• Title/Summary/Keyword: 불포화 폴리에스테르

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Development of Glass Fiber Composite Material to Extend the Life of Fly Ash Transport Pipe: Wear Test (비회 운송관의 수명연장을 위한 유리섬유 복합재의 개발: 내마모성 평가)

  • Jeong, Gyu-Sang;Chang, Yoon-Sang
    • Clean Technology
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    • v.15 no.1
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    • pp.16-22
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    • 2009
  • In this study, a fiber reinforced plastic (FRP) pipe with superior wear resistance was developed to replace the fly ash pipe of cast iron. Wear test was performed with various combinations of SiC filler and resin materials of unsaturated polyester, vinylester, epoxy, and phenol. Test results of ASTM D4060 showed the optimal combinations of resin, filler size, and resin/filler ratios. Test results of comparison between FRP and cast iron showed the possibility to replace cast iron pipe with the FRP pipe. Field test executed to compare the wear resistance between cast iron pipe and developed FRP pipe showed the superiority of the FRP pipe.

Dielectric Properties of Unsaturated Polyester Resin for Electric Safety (전기 안전에 관한 불포화폴리에스테르 수지의 유전특성)

  • 이성일;권호영
    • Journal of the Korean Society of Safety
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    • v.6 no.3
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    • pp.12-20
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    • 1991
  • The dielectric properties that effect to electric safety for unsaturated Pelvester resin were studied over the temperature range of 30-40[$^{\circ}C$] and the frequency range of 110~3$\times$10$^{6}$ [Hz]. According to the results of the study, it has been observed that two kinds of dielectric losses in electric safety were existed by the molecular movement of C-H and OH group. When the ,adio of hardener was 1.5[%], the characteristics of specimens were excellent in view of the electrical materical. In the range of measuring frequency the dielectric constants and the dielectric losses were 3.5~5.5 and 10$^2$~10$^3$ respectly. The activation energy of loss spectrum in aspect of electric safety and the entropy appeared at the 30[$^{\circ}C$] were 33.4[Kacl/mole] and 54.9[cal/mole.deg] respectly.

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Preparations and Interfacial Phenomena of Hybrid Composites (Hycom) Containing Wasted Stone Powders and Tire Chips (폐석분과 폐타이어 칩을 충진제로 한 혼성복합재(Hycom)의 제조 및 계면현상 연구)

  • Hwang, Teak-Sung;Cha, Ki-Sik
    • Journal of Adhesion and Interface
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    • v.2 no.1
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    • pp.1-8
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    • 2001
  • In this study, wasted stone powders (WSP) obtained from sludge and Wasted Tire Chips (WTC) as fillers have been used to formulate polymer hybrid composites based on Unsaturated Polyester (UPE) resin. To further enhance not only the interfacial bond between the inorganic filler and the polymer matrix, but also the filler dispersion by wetting the particulate surfaces to uniformly spread the resin during the mixing, silane coupling agent[${\gamma}$-methacryloxy propyl trimethoxy silane (${\gamma}$-MPS)] was used. The influences of organic recycled fillers contents and the concentrations of coupling agent in polymer hybrid composite formulations have been investigated from a mechanical and microstructural point o view through Mercury Porosimeter and SEM.

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Acid Resistance of Unsaturated Polyester Mortar Using Crushed Wate Glass (폐유리를 골재로 사용한 불포화폴리에스테르 모르타르의 내산성에 관한 연구)

  • 한창호;최길섭;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.339-342
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    • 2000
  • Recently, the importance of the conutermeasures for waste materials has pointed out. Waste glass is also one to waste materials used for the recycling in construction sites. The crushed waste glass has been used to make a glass polymer composite that can be applied for sewer, storm drain pipe and interlocking block, etc. In this study, the crushed waste glass is explored with the possibility of recycling it, as a substitute for fine aggregates. The prepose of this investigation is to improve the strengths and acid resistance of the UP mortars using crushed waste glass. The UP mortars are prepare with blast furnace slag fly ash filler. the UP-fine aggregate ratios the crushed waste glass replacements for fine aggregate are tested strengths before and after immersion(H (아래첨자2)SO(아래첨자4) 10%), weight change and acid resistance are also tested. From the test results, the relative strength or UP mortars using fly ash as filler are found to be somewhat superior to that of the UP mortars using blast furnace as filler, And a UP mortar with fly ash as a filler, a UP-fine aggregate ratio of 15% and a waste glass replacement if 50% for fine aggregate is recommended as optimal mix proportion of UP mortar using crushed waste glass. Accordingly, it is enough to assure the use of the crushed waare glass as an aggregate for the production of UP mortar.

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An Experimental Study on the fluidity properties of Polymer Concrete According to Replacement Ratio of Rapidly-Chilled Steel Slag and polymer resin (급냉 제강 슬래그 대체율과 폴리머 수지에 따른 폴리머 콘크리트의 유동특성에 관한 실험적 연구)

  • Choi, Duck-Jin;Kim, Jae-Won;Sun, Joung-Soo;Kim, Ha-Suk;Hwang, Eui-Hwan;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.11a
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    • pp.75-78
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    • 2007
  • The steel slag, a by-product which is produced by refining pig iron during the manufacture of steel, is mainly used as road materials after aging. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. However, steel slag used in this study was controled by a air-jet method which rapidly cools substance melted at a high temperature. The rapidly-chilled method would prevent from generation of free-CaO in steel slag. Also, Molten steel slag rapidly-chilled by air in high speed becomes a fine aggregate of nearly spherical shape. This study dealt with the influence of the using rate of rapidly-chilled steel slag and polymer resin on fluidity of polymer concrete, as a results Since RCSS has spherical shape and high density, up to replacement ratio of 100%, increases concrete fluidity under same polymer content and decrease polymer content in order to secure the same fluidity

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Recycling of Separate Glass Fiber from Waste Printed Circuit Boards Using Attrition Mill and DMF (어트리션 밀과 DMF 용매를 이용한 폐 인쇄회로기판에서 분리된 재생 유리섬유의 재활용)

  • Kim, Jong-Seok;Lee, Jae-Cheon;Jeong, Jin-Ki
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.894-899
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    • 2012
  • In recent years, recycling process has come to be necessary for separating metals, glass fibers and polymer from WPCBs (waste printed circuit boards) due to an increasing amount of electronic device waste. In this study, dimethylformamide (DMF) and attrition mill reactor were used to separate the component such as metals, glass fiber and epoxy resin from WPCBs. Separation of glass fiber from WPCBs was carried out under stirring rates 300~600 revolution per minute (rpm) for 1~2 h as the various agitator. The recycled glass fibers (RGF) were analyzed by thermogravimetric analyzer (TGA) for degree of separation of epoxy resin in the WPCBs. The degree of separation of epoxy resin of WPCBs increased in attrition mill agitator as a mechanochemical process for recycling WPCBs. The RGF separated in the WPCBs was applied as a reinforcement in the RGF/unsaturated polyester composites to reuse as a reinforcement.

Evaluation of Composite Mold for Small Composite Propeller (소형 복합재료 프로펠러를 위한 복합재료 몰드 평가)

  • Nhut, Pham Thanh;Yum, Young Jin
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.2
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    • pp.279-285
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    • 2013
  • The feasibility of substituting a composite mold for an aluminum mold in the fabrication of a small ship propeller was investigated. A small three-blade aluminum propeller was used as a plug for manufacturing the composite mold. A GRPG composite mold and propeller were made from an unsaturated polyester resin, Epovia gelcoat, and woven and mat glass fibers using the compression and vacuum method at room temperature. The hardness and surface roughness and the strength and deformation of the compression and suction molds were experimentally determined. The results were compared with the ISO 484/2 standard and some aluminum alloy materials. The results showed that the deformation of the mold satisfied the tolerance of the thickness of the blade. Some characteristics of the GRPG composite mold were better than those of the aluminum alloy mold (surface smoothness, weight, performance, and cost), and some characteristics were similar (detachment ability and life-cycle). Therefore, the composite mold is considered suitable for the fabrication of a small composite ship propeller.

A Study on the Heat Resistance of Light-Weight Polymer Concrete Composites (경량 폴리머 콘크리트 복합체의 내열성능에 관한 연구)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.6
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    • pp.131-137
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    • 2008
  • In recent years, the light-weight aggregate has widely been used to reduce the weight of construction structures, and to achieve the thermal insulation of building structures. The purpose of this study is to evaluate the heat resistance of polymer concrete composites with light-weight aggregate made by binders as resin and cement with polymer dispersion. The light-weight polymer concrete composites are prepared with various conditions such as binder content, filler content, void-filling ratio, light-weight aggregate content and polymer-cement ratio, and tested for heat resistant test, and measured the weight reducing ratio, strengths and exhaustion content of gas such as CO, NO and $SO_2$. From the test results, the weight reducing ratio of light weight polymer concrete using UP binder after heat resistance test increase with an increase in the UP content irrespective of the filler content. The weight reducing ratio of polymer cement concrete is considerably smaller than that of UP concrete. In general, the strengths after heat resistance of polymer concrete composites are reduced about 40 to 65% compared with those before test. The exhausted quantity of CO, NO and $SO_2$ gases in polymer concrete composites is less than EPS(Expanded poly styrene). From the this study, it is confirmed that the many types gases discharge according to binder type of polymer concrete composites, its amount is controlled by selection of the binder type and mix proportions.

A Study on the Preparation and Mechanical Properties of Hybrid Composites Reinforced Waste FRP and Urethane Foam (폐 FRP/Urethane Foam 충진 혼성복합재의 제조 및 기계적 물성에 관한 연구)

  • 황택성;신경섭;박진원
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.564-570
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    • 2000
  • The waste FRP occured in the fabrication of SMC (sheet molding compound) bathtubs and the waste polyurethane foam occured in electronic manufacture and waste insulator were applied as a soundproof and light weight pannel in the waste FRP unsaturated polyester matrix resin composites to recycle. The effect of filler contents on the mechanical properties and interfacial phenomena of the filler and matrix on the composites was evaluated. The tensile strength of composites reached its maximum value of 82.34 MPa when the filler content was 70 wt%, and the more content of reinforcement is increased, the more tensile modulus was decreased. The flexural strength and modulus of composites, reinforced 70 wt% with filler content, were dominant compared to the other samples to 72.5 MPa, 958.4 MPa respectively. When composite of reinforced 70 wt% with filler content, it was confirmed that pull out phenomena and cracks did not occur in the interface of reinforcement and matrix resin through the SEM observation. Also, waste FRP and urethane foam were dispersed well into matrix resin as filler.

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A study on fatigue properties of GFRP in synthetic sea water (인공해수중 GFRP의 피로특성에 관한 연구)

  • 김연직;임재규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.6
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    • pp.1351-1360
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    • 1993
  • The fatigue behavior of GFRP composites is affected by environmental parameters. Therefore, we have to study on effect of sea water on fatigue behavior of GFRP composites as to maintain the safety and confidence in design of ocean structure of GFRP. In this paper, we investigated the fatigue properties of chopped strand glass mat/polyester composite in synthetic sea water. (pH 8.2) In case of the glass fiber (CSM type) reinforced polyester composite materials, the fatigue crack in the both dry and wet specimens tested in air or synthetic sea water occurred at the initial of cycle. Thereafter, it was divided with two regions that one decreased with the crack extension and the other increased with the crack extension. The transition point occurred during the crack propagation shifted to high ${\Delta}K$ value as load increase but its point is not changed regardless of immersion or test environment under a constant load. The synthetic sea water degrades the bond strength between fiber and matrix, thereby the tendency of rapid deceleration and acceleration of the crack growth was appeared.