• Title/Summary/Keyword: 비다공성

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폴리프로필렌 중공사막의 용융방사

  • 김진호;강민수;김성수
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.75-76
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    • 1996
  • 다공성 고분자 분리막을 제조하는 방법으로 기존의 용매교환법을 대신하여 내용매성, 내약품성 및 내열성이 매우 뛰어난 고분자를 소재로하여 다공성 고분자막을 만드는 열유도 상분리법(Thermally Induced Phase Separation, TIPS)이 개발되었다. TIPS공정에서는 주로 고분자/희석제 system의 열역학적인 불안정성에 의하여 polymer-rich phase와 polymer-lean phase로 상이 분리되는 liquid-liquid phase separation과 결정성 고분자의 결정화에 의한 solid-liquid phase separation을 주로 상분리 mechanism으로 사용하고 있다. 따라서 위에 언급된 TIPS 이론에 근거한 melt spinning 공정에 의하여 PP 중공사막을 제조하였는데 wet spinning 공정에 의한 용매 교환법에 비해 비교적 공정이 단순하고 다공도를 조건하기가 용이하며 구조 및 성능면에서도 높은 재현성을 가지고 있다. 또한 우수한 소재임에도 불구하고 절절한 용매의 부재로 용매교환법에서 사용할 수 없었던 폴리올레핀계, 나일론계, 방향족출합계 고분자를 사용할 수 있게 되어 소재의 폭이 넓어졌다는데에 가장 큰 장점이 있다. 본 연구에서는 PP중공사막을 제조하기 위하여 먼저 용융 방사장치를 제작하였고 melt spinning 공정에 의해 막을 제조하는데 적합한 방사조건들을 확립한 후 결정된 방사조건에 의해 얻어진 PP 중공사막의 구조 및 성능에 영향을 미치는 인자들에 관하여 조사하였다.

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Fabrication of Nano-sized Core-Shell Transition Metal/Oxides by Selective Oxidation (선택적 산화에 의한 코어-쉘 구조의 전이금속/산화물 나노 입자 제조)

  • Choe, U-Seong;Choe, Seung-Mok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.99.2-99.2
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    • 2017
  • 전이금속 산화물은 비교적 높은 용량 (700~1000 mAh/g)을 갖기 때문에 차세대 리튬전지용 음극으로서 많은 연구가 진행되어 왔다. 나노 코어-쉘 구조의 다공성 전이금속/전이금속 산화물 구조는 높은 비 표면적의 산화물과 높은 전기전도성을 가지는 금속 코어로 구성되어 고효율 리튬전지에 적용가능하다. 본 연구에서는 구리 소재 상에 나노코어구조의 구리/코발트 입자를 전기화학적으로 석출시킨 후 구리의 산화가 일어나지 않는 전해질/전위 조건에서 코발트만 선택적으로 산화시켜 코어-쉘 구조의 다공성 전이금속/전이금속 산화물 구조를 얻을 수 있었다. 제조된 나노 코어-쉘 구조의 다공성 전이금속/전이금속 산화물 입자를 리튬전지의 음극으로 사용하여 매우 우수한 충/방전 안정성을 나타냄을 확인할 수 있었다.

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An Experimental Study on Thermal Property of Porous Concrete Containing Bottom Ash (바텀애시를 활용하는 다공성 콘크리트의 열전도 특성에 관한 실험 연구)

  • Jeong, Seung-Tae;Kim, Bum-Soo;Park, Ji-Hun;Yang, In-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.625-632
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    • 2021
  • In this paper, the applicability of bottom ash to insulation concrete was investigated to increase the utilization of bottom ash. Bottom ash was used as the aggregates in porous concrete and extensive experiments were conducted to investigate the characteristics of porous concrete using two types of bottom ash aggregates. The water-binder ratios of 0.25 and 0.35 were chosen and concrete specimens was produced with the compaction of 0.5, 1.5, and 3.0MPa to analyze the material properties at different compaction conditions. After concrete specimens were cured for 28 days at water tanks, unit weight, total void ratio, and thermal conductivity were measured. Based on the measured experimental results, the relationships between the unit weight, total void ratio, and thermal conductivity of porous concrete containing bottom ash was presented.

Effect of Additive Ball Clay on Physical Properties of Porous Ceramic (볼 클레이 첨가에 따른 세라믹 다공체의 물리적 특성변화)

  • Kang, Young-Sung;Kim, Sang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.109-112
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    • 2014
  • A porous ceramic which has fine porosity and small specific gravity is made with Cenosphere and Ball Clay under condition of $1,250^{\circ}C$ in calcination temperature and 30 minutes of calcination time. The average size of porous ceramic was about $2.5{\times}10^{-5}$ m and pores are well developed. The void-fraction of porous ceramic was 67.1% under the input of Cenosphere and Ball clay with the weight ratio of 100 to 5. However, as weight ratio of Ball Clay increased to 20, 40, 100, the void fraction decreased to 58.4, 56.7, 47% respectively. When the weight ratio of Cenosphere and Ball Clay was 100 to 100, the apparent density of porous ceramic was $1.04g/cm^3$. which is twice the density when the weight ratio of Ball Clay was 5. On the other hand, absorption rate decreased by at least 100%. In condition of weight ratio of Cenosphere and Ball Clay was 100 to 100, compressive strength of porous ceramic was 30 (MPa), improve by about 76% or more when the weight ratio of Ball Clay was 5.

Thermal Diffusivity Measurement of Carbon/Epoxy and Porous Thermal Insulation Material under Vacuum Condition Using Cyclic Heating Method (주기가열법을 이용한 탄소/에폭시 및 다공성 단열재의 진공 열확산도 측정)

  • Nam, Gi-Won;Yi, Yeong-Moo;Ohnishi, Akira;Kong, Cheol-Won
    • Composites Research
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    • v.20 no.5
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    • pp.20-25
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    • 2007
  • Cyclic heating method is useful method for measuring the thermal diffusivity of porous materials. The main object of this paper is to develop and verify the thermal diffusivity measuring system of porous materials under vacuum condition. To verify this method, thermal diffusivities of the alumina ($Al_2O_3$) specimen and polystyrene foam were measured. Thermal diffusivities of these specimens were agreed with reference values. Thermal diffusivities of carbon/epoxy and porous insulation material were measured at atmospheric room temperature condition and vacuum condition respectively. Thermal diffusivities of carbon/epoxy and porous insulation material under vacuum are reduced by 66.4% and 64.9% compared to the thermal diffusivities under the atmospheric condition. These differences are considered the effect of the porous insulation material with an air.

Correlation Analysis between Unit Weight and Thermal Conductivity in Porous Concrete Containing Natural Fine and Bottom Ash Aggregates (바텀애시와 천연 잔골재를 혼입한 다공성 콘크리트의 단위질량과 열전도도의 상관분석)

  • Seung-Tae Jeong;In-Hwan Yang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.542-551
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    • 2023
  • In this paper, the thermal properties of porous concrete containing natural fine aggregates in bottom ash aggregates were analyzed. In this study, natural fine aggregates were used for bottom ash aggregates to understand the material properties of each aggregate and then used as an aggregate for porous concrete. A porous concrete specimen was manufactured by fixing the water-binder ratio at 0.25 and designating the compaction at 0.5, 1.5, and 2.5 MPa. Unit weight, total void ratio and thermal conductivity test were measured and discussed. As the compaction increased and the mixing ratio of natural fine aggregates increased, the unit weight and thermal conductivity increased, and the total void ratio decreased. In addition, the correlations between unit weight, total void ratio and thermal conductivity of porous concrete with previous experimental data were presented and the correlation coefficient (R2) was also analyzed.

Nonlinear Acoustical Modeling of Poroelastic Materials (비선형성을 고려한 탄성 다공성 재질의 음향학적 모델링)

  • 김진섭;이수일;강영준
    • Journal of KSNVE
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    • v.9 no.6
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    • pp.1218-1226
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    • 1999
  • In this paper, the extended Biot's semilinear model was developed. Combining the extended Biot model with the dynamic equation yields the nonlinear wave equation in poproelastic sound absorbing materials. Both perturbation and matching techniques are used to find solutions for nonlinear wave equations. By comparing results between linear and nonlinear wave solutions, characteristics of nonlinear waves in poroelastic sound abosrbing materials have been studied. Nonlinear waves were found to be attenuated faster than the linear ones. A maximum amplitude of the nonlinear wave occurred near its surface boundaries and decay quickly with distance from the surface. It has also been found that, if the amplitudes of linear waves are known at the surface boundaries, those of nonlinear ones can be determined. This will be the basis of finding effects of nonlinearity on the absorption coefficient and the transmission loss.

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Fluorescent Enhancement of Bloody Fingermarks Deposited on Dark non-porous Surfaces (어두운 비다공성 표면에 유류된 혈지문 형광 증강에 관한 연구)

  • Kim, Ji-Yeon;Kim, Chae-Won;Kim, Ju-Eun;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.18 no.2
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    • pp.124-131
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    • 2018
  • This study aimed to compare effectiveness of fluorescent reagents for enhancing blood such as acid yellow 7, rhodamine 6G, eosin Y. AY7 and eosin Y have been introduced in Korea as fluorescent reagents for enhancing blood, but not rhodamine 6G. In this study, researchers photographed when each reagents gave the most effective results. Consequently, rhodamine 6G was superior to the others. Eosin Y enhanced bloody fingermarks weakly compared to AY7 and rhodamine 6G. Furthermore, the more depletion trials were done, the less effectiveness were shown. Therefore, researchers recommended that crime scene investigators try to use rhodamine 6G fluorescent reagents for enhancing blood.

Multi-scale simulation of drying process fey porous materials using molecular dynamics (part 3: multi-scale simulation) (분자동역학을 이용한 다공성 물질 건조공정 멀티스케일 시뮬레이션(3부: 멀티스케일 시뮬레이션))

  • Baik S.M.;Keum Y.T.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.4
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    • pp.168-174
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    • 2005
  • In this study, the numerical simulation of drying processes for porous materials is performed by employing the hierarchical multi-scale modeling and the nano-scale material properties obtained from the molecular dynamics simulation. The multi-scale simulation system is set up using pre- and post-processors and the drying process of electric porous ceramic insulator is simulated. The temperature, moisture, residual stress, and displacement distributions are compared with those based on homogenized properties.

Visualization and Quantification of Dissolution of Dense Nonaqueous Phase Liquid Entrapped in Porous Media (다공성 매체내 유기용매(DNAPL)의 용해현상 시각화 및 정량화 연구)

  • Ju, Byung-Kyu;Jeong, Seung-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.16 no.1
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    • pp.46-52
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    • 2008
  • Oils and chlorinated solvents leaking to the subsurface are entrapped in the soil pore and these are called as nonaqueous phase liquids (NAPL). NAPL entrapped in porous media acts as a continuous source for surface and ground water contamination. This study visualized dissolution of trichloroethylene (TCE) entrapped in porous media and quantified the velocity of TCE dissolution using an image analysis technique. As the water velocity increased, the level of dissolution increased. The results imply that a TCE contaminated region having a high infiltration rate and groundwater velocity may result in severe groundwater contamination. Microscopic images of TCE entrapped in porous media showed that TCE present in the preferential flow paths was easily dissoluted into the water phase. However, TCE present in the stagnant flow region was visualized for long time. The results imply that TCE would be still present in the soil if TCE is detected in goundwater.

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