• Title/Summary/Keyword: 산증

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p-Toluenesulfonate Ester Derivatives of Benzendiol as Novel Acid Amplifiers (새로운 산증식제로 벤젠다이올의 p-톨루엔술폰산 에스터 유도체에 관한 연구)

  • Kang, Ji Eun;Hong, Kyoun Il;Lim, Kwon Taek;Jeong, Yeon Tae
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.660-663
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    • 2005
  • Aiming the development of novel acid amplifiers, 2-hydroxyphenyl-4-methylbenzenesulfonate (1), 3-hydroxyphenyl-4-methylbenzene sulfonate (2), 4-hydroxyphenyl-4-methylbenzenesulfonate (3) were synthesized as the aromatic acid amplifiers with good thermal stability. They were autocatalytically generated p-toluenesulfonic acid in the presence of small amount of acid evolved from a photoacid generator. These aromatic sulfonates showed excellent thermal stability in PtBMA film and were proven to be the first aromatic acid amplifier to act as a photosensitivity enhancer. When these compounds were coupled with a chemically amplified photoresist system, photosensitivity was enhanced up to 3~6 folds.

당뇨병 돋보기 II-당뇨병성 급성 합병증-케톤산증

  • Hong, Ji-Yeong
    • The Monthly Diabetes
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    • s.214
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    • pp.35-37
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    • 2007
  • 당뇨병환자에서 발생하는 가장 중요한 급성 합병증인 당뇨병성 케톤산증이나 고삼투성 비케톤성 혼수는 인슐린의 투여를 중단하였거나 감염, 외상 등의 신체적 손상이나 정신적 스트레스에 의하여 인슐린에 대한 길항 호르몬들이 과분비돼 발생한다. 일반적으로 당뇨병성 케톤산증은 인슐린 의존형 당뇨병환자 중 주로 젊은 층에서 자주 나타나며 병의 경과가 빠르게 진행되기 때문에 고삼투압 상태보다는 케톤산혈증이 주요 문제가 된다. 반면에 고삼투압성 비케톤성 혼수는 인슐린 비의존형 당뇨병환자 중 주로 노인층에서 호발하며 병의 경과가 서서히 진행하기 때문에 심한 고혈당 상태로 인한 고삼투압 상태가 주요 문제가 된다. 이와같은 당뇨병의 급성 대사성 합병증들은 치료가 지연되거나 적절한 치료가 행해지지 못했을 때는 예후가 극히 불량하며 사망률 또한 높은 것으로 보고되고 있다. 이에 급성 대사성 합병증 중 당뇨병성 케톤산증의 병인, 진단 및 치료 등을 알아보기로 한다.

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A New Evaluation Method of UV Curing Process by Using Electrical Properties (전기적 특성을 이용한 UV 경화 프로세스에 대한 새로운 평가방법)

  • Lee, Mun-Hag;Kim, Sung-Bin;Son, Se-Mo;Cheon, Jae-Kee
    • Korean Chemical Engineering Research
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    • v.43 no.3
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    • pp.393-400
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    • 2005
  • A novel evaluation method was investigated for measuring the ability of acid amplification of acid amplifier. The method was based on the measurement of conductivity change by the acid generation according to UV radiation. It was found that the decrease of conductivity was caused by photopolymerization of epoxy monomer during UV curing process of ink film and by the rate of UV curing. In this paper, the novel acid amplifiers were synthesized and measured thermal stability by means of DSC. It was found that mono-type acid amplifiers were more stable than di-type. It was possible to make the dynamical evaluation of the curing rate of UV curable ink in curing process by this method.

Effect of Acid Amplifier, 4-Hydroxy-4'-p-tosyloxy Isopropylidene Dicyclohexane, on the Kind of Resin in Chemically Amplified Photoresist (화학 증폭형 포토레지스트 수지의 종류에 따른 산증식제 4-Hydroxy-4'-p-tosyloxy Isopropylidene Dicyclohexane의 효과)

  • Kang, Ji Eun;Lim, Kwon Taek;Jeong, Yeon Tae
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.262-266
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    • 2005
  • We compared the effects of a representative aliphatic acid amplifier, 4-hydroxy-4'-p-tosyloxy isopropylidene dicyclohexane, doped in poly[tert-butyl methacrylate] (pTBMA), poly[tetrahydropyranyl methacrylate] (pTHPMA) or poly[tert-butoxycarbonyloxystyrene] (pTBOCST) resin film as acid labile polymer in view of thermal stability and photosensitivity enhancement. The acid amplifier was stable up to 20 min in pTBMA and pTBOCST film and up to 5 min in pTHPMA film at $120^{\circ}C$. pTBMA and pTHPMA films doped with the acid amplifier showed four times and two times higher photosensitivity, respectively. But pTBOCST showed negligible photosensitivity enhancement. Photosensitivity enhancement and thermal stability were found to be affected by the resin.

Determination of Sulfur Dioxide in Pickles by Acid Distillation-HPLC Method and Monnier Williams Modified Method (산증류-HPLC법과 모니어윌리암스변법을 이용한 절임류중의 이산화황 함량 분석)

  • Jung, So-Young;Kim, Il-Young;Kim, Sung-Dan;Jang, Mi-Ra;Chang, Min-Su;Han, Ki-Young
    • Korean Journal of Food Science and Technology
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    • v.35 no.6
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    • pp.1028-1032
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    • 2003
  • To assess accurate methods for measuring sulfur dioxide residue in pickles, the acid distillation HPLC-UV method and Monnier Willams modified method were examined. By the acid distillation HPLC-UV method, sulfites released from pickles by acid distillation were absorbed in 1% triethanolamine solution and detected as sulfite ion by HPLC with UV monitoring at 240nm. An anion exchange column was employed with 1.8mM $Ma_2CO_3-1.7mM\;NaHCO_3$ solution as a mobile phase, $84.0{\sim}91.7%$ of sulfite added to pickled radish were recovered. Total sulfite levels from 48 kinds of pickles analyzed by acid distillation HPLC-UV was compared with those analyzed by the Monnier Williams modified method. The Monnier Williams modified method showed higher levels of sulfur dioxide than the acid distillation HPLC-UV method due to the presence of volatile acids in pickles. The concentration of sulfur dioxide was in the range of $N.D{\sim}173.05ppm$ in pickled radish and over 30ppm of sulfur dioxide from 3 samples by the acid distillation-HPLC-UV method.

원로와의 대담-치의학역사의 산증인 이춘근 박사

  • Lee, Gwang-Yeong
    • The Science & Technology
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    • v.28 no.12 s.319
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    • pp.82-84
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    • 1995
  • 우리나라 치의학 역사의 산증인이며 구강외과학의 개척자인 이춘근 박사는 새벽 4시면 어김없이 일어나 집 가까이에 있는 교회에서 5시 새벽기도를 시작으로 하루의 일과를 연다. 올해 희수를 맞은 이박사는 1918년 평북 구성군 방현면 남시에서 태어났다. 이박사는 1983년 2월 말 정년퇴직후 한남동에 치과의원을 개원, 아침 10시부터 환자를 돌보고 있다. 서울대 명예교수로 요즘도 매 금요일 서울대 치대에 나가 대학원 학생들의 세미나를 주재한다.

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