• Title/Summary/Keyword: 산소 요구도

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비활성 가스제너레이터 성능분석

  • 김수용
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1999.04a
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    • pp.14-14
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    • 1999
  • 비활성 가스제너레이터는 가스터빈 추진기관 및 기타 열기관을 이용하여 연소가 되지 않는 저온의 공기를 생산하는 기계장치를 말하며 이러한 저온의 비활성 기체를 화재 지역에 분사하는 경우 기존의 소방수를 이용한 화재 진압방식보다 매우 효율적으로 화재진압에 사용되어 질 수 있다. 일반적으로 민항기 등의 가스터빈 추진 기관에서 배기되는 기체내에는 터빈입구온도(TIT : Turbine Inlet Temperature)및 초과공기지수(Excess Air Coefficient)에 따라 다르게 나타나지만 TIT가 1500$^{\circ}$K인 경우 약 13-14%정도의 산소가 잔존하는 것으로 알려져 있다. 따라서 본 연구에서는 가스터빈 및 열교환 시스템 그리고 터빈 1단 등의 시스템 조합율을 통하여 대기 중의 기체의 온도를 영하 2$0^{\circ}C$ 및 산소함유량을 약 5%수준까지 낮춤으로서 이를 대형 화재 진압에 사용하기 위한 연구이다. 비활성 가스제너레이터에 사용하는 연료로는 Kerosene 및 CNG(Compressed Natural Gas)등이 사용될 수 있으며, 유량이 8.1kg/sec인 터보축 가스터빈 엔진을 사용하는 경우 18750㎥ 부피의 비활성기체를 생산하는데 Kerosene 연료가 약 1톤(200$ 이하)이 필요한 것으로 계산되며 이에 소요되는 시간도 약 52분에 지나지 않는 것으로 계산되었다. 만일 50kg/sec의 보다 큰 가스터빈 엔진을 사용하는 경우 약 9분 정도가 필요한 것으로 계산되었다. 사용되는 가스터빈은 압축비가 15, 열교환기의 효율이 $\varepsilon$=0. 그리고 최종 터빈 1단의 팽창비가 1.25가 적합한 것으로 계산된다. 연구 분석 결과 기술적 문제점으로는 배기 가스온도가 낮은데 따른 출구 부분의 Bearing, Sealing이 문제가 될 수 있다고 판단되며 배기 가스 자체에 대기 공기중에 함유되어 있던 습기가 얼어붙는(Icing화) 문제가 발생하기 때문에 배기가스의 Icing을 방지하기 위하여 압축기 끝단에서 공기를 추출하여 배기부분에 송출할 필요성이 있는 것으로 판단되었다. 출구가스의 기체 유동속도가 매우 빠르므로 (100-l10m.sec) 이를 완화하기 위한 디퓨저의 설계가 요구된다고 판단된다. 또 연소기 후방에 물을 주입하는 경우 열교환기 및 기타 부분품에 발생할 수 있는 부식 및 열교환 효율 저하도 간과할 수 없는 문제로 파악되었다. 이러한 기술적 문제가 적절히 해결되는 경우 비활성 가스 제너레이터는 민수용으로는 대형 빌딩, 산림, 유조선 등의 화재에 매우 적절히 사용되어 질 수 있을 뿐 아니라 군사적으로도 군사작전 중 및 공군 기지의 화재 그리고 지하벙커에 설치되어 있는 고급 첨단 군사 장비 등의 화재 뿐 아니라 대간첩작전 등에 효과적으로 활용될 수 있을 것으로 판단된다.

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Electric-field Assisted Photochemical Metal Organic Deposition for Forming-less Resistive Switching Device (전기장 광화학 증착법에 의한 직접패턴 비정질 FeOx 박막의 제조 및 저항변화 특성)

  • Kim, Su-Min;Lee, Hong-Sub
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.77-81
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    • 2020
  • Resistive RAM (ReRAM) is a strong candidate for the next-generation nonvolatile memories which use the resistive switching characteristic of transition metal oxides. The resistive switching behaviors originate from the redistribution of oxygen vacancies inside of the oxide film by applied programming voltage. Therefore, controlling the oxygen vacancy inside transition metal oxide film is most important to obtain and control the resistive switching characteristic. In this study, we introduced an applying electric field into photochemical metal-organic deposition (PMOD) process to control the oxidation state of metal oxide thin film during the photochemical reaction by UV exposure. As a result, the surface oxidation state of FeOx film could be successfully controlled by the electric field-assisted PMOD (EFAPMOD), and the controlled oxidation states were confirmed by x-ray photoelectron spectroscopy (XPS) I-V characteristic. And the resistive switching characteristics with the oxidation-state of the surface region could be controlled effectively by adjusting an electric field during EFAPMOD process.

Prediction in Dissolved Oxygen Concentration and Occurrence of Hypoxia Water Mass in Jinhae Bay Based on Machine Learning Model (기계학습 모형 기반 진해만 용존산소농도 및 빈산소수괴 발생 예측)

  • Park, Seongsik;Kim, Byeong Kuk;Kim, Kyunghoi
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.34 no.3
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    • pp.47-57
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    • 2022
  • We carried out studies on prediction in concentration of dissolved oxygen (DO) with LSTM model and prediction in occurrence of hypoxia water mass (HWM) with decision tree. As results of study on prediction in DO concentration, a large number of Hidden node caused high complexity of model and required enough Epoch. And it was high accuracy in long Sequence length as prediction time step increased. The results of prediction in occurrence of HWM showed that the accuracy of nonHWM case was 66.1% in 30 day prediction, it was higher than 37.5% of HWM case. The reason is that the decision tree might overestimate DO concentration.

Environmental Pollutants in Streams of Andong District and Insect Immune Biomarker (안동지역 하천의 환경오염물질과 곤충면역 생체지표 분석)

  • Ryoo Keon Sang;Ko Seong-Oon;Cho Sunghwan;Lee Hwasung;Kim Yonggyun
    • Korean journal of applied entomology
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    • v.44 no.2
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    • pp.97-108
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    • 2005
  • Samples of water, soil, and sediment were taken from 10 streams near Andong, Korea in May 2004. To assess the degree of environmental pollution of each stream, chemical pollutants such as total notrogen (T-N), total phosphorus (T-P), chemical oxygen demand (COD), heavy metals, organophosphorus pesticides, organochlorine pesticides, and dioxin-like PCB congeners were analyzed by standard process tests or U.S. EPA methods. In addition, biomarkers originated from insect immune systems of beet armyworm, Spodoptera exigua, were used to analysis of the environmental samples. Except Waya-chun stream showing T-N content of 9.12 mg/L, most streams were contaminated with relatively low levels of overall pollutants in terms of T-N, T-P, and COD, compared to their acceptable environmental levels designated by the Ministry of Environment. Contents of Pb and Cd in samples of each stream were much lower than environmentally permissible levels. However, several times higherconcentrations of Pb and Cd were found in locations at Mi-chun, Kilan-chun, and Hyunha-chun streams, in comparison with other streams. Diazinon, parathion, and phenthoate compounds among organophosphorus pesticides were detected as concentrations of 0.19, 0.40, and $1.13\;{\mu}g/g$, respectively, from soil sample collected in the vicinity of Mi-chun stream. On the other hand, 16 organochlorine pesticides and 12 dioxin-like PCB congeners, known as endocrine disrupting chemicals, selected in this study were not found above the limit of detection. Biomarker analyses using insect immune responses indicated that Waya-chun stream was suspected as exposure to environmental pollutants. Limitation and compensation of both environmental analysis techniques are discussed.

Distribution characteristics of chemical oxygen demand and Escherichia coli based on pollutant sources at Gwangyang Bay of South Sea in Korea (남해 광양만에서 오염원에 따른 화학적 산소요구량과 대장균의 해역별 분포특성)

  • Baek, SeungHo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3279-3285
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    • 2014
  • This study aimed to understand seasonal and geographical characteristic of chlorophyll-${\alpha}$ (chl-${\alpha}$), COD (chemical oxygen demand) and Escherichia coli at Gwangyang Bay during the period from February 2010 to November 2012. The bay is divided into three different zones based on the pollutant levels and geographical characteristics. During the study periods, water temperature, salinity, Chl. ${\alpha}$, and chemical oxygen demand (COD) varied in the range of $4.68-28.63^{\circ}C$, 1.94-33.84 psu, 0.31-35.10 ${\mu}gL^{-1}$, and 0.70-13.35 $mgL^{-1}$, respectively. Total chl-a concentration were high at the zone I, which can be characterized as a semi-enclosed eutrophic area, and it were low at the zone III, which is influenced by low nutrients of surface warm water current from offshore of the bay. The high concentration of COD was observed at inner bay during the four seasons and the water quality level was kept to be bad condition during spring season at the zone II, which is influenced by Seomjin River water. The highest colony form of E. coli was recorded to be 3550 $cfuL^{-1}$ during summer at station 1 (zone I), whereas it was relatively kept low level during all seasons at the zone III. As a result, the E. coli was correlated with water temperature (r=0.31 p<0.05) and salinity (r=-0.55 p<0.05), implying that those parameters have play an important crucial role in proliferation of E. coli. Consequently, our results indicated that the E. coli can be significantly promoted within pollutant sources including the high nutrients supplied by rive discharge during spring and summer rainy seasons in semi-enclosed area of Gwangyang Bay.

Evaluation of Water Quality Characteristics in the Nakdong River using Statistical Analysis (통계분석을 이용한 낙동강유역의 수질변화 특성 조사)

  • Choi, Kil Yong;Im, Toe Hyo;Lee, Jae Woon;Cheon, Se Uk
    • Journal of Korea Water Resources Association
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    • v.45 no.11
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    • pp.1157-1168
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    • 2012
  • In this study, we assess changes in water quality trends over time based on certain control measurements in order to identify and analyze the cause of the trend in water quality. The current water pollution in the Nakdong River was analyzed, as it suggests that the significant changes in water quality have occurred in between 2006 and 2010. Based on monthly average data, we have examined for trends of the Nakdong River watershed in water temperature, Biological Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Total Nitrogen (TN), and Total Phosphorus (TP). Moreover, we have investigated seasonal variation of water quality of sites within the Nakdong River Basin by implementing further analyses such as, Correlation Coefficient, Regression Analysis, Hierarchical Clustering Method, and Time Series Analysis on SPSS. Geology and topography of the watershed, controlled by various conditions such as, climate, vegetation, topography, soil, and rain medium, have been affected by the non-homogeneity. Our study suggests that such variables could possibly cause eutrophication problems in the river. One possible way to overcome this particular problem is to lay up a ship on the river by increasing the nasal flow measurement of the Nakdong River during rainy season. Moreover, the water management requires arranging the measurement of the flow in order to secure the river while the numerous construction projects need to be continuously observed. However, the water is not flowing tributary of the reason for the timing to be flowing in a natural state of river water and industrial water intake because agriculture. Therefore, ongoing research is needed in addition to configuration of all observations.

Ship Sewage Treatment Using Fixed Media Method (고정식 메디아법을 이용한 선박의 오폐수 처리)

  • Han, Sang-Hwa;Lee, Dea-Ho;Nyung, Bu-Nyung;Bae, Sang-Bum;Yoon, Jong-Mun
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.2
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    • pp.99-104
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    • 2010
  • The purpose of this study is to develop Sewage Treatment Plant that treat sewage which occurred in ship using fixed media method and to consider applicable to the Pilot Scale device of the STP regulations in MLTM(Ministry of Land, Transport and Maritime Affairs) and MEPC(Marine Environment Protection Committee). In test results, pH geometric mean was 7.68, $BOD_5$(Biochemical Oxygen Demand) geometric mean was 7.28 mg/l, $COD_{cr}$(Chemical Oxygen Demand) geometric mean was 48.39 mg/l, TSS(Total Suspended Solid) geometric mean was 18.00/l, Residual chlorine geometric mean was 0.19 mg/l, and E. coli geometric mean was 1CFU/100 ml. In addition, about 97.4% of $BOD_5$ was reduced, the $COD_{cr}$ reduction averaged 96.4%and the TSS reduction averaged 97.6%. STP have been determined by the MLTM and MEPC regulation of the marine pollution prevention equipment for performance testing product.

Simple Material Budget Modeling for a River-Type Reservoir (하천형 저수지의 단순 물질수지 모델링)

  • Yoon, Seong-Kyu;Kong, Dong-Soo;Bae, Wookeun
    • Journal of Korean Society on Water Environment
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    • v.26 no.3
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    • pp.420-431
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    • 2010
  • Simple material budget models were developed to predict the dry season water quality for a river-type reservoir in Paldang, Republic of Korea. Of specific interest were the total phosphorus (TP), chlorophyll ${\alpha}$ (Chl. ${\alpha}$), 5-day biochemical oxygen demand (BOD), and chemical oxygen demand (COD). The models fit quite well with field data collected for 20 years and have enabled the identification of the origins of organic materials in the reservoir. The critical hydraulic load that determines the usability of phosphorus for algal production appeared to be about $1.5m\;d^{-1}$. When a hydraulic load was smaller than the critical value, the concentrations of $Chl.{\alpha}$, COD, and BOD in the reservoir water became sensitive to internal algal reactions such as growth, degradation, and settling. In spite of the recent intensive efforts for organic pollutant removal from major point sources by central and local governments, the water quality in the reservoir had not been improved. Instead, the concentration of COD increased. The model analysis indicated that this finding could be attributed to the continuing increase of the algal production in the reservoir and the allochthonous load from non-point sources. In particular, the concentrations of COD and BOD of algal origin during 2000~2007, each of which is comprised of approximately one half of the total, were approximately 2.5 times higher than those observed during 1988~1994 and approximately 1.3 times higher than those between 1995~1999. The results of this study suggested that it is necessary to reduce the algal bloom so as to improve the water quality of the reservoir.

Change of Solubilization Characteristics of Rice Straw by Different Pre-treatments (전처리 방법에 따른 볏짚의 가용화 특성 변화)

  • Hong, Seung-Gil;Shin, JoungDu;Heo, Jeong-Wook;Park, Woo-Kyun;Kwon, Soon-Ik;Park, Noh-Back;Shin, Hyun-Seon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.20 no.1
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    • pp.71-77
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    • 2012
  • In order to find a feasibility of applying an agricultural biomass to the anaerobic digestion system, the effects of pre-treatment of rice straw was investigated by different sizes,temperatures, ultrasonic frequencies, and with/without NaOH treatment on the change of soluble organic matter, which is generated most dominantly in Korea. It was observed that SCOD(soluble chemical oxygen demand) as the index for the decomposition of rice straw increased with the smaller particle size, higher reaction temperature and alkali treatment. With treatment of 5% NaOH, it was shown that the highest concentrations of SCOD were observed at 9,000 mg $L^{-1}$ and 6,000mg $L^{-1}$ at $35^{\circ}C$ and $55^{\circ}C$, respectively. Agitating with ultrasonic irradiation could be enhanced SCOD of rice straw less than 3 cm with 40 kHz of ultrasound. Optimal RPM in this study was at 150 rpm regardless of reaction temperatures.

Study on Reducing Methods of Natural Food-borne Pathogenic Microorganisms Originated from Saengshik (생식 중 자연환경유래 위해미생물 저감화 방법에 관한 연구)

  • Chang, Tae-Eun;Han, Jeong-Su;Song, Ok-Ja;Chung, Dong-Hwa;Shin, Il-Shik
    • Korean Journal of Food Science and Technology
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    • v.36 no.6
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    • pp.1020-1025
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    • 2004
  • In previous paper, contaminations of food-borne pathogenic bacteria of Saengshik was found to occur during processing, because detection rates of food-borne pathogenic bacteria in final products were higher than those of raw materials. In this study, methods to reduce food-borne pathogenic bacteria and improved manufacturing process were developed for microbial safety of Saengshik. Food-borne pathogenic bacteria in raw materials were reduced to about 0.5-2.0 log cfu/g when seven kinds of raw materials were washed with electrolyzed water and ozonated water, but food-borne pathogenic bacteria could not be removed completely. After improvement of manufacturing process, numbers of food-borne pathogenic bacteria were same or decreased to levels of raw materials. Gaseous ozone and Biocon could control air-borne bacteria under $1{\times}10^1$ cfu/1000 L of air in pulverization and mixing rooms.