• Title/Summary/Keyword: 분해 영향 인자

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Study of Degradation of Bisphenol A with $TiO_2$ Powder in CPC System (CPC (Compound Parabolic Collector) 내 이산화티탄을 이용한 비스페놀 A (Bisphenol A)의 분해에 관한 연구)

  • Hwang, An-Na;Park, Myung-Hee;Lim, Beom-Guk;Khim, Jee-Hyeong
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.1
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    • pp.107-112
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    • 2011
  • In this study, photocatalytic degradation and mineralization of bisphenol A (BPA), which has been listed as one of endocrine disruptors, were carried out in the CPC system using $Tio_2$ slurry and UVA irradiation. The degradation efficiency has been investigated under the controlled parameters including initial concentration (5, 10, 20 mg/L), dosage of $Tio_2$ (0.1, 0.5, 1.0 g/L), UVA power (0, 80, 120 W) and temperature (0, 20, 30). At 10mg/L of initial concentration, BPA was degraded above 80% after 10min, BPA were degraded 97% and 49% at 20 mg/L and 30 mg/L, respectively. At $Tio_2$ dosage was 0.1 and 0.5 g/L, the degradations of BPA showed similar trend and were about 70% after 1 hr, and the degradation of BPA was above 80% after 30 min at 1 g/L of $Tio_2$ dosage. The increase of degradation seem to be due to the increase in the total surface area, namely number of active sites, available for the photocatalytic reaction as the dosage of photocatalyst increased. When the UVA power was 120 W, BPA was degraded rapidly above 60% after 10min of reaction time. To investigate the effect of temperature, carried out experiment controlled temperature, there were no significant differences depending on the temperature. After 1hr, the degradation of BPA were 46%, 67%, and 69% at 10, 20 and $30^{\circ}C$.

풍력발전시스템용 증속기 신뢰성 확보 기술

  • Lee, Geun-Ho;Park, Yeong-Jun
    • Journal of the KSME
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    • v.54 no.7
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    • pp.40-45
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    • 2014
  • 풍력발전시스템은 육상용에서 해상용으로 개발되며 대형화하고 있는 추세이다. 풍력발전시스템이 해상용 등으로 대형화되면서 유지, 보수에 높은 비용이 소요되고 이에 따라 신뢰성을 확보하기 위한 요구가 더 커지고 있다. 증속기의 경우 고장 빈도도 낮지 않고, 고장 발생 시 심각도가 높아 신뢰성이 가장 높게 요구된다. 최근 증속기의 신뢰성을 확보하기 위한 연구 개발에서 수명에 가장 영항을 크게 미치는 조건으로 적용하중 영향에 대한 비토크 하중(non-torque load)과 유성기어열의 설계 인자로 취급되는 하중 분할(load sharing), 치면 하중 분포(face-load distribution) 그리고 이를 필수적으로 입증하고자 요구되는 시험/평가 기술에 대하여 소개하고자 한다.

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A development of tracking model for the cause of defect electrical sheet(grain oriented) (전기강판 GO재 재질불량원인 추적 Model개발)

  • 김상철
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 1991.10a
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    • pp.423-439
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    • 1991
  • 본 연구의 목적은 당제철소에서 생산하는 제품중 전기강판 방향성 제품의 제질(철손) 불량원인을 추적하여 조업 guidance를 제시하는 model개발이다. model개발은 현장조업 data에 대해 상관분석, 회귀분석, 분산분석등의 통계적분석을 통하여 재질에 영향을 미치는 주 관련인자들의 조업기준 재정립과 menu화면에 의한 자동 불량원인 추적 model을 개발하였으며, model개발을 위한 사용 tool은 SAS package를 활용하였다.

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내염소성을 갖는 개질 폴리아미드막의 제조 II. 이미드기를 갖는 폴리아미드의 합성

  • 오부근;이영무;김재진
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.04a
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    • pp.30-30
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    • 1993
  • 막 자체가 갖는 성능은 역삼투공정의 효율성에 영향을 미치는 상당히 중요한 인자이다. 따라서 역삼투막이 가져야 할 조건은 높은 염배제율 뿐만아니라 물의 투과유량도 커야하며, 가수분해나 산화에 의한 성능저하가 없어야 한다. 폴리아미드막을 이용한 역삼투공정은 이미 보편화되어 있으며, 특히 가교폴리아미드를 선택층으로 가지는 박층복합막은 그 성능이 우수한 것으로 알려져왔다. 폴리아미드막은 우수한 물투과유량 및 염배제율을 가지고 있어 이미 상품화 되어있지만 내화학성의 향상에 있어서는 아직도 연구개발중에 있으며, 특히 막세척시 사용되는 염소에 대한 저항성 향상이 절실히 요구되고 있는 실정이다.

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Hydrogen Peroxide Sensitive Biosensors Based on Mugwort-Peroxidase Entrapped in Carbon Pastes (탄소반죽에 쑥 과산화효소를 고정한 과산화수소 감응 바이오센서)

  • Yoon, Kil Joong
    • Applied Chemistry for Engineering
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    • v.26 no.5
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    • pp.624-629
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    • 2015
  • A biosensor including the homogenized tissue of mugwort embedded in carbon paste, which senses hydrogen peroxide, was constructed and its electrochemical properties were validated using voltammetry. The good linearity of Hanes-Woolf plot implied that the reduction reaction of substrate was catalyzed by mugwort peroxidase at the electrode surface. Also the small value of symmetry factor, 0.28, indicated that electrochemical kinetics of the sensor is very sensitive to the change of electrode potential. Many experimental results collected above proved that the dissociation of hydrogen peroxide is dependent on the catalytic power of mugwort peroxidase qualitatively and quantitatively at the surface of the mugwort electrode. It is our firm belief that the marketed HRP can be replaced with mugwort tissue.

Nutritional Factors Affecting Efficiency of a Bioremediation Process for Diesel-Contaminated Soil (경유오염 토양의 생물정화공정에 대한 영양인자의 영향 분석)

  • No, Sang-Cheol;Lee, Cheol-Hyo;Jang, Deok-Jin
    • KSBB Journal
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    • v.14 no.4
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    • pp.503-510
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    • 1999
  • In order to analyze nutritional factors affecting in situ bioremediation of diesel degradation and cell viability were studied by varying nutritional conditions. In column experiments packed with diesel-contaminated soil, nitrogen was found to be the major limiting nutrient. When nitrogen was added to soil at four different levels of C : N (100 : 5, 100 : 10, 100 : 15, and 100 : 20 mg N/kg dry soil), the greatest simulation of microbial activity occurred at the lowest, rather than the highest nitrogen addition. However, no significant effects was observed when phosphorus and air were added. No matter how the incubation mode varied, less than 50% of the diesel was remained after 7 days of treatment, presumably because the residual hydrocarbons were adsorbed on soil particles, adsorption

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Thermomechanical Analysis of Composite Structures in Pyrolysis and Ablation Environments (열분해 및 삭마 환경의 복합재 구조물의 열기계적 연계 해석)

  • Choi, Youn Gyu;Kim, Sung Jun;Shin, Eui Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.8
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    • pp.597-604
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    • 2013
  • A coupled thermomechanical analysis of composite structures in pyrolysis and ablation environments is performed. The pyrolysis and ablation models include the effects of mass loss, pore gas diffusion, endothermic reaction energy, surface recession, etc. The thermal and structural analysis interface is based upon a staggered coupling algorithm by using a commercial finite element code. The characteristics of the proposed method are investigated through numerical experiments with carbon/phenolic composites. The numerical studies are carried out to examine the surface recession rate by chemical and mechanical ablation. In addition, the effects of shrinkage or intumescence during the pyrolysis process are shown.

Destruction of Spent Organic ion Exchange Resins by Ag(II)-Mediated Electrochemical Oxidation (Ag(II)매개산화에 의한 폐 유기이온교환수지의 분해)

  • Choi Wang-Kyu;Nam Hyeog;Park Sang-Yoon;Lee Kune-Woo;Oh Won-Zin
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.183-189
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    • 1999
  • A study on the destruction of organic cation and anion exchange resins by electro-generated Ag(II) as a mediator was carried out to develop the ambient-temperature aqueous process, known as Ag(II)-mediated electro-chemical oxidation (MEO) process, for the treatment of a large quantity of spent organic ion exchange resins as the low and Intermediated-level radioactive wastes arising from the operation, maintenance and repairs of nuclear facilities. The effects of controllable process parameters such as applied current density, temperature, and nitric acid concentration on the MEO of organic ion exchange resins were investigated. The cation exchange resin was completely decomposed to $CO_2$. The current efficiency increased with a decrease in applied current density while nitric acid concentration and temperature on the MEO of cation exchange resin did not affect the MEO. On the other hand, anion exchange resins were decomposed to CO and $CO_2$. The ultimate conversion to CO was about $10\%$ regardless of temperature. The destruction efficiencies to $CO_2$ were dependent upon temperature and the effective destruction of anion exchange resin could be obtained above $60^{\circ}C$.

A Study on Synthesis and Hydrolysis of the Maleated Polyethylene Wax (무수말레인산으로 그라프트된 폴리에틸렌 왁스의 중합과 가수분해에 대한 연구)

  • Yu, Si-Won;Choi, Joong-So;Na, Jae-Sik
    • Clean Technology
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    • v.19 no.4
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    • pp.393-400
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    • 2013
  • In this study, Polyethylene wax, which was produced in manufacturing process of high density polyethylene was grafted with maleic anhydride (MAH). The influences of reaction parameters on the graft polymerization as well as the effect of hydrolysis of the anhydride functions were investigated. The results show that the grafting degree increased and conversion of maleic anhydride decreased with an increase in MAH monomer content. This means the highest grafting efficiency for the reaction can be met when MAH monomer content is about 15 wt%. DCP (dicumyl peroxide) and DTBP (di-tert-butyl peroxide) have been used as the initiator and the highest yield of grafting was obtained when the initiator content is about 0.5 wt%. However, It can be seen that the gel content values of this polyethylene wax grafted MAH were below 2%. It was also observed that the grafting degree increased with an increase in reaction temperature and the maximum value was reached 2 hours later. Although MAH functions grafted onto polyethylene wax were mainly in the carboxylic acid forms, some anhydride form of MAH appeared in over 5% of grafting degree. As a result of hydrolysis reaction, it was observed that the conversion of anhydride group into carboxylic acid group was reached up to 10%.

Object-oriented image segmentation and classification for precise digital forest type map (정밀 디지털 임상도 제작을 위한 객체지향 영상분할 및 분류)

  • Kim, So-Ra
    • Proceedings of the KSRS Conference
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    • 2008.03a
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    • pp.224-230
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    • 2008
  • 본 연구는 산림 내 임상을 구획하기 위해 고해상도 IKONOS 위성영상을 객체 지향기반으로 분할 및 분류하였다. 영상분할 시 분광정보와 공간정보를 동시에 이용하여 모양이나 분광정보에 있어서 동질한 영역이라고 정의되는 영상객체를 생성하였다. 분할된 영상을 분류계급(class)으로 분류하기 위하여 NDVI와 경사, 방위, 고도 등 지형인자를 새로운 레이어로 추가시키고, 분류개념을 형성하기 위하여 퍼지 규칙을 사용하였다. 영상의 획득시기가 5월초인 점을 감안하여 NDVI는 0.2, 경사 $^{\circ}5^{\circ}$ 그리고 고도 130m를 기준으로 산림과 비산림지역을 분류할 수 있었고, 지형인자에 영향을 많이 받는 굴참나무와 신갈나무 또한 효율적으로 분류할 수 있었다.

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