• Journal of Ocean Engineering and Technology
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• v.23 no.4
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• pp.58-63
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• 2009

Two kinds of welding methods are used for austenitic 304 stainless steel: laser welding and TIG welding. The difference in the corrosion characteristics of the welded zone between these two welding methods was investigated using electrochemical methods, such as corrosion potential measurements, polarization curves, cyclic voltammograms, etc. The Vickers hardnesses of all the welded zones (WM: Weld Metal, HAZ: Heat Affected Zone, BM: Base Metal) showed relatively higher values in the case of laser welding than for TIG welding. Furthermore, the corrosion current densities of all the welding zones showed lower values compared to TIG welding. In particular, the corrosion current density of the HAZ with TIG welding had the highest value of all the welding zones, which suggests that chromium depletion due to the formation of chromium carbide appears in the HAZ, which is in the range of the sensitization temperature. Thus, it can easily be corroded with a more active anode. Consequently, we found that the corrosion resistance of all of the welding zones for austenitic 304 stainless steel could apparently be improved by using Laser welding.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.667-673
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• 1998

Rebar corrosion in a simulated pore solution (SPS) with chloride ion was analyzed by Tafel and AC impedance method and corrosion effects of surface roughness and iron oxide layer were also investigated. Corrosion estimation of rebar by electrochemical impedance spectroscopy is very useful, and the measured value can be adapted to proposed electrochemical equivalent circuit model. Corrosion potential increased to the cathodic direction as the concentration of chloride ions increased and corrosion current had the same tendency as above. Surface films were analyzed with scanning electron microscope and Auger electron spectroscopy. Thermally oxidized layer by torch flame for 15 sec was very poor at anti-corrosive property. The corrosion rate of rebar increased as the surface roughness increased. Also, higher temperatures above RT of SPS in initial stage caused a rebar to be corroded faster.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.17 no.2
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• pp.105-108
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• 1981

The oceanic effect on the climate of the southern coast of Korea was analysed based on the sea surface temperature and in order to study relationships between the fluctuation of the sea surface temperature and that of climatic elements. Meteolorogical data from 1960 to 1979 were used. In the year when difference between the air and water temperature was maximum, the air temperature in southern coast was higher than normal year. A fluctuation of the sea surface temperature plays an important influence to determine the variation of the air temperature in the coastal area. Humidity of the coastal climate depends upon the oceanic effect in summer, but not in winter. This results may be due to prevailing wind effect. The oceanic effect on the precipitation in the coastal area is not found.

• Geophysics and Geophysical Exploration
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• v.12 no.1
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• pp.33-40
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• 2009

In field surveys using the dipole-dipole electrical resistivity method, we often encounter negative apparent resistivity. The term 'negative apparent resistivity' refers to apparent resistivity values with the opposite sign to surrounding data in a pseudosection. Because these negative apparent resistivity values have been regarded as measurement errors, we have discarded the negative apparent resistivity data. Some people have even used negative apparent resistivity data in an inversion process, by taking absolute values of the data. Our field experiments lead us to believe that the main cause for negative apparent resistivity is neither measurement errors nor the influence of self potentials. Furthermore, we also believe that it is not caused by the effects of induced polarization. One possible cause for negative apparent resistivity is the subsurface geological structure. In this study, we provide some numerical examples showing that negative apparent resistivity can arise from geological structures. In numerical examples, we simulate field data using a 3D numerical modelling algorithm, and then extract 2D sections. Our numerical experiments demonstrate that the negative apparent resistivity can be caused by geological structures modelled by U-shaped and crescent-shaped conductive models. Negative apparent resistivity usually occurs when potentials increase with distance from the current electrodes. By plotting the voltage-electrode position curves, we could confirm that when the voltage curves intersect each other, negative apparent resistivity appears. These numerical examples suggest that when we observe negative apparent resistivity in field surveys, we should consider the possibility that the negative apparent resistivity has been caused by geological structure.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.7
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• pp.890-899
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• 2014

Austenitic stainless steel is widely used in various industries due to its excellent corrosion resistance. However, Cr carbides precipitation along the grain boundaries after heat treatment or welding may develop Cr depleted zone, which acts as a preferential site for intergranular corrosion attack. To resolve this, carbon stabilizing element such as Ti or Nb are added to suppress formation of Cr carbides. However, there are few reports on corrosion characteristics under seawater environment of the stabilized stainless steel. This study investigated the effects of alloying contents on the electrochemical characteristics in seawater of stainless steel containing stabilizing element(Ti and Nb). To achieve this, the changes on the microstructure due to alloying were observed with microscope, and the electrochemical characteristics were determined by measurement of natural potential and potentiodynamic polarization experiments. The microscopic observation revealed that all specimens had inclusions other than the austenite matrix phase due to the addition of alloying elements. Such inclusions are considered to have different electrochemical characteristics from those of the matrix, and thus a clear distinction was found according to the type of stabilizers and the contents. The results of this study suggest that it is important to consider the effects of alloying contents on the electrochemical characteristics in seawater with the addition of Ti or Nb into austenitic stainless steel.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.13 no.1
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• pp.11-19
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• 2015

The production of nuclear fuel cladding tube is expected to increase with the nuclear power plant expansion. Zirconium(Zr) scrap that is generated during manufacturing is also expected to increase. Zr electrorefining experiment was carried out in the fluoride salt of LiF-KF-ZrF₄ using multiple electrode for scale up and improving throughput Zr electrorefiner develop-ment. The Zr reduction peak observed at-0.8 V(vs.Ni). Polarization behavior showed that the amount of applied current increases because of decreasing cell resistance as the number of cathode increases. Experimental results showed the highest recovery rate about 98% at lowest current density of 25.64 mA/cm² using 6 electrodes. XRD and TG analysis result show that pure Zr was recovered 99.92% and ICP analysis shows that lower impurity content than conventional impurity content of the Anode(97.8%). Electrorefining consumes energy about 7.15 kWh/kg less than 39.7% compared to the Kroll process using 6 electrode width of 20 mm and height of 65 mm. Because of increasing cell efficiency and recovery rate, using multiple cathode is determined as an efficient technique for scale up electrorefining Zr scrap.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.6
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• pp.2879-2887
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• 2011

This research is aimed for the better understanding of corrosion behavior of carbon steel in ETA or $NH_3$ solution at high temperature. To minimize the corrosion it is important to select proper pH control agent(s), which also let it maintain basic or reductive environment inside the steel pipe. This work will provide the practical guideline which can be applied to the nuclear power plant for developing the life extension method of carbon steel. Experiments were carried out by measuring the corrosion rate using the potentiodynamic polarization curve of carbon steel in ETA and NH3 at different temperatures. The corrosion rate was estimated by using the Tafel curve measured under various test conditions: i) $NH_3$ is less than ETA as a pH agent. ii) the corrosion was reduced at high pH, and iii) the corrosion was maximum in the temperature range of $150\sim200^{\circ}C$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.1
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• pp.1-5
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• 2009

In this study, we performed growth of InGaN/GaN multi quantum well (MQW) structures on semi-polar (1-10]) GaN facet on 8-degree off oriented stripe patterned (100) Si substratcs by MOVPE. The structural and optical properties of the InGaN/GaN multi quantum well (MQW) structures grown on (1-101) GaN stripe depend on $NH_3$ flow rate, TMI flow rate and growth temperature are characterized by cathodoluminescence (CL) and scanning electron microscopy (SEM). With the decrease of $NH_3$ flow rate, the threading dislocation of (1-101) GaN is considerably reduced. We could control the transition wavelength of InGaN/GaN MQW structures from 391.5 nm to 541.2 nm depend on the growth conditions.

• Journal of Advanced Marine Engineering and Technology
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• v.39 no.7
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• pp.779-785
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• 2015

Cathodic protection is recognized as the most cost-effective and technically appropriate corrosion prevention method for the submerged zone of offshore structures, ships, and deep-sea facilities. When cathodic protection is applied, the cathodic currents cause dissolved oxygen reduction, generating hydroxyl ions near the polarized surface that increase the interfacial pH and result in enhanced carbonate ion concentration and precipitation of an inorganic layer whose principal component is calcium carbonate. Depending on the potential, magnesium hydroxide can also precipitate. This mixed deposit is generally called "calcareous deposit." This layer functions as a barrier against the corrosive environment, leading to a decrease in current demand. Hence, the importance of calcareous deposits for the effective, efficient operation of marine cathodic protection systems is recognized by engineers and scientists concerned with cathodic protection in submerged marine environments. Calcareous deposit formation on a marine structure depends on the potential, current, pH, temperature, pressure, sea-water chemistry, flow, and time; deposit quality is significantly influenced by these factors. This study determines how calcareous deposits form in sea water, and assesses the interrelationship of formation conditions (such as the sea water temperature and surface condition of steel), deposited structure, and properties and the effectiveness of the cathodic protection.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.6
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• pp.709-714
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• 2018

This study researched the reasons for changing polarity in accordance with junction properties in an interface of semiconductors. The contact properties of semiconductors are related to the effect of the semiconductor's device. Therefore, it is an important factor for understanding the junction characteristics in the semiconductor to increase the efficiency of devices. For generation of various junction properties, carbon-doped silicon oxide (SiOC) was deposited with various argon (Ar) gas flow rates, and the characteristics of the SiOC was varied based on the polarity in accordance with the Ar gas flows. Tin-doped zinc oxide (ZTO) as the conductor was deposited on the SiOC as an insulator to research the conductivity. The properties of the SiOC were determined from the formation of a depletion layer by the ionization reaction with various Ar gas flow rates due to the plasma energy. Schottky contact was good in the condition of the depletion layer, with a high potential barrier between the silicon (Si) wafer and the SiOC. The rate of ionization reactions increased when increasing the Ar gas flow rate, and then the potential barrier of the depletion layer was also increased owing to deficient ions from electron-hole recombination at the junction. The dielectric properties of the depletion layer changed to the properties of an insulator, which is favorable for Schottky contact. When the ZTO was deposited on the SiOC with Schottky contact, the stability of the ZTO was improved by the ionic recombination at the interface between the SiOC and the ZTO. The conductivity of ZTO/SiOC was also increased on SiOC film with ideal Schottky contact, in spite of the decreasing charge carriers. It increases the demand on the Schottky contact to improve the thin semiconductor device, and this study confirmed a high-performance device owing to Schottky contact in a low current system. Finally, the amount of current increased in the device owing to ideal Schottky contact.