• Title/Summary/Keyword: 붕소

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Effect of Boron Contained Compound Fertilizer on Chestnut Trees (밤나무 전용복비(專用複肥) 비효시험(肥效試驗))

  • Maeng, Do-Weon;Chung, In-Ku
    • Korean Journal of Soil Science and Fertilizer
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    • v.16 no.3
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    • pp.250-255
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    • 1983
  • Newly manufactured compound fertilizers for chestnut trees developed by Chosun Fertilizer Inc. were tested to evaluate their effectiveness. An experiment was carried out in chestnut farm with 4 years old Eungi Var. from 1981 to 1982. The results obtained are as follows: 1. The growth of chestnut trees was generally good in plots of compound fertilizer contained boron (B C F). 2. The number of ripened strobiles was significantly increased by reducing the ratio of dropped strobiles in plot of B C F. 3. The yield of chestnut by B C F was markedly increased, 6 times more than that of compound fertilizer without boron. 4. Boron content in soil and plant by application of B C F was relatively high, resulting in high production of chestnut. 5. B C F was effective in chestnut orchard to increase nut production markedly.

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Suppression of Boron Penetration into Gate Oxide using Amorphous Si on $p^+$ Si Gated Structure (비정질 실리론 게이트 구조를 이용한 게이트 산화막내의 붕소이온 침투 억제에 관한 연구)

  • Lee, U-Jin;Kim, Jeong-Tae;Go, Cheol-Gi;Cheon, Hui-Gon;O, Gye-Hwan
    • Korean Journal of Materials Research
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    • v.1 no.3
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    • pp.125-131
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    • 1991
  • Boron penetration phenomenon of $p^{+}$ silicon gate with as-deposited amorphous or polycrystalline Si upon high temperature annealing was investigated using high frequency C-V (Capacitance-Volt-age) analysis, CCST(Constant Current Stress Test), TEM(Transmission Electron Microscopy) and SIMS(Secondary Ion Mass Spectroscopy), C-V analysis showed that an as-deposited amorphous Si gate resulted in smaller positive shifts in flatband voltage compared wish a polycrystalline Si gate, thus giving 60-80 percent higher charge-to-breakdown of gate oxides. The reduced boron penetration of amorphous Si gate may be attributed to the fewer grain boundaries available for boron diffusion into the gate oxide and the shallower projected range of $BF_2$ implantation. The relation between electron trapping rate and flatband voltage shift was also discussed.

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Selective Reduction with Zinc Borohydride. Reaction of Zinc Borohydride with Selected Organic Compounds Containing Representative Functional Groups (수소화붕소아연에 의한 선택환원. 수소화붕소아연의 대표적 유기화합물과의 반응)

  • Yoon Nung Min;Ho Jun Lee;Hye Kyu Kim;Jahyo Kang
    • Journal of the Korean Chemical Society
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    • v.20 no.1
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    • pp.59-72
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    • 1976
  • The addition of one mole of zinc chloride to 2.33 moles of sodium borohydride in tetrahydrofuran at room temperature gave a clear chloride-free supernatant solution of zinc borohydride after stirring three days and standing at room temperature.The approximate rates and stoichiometry of the reaction of zinc borohydride with 54 selected organic compounds were determined in order to test the utility of the reagent as a selective reducing agent. Aldehydes and ketones were reduced rapidly, aromatic ketones being somewhat slowly, and the double bond of cinnamaldehyde was not attacked. Acyl halides were reduced rapidly within one hour, but acid anhydrides were reduced at a moderate rate. Carboxylic acids, both aliphatic and aromatic, were slowly reduced to alcoholic stage. Esters were inert to this reagent but a cyclic ester, γ-butyrolactone, was slowly attacked. Primary amides were reduced slowly with partial evolution of hydrogen, whereas tertiary amides underwent neither reduction nor hydrogen evolution. Epoxides and nitriles were all inert, as well as nitro, azo, and azoxy compounds. Cyclohexanone oxime and phenyl isocyanate were reduced slowly but pyridine was inert. Disulfide, sulfoxide, sulfone and sulfonic acids were stable to this reagent.

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Estimation of the impurity segregation in the multi-crystalline silicon ingot grown with UMG (Upgraded Metallurgical Grade) silicon (UMG(Upgraded Metallurgical Grade) 규소 이용한 다결정 잉곳의 불순물 편석 예측)

  • Jeong, Kwang-Pil;Kim, Young-Kwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.5
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    • pp.195-199
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    • 2008
  • Production of the silicon feedstock for the semiconductor industry cannot meet the requirement for the solar cell industry because the production volume is too small and production cost is too high. This situation stimulates the solar cell industry to try the lower grade silicon feedstock like UMG (Upgraded Metallurgical Grade) silicon of 5$\sim$6 N in purity. However, this material contains around 1 ppma of dopant atoms like boron or phosphorous. Calculation of the composition profile of these impurities using segregation coefficient during crystal growth makes us expect the change of the type from p to n : boron rich area in the early solidified part and phosphorous rich area in the later solidified part of the silicon ingot. It was expected that the change of the growth speed during the silicon crystal growth is effective in controlling the amount of the metal impurities but not effective in reducing the amount of dopants.

Experimental Study of Interfacial Friction in NaBH4 Solution in Microchannel Dehydrogenation Reactor (마이크로채널 탈수소 화학반응기에서 수소화붕소나트륨 수용액의 계면마찰에 대한 실험연구)

  • Choi, Seok Hyun;Hwang, Sueng Sik;Lee, Hee Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.2
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    • pp.139-146
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    • 2014
  • Sodium borohydride ($NaBH_4$) is considered as a secure metal hydride for hydrogen storage and supply. In this study, the interfacial friction of two-phase flow in the dehydrogenation of aqueous $NaBH_4$ solution in a microchannel with a hydraulic diameter of $461{\mu}m$ is investigated for designing a dehydrogenation chemical reactor flow passage. Because hydrogen gas is generated by the hydrolysis of $NaBH_4$ in the presence of a ruthenium catalyst, two different flow phases (aqueous $NaBH_4$ solution and hydrogen gas) exist in the channel. For experimental studies, a microchannel was fabricated on a silicon wafer substrate, and 100-nm ruthenium catalyst was deposited on three sides of the channel surface. A bubbly flow pattern was observed. The experimental results indicate that the two-phase multiplier increases linearly with the void fraction, which depends on the initial concentration, reaction rate, and flow residence time.

Molecular Dynamics and Micromechanics Study on Mechanical Behavior and Interfacial Properties of BNNT/Polymer Nanocomposites (분자동역학 전산모사와 미시역학 모델을 이용한 질화붕소 나노튜브/고분자 복합재의 역학적 물성 및 계면특성 예측)

  • Choi, Seoyeon;Yang, Seunghwa
    • Composites Research
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    • v.30 no.4
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    • pp.247-253
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    • 2017
  • In this study, the mechanical behavior and interface properties of boron nitride nanotube-poly(methyl methacrylate) nanocomposites are predicted using the molecular dynamics simulations and the double inclusion model. After modeling nanocomposite unit cell embedding single-walled nanotube and polymer, the stiffness matrix is determined from uniaxial tension and shear tests. Through the orientation average of the transversely isotropic stiffness matrix, the effective isotropic elastic constants of randomly dispersed microstructure of nanocomposites. Compared with the double inclusion model solution with a perfect interfacial condition, it is found that the interface between boron nitride nanotube and polymer matrix is weak in nature. To characterize the interphase surrounding the nanotube, the two step domain decomposition method incorporating a linear spring model at the interface is adopted. As a result, various combinations of the interfacial compliance and the interphase elastic constants are successfully determined from an inverse analysis.

Development of Boron Doped Carbon Using CO2 Reduction with NaBH4 for Vanadium Redox Flow Battery (수소화 붕소 나트륨 (NaBH4) 과 이산화탄소의 환원을 이용한 바나듐 레독스 흐름전지용 탄소 촉매 개발)

  • Han, Manho;Kim, Hansung
    • Journal of the Korean Electrochemical Society
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    • v.21 no.1
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    • pp.1-5
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    • 2018
  • In this study, boron - doped carbon was prepared by reducing carbon dioxide ($CO_2$) at high temperature by using sodium borohydride ($NaBH_4$). The boron - doped carbon was coated on carbon felt and applied as an electrode for a vanadium redox battery cell. As a result of electrochemical performance evaluation, reversibility of carbon felt coated with boron doped carbon compared to pure carbon felt was improved by about 20% and charge transfer resistance was reduced by 60%. In the charge / discharge results, energy density and energy efficiency were improved by 21% and 12.4%, respectively. These results show that carbon produced by reduction of $CO_2$ can be used as electrode material for redox flow battery.

Synthesis of Aminated PP-g-styrene Fibrous Ion-Exchanger for Separation of Boron from Ground-Water (지하수로부터 붕소이온 분리를 위한 아민화 PP-g-styrene 이온교환체 섬유의 합성과 붕소 음이온 흡착에 관한 연구)

  • Hwang, Taek-Sung;Lee, Jin-Hyok;Lee, Myun-Joo
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.451-459
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    • 2001
  • Fabric ion-exchanger, aminated PP-g-styrene was synthesized with styrene monomer onto PP staple fiber by pre-irradiational grafting with E-beam and subsequent chloromethylation and amination. Degree of grafting was increased with increasing the styrene monomer concentration and the highest degree of grafting was obtained 118% at a monomer concentration of 80% styrene. Optimum condition of Mohr's salt and sulphuric acid were 1.0 ${\times}\;10^{-3}$ M and 0.1 M. Amount of amination was increased with increasing degree of grafting. Swelling ratio of aminated PP-g styrene was higher than that of trunk polymer. Ion-exchange capacity was 6.7 meq/g, which was three times greater than commercial ion-exchanger. Optimum condition of baron ion adsorption was pH 4 and amount of adsorption were increased with increasing the amount of amination.

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Effect of Boron Nitride on Mechanical Properties, Thermal and Electrical Conductivities of Carbon Fiber Reinforced Plastics (탄소섬유강화 복합소재의 열적, 전기적, 기계적 특성에 대한 질화붕소 첨가제의 효과)

  • Hong, Hyunkee;Bae, Kwak Jin;Yu, Jaesang
    • Composites Research
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    • v.33 no.3
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    • pp.153-160
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    • 2020
  • In this paper, hexagonal boron nitride (h-BN) particles were added between the sheets of prepreg, and the effect of on many properties of BN-embedded carbon fiber reinforced plastics was investigated. The amount of BN particles which corresponds with 0 to 15 wt% of total resin weight was used as an additive material. The tensile strength and the inter-laminar shear strength of BN-embedded CFRP samples were improved by maximally 13.6%, and 6.7%, respectively. The tendency changes of thermal, electrical conductivities and the morphology of cross-section of CFRPs were also observed. This study suggests the possibility of controlling the characteristics of carbon fiber-BN-epoxy composites to use for aerospace applications.