• Title/Summary/Keyword: 사진공정

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Cracker Cell을 이용한 $CuInSe_2$ 박막의 셀렌화 공정 연구

  • Go, Hang-Ju;Kim, Hyo-Jin;Han, Myeong-Su;Kim, Dae-Yeong;Park, Gwang-Hun;Park, Jae-Hyeong;Jo, Yu-Seok;Ha, Jun-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.163-163
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    • 2011
  • 셀레늄(Selenium: Se) cracker cell을 이용하여 셀렌화한 $CuInSe_2$ (CIS)박막에 대해 연구한 결과를 발표하고자 한다. 화석연료의 과도한 사용으로 지구온난화라는 환경문제가 대두되면서 영구적이고 무상의 태양에너지 이용에 대한 필요성이 점차 높아지고 있다. 빛에너지를 전기에너지로 변화시키기 위한 태양전지는 재료에 따라 다양하게 개발되고 있으며 그 중 가장 주목을 받고 있는 것 중의 하나가 $CuInSe_2$을 광흡수층으로 하는 CIS 박막 태양전지이다. CIS 박막은 태양전지의 광흡수층으로 사용되는데 직접천이형 밴드구조를 가지고 있고, 약 $10^5$ $cm^{-1}$의 높은 광흡수계수를 가지고 있어 태양전지 광흡수층으로 적합한 물질로 각광받고 있다. CIS는 에너지 밴드갭이 ~1 eV로 실리콘과 유사한 밴드갭을 가지고 있으나 이는 Ga, Al을 In 대신 치환함으로 조절할 할 수 있다. 무엇보다도 sodalime 유리와 같은 저가의 기판위에 스퍼터와 같은 장치로 대면적 CIS 박막태양전지를 만들 수 있다는 것이 산업적인 면에서 장점으로 알려져 있다. 본 연구에서는 sodalime 유리기판 위에 스퍼터 방법으로 CIS 박막을 증착하고 Se cracker cell로 셀렌화하여 CIS 박막을 제조하는 것을 조사연구 하였다. 스퍼터를 이용하여 유리기판위에 Mo (Molybdenum)을 증착하고 그 위에 Cu-In-Se박막을 증착하였다. Cu-In-Se/Mo/유리기판 시료는 동일 챔버에서 Se cracker cell을 이용하여 셀렌화 처리 하였다. 물성비교를 위하여 Knudson-cell을 이용한 셀렌화도 시행하였다. Se cracker cell은 고체 Se를 가열하는 부분(R-zone)과 Se flux를 cracking 하는 부분(C-zone)으로 나누어져 있으며 C-zone은 700$^{\circ}C$로 고정하였다. 셀렌화 기판 온도는 425$^{\circ}C$로 고정하였고 Se cracker 온도는 330~375$^{\circ}C$까지 변화시켜 가며 CIS 박막을 제조하였다. 제조된 CIS 박막의 물성 조사는 사진, 현미경, SEM, EDX, XRD, Hall effects를 이용하였다. Se cracker cell로 셀렌화한 CIS 박막은 island 구조를 하고 있음을 알 수 있었다. CIS 박막의 island의 크기와 모양은 셀렌화시 R-zone 온도(Cu-In-Se 박막에 조사되는 셀레늄의 량)에 큰 영향을 받았다. 셀렌화시 셀레늄량이 적을 때는 island가 커지며 불균일해지고 셀레늄량이 많을 때 island가 작고 균일해지는 경향을 SEM을 통해 관찰할 수 있었다. X-ray 회절을 통해 셀레늄량이 적을 경우 CIS 결정이외의 결정이 박막내에 형성됨을 알 수 있었다. 학술회의에서 Se cracker cell을 이용한 셀렌화에 관한 보다 깊은 연구결과를 발표하고자 한다.

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A Study on the Warpage of Injection Molded Parts for the rapid Cooling and Heating Device (급속냉각·가열장치에 따른 사출성형품의 휨에 관한 연구)

  • Lee, Min;Kim, Tae-Wan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.8
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    • pp.5074-5081
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    • 2015
  • A method for improving the warpage of the plastic part is a method of removing residual stress of the plastic product. that a non-uniform cooling are appeared in the injection molding process make uniform cooling. this study was developed the Rapid heating and cooling device used peltier module for uniform cooling. Make the Rapid heating and cooling device(RCHD), for Traditional water cooling device(TWCD) method and the Rapid heating and cooling method warpage were compared and were analyzed and the materials used amorphous ABS polymer. various warpage were compared for the process parameters such as packing pressure, packing time, resin temperature, mold temperature, In the amorphous ABS polymer, TWCD method has higher warpage than RCHD method and show the result to be a bit more uniform cooling. The distribution state of the ABS polymer was confirmed Through the Scanning electron microscope. In the TWCD method the distribution state of the polymer be densely distributed, and RCHS method be distributed wider than TWCD method. this is that injection molded parts be seen that cooling was made uniformly, As the temperature of the mold is gradually progress, Particles of the polymer is increased this is that internal stress was reduced.

Quality changes in the lotus root frozen under different conditions (냉동조건에 따른 연근의 품질 변화)

  • Park, Seung-Jong;Song, Kyung Bin
    • Food Science and Preservation
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    • v.22 no.1
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    • pp.44-50
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    • 2015
  • This study was performed to optimize the preparation of frozen lotus roots. Prior to freezing, an optimal blanching condition at $100^{\circ}C$ for 5 min was established, based on the microbial growth, texture, total phenolic content (TPC), and sensory evaluation results. The blanched samples were then frozen under various freezing conditions ($-20^{\circ}C$ in a freezer for 2 hr, $-70^{\circ}C$ in a gas nitrogen convection chamber for 7 min, and $-196^{\circ}C$ in liquid nitrogen for 20 sec), and their qualities after thawing were determined. The scanning electron microscopic analysis indicated that the microstructure of the sample frozen at $-70^{\circ}C$ was similar to that of the control sample, compared with the other freezing conditions (-20 and $-196^{\circ}C$). The antioxidant activities of the frozen samples decreased compared to those of the control, but there was no significant (p<0.05) difference among the treatments. In terms of TPC, the samples frozen at -70 and $-196^{\circ}C$ had significantly (p<0.05) higher values than the sample frozen at $-20^{\circ}C$. In addition, the drip loss of the sample frozen at $-20^{\circ}C$ was higher than those of the other frozen samples. These results suggest that freezing at $-70^{\circ}C$ in a gas nitrogen convection chamber can be an optimal freezing method of producing high-quality frozen lotus roots.

The Effects on The Glass Processing by Alumina Addition in Soda Lime Glass (소다석회유리에서 Alumina첨가제에 따른 제병 공정의 영향)

  • Choi, Young-June;Kim, Jong-Ock;Kim, Taik-Nam
    • The Journal of Engineering Research
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    • v.4 no.1
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    • pp.69-85
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    • 2002
  • The chemical composition of bottle glass is consisted of Na2O-CaO-SiO2. However the cullet is mornally used in order to decrease the melting tsmperature. This induce the productivity of bottle and decreases the cost. The addition of plate glass decreases the Al2O3 content and in fluence the stone phenomenon and devitification in botle glass. Tus the Feldspar is added in order to increase the Al2O3 content when plate cullet was added in melting. The Tridymite crystal was observed over 7.5% Al2O3 contents, which shown as white crystal in appearance. It is Supposed that the Wollastonite Would be occurred in more over 7.5% Al2O3. This fad id well consised With the Litertctures.

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Analysis of Elastic Constants in SiC Particulate Reinforced Al Matrix Composites by Resonant Ultrasound Spectroscopy (초음파 공명 분광법(RUS)을 이용한 SiC 입자강화 Al 기지복합재료의 탄성계수 해석)

  • Jung, Hyun-Kyu;Cheong, Yong-Moo;Joo, Young-Sang;Hong, Soon-Hyung
    • Journal of the Korean Society for Nondestructive Testing
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    • v.19 no.3
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    • pp.180-188
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    • 1999
  • The dynamic elastic properties of metal matrix composites were investigated by resonant ultrasound spectroscopy(RUS). The composites used in this study consisted of 2124 aluminum alloy reinforced with different concentrations of SiC particles. RUS can determine the nine independent elastic stiffness($C_{ij}$) for the orthorhombic symmetry on a small specimen simultaneously. The elastic constants were determined as a function of the volume fraction. A concept of effective aspect ratio. which combine the aspect ratio and the orientation of reinforcement. was used to calculate the initial moduli from Mori-Tanaka theory for the input of RUS minimization code. Young's moduli can be obtained from the measured stiffnesses. The results show that the elastic stiffness increases with increment of the particle content. The behavior of elastic stiffness indicates that the particle redistribution induced by the extrusion process enlarges the transversely isotropic symmetry as the fraction of reinforced particles increase. This relationship could be used for determination of the volume fractions of reinforcement as a potential tool of nondestructive material characterization.

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Revisiting of ancient tombs in Neungsan-ri, Buyeo (부여(扶餘) 능산리고분군(陵山里古墳群) 성격(性格)에 대한 재고(再考))

  • Kim, Gyu-un;Yang, Suk-ja
    • Korean Journal of Heritage: History & Science
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    • v.49 no.2
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    • pp.104-121
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    • 2016
  • Royal tombs in Neungsan-ri had been studied several times during the Japanese Colonial era. But, conceiving the general complexion of them is difficult for lack of data and analysis of previous studies are still insufficient. Thus, necessity of new approach and understanding in Royal tombs in Neungsan-ri are emphasized by the reviewing existing studies and conservation history. The Serial numbers of the Royal tombs in Neungsan-ri has been registered arbitrarily without clear guidelines from Japanese Colonial era until present time. It means previous studies were devoid of consideration for serial number changes. And, research has shown that Royal tombs in Neungsan-ri counts at least twenty, taking No.8 tomb of recent study into consideration. Moreover, in case of eastern tombs it needs changes in the existing perception that Royal tombs in Neungsan-ri consist of only six-tombs because there was no difference between eastern tombs and central sixtombs considering the burial chamber and lacquered wooden(koyamaki) Coffin. Ultimately, current state of Royal tombs in Neungsan-ri doesn't have authenticity because they had been found and regulated in the Japanese Colonial era. Consequently, it is required to overall study into entrance to burial chamber and covered burial stone marker and exaggerated mounds, ignored another tombs other than six-tombs in the center.

A Study on Attitudes Toward Ethical Issues in Artificial Intelligence Art (인공지능 예술 윤리 문제에 대한 인식 및 태도 연구)

  • Eunjoon Lee
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.6
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    • pp.19-28
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    • 2024
  • The study explores the ethical issues surrounding AI-generated art, which is rapidly becoming more prevalent across various fields. AI technology has revolutionized art creation and management, but this rise has sparked debates on the creativity, ethics, and social responsibility of AI-generated artworks. The study aims to examine and analyze attitudes toward these ethical concerns, focusing on the recognition of AI art's creativity, its social responsibility, and ways to address ethical issues in its creation process. It emphasizes the need to recognize AI's unique creativity while establishing clear ethical guidelines to manage these new forms of art. Key findings indicate that while AI democratizes art by enabling more people to engage in creation, it also risks diluting the unique creativity of human artists and impacting their market positions. The research highlights the necessity of indicating sources and securing permissions to avoid copyright infringements and calls for automated copyright management systems and ethical standards. Moreover, it underscores the importance of ensuring AI-generated art does not reinforce social biases and is accessible and fairly distributed. The study concludes that ongoing research and policy development are essential to ensure AI art positively impacts society and culture, fostering innovative and creative expressions responsibly.

A Study on the Adolescent Sibling Relationship through Photovoice (포토보이스를 통해 본 청소년기 형제자매관계에 관한 연구)

  • Kim, Jiseul;Jun, Mikyung
    • Journal of Korean Home Economics Education Association
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    • v.36 no.2
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    • pp.15-31
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    • 2024
  • This study employs photovoice research methodology to investigate adolescents' experiences in sibling relationships and to analyze the impact of sibling interactions on their development and growth. The participants comprised eight high school students with one sibling (four males and four females) residing in the Incheon region. The research process encompassed several stages: participant recruitment, orientation, photovoice activity (focus group interviews), data analysis, and conclusion derivation. During the photovoice activity, participants engaged in a narrative process of photographing, interpreting, and discussing their experiences. The narratives were categorized into four primary themes: structure and environment, emotional interactions, roles, and parental subsystems. The conclusions drawn from the study are as follows: First, the similarity formed in sibling relationships during adolescence contributes to psychological stability. Second, roles and expectations based on birth order can cause stress for adolescents, indicating the need for equitable role adjustments within the family. Third, conflict in sibling relationships is crucial for enhancing problem-solving and social relationship skills. Lastly, consistent parenting attitudes significantly affect the emotional well-being of siblings. This study emphasizes the significance of fostering a deeper understanding of human development and family relationships through an exploration of adolescent sibling dynamics within home economics education.

A Study on the Fouling of Ultrafiltration Membranes Used in the Treatment of an Acidic Solution in a Circular Cross-flow Filtration Bench (순환식 막 모듈 여과장치를 이용한 산성용액의 수처리 공정 시 발생하는 한외여과막 오염에 관한 연구)

  • Kim, Nam-Joon;Choi, Chang-Min;Choi, Yong-Hun;Lee, Jun-Ho;Kim, Hwan-Jin;Park, Byung-Jae;Joo, Young-Kil;Kang, Jin-Seok;Paik, Youn-Kee
    • Membrane Journal
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    • v.19 no.3
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    • pp.252-260
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    • 2009
  • The effects of the treatment of an acidic solution at pH 2 on polyacrylonitrile ultrafiltration (UF) membranes were investigated using a circular cross-flow filtration bench with a membrane module. A substantial reduction in the membrane permeability was observed after 80 hours' treatment of the acidic solution. In addition, the analyses of the sample solutions by ultraviolet/visible absorption spectroscopy and gas chromatography/mass spectrometry (GC/MS), which were taken from the feed tank as a function of the treatment time, showed that a new organic compound was produced in the course of the treatment. From a thorough search of the mass spectral library we presumed the new compound to be 1,6-dioxacyclododecane-7,12-dione (DCD), one of the well-known additives for polyurethane. Based on further experimental results, including the scanning electron microscope (SEM) images and the solid-state NMR spectra of the membranes used for the treatment of the acidic solution, we suggested that the decrease of the permeate flux resulted not from the deformation of the membranes, but from the fouling by DCD eluted from the polyurethane tubes in the filtration bench during the treatment. Those results imply that the reactivity to an acidic solution of the parts comprising the filtration bench is as important as that of the membranes themselves for effective treatments of acidic solutions, for efficient chemical cleaning by strong acids, and also in determining the pH limit of the solutions that can be treated by the membranes.

Dry Etching of GaAs and AlGaAs in Diffuion Pump-Based Capacitively Coupled BCl3 Plasmas (확산펌프 기반의 BCl3 축전결합 플라즈마를 이용한 GaAs와 AlGaAs의 건식 식각)

  • Lee, S.H.;Park, J.H.;Noh, H.S.;Choi, K.H.;Song, H.J.;Cho, G.S.;Lee, J.W.
    • Journal of the Korean Vacuum Society
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    • v.18 no.4
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    • pp.288-295
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    • 2009
  • We report the etch characteristics of GaAs and AlGaAs in the diffusion pump-based capacitively coupled $BCl_3$ plasma. Process variables were chamber pressure ($50{\sim}180$ mTorr), CCP power ($50{\sim}200\;W$) and $BCl_3$ gas flow rate ($2.5{\sim}10$ sccm). Surface profilometry was used for etch rate and surface roughness measurement after etching. Scanning electron microscopy was used to analyze the etched sidewall and surface morphology. Optical emission spectroscopy was used in order to characterize the emission peaks of the $BCl_3$ plasma during etching. We have achieved $0.25{\mu}m$/min of GaAs etch rate with only 5 sccm $BCl_3$ flow rate when the chamber pressure was in the range of 50{\sim}130 mTorr. The etch rates of AlGaAs were a little lower than those of GaAs at the conditions. However, the etch rates of GaAs and AlGaAs decreased significantly when the chamber pressure increased to 180 mTorr. GaAs and AlGaAs were not etched with 50 W CCP power. With $100{\sim}200\;W$ CCP power, etch rates of the materials increased over $0.3{\mu}m$/min. It was found that the etch rates of GaAs and AlGaAs were not always proportional to the increase of CCP power. We also found the interesting result that AlGaAs did not etched at 2.5 sccm $BCl_3$ flow rate at 75 mTorr and 100 W CCP power even though it was etched fast like GaAs with more $BCl_3$ gas flow rates. By contrast, GaAs was etched at ${{\sim}}0.3{\mu}m$/min at the 2.5 sccm $BCl_3$ flow rate condition. A broad molecular peak was noticed in the range of $500{\sim}700\;mm$ wavelength during the $BCl_3$ plasma etching. SEM photos showed that 10 sccm $BCl_3$ plama produced more undercutting on GaAs sidewall than 5 sccm $BCl_3$ plasma.