1/2}Ti_{1/2})O_3$ has the 1:1 ordered monoclinic structure with the lattice parameters of $a = 5.5467(3){\AA}, b = 5.5616(3){\AA}, c = 7.8426(5) {\AA} and \beta = 89.9589 (2)^{\circ}$ The spacegroup of LMT is $P2_1/n$. Monoclinic LMT has the in­phase and anti-phase tilting of octahedra with the $a^_a^_c^_$ tilting system. Anti-parallel shift of A-site cations was also found in LMT. The relative density of the specimens sintered above $1600^{\circ}C$ was ranged between 95 % and 96 % of the theoretical density and the dielectric constant of specimens was about 28. The highest $Q\timesf$ achieved in this investigation was 63,100 for the specimen sintered at $1630^{\circ}C$ for 5 hr. Temperature coefficient of resonance frequency ranged from $>-74 ppm/^{\circ}C ~ -79 ppm/^{\circ}C$.

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Performance Based Evaluation of Concrete Strength and Freeze-Thaw Resistance from Wind Speed - Sunlight Exposure Time Effect (풍속과 일조시간에 따른 콘크리트의 강도 및 동결융해 저항성 성능중심평가)

  • Kim, Tae-Kyun;Choi, Seung-Jai;Choi, Ji-Hun;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.49-58
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    • 2017
  • The phenomena that we experience in everyday life such as snow, rain, wind, and temperature are referred to as weather, and the average state of atmospheric phenomena that occur over a long period of time in a specific region is referred to as climate. In addition, significant variation of climate compared to the average state is referred to as climate change. Concrete structures can have various problems when exposed to elements. Among the problems, the freeze-thaw problem due to extreme climatic factors such as heavy rain and snowfall has become a particularly significant issue recently. The concrete that has been subjected to repeated freeze-thaw rather than too high or low temperature shows serious degradation of durability, and the performance of structures with degraded performance is difficult to recover. Therefore, in this study, concrete durability performance with respect to freeze-thaw from curing conditions change due to wind speed and sunshine exposure time. Concrete freeze-thaw experiment are performed. using wind speed and sunlight exposure time. Also, performance based evaluation through the satisfaction curve based on the freeze-thaw test results are performed.

Relationship Between Above-and Below-Ground Biomass for Norway Spruce (Picea abies) : Estimating Root System Biomass from Breast Height Diameter (독일가문비나무(Picea abies [L.] Karst)의 지상부(地上部)와 지하부(地下部) 생체량(生體量)에 관(關)한 연구(硏究) : 흉고직경(胸高直徑)에 의한 뿌리생체량(生體量) 추정(推定))

  • Lee, Do-Hyung
    • Journal of Korean Society of Forest Science
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    • v.90 no.3
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    • pp.338-345
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    • 2001
  • This study was conducted to elucidate the relationship between the root structure and the crown structure of Norway spruce(Picea abies [L.] Karst), and thereafter to obtain the regression equation for the estimation of relative root and needle biomass using the tree height and diameter at breast height(DBH) without measurement of root and needle biomass. The study site was Barbis stands of Harz region located in central part of Germany. Five dominant and three co-dominant trees of 30 to 40 year-old Norway spruce were selected and tree height, diameter at breast height, clear bole length, weight of total needle and branch, cross section and sapwood area at breast height for biomass of above ground part and also the length of root, the number of root, the weight of root, the cross section area of root etc. by dividing the horizontal and vertical roots for below ground part of tree were measured. The significantly correlation was shown between the biomass of most of variables of above ground parts and those of below ground parts. For the diameter of breast height to the weight of total root, regression equation was Y = 3.56X - 45.94 and decision coefficient was 0.96 showing highly correlation. The weight of total branches and needles, and the tree height etc. of above ground parts showed highly positive relationship with below ground biomass. The results obtained from this study can be used to the estimating of biomass of below ground using variables of above ground such as DBH in the 30 to 40 year-old Norway spruce stands.

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Humidity Sensitive Properties of Polymer Electrolytes of Quaternary Ammonium methacrylate derivatives (메타크릴레이트계 4차 암모늄 유도체 고분자 전해질의 감습특)

  • Kim, Tae-Mi;Gong, Myeong-Seon;Lee, Im-Yeol;Park, Jeong-Gi
    • Korean Journal of Materials Research
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    • v.3 no.6
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    • pp.598-605
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    • 1993
  • Methacryloxyethyl dimethyl alkyl($C_{1}\sim C_{12}$, benzyl and 2, 2-diethoxy ethyl) ammonium bromide monomers were prepared to investigate the relative humidity characteristics for polymer electrolytes with different chemical structures. They were coated on the alumna substrate printed comblike gold electrode by photopolymerization after micro-syringe injection. As the thickness of rhe humid membrane increased, the impendance decreased, whereas the impedance ~ncreased as the carbon cham of alkyl substituent in the monomer increased. The impendance of the polymeric electrolytes with $C_6\sim C_8$ substituents were varied from 19M$\Omega$ to 5K$\Omega$ for the range of 30-90% Mi. The temperature depedence coefficient in the range of 15-$35^{\circ}C$ was found to be -0.45% $RH/^{\circ}C$and the hysteresis falled within the range of $\pm$2% RH. The response time was 35 second for varying humldity from 33% to 85% RH.

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Sintering and Electrical Properties of Mn-doped ZnO-CaO Varistor (Mn 첨가에 따른 ZnO-CaO 바리스터의 소결 및 전기적 특성)

  • Lee, Jae-Ho;Hong, Youn-Woo;Shin, Hyo-Soon;Yeo, Dong-Hun;Moon, Joo-Ho;Kim, Jong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.310-310
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    • 2010
  • ZnO 바리스터는 정전기 (ESD) 및 순간적인 써지(surge)로부터 전자기기 및 전자회로 등을 보호하기 위해 개발된 전자 세라믹스 소재이다. 최근 전자기기 등의 고속통신 추세에 따라 ZnO 바리스터는 높은 비선형 특성과 함께 보다 낮은 유전율 및 유전손실 특성이 특별히 요구되고 있다. 본 연구에서는 현재 양산되고 있는 Bi-계와 Pr-계 ZnO 바리스터가 아닌 새로운 조성계에 $Mn_3O_4$를 0.0~3.0 at% 첨가하여 소결 및 전기적 특성들 살펴보았다. 시편은 일반적인 세라믹 공정에 따라 제조하여 $1200^{\circ}C$에서 1 시간 공기 중에서 소결하였으며, 소결 및 전기적 특성과 유전 특성(밀도, 미세구조, I-V 특성, 유전율, 유전손실, ZnO 비저항)은 FE-SEM, Keithley237, Agilent 4294a 및 Agilent 4991a 장비를 사용하여 첨가제에 따른 ZnO 바리스터의 특성 변화를 관찰하였다. 그 결과 Mn이 0.2 at% 첨가한 계의 바리스터의 상대밀도는 95%, 비선형계수는 14, 유전율은 140 (at 1MHz), 손실값은 0.147 (at 1 MHz)를 나타내었다. 이를 통하여 새로운 바리스터 조성계에서 Mn의 첨가에 따른 효과에 대하여 논하였다.

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Study on Damping Coefficient of Shock Absorber with Magnetic Effects (자기효과를 이용한 충격흡수장치의 감쇠계수에 관한 연구)

  • Yi, Mi-Seon;Bae, Jae-Sung;Hwang, Jae-Hyuk;Hwang, Do-Sun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.39 no.9
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    • pp.832-838
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    • 2011
  • The shock absorber with magnetic effect is suggested for a lunar lander. The shock absorber consists of a metal tube, a piston rod, and several permanent magnets moved by a piston rod in the tube, and the shock energy can be dispersed and dissipated by magnetic effects such as the magnetic force existed between a metal and magnets and the eddy current effect generated by a relative motion with a conductor and magnets. Besides, the shock-absorbing effect similar to that of a coil spring can be obtained by arranging the magnets in line, which are facing the same polar each other. The device has a very simple structure and is usable in space due to the unnecessariness of any oil or gas. The shock absorber was designed and manufactured for experiments and its spring and damping characteristics were studied by the theoretical, analytical and experimental methods.

The Electrical Characteristics of Ceramic Capacitor for High Voltage (고전압용 세라믹 커패시터의 전기적 특성)

  • 홍경진;김태성
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.1
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    • pp.53-59
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    • 1999
  • The ceramic capacitor was fabricated by $(Ba_{0.85}Ca_(0.15)TiO_3+ZnO$ + ZnO(from 0.1 to 0.4 mol ratio). The electrical and structural properties of ceramic capacitor for high voltage application was studied in this study. The relative rensity of ceramics capacitor has shown high in all specimen. The grain was a small size from $1.0[\mum]$ to $1.22[\mum]$ and it was increased with ZnO at 0.3 mol ratio. It was stabilized that the temperature coefficient of ceramic capacitor to change temperature had below 100[ppm] at 0.12~10[kHz]. The dielectric reIaxation time was decreased by interface polarization over $110[^{\circ}C]$ and it was increased by space polarization of paraelectric layer below $110[^{\circ}C]$. The insulating layer was increased with ZnO and dielectric constant to voltage was stabilized by 0.1[%].0.1[%].

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Statistical methods for evaluating the tracking phenomenon of blood pressure (혈압의 역학적 연구와 지속성(tracking)에 대한 통계학적 분석)

  • Suh, Il;Nam, Chung-Mo;Kang, Hyung-Gon
    • The Korean Journal of Applied Statistics
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    • v.6 no.2
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    • pp.191-200
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    • 1993
  • This study introduced speical characteristics of an epidemiologic study on blood pressure and compared several statistical methods for evaluating the tracking phenomenon of blood pressure for Korean children. While correlation coefficients adjusted for measurement error are commonly used for the evaluation of tracking, it is hard to interpretate the results when correlation functions for lag-difference are not monotonous. McMahan defined a tracking as maintenance of relative rank over time and calculated tracking index usng growth curve model. The tracking index in McMahan's model is complicate to calculate, and it is hard to determine the degree of growth curve parameter. Blomqvist showed the relationship between the rate of change and the initial value. This concept could be extended for the evaluation of tracking. However, it is not so easy to interpretate the estimates in his model when those are non-positive.

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Experiments on Stability of Armor Rocks on Rear Slope of Rubble Mound Structures under Wave Overtopping Condition with Rectangular Crest Element (월파조건에서 직사각형 상치콘크리트가 설치된 경사제 항내측 사면에 거치된 피복석의 안정성 실험)

  • Young-Taek Kim;Jong-In Lee
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.35 no.5
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    • pp.102-108
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    • 2023
  • In this study, hydraulic model tests were performed to investigate the stability of armor units at harbor side slope for rubble mound structures. The armor units on the rear slope were rocks. The Korean design standard for harbor and fishery port suggested the design figures that showed the ratio of the armor weight for each location of rubble mound structures and it could be known that the same weight ratio was needed to the sea side and rear side slope of rubble mound structures. The crest elements were commonly applied to the design process of rubble mound structures in Korea and the investigation of the effects of super structures would be needed. The damage rate (S =2) was applied and the stable wave height was measured for each test condition. The results were suggested as the armor weight ratio of the rear side slope(armor rock) to the sea side slope (tetrapod) in relation to the relative crest height.