• Title/Summary/Keyword: 불안정 이론

Search Result 185, Processing Time 0.027 seconds

DFT Study for the Thermodynamic Stability and Binding Energeticsof SnOn, SnO2n, SnO3n (n = 1~4) (SnOn, SnO2n, SnO3n (n = 1~4)의 열역학적 안정성과 결합에너지에 대한 DFT 이론 연구)

  • Kim, Si-Jo;Kim, Seung-Joon
    • Journal of the Korean Chemical Society
    • /
    • v.53 no.5
    • /
    • pp.512-520
    • /
    • 2009
  • The theoretical calculations for $S_nO_n,\;S_nO_{2n},\;S_nO_{3n}\;(n\;=\;1{\sim}4)$ have been considered at the B3LYP level of theory with various basis sets. The optimized geometries, harmonic vibrational frequencies, and binding energies are evaluated to elucidate the thermodynamic stability and spectroscopic properties. The harmonic vibrational frequencies for the molecules considered in this study show all real numbers implying true minima. The binding energies due to increasing of $S_nO_n,\;S_nO_{2n},\;S_nO_{3n}$ monomers are calculated at the MP2/6-311G** level of theory. For $S_nO_n\;(n\;=\;1{\sim}4)$, the binding energy difference is about 20∼25 kcal/mol by adding SO monomer. For $SO_2\;and\;SO_3\;(n\;=\;1{\sim}4)$, the binding energy differences are relatively small by comparing to $S_nO_n$.

A Performance Evaluation of Beam Finite Elements with Higher-order Derivatives' Continuity (고차미분 연속성을 가지는 유한요소 보 모델들에 대한 성능평가)

  • Lee, Gijun;Kim, Jun-Sik
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.30 no.4
    • /
    • pp.335-341
    • /
    • 2017
  • In this paper, beam finite elements with higher-order derivatives' continuity are formulated and evaluated for various boundary conditions. All the beam elements are based on Euler-Bernoulli beam theory. These higher-order beam elements are often required to analyze structures by using newly developed higher-order beam theories and/or non-classical beam theories based on nonlocal elasticity. It is however rare to assess the performance of such elements in terms of boundary and loading conditions. To this end, two higher-order beam elements are formulated, in which $C^2$ and $C^3$ continuities of the deflection are enforced, respectively. Three different boundary conditions are then applied to solve beam structures, such as cantilever, simply-support and clamped-hinge conditions. In addition to conventional Euler-Bernoulli beam boundary conditions, the effect of higher-order boundary conditions is investigated. Depending on the boundary conditions, the oscillatory behavior of deflections is observed. Especially the geometric boundary conditions are problematic, which trigger unstable solutions when higher-order deflections are prescribed. It is expected that the results obtained herein serve as a guideline for higher-order derivatives' continuous finite elements.

Effects of Hydrocarbon Addition on Cellular Instabilities in Expanding Syngas-Air Spherical Premixed Flames (합성가스와 공기를 혼합한 예혼합화염의 셀 불안정성에 있어서 탄화수소 계 연료첨가에 대한 효과)

  • Vu, Tran Manh;Song, Won-Sik;Park, Jeong;Kwon, Oh-Boong;Bae, Dae-Seok;Yun, Jin-Han;Keel, Sang-In
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.35 no.2
    • /
    • pp.179-188
    • /
    • 2011
  • Experiments were conducted in a constant-pressure combustion chamber to investigate the effects of hydrocarbon addition on cellular instabilities of syngas-air flames. The measured laminar burning velocities were compared with the predicted results computed using reliable kinetic mechanisms with detailed transport and chemistry. The cellular instabilities that included hydrodynamic and diffusional-thermal instabilities of the hydrocarbon-added syngas-air flames were identified and evaluated. Further, experimentally measured critical Peclet numbers for fuel-lean flames were compared with the predicted results. Experimental results showed that the laminar burning velocities decreased significantly with an increase in the amount of hydrocarbon added in the reactant mixtures. With addition of propane and butane, the propensity for cell formation was significantly diminished whereas the cellular instabilities for methane-added syngas-air flames were not suppressed.

Analysis on Korean Public Rental Housing Market based on System Thinking (시스템사고를 이용한 국민임대주택 공급시장분석)

  • Kim, Tae-Young;Kim, Jae-Jun;Lee, Chan-Sik;Ahn, Hee-Jin
    • Korean Journal of Construction Engineering and Management
    • /
    • v.7 no.5
    • /
    • pp.115-127
    • /
    • 2006
  • Although the Korean government have made a plan of housing market with supply and concentrated on the welfare of the people, there are still a lot of problem in housing market for lack of a long-term vision and consistent policy of the government. The plan of 115% of housing diffusion in 2012 is in progress after its acquisition of 100% in 2002, but there are no changes in the rental housing rate of 43% in 2003. In addition, there are getting worse circumstances in the instability of housing market and the low-income bracket, because of the Korean construction firms' bankruptcy with an increase of unsold hosing and a rapid increase of housing prices. The government have made the strategy of revitalizing the economy and regional development by means of a million public rental housing plan for the low-income bracket and welfare. This paper introduces the basic information of the subjective strategy establishment with the analysis of the reciprocal action of influence factors for public rental housing by system dynamics theory and the effect of public rental housing in housing supply market which has a long-term dynamic form.

The Relationship among Job stress, Emotional labor, Resilience and Mental Health in Firefighters (소방공무원의 정신건강과 직무스트레스, 감정노동, 회복탄력성간의 융합관계)

  • Kim, Yeon-Jung;Kim, Jin-Hyeon;Shim, Gyu-Sik
    • Journal of the Korea Convergence Society
    • /
    • v.8 no.12
    • /
    • pp.379-389
    • /
    • 2017
  • The purposes of this study were to identify the relationships among job stress, emotional labor, resilience, mental health and to determine the influences on mental health in firefighters. The participants were 391 firefighters in Chung-Nam and some variables related to job stress, emotional labor, resilience, mental health were measured using reliable instruments. There showed significant positive relationships of mental health with job stress, emotional labor and negative relationships with resilience. Among predictors, job stress(job insecurity, lack of reward, occupational climate), emotional labor, resilience had statistically significant influence on mental health. Mental health programs to decrease job stress and emotional labor, and to enhance resilience are essential to improve the mental health of firefighters.

Design of the Feed Forward Controller in Digital Method to Improve Transient Characteristics for Dynamic Voltage Restorers (동적전압보상기의 과도특성을 개선하기 위한 디지털방식의 전향제어기 설계)

  • 김효성;이상준;설승기
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.9 no.3
    • /
    • pp.275-284
    • /
    • 2004
  • This paper discusses how to control the compensation voltages in dynamic voltage restorers (DVR). On analyzing the power circuit of a DVR system, control limitations and control targets are presented for the voltage compensation in DVRs. Based on the preceded power stage analysis, a novel controller for the compensation voltages of DVRs is proposed by a feed forward control scheme. This paper discusses also the time delay problems in the control system of DVRs. Digitally controlled DVR systems normally have control delay at amount of one sampling time of the control system and a half of the switching period of the DVR inverter. The control delay in digital controllers increases the dimension of the system transfer function one degree higher, which makes the control system more complicate and more unstable. This paper proposes a guide line to design the control gain, appropriate output filter parameters and inverter switching frequency for DVRs with digital controllers. Proposed theory is verified by an experimental DVR system with a full digital controller.

Analysis of two-stage Continuous Culture System by Transient Response of Single-stage Continuous Culture System (일단 연속 생물반응기의 과도상태 거동을 이용한 이단 연속 생물반응기의 해석)

  • 박성훈;공인수
    • KSBB Journal
    • /
    • v.7 no.4
    • /
    • pp.308-316
    • /
    • 1992
  • Two-stage continuous culture system has been studied intensively to maximize the productivity of a cloned gene product in unstable recombinant microorganism. As an effort to optimize the two-stage process, transient behavior of the second-stage was studied theoretically as well as experimentally using Escherichia coli Kl2$\delta$Hl$\delta$trp. A mathematical model describing the transient response to a step change in dilution rate was developed based on the assumption that the adaptation rate of cell growth is proportional to the available growth potential, which is defined as the difference in dilution rates between before and after shift-up. The kinetic parameters appearing in the model equations were the dimensionless step increase in growth rate($\alpha$) and the adaptation rate constant(k). These parameters were evaluated for various dilution rates and temperatures by washout method. This relatively simple adaptation model could predict the specific growth rate of the second-stage successfully. Advantage and disadvantage of the proposed model are also discussed.

  • PDF

The Study on Single Injection Locking Phenomenon for Multi-Frequency Generator Design (다중 주파수 발생기 설계를 위한 단일 인젝션 락킹 현상에 관한 연구)

  • Jeong, Seung-Hyeon;Min, Kyeong-Han;Lee, Seon-Gyu;Jeong, Jin-Won;Lee, Seung-Dae
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.14 no.6
    • /
    • pp.1037-1044
    • /
    • 2019
  • This study describes injection locking phenomena for multi-frequency generator design. For the design of the multi-frequency generator, we describe the basic theory of injection locking phenomenon and conduct a single injection locking experiment based on it. The experiments was conducted by applying injection signals that vibrates consistently to oscillators which vibrates unstablely compared to injection signals. Injection signal was applied using a Howland current source and circuit was designed using a Colpitts oscillator. The results of the experiment showed that each oscillator oscillates reliable when injection signals(840kHz, 500kHz) are injected. Through the results of a single injection locking experiment, it is confirmed that injection locking phenomena can be applied in the design of the multi-frequency generator.

A Study on Orbit Stability and Control Method for Displaced Non-Keplerian Orbits by Using Pitch Angle Variation (변위 비케플러 궤도의 안정성 분석 및 피치각 변화를 이용한 제어기법 연구)

  • Kim, Mingyu;Lee, Jeongpyo;Kim, Jeongrae
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.42 no.10
    • /
    • pp.823-832
    • /
    • 2014
  • Displaced non-Keplerian orbit, center of mass is displaced from orbit plane, enables special spacecraft missions. It requires continuous thrust to maintain the orbit, and solar sail is useful for this purpose. Equations for feasible region and stability analysis are derived for non-Keplerian orbit for general continuous thrust. Differences for solar sail spacecraft are discussed. Non-keplerian orbits are classified into four types. Location-specific required accelerations for orbit maintenance are calculated. Orbit stabilities of each orbit type are analyzed and verified by numerical simulations. In order to control non-Keplerian orbit in unstable region, a control algorithm using the real-time LQR control is developed and evaluated by numerical simulations.

Diagnosis Method and Characteristic Analysis of Shorted Turns on Generator Rotor using Flux Sensorless (자속센서리스 회전자 층간단락 진단기법 및 특성해석)

  • Kim Sun-Ja;Jeon Ywun-Seok;Lee Seung-Hak;Jeong Byung-Hwan;Lee Myung-Un;Choe Gyu-Ha
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.10 no.3
    • /
    • pp.257-263
    • /
    • 2005
  • Short-circuit rotor windings on a generator causes unstable oscillation of unbalance of flux, asymmetrical heat. In order to prevent serious accidents of short-circuit rotor windings, it is important to study the shorted-turn diagnosis method for rotor windings of the generator. To improve the defects of the diagnosis with sensors, the new sensorless method for rotor shorted-turn diagnosis is proposed, which is to measure the electrical values of the voltage and current at the generator and then to detect if the shorted-turned phenomena would occurred. For the feasibility of the suggested method the theoretical results are shown in the aspects of the air-gap flux density, the flux leakage, the generated output voltage and the shorted field current through the digital simulation. Also the possibility of decision for the suggested sensorless method could be shown in this paper.