• Title/Summary/Keyword: 비다공성

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Fabrication and Characterization of Porous Carbon Electrode for Electrosorption (전기흡착용 다공성 탄소전극의 제조 및 특성 분석)

  • Park, Nam-Soo;Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.409-414
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    • 2008
  • Porous carbon electrode for electrosorption was prepared by a wet phase inversion method. Carbon slurry that was a mixture of activated carbon powder(ACP) and PVdF solution was cast directly upon a graphite sheet by means of a casting knife. Porous carbon electrodes were fabricated by immersing the cast film in pure water as a non solvent. Physical and electrochemical properties of carbon electrodes prepared with various ACP contents(50.0, 75.0, 83.3, 87.5, 90.0 wt %). From the SEM images we can verify that the electrode was porous. The average pore sizes determined for the electrodes fabricated with various ACP contents ranged from 72.7 to 86.4 nm and the size decreased as the ACP content increased. The electrochemical properties were characterized by cyclic voltammetry(CV) method. All of the voltammograms showed typical behavior of an electric double layer charging/discharging on the carbon surface. The capacitance increased with the ACP content and the values ranged from 2.18 F/cm$^2$ for 50 wt% ACP to 4.77 F/cm$^2$ for 90 wt% ACP.

Preparation of $SiO_2-TiO_2$ Porous Composite Pigments Using a Pickering Emulsion Method as Template (피커링 에멀젼을 형판으로 하는 $SiO_2-TiO_2$ 다공성 분체의 제조)

  • Lee, Sang-Gil;Kim, Young-Ho;Hong, Jun-Ki;Pyo, Hyeong-Bae;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.377-392
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    • 2012
  • It has been known that small solid particles act as a stabilizer in pickering emulsion system. In this study, we successfully prepared stable pickering emulsion in n-hexylalcohol and water system with $TiO_2$ whose surface was treated by alkylsilane. The optimum condition to prepare pickering emulsion stabilized by $TiO_2$ particles was determined by amount of $TiO_2$ particles and ratio of water and oil phase. The type of pickering emulsion was dependent on wettability of particles for water and n-hexylalcohol. When the amount of $TiO_2$ particles increased up to 5.00 wt%, the stability of pickering emulsion was showed to be improved. The most stable pickering emulsion was prepared in the case of W/O type which has the ratio of oil and water phase (3 : 7). We tried to prepare porous $SiO_2-TiO_2$ composite pigments using a pickering emulsion as template at the optimal condition. Porous pigments were synthesized with Ludox HS-30 as an inorganic material by sol-gel process. The characteristics and shape of porous pigments were measured by optical microscope, SEM, BET, XRD and EDS.

The Development of Scrubber for F-gas Reduction from Electronic Industry Using Pressure Swing Adsorption Method and Porous Media Combustion Method (압력순환흡착법과 다공성 매체 연소법을 이용한 전자산업 불화가스 저감 스크러버 개발)

  • Chung, Jong Kook;Lee, Ki Yong;Lee, Sang Gon;Lee, Eun Mi;Mo, Sun Hee;Lee, Dae Keun;Kim, Seung Gon
    • Clean Technology
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    • v.23 no.2
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    • pp.181-187
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    • 2017
  • The perfluorocompounds (PFCs) emitted from the semiconductor and display manufacture is treated by abatement systems which use various technologies, such as combustion, thermal, plasma, catalyst. However, it is required that the system should overcome their drawbacks with excess energy consumption and low removal efficiency. The new technology using combination of pressure swing adsorption and excess enthalpy combustion for the reduction of PFCs emissions were developed and analyzed its characteristics. PFCs concentration ratio and PFCs loss factor were calculated from measuring concentration of PFCs at the calculated by comparing concentration of PFCs at the combustor's inlet and outlet. There were performance evaluations with various gas flow for comparing energy consumption and removal efficiency with existing equipments. The concentration ratio and the loss factor of PFCs were 1.65, 8.2%, respectively, when the total gas flow of the pressure swing absorption (PSA) inlet was 204 liter per minute (LPM) and $CF_4$ concentration was 1412 ppm. In comparison with existing system at constant condition, $CF_4$ removal efficiency for a porous media combustion (PMC) showed the improvement more than 16% and the consumed energy was also reduced up to approximately 41%. Then, the total gas flow introduced into PMC and $CF_4$ concentration were 91-LPM and 2335 ppm, respectively, and the destruction and removal efficiency of $CF_4$ was about 96% at 19-LPM $CH_4$, and 40-LPM $O_2$.

Permeability Evaluation of OPC and GGBFS Concrete with Cold Joint (콜드조인트를 가진 OPC 및 GGBFS 콘크리트의 투수성 평가)

  • Choi, Se-Jin;Kim, Seong-Jun;Moon, Jin-Man;Kwon, Seung-Jun
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.435-441
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    • 2015
  • Concrete, as a porous media, has permeability and it is considered as a major parameter for durability evaluation. Cold joint caused by delayed placing of concrete accelerates water permeation and intrusion of harmful ions. In the paper, concrete specimens containing GGBFS (Ground Granulated Blast Furnace Slag) and OPC (Ordinary Portland Cement) are prepared with cold joint section, and water permeability and water flow at the age of 91 days are measured for 2 weeks. Sound concrete with GGBFS shows decreased permeability to 89% for sound concrete with OPC and 0.86 of decreasing ratio is evaluated in GGBFS concrete with cold joint. Through WPT (Water Penetration Test), the effects of mineral admixture and cold joint on water permeability are evaluated, and variation in water behavior via cold joint is analyzed through probabilistic method as well.

화학 증착(CVD)에 의한 선택적 수소 투과성 $SiO_2$ 무기막의 제조

  • 남석우;홍성안
    • Proceedings of the Membrane Society of Korea Conference
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    • 1992.04a
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    • pp.29-32
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    • 1992
  • 무기물질로 제조된 분리막은 대부분의 유기고분자 분리막에 비하여 열에 강하고, 구조의 안정성이 있으며, 유독 물질 및 미생물등에 영향을 덜받는다는 장점이 있어 폐수 처리, 식품 가공 및 생물 공학적 분리 목적으로 많은 연구가 진행되어 왔다. 최근 재료기술의 발달로 양질의 세라믹 분리막이 제조 가능하게 되었으며 다공성 alumina, zirconia, glass 분리막은 현재 4 nm - 5$\mu$m의 기공 범위로 상용화 되어 있다.

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Flow Analysis of the Oxidizer Manifold for a Liquid Rocket Combustor using OpenFOAM (OpenFOAM을 이용한 액체 로켓 연소기의 산화제 매니폴드 내 유동 해석)

  • Joh, Mi-Ok;Han, Sang-Hoon;Kim, Seong-Ku;Choi, Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.9
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    • pp.781-788
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    • 2012
  • Flow in the oxidizer manifold of a liquid rocket combustor has been analysed using an open source CFD toolbox, OpenFOAM. The applicability of OpenFOAM to the problems with complex geometries involving porous media zones for simulating the pressure drop induced by the injectors has been evaluated by performing turbulent, incompressible steady-state flow analysis. The usefulness and applicable area of the OpenFOAM as a design evaluation and analysis tool will be confirmed and enlarged by further evaluation with various computational cases representing major physical phenomena in rocket combustion devices.

Development of a New Artificial Latent Fingerprint Aqueous Solution by Improving Lipid Composition (지질조성 개선을 통한 새로운 인공 잠재지문 수용액의 개발)

  • Sang-Yoon LEE;Hwa-Seon LIM;Ki-Jong RHEE
    • Korean Journal of Clinical Laboratory Science
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    • v.56 no.1
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    • pp.99-103
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    • 2024
  • Previous artificial latent fingerprint solution has shown unsatisfactory results. Therefore, in this study, we developed an artificial latent fingerprint solution close to the actual fingerprint composition by improving the lipid composition. We mixed lipid solution with amino acid solution at v/v ratios as follows: 2:3, 1:4, 1:5, 1:8, 1:10, 1:20. We then dropped the same amount of each proportion of artificial latent fingerprint solution on porous paper and non-porous slide glass. Subsequently, each sample was treated with Oil red O, Cyanoacrylate fuming and Basic yellow 40 staining. As the concentration of lipids decreased, the output also decreased. Both types of surfaces and all concentrations were visually confirmed very well. In addition, the reactivity to lipids was significantly higher compared to the previous artificial latent fingerprint solution. Furthermore, for the quantitative evaluation, it is necessary to conduct additional research on the printing of the artificial latent fingerprint solution.

Removal and Recovery of VOCs using a Hallow Fiber Membrane Module (중공사막모듈에 의한 휘발성유기화합물의 제거 및 회수)

  • 강창국;차준석;전배혁
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.116-117
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    • 1997
  • 1. 서론 : 다양한 산업공정에서 대기중으로 배출되는 휘발성유기화합물들은 물리, 화학적성질과 그들이 생성되는 기술적인 조건등에 따라 소각, 응측, 흡착, 흡수 등의 처리기술들이 사용되어왔다. 이러한 기존의 처리기술들은 안전성, 성능, 운전비, 시설공간 및 비용 등의 면에서 크게 만족스럽지 못하였다. 이에 비하여 분리막을 이용한 공정은 배출가스에 대한 처리농도범위가 광범위하고 장치가 간단하여 시설투자비 및 운전비용이 낮으며 제거효율도 매우 높은 것으로 알려져 왔다. 본 실험에서는 비다공성의 중공사막모듈을 통한 휘발성유기화합물의 분리특성을 고찰하였고, 휘발성유기화합물의 농도와 feed가스의 유량 및 막양단의 압력차 등을 변화시키면서 막의 성능을 실험적으로 조사하였다.

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Structure Dependent Electrocatalysis for Electroreduction of Oxygen at Nanoporous Gold Surfaces (나노다공성 금 표면상에서 구조 변화에 따른 전기화학적 산소환원 촉매활성)

  • Choi, Su-Hee;Choi, Kyoung-Min;Kim, Jong-Won
    • Journal of the Korean Electrochemical Society
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    • v.15 no.2
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    • pp.83-89
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    • 2012
  • We investigate the electrocatalytic activities for oxygen reduction at nanoporous gold (NPG) surfaces fabricated by selective dissolution of Ag from electrodeposited Ag-Au layers on electrode surfaces. The structure of NPG was controlled by changing the concentration ratios of precursor metal complexes during the electrodeposition of Ag-Au layers and the corresponding surface morphology and surface area was examined. NPG structures with Ag/Au ratio of 2.0 exhibited the highest electrocatalytic activity for oxygen reduction, where the nanoporous structure plays a key role, but the surface area does not affect on the electrocatalytic activity. The mechanism of electroreduction of oxygen was investigated by rotating disk electrode techniques. In acidic media, oxygen was first reduced to hydrogen peroxide followed by further reduction to water through 2-step 4-electron mechanism, whereas the oxygen was reduced directly to water by 4-electron mechanism in basic media.

On the Thermal Boundary Conditions at the Interface Between the Porous Medium and the Impermeable Wall (다공성 매질과 비투과성 벽면 사이의 경계면에 대한 열적 경계 조건)

  • Kim, Deok-Jong;Kim, Seong-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.12
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    • pp.1635-1643
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    • 2000
  • The present work investigates a heat transfer phenomenon at the interface between a porous medium and an impermeable wall. In an effort to appropriately describe the heat transfer phenomenon at the interface, the heat transfer at the interface between the microchannel heat sink, which is an ideally organized porous medium, and the finite-thickness substrate is examined. From the examination, it is clarified that the he heat flux distribution at the interface is not uniform for the impermeable wall with finite thickness. On the other hand, the first approach, based on the energy balance for the representative elementary volume in the porous medium, is physically reason able. When the first approach is applied to the thermal boundary condition, and additional boundary condition based on the local thermal equilibrium assumption at the interface is used. This additional boundary condition is applicable except for the very th in impermeable wall. Hence, for practical situations, the first approach in combination with the local thermal equilibrium assumption at the interface is suggested as an appropriate thermal boundary condition. In order to confirm our suggestion, convective flows both in a microchannel heat sink and in a sintered porous channel subject to a constant heat flux condition are analyzed. The analytically obtained thermal resistance of the microchannel heat sink and the numerically obtained overall Nusselt number for the sintered porous channel are shown to be in close agreement with available experimental results when our suggestion for the thermal boundary conditions is applied.