• Title/Summary/Keyword: 산화작용

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Application of Electron Energy Loss Spectroscopy - Spectrum Imaging (EELS-SI) for Microbe-mineral Interaction (생지구화학적 광물변이작용 연구에서 전자에너지 손실 분광 분석 - 스펙트럼 영상법의 활용)

  • Yang, Kiho;Park, Hanbeom;Kim, Jinwook
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.1
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    • pp.63-69
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    • 2019
  • The oxidation states of structural Fe in minerals reflect the paleo-depositional redox conditions for the biologically or abiotically induced mineral formation. Particularly, nano-scale analysis using high-resolution transmission electron microscopy (HRTEM) and electron energy loss spectroscopy (EELS) is necessary to identify evidence for the microbial role in the biomineralization. HRTEM-EELS analysis of oxidation states of structural Fe and carbon bonding structure differentiate biological factors in mineralization by mapping the distribution of Fe(II)/Fe(III) and source of organic C. HRTEM-EELS technique provides geomicrobiologists with the direct nano-scale evidence of microbe-mineral interaction.

Effect of Herbicide Paraquat on NAD(H)-Redox-cycle (제초제 Paraquat의 NAD(H) 산화환원에 대한 영향)

  • Kim Mi-Lim;Choi Kyung-Ho
    • Journal of Life Science
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    • v.15 no.2 s.69
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    • pp.304-310
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    • 2005
  • This study was carried out to investigate the effect of herbicide paraquat (1,1-dimethyl-4,4-bipyridilium dichloride) on the electron transport system of the cell. When actively growing cells of bacteria were exposed to the 1.0 mM paraquat, more than $50\%$ of the cells were killed at 0 hour. But specific activities of superoxide dismutase (SOD) were not changed at 0 hour of paraquat treatment. Oxido-reductions of NAD (H) by the suspension of bacterial membtane, rat mithochondria and NAD-dependent dehydrogenase were accelerated by paraquat treatment.

Antioxidative Characteristics of Fermented Soybean Sauce on the Oxidation of Fatty Acid Mixture (지방산의 산화(酸化)에 대한 양조간장의 항산화(抗酸化) 특성)

  • Cheigh, Hong-Sik;Lee, Jeong-Soo;Moon, Gap-Soon;Park, Kun-Young
    • Korean Journal of Food Science and Technology
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    • v.22 no.3
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    • pp.332-336
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    • 1990
  • Antioxidative characteristics of freeze dried soybean sauce powder (SSP) on the oxidation reaction of linoleic acid mixture(LA) were evaluated by the determinations of peroxide formation, synergistic property, hydrogen donation and lipoxygenase activity. SSP was found to possess a considerable potentiality of antioxidant activity on the formation of hydroperoxides in the LA oxidation reaction system at $50^{\circ}C$ for 144hrs. This antioxidative effect was increased by the concentration from 0.02% to 0.5% of SSP in the reaction system. Under the condition of presence of ferric chloride (10 ppm) in the reaction system. appreciable effect of SSP on the synergistic antioxidation were observed. On the other hand, hydrogen donation property of SSP onto ${\alpha},\;{\alpha}'-diphenyl-{\beta}-picrylhydrazyl$ was found and inhibitory ability of SSP on LA oxidation was also shown in the reaction system of lipoxygenase-catalized oxidation.

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전통젓갈 유래 저분자 peptide의 항산화 작용과 항혈액응고 작용

  • 김동수;김영명;조진호;김우재
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2003.05a
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    • pp.119-120
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    • 2003
  • 식품에서 peptide는 영양, 맛 그리고 건강기능성에 영향을 미침으로써 식품에 매우 중요한 역할을 한다. 지질의 산화는 식품에 있어 색깔, 식품의 질, 향취 등을 나쁘게 하며 지질이 산화하게 되면 활성라디칼, 과산화물을 비롯하여 저분자 카르보널화합물 등 각종 활성화합물이 생성되는데 이들 활성화합물과 노화와는 밀접한 상관관계가 있다고 알려지고 있어 관심이 고조되고 있다. (중략)

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Antioxidative Characteristics of Plant Phenolic Compounds (식물 phenolic compounds의 항산화성)

  • 최홍식;이창용
    • Journal of Life Science
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    • v.3 no.1
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    • pp.9-17
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    • 1993
  • 식물 특히, 우리가 섭취하고 있는 식품에 널리 존재하고 있는 phenolic compounds는 simple phenols과 phenolic acids, hydroxycinnamic acid derivatives 그리고 flavonoids 등의 세가지 종류들로 나누고 있다. 이들 물질은 일정수준의 항산화성, 항돌연변이원성, 항암성을 지니고 있다. 본 총설에서는 식물성 phenolic compounds의 특성, 산화작용과 항산화작용, phenolic compounds의 항산화 메카니즘, 그리고 식물성 phenolic compounds들의 항산화능 등에 대하여 차례로 살핀다. 특히, 우리가 일상적으로 섭취하고 있는 식품에서의 이들 물질과 그들의 항산화성에 대한 최근 연구결과들을 중심으로 고찰한다.

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Antioxidant Effect of Soyasaponin on the Liposomal Phospholipid Membrane (인지질 Loposome 에 미치는 대두 Saponin의 항산화효과)

  • 신미옥;배송자;김남홍
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.4
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    • pp.381-385
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    • 1992
  • The effect of antioxidant activity of soyasaponin on the liposomal phospholipid membrane were investigated by spectrophotometry. The oxidation index and oxidation rate of ${\alpha}-tocopherol$ containing egg phosphatidylcholine (EPC) liposomes were markedly decreased in the presence of soyasaponin relative to those of purephospholipid liposmes. ${\alpha}-tocopherol$ containing liposomes delayed the oxidation of liposomes. Especially soyasaponin stimulated the antioxidant activity of ${\alpha}-tocopheroal$ in liposomes. These results indicates that soyasaponin in liposomes had some additive effect on antioxidant of ${\alpha}-tocopherol$ toward liposomes.

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THE EFFECT OF THE SAPONIN FRACTION OF PANAX GINSENG C.A. MEYER ON THE ANTIOXIDANT ACTIVITY OF TOCOPHEROL (한국산 인삼(Panax ginseng C. A, Meyer)의 사포닌 성분이 ${\alpha}-tocopherol$의 항산화작용에 미치는 영향)

  • Hong Sa-Duk;Koo Ja-Don;Park Gyeong Suk;Hong Jeong Tae
    • Proceedings of the Ginseng society Conference
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    • 1984.09a
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    • pp.113-118
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    • 1984
  • The effect of the saponin fraction extracted from Panax ginseng C.A. Meyer on the antioxidant activity of ${\alpha}-tocopherol$ was investigated in vitro as well as in vivo. Microsomal preparation of albino rat (Sprague-Dawley, 180-200g) was incubated in the mixture containing NADPH, $Fe^{3+},$ ATP, ${\alpha}-tocopherol$ with and/or without ginseng saponin fraction for 30 minutes and the malondialdehyde formed was assayed and found that the saponin fraction stimulated the antioxidant activity of ${\alpha}-tocopherol$ cooperatively. It was also realized that the cooperative stimulation of the antioxidant activity of ${\alpha}-tocopherol$ was most eminent when the concentration of the saponin fraction was around $10^{-5}\%$ in the reaction mixture. Alcoholic suspension of ${\alpha}-tocopherol$ with and/or without ginseng saponin fraction was administered orally to rats in which the lipid peroxidation was induced by ethanol administration and the lipid peroxide contents of the liver were assayed at certain periods of time after ${\alpha}-tocopherol$ administration in this animal. It was reported that the saponin fraction stimulated the absorption of ${\alpha}-tocopherol$ in rats and this was confirmed again in the present work. From the previous work and present experimental results, it seemed that the saponin fraction accelerated the absorption of ${\alpha}-tocopherol$ and therefore stimulated the antioxidant activity of ${\alpha}-tocopherol$ more effectively in the animal body.

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Effect of Interaction between Protocatechualdehyde Produced from Streptomyces lincolnensis M-20 and Copper Ions on Antioxidant and Pro-oxidant Activities (Streptomyces lincolnensis M-20 균주에서 생산된 Protocatechualdehyde와 구리 이온의 상호 작용이 항 산화 및 산화 촉진 활성에 미치는 영향)

  • Kim, Kyoung-Ja;Lee, Jae-Hun;Yang, Yong-Joon
    • Korean Journal of Microbiology
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    • v.50 no.1
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    • pp.22-26
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    • 2014
  • Protocatechualdehyde (PA) is phenolic compound having antioxidative and antitumor activities. PA was purified from supernatant of Streptomyces lincolnensis M-20. In the presence of copper ion, PA acted as pro-oxidant. The antioxidant activity was assessed with the 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay, and the pro-oxidant effect of PA on DNA damage as pBR322 plasmid DNA-cleaving agents in the presence of Cu(II) ions was investigated. The involvement of reactive oxygen species (ROS) in the DNA damage was confirmed by the inhibition of the DNA breakage by using glutathione (GSH), specific scavenger of ROS. When the increase in ROS reaches a certain level (the toxic threshold), it may trigger cell death. The formation of the PA/Cu(II) chelate complex was confirmed by reaction with ethylenediamine-tetraacetic acid (EDTA), a well-known chelating agent for metal ions, by using UV/Vis spectroscopic analysis.

Effect of Lipoxygenase, ${\beta}-Carotene$, ${\alpha}-Tocopherol$ and Water Activity on the Oxidation of Linoleic Acid in Starch-Solid Model System (고형상의 모델시스템에 있어서 리놀레산의 산화에 미치는 리폭시게나아제, 카로틴, 토코페롤 및 수분활성의 영향)

  • Kim, Hae-Gyoung;Cheigh, Hong-Sik;Song, Yeong-Ok
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.1
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    • pp.23-28
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    • 1992
  • Starch solid model system was employed to investigate the effect of lipoxygenase, ${\beta}-carotene$, ${\alpha}-tocopherol$ and water activity on the oxidation of linoleic acid. The rate of oxidation of linoleic acid by lipoxygenase was increased with the increase in water activity, Addition of ${\beta}-carotene$ and ${\alpha}-tocopherol$ to this system has been shown to inhibit the oxidation of linoleic acid and ${\alpha}-tocopherol$ was more effective antioxidant than ${\beta}-carotene$. However, an increase in the concentration of ${\beta}-carotene$ was found to have a strong antioxidant effect in the solid model system. And also the antioxidative action of ${\beta}-carotene$ was increased with increasing water activity in this system.

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