• Title/Summary/Keyword: 불요 특성

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Preparation and Properties of PE Heterogeneous ion Exchange Membrane with Bead and Fibrous ion Exchanger (비드와 섬유이온교환체 고정 PE 불균질 이온교환막의 제조 및 특성)

  • 황택성;박명규;강경석
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.575-581
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    • 2002
  • Heterogeneous ion exchange membranes were prepared by mixing polyethylene as matrix with bead and fibrous anionic ion exchangers at different mixing ratio. Generally, ion exchange capacities were increased with increasing the ratio of the fibrous ion exchanger content. The highest ion exchange capacity of the membrane was 1.86 meq/g at 30wt% IXF (ion exchange fiber) in the membrane. The water uptake, fixed ion concentration, and ion transport number of the membrane increased with increasing the content of the fibrous ion exchanger. However, the electrical resistivity of the membrane was decreased with increasing the content of the fibrous ion exchanger. The lowest electrical resistivity of 5$\Omega$/$\textrm{cm}^2$ was observed at 30 wt%of IXF.

Microstructural Evaluation of $CO_2$ Oxidation Process of High Modulus Carbon Fibers by XRD Analysis (XRD를 이용한 고강성 탄소섬유의 이산화탄소 산화 중에 발생하는 구조변화 해석)

  • 노재승
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.228-228
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    • 2003
  • 고강성 탄소섬유는 높은 비강도 및 고 강성 특성 때문에 탄소-탄소 복합재료의 가장 우수한 강화재로 각광을 받고 있다. 이 섬유는 미세 결정립의 높은 이방성을 나타내며, 이러한 높은 흑연화 특성은 기계적, 전기적, 전기적 그리고 화학적 특성 등을 좋게한다. 이러한 모든 방면에서의 우수한 특성 때문에 항공우주 재료분야에 의심 없이 가장 우수한 재료로 고려되고 있다. 이렇게 가벼우면서 고온강도가 요구되는 재료로써 탄소재료가 이용되면서 rocket의 nozzle이나 nosecone으로의 응용에는 고온 산화가 중요한 연구주제로 대두되어 왔다. 탄소재료의 산화반응은 결정구조 인자 및 그 배열에 가장 큰 영향을 받는다고 알려져 있는데, 출발원료 및 제조 조건에 따라 그 구조 및 배열이 현격하게 달라진다. 탄소재료의 구조 해석은 주로 TEM과 XRD를 이용해 왔다. 많은 연구자들은 오래 전부터 탄소재료 연구에 TEM에서 얻은 상이 불확실하고 문제가 있다고 보고하였고, 최근 TEM 장치의 발달과 더불어 실제 구조를 얻기가 가능함을 보여주고 있다 그러나 TEM 시편은 여전히 작고 시편으로부터 얻는 정보는 불과 nm 수준이다. 따라서 일반적으로 TEM으로 얻은 정량적인 정보는 불과 특정한 점에서의 정보이기 때문에 여전히 논란의 소지가 많다. XRD는 탄소재료의 미세구조 해석을 위하여 가장 널리 이용되는 분석기기이다.

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Preparation of Heterogeneous Bipolar Membranes Using Poly (phenylene oxide, PPO) Polyelectrolyte and Their Water Splitting Properties (Poly (phenylene oxide, PPO) 고분자 전해질을 이용한 불균질 바이폴라막 제조 및 물분해 특성)

  • Kim, In Sik;Hwang, Seong Yeon;Kang, Byung Gwan;Hwang, Taek Sung
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.65-72
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    • 2019
  • In this study, heterogeneous ion exchange membranes were prepared by casting method with various mixing ratios of PPO ion-selective solution and ion exchange resin. Then heterogeneous bipolar membranes were prepared by using this. The water content of heterogeneous cation and anion exchange membranes were 60~80% respectively, the ion exchange capacity was 2.81~3.26 meq/g, 2.31~2.74 meq/g and electrical resistances were $1.65{\sim}1.45{\Omega}{\cdot}cm^2$ and $1.55{\sim}1.05{\Omega}{\cdot}cm^2$. The tensile strength of heterogeneous bipolar membrane was lower than that of PPO resin before functionalization ($700Kg_f/cm^2$). The tensile strength of heterogeneous bipolar membrane with catalyst layer was lower than that of non-catalytic heterogeneous bipolar membrane. The water splitting voltage of the heterogeneous bipolar membrane with catalyst layer was low and stable at a minimum of 1.7~1.8 V, maximum 3.9~4.0 V, and the water splitting voltage of the non-catalytic heterogeneous bipolar membrane was constant at 3.8~4.0 V.

Evaluation Method of Rock Characteristics using X-ray CT images (X-ray CT 이미지를 이용한 암석의 특성 평가 방안)

  • Kim, Kwang Yeom;Yun, Tae Sup
    • Tunnel and Underground Space
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    • v.29 no.6
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    • pp.542-557
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    • 2019
  • The behavior of rock mass is influenced by its microscopic feature of internal structure generating from forming and metamorphic process. This study investigated a new methodology for characterization of rock based on the X-ray CT (computed tomography) images reflecting the spatial distribution characteristics of internal constituent materials. The X-ray image based analysis is capable of quantification of heterogeneity and anisotropy of rock fabric, size distribution and shape parameter analysis of rock mineral grains, fluid flow simulation based on pore geometry image and roughness evaluation of unexposed joint surface which are hardly acquired by conventional rock testing methods.

Design of a Novel low Pass Filler will Low Spurious Response for Satellite Transponder (위성중계기를 위한 낮은 불요 특성을 갖는 새로운 형태의 저역통과 필터 설계)

  • 이문규;류근관;염인복;이성팔
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2001.11a
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    • pp.172-175
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    • 2001
  • A novel microstrip type low-pass filter using thin or thick film resistors is proposed to efficiently eliminate harmonic spurious response in stop-band. The proposed low-pass filter shows the spurious suppression enhancement of 20 dB over a conventional one. The designed low-pass filter could be used as a harmonic rejection filter of a local oscillator for Ku-band satellite payload system.

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A post-processing program for analysis of ADCPs (ADCP 측정자료 분석을 위한 후처리 프로그램)

  • Lee, Hea-Eun;Lee, Chan-Joo;Kim, Dong-Gu;Kim, Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.426-430
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    • 2009
  • 본 연구에서는 ADCP 측정자료를 효율적으로 활용할 수 있도록 ADCP 이동측정법 자료의 후처리 프로그램을 개발하였다. 먼저, 측정된 ensemble과 방위별 유속으로 표시되던 단면유속분포를 한 눈에 알아볼 수 있도록 좌표를 정리하고 주흐름방향 유속을 출력하는 등, Sontek과 RDI 자료 취득 소프트웨어의 ascii 파일을 사용자가 쉽게 알아보고 가공할 수 있도록 변형하였다. 또한, 기존 ADCP 사용과 관련하여 발표된 screening 및 smoothing 기법을 적용하여 유효한 유속자료를 선별하고 단면의 평균 흐름에 근접한 유속자료를 제공하도록 하였다. 멱함수를 이용한 외삽으로 측정불가역의 유속 및 유량을 추정하였으며, 총 53개 측정자료의 유량을 추정한 결과 ADCP 소프트웨어가 제공하는 유량과 평균 1.33 %의 오차를 보였다. 마지막으로, 정리된 ADCP 자료로부터 하천의 주요 수리학적 특성을 추정하도록 하여 하천단면을 횡단하는 간단한 ADCP 측정만으로도 많은 시간과 노력을 들여 측정하던 하천의 특성을 신속히 파악할 수 있도록 하였다.

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Preparation and Desalination Characteristics of Highly Durable Heterogeneous Cation-exchange Membrane Based on Polyvinylidene Fluoride (PVDF) by Casting Method for Electrodialysis (캐스팅법에 의한 전기투석용 고내구성 Polyvinylidene Fluoride (PVDF)계 양이온 불균질 이온교환막 제조 및 탈염특성)

  • Ko, Dae Young;Kim, In Sik;Hwang, Taek Sung
    • Membrane Journal
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    • v.26 no.2
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    • pp.97-107
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    • 2016
  • This study was carried out to prepare a heterogeneous cation exchange membrane by mixing polyvinylidene fluoride (PVDF), commercial cation exchange resin and sulfonated poly(phenylene oxide)(SPPO) in order to propose an optimum condition for the preparation, and to compare its properties with commercial membrane. Study results show that the ion exchange capacity and electrical resistance were outstanding when the ratio of polymer matrix was less than 30% comparing between PVDF-IER, PVDF-SPPO and PVDF-SPPO-IER. The tensile strength was confirmed that seemed a hard look was five times greater compared to the commercial heterogeneous membrane, despite the weak durability of PVDF resin. Therefore, when chemical and mechanical properties are considered, the optimum mixing ratio between PVDF, IER and SPPO was 30 : 70, at which electric resistance was measured as $3{\sim}5{\Omega}{\cdot}cm^2$, ion exchange capacity as 0.6~1.0 meq/g, while mechanical strength was in a range of $12{\sim}15kgf/cm^2$.

Performance of Membrane Capacitive Deionization Process Using Polyvinylidene Fluoride Heterogeneous Ion Exchange Membranes Part I : Preparation and Characterization of Heterogeneous Ion Exchange Membranes (폴리비닐플루오라이드 불균질 이온교환막을 이용한 막 결합형 축전식탈염공정의 탈염 성능 Part I : 불균질 이온교환막의 제조 및 특성)

  • Park, Cheol Oh;Rhim, Ji Won
    • Membrane Journal
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    • v.27 no.1
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    • pp.84-91
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    • 2017
  • In this study, heterogeneous ion exchange membranes were prepared by mixing cation or anion exchange resins and commercial polyvinylidene fluoride (PVDF) for MCDI process. The mixing ratios of PVDF and ion exchange resins were 1 : 1, 1.4 : 1, 2 : 1, and 3 : 1. We characterized SEM, water content, ion exchange capacity, methanol permeability, and ion conductivity. In the viewpoint of membrane characterization, the blending ratio of 2 : 1 showed the best. For the blending ratio of 2 : 1, heterogeneous cation exchange membrane showed the water content 34%, ion exchange capacity 1.54 meq/g, ion conductivity 0.019 S/cm, and methanol permeability $2.28{\times}10^{-7}{\sim}8.86{\times}10^{-7}cm^2/s$ while In the case of heterogeneous anion exchange membrane, the result showed 37%, 2.18 meq/g, and 0.034 S/cm and $1.46{\times}10^{-7}{\sim}8.66{\times}10^{-7}cm^2/s$.