• Title/Summary/Keyword: 분극전류

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Determination of optimum protection potential for cathodic protection of offshore wind-turbine-tower steel substructure by using potentiostatic method (정전위법에 의한 해상풍력 타워 구조물용 강재의 음극방식을 위한 최적방식전위 결정)

  • Lee, Jung-Hyung;Jung, Kwang-hu;Park, Jae-Cheul;Kim, Seong-Jong
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.3
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    • pp.230-237
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    • 2017
  • In this study, electrochemical methods were used to determine the optimum protection potential of S355ML steel for the cathodic protection of offshore wind-turbine-tower substructures. The results of potentiodynamic polarization experiments indicated that the anodic polarization curve did not represent a passivation behavior, while under the cathodic polarization concentration, polarization was observed due to the reduction of dissolved oxygen, followed by activation polarization by hydrogen evolution as the potential shifted towards the active direction. The concentration polarization region was found to be located between approximately -0.72 V and -1.0 V, and this potential range is considered to be the potential range for cathodic protection using the impressed current cathodic protection method. The results of the potentiostatic experiments at various potentials revealed that varying current density tended to become stable with time. Surface characterization after the potentiostatic experiment for 1200 s, by using a scanning electron microscope and a 3D analysis microscope confirmed that corrosion damage occurred as a result of anodic dissolution under an anodic polarization potential range of 0 to -0.50 V, which corresponds to anodic polarization. Under potentials corresponding to cathodic polarization, however, a relatively intact surface was observed with the formation of calcareous deposits. As a result, the potential range between -0.8 V and -1.0 V, which corresponds to the concentration polarization region, was determined to be the optimum potential region for impressed current cathodic protection of S355ML steel.

Effect of Sr/Ta mole ratio on the ferroelectric properties of SBT thin films fabricated by LSMCD process (LSMCD 공정으로 제조한 SBT 박막의 Sr/Ta 몰비에 따른 강유전 특성)

  • 박주동;김지웅;오태성
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.360-366
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    • 2000
  • $Sr_xBi_{2.4}Ta_2O_9$ (SBT) thin films of 150 nm thickness were prepared using LSMCD (Liquid Source Misted Chemical Deposition) process with variation of the Sr/Ta mole ratio of 0.35~0.65, and their crystalline phase, microstructure, ferroelectric properties and leakage current characteristics were investigated. Ferroelectric characteristics of the LSMCD-derived SBT films were optimized at the Sr/Ta moleratio of 0.425. The remanent polarization (2Pr) and coercive field (Ec) of the SBT film with the Sr/Ta mole ratio of 0.425 were measured as 15.01 $\mu$C/$ \textrm{cm}^2$ and 41 kV/cm at an applied voltage of $\pm$5 V respectively. LSMCD-derived SBT films with the Sr/Ta mole ratio of 0.35~0.5 exhibited leakage current densities lower than $10^{-5} A/\textrm{cm}^2$ at an applied field of 100 kV/cm, and excellent fatigue-free characteristics of the remanent polarization decrement less than 1% after $10^{10}$ switching cycles at$\pm$5 V.

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Analysis of the Electromagnetic Scattering of Resistive Strip Grating with Uniform Resistivity on a Grounded Dielectric Layer - H-Polarization Case - (접지된 유전체 위의 저항율이 일정한 저항띠 격자구조에 대한 전자파 산란 해석 - H-분극인 경우 -)

  • Tchoi Young-Sun;Yang Seung-In
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.31 no.3A
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    • pp.321-327
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    • 2006
  • In this paper, when a H-polarized plane wave is incident on the grating consisting of uniform resistive strips, electromagnetic scattering is analyzed using the moment of methods (MoM). The current density of each resistive strip on a grounded dielectric plane is fixed by zero at both edges. To satisfy the condition at both ends of each resistive strip, the induced surface current density is expanded in a series of cosine and sine functions. The scattered electromagnetic fields are expanded in a series of floquet mode functions. The boundary conditions are applied to obtain the unknown current coefficients. According to the variation of the involving parameters such as strip width and spacing and angle of the incident field, numerical simulations are performed by applying the Fourier-Galerkin moment method. The numerical results of the normalized reflected power for resistive strips case for zero and several resistivities are obtained.

Spectral Inversion of Time-domain Induced Polarization Data (시간영역 유도분극 자료의 Cole-Cole 역산)

  • Kim, Yeon-Jung;Cho, In-Ky
    • Geophysics and Geophysical Exploration
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    • v.24 no.4
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    • pp.171-179
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    • 2021
  • We outline a process for estimating Cole-Cole parameters from time-domain induced polarization (IP) data. The IP transients are all inverted to 2D Cole-Cole earth models that include resistivity, chargeability, relaxation time, and the frequency exponent. Our inversion algorithm consists of two stages. We first convert the measured voltage decay curves into time series of current-on time apparent resistivity to circumvent the negative chargeability problem. As a first step, a 4D inversion recovers the resistivity model at each time channel that increases monotonically with time. The desired intrinsic Cole-Cole parameters are then recovered by inverting the resistivity time series of each inversion block. In the second step, the Cole-Cole parameters can be estimated readily by setting the initial model close to the true value through a grid search method. Finally, through inversion procedures applied to synthetic data sets, we demonstrate that our algorithm can image the Cole-Cole earth models effectively.

An Evaluation on Electrochemical Polarization Characteristics and Material Degradation for Cr-Mo-V Steel (Cr-Mo-V강의 전기화학적 분극 특성과 재질열화 평가)

  • Kwon, Il-Hyun;Lee, Song-In;Ha, Jeong-Soo;Yu, Hyo-Sun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.3
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    • pp.267-274
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    • 2002
  • This research is described on the applicability of a electrochemical techniques for evaluating nondestructive material degradation with various polarization characteristics for Cr-Mo-V steel. The applied electrochemical technique is anodic polarization test which are widely used to evaluate the corrosion rate and/or sensitization at depleted zone of strengthening elements mainly caused by thermal experience for stainless steels. The evaluation of material degradation is performed by small punch test which has been well known as micromechanics test method using specimen size of $10{\times}10{\times}0.5mm$. The 1,000hrs aged material at $630^{\circ}C$ shows the highest material degradation$({\Delta}[DBTT]_{SP})$, but the 2,000hrs and 3,000hrs aged materials show the decrease of ${\Delta}[DBTT]_{SP}$ as aging time increases. It is observed that the difference of current density $({\Delta}I_{FP}\;and\;{\Delta}I_{SP})$.

Effect of Si on the Corrosion Properties of Mg-Li-Al Light Alloy (경량화 Mg-Li-Al합금의 내식성에 미치는 Si의 영향)

  • 김순호
    • Resources Recycling
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    • v.7 no.5
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    • pp.52-57
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    • 1998
  • Effect of Si in the electrochemical corrosion characteristics of Mg-Li-Al light alloy has been investigated by means of potentiodynamic polarization study. The elecrochemical behaviors were evaluated in 003% NaCl solution and the solution buffered with KH$_{2}PO_{5}{\cdot}$NaOH at room temperature. It was found that the addition of very small quantity of Si (0.48 wt%) in Mg-Li-Al light alloy increased corrosion rates and amount of corrosion products and decreated the pitting resistance of the alloy. From the results it was concluded that Si which is added to increase the strength of Mg-Li-Al alloy is harmful to corrosion properties of the alloy.

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Study on the Characteristic due to the Various Polarity based on the Carbon Contents in Organic Thin Film (유기물 박막에서 탄소 함량에 따라서 달라지는 분극의 변화에 따른 특성 변화에 대한 연구)

  • Oh, Teresa
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.9
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    • pp.2065-2070
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    • 2010
  • The diluted PMMA treated $SiO_2$ films as an passivation materials for semiconductor devices was researched by using the FTIR spectra. The diluted PMMA solution with various ratios changed the surface of $SiO_2$ film as the hydrophilic, hydrophobic or hybrid type properties. The sample 7 with little carbon content showed dramatically the chemical variation by the FTIR spectra analysis. Beacuse the little carbon with electrons decreased the polarity and surface energy on the $SiO_2$ film, and then became a stable bonding structure and decreased the leakage current. The FTIR spectra can define the detail variation due to the chemical reaction on the organic thin film, and help to research the characteristic of the organic materials.

Preparation and Properties of $(Bi, La)Ti_3O_{12}$ Ferroelectric Thin Films by Sol-Gel Method (졸-겔법에 의한 $(Bi, La)Ti_3O_{12}$ 강유전체 박막의 형성과 특성연구)

  • 황선환;이승태;장호정;장영철
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.173-176
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    • 2002
  • B $i_{3.3}$L $a_{0.7}$ $Ti_{3}$ $O_{12}$(BLT) 강유전체 박막을 Pt/Ti/ $SiO_2$/Si 기판위에 졸-겔법 (sol-gel method) 으로 스핀코팅하여 Metal-Ferroelectric-Metal(MFM) 구조의 커패시터를 형성하였다. BLT 박막의 결정성은 후속열처리 온도가 증가할수록 향상되었으며 $R_{근}$값은 as~coated된 BLT 박막의 경우 3.8$\AA$를 나타내었으나 열처리 온도를 $700^{\circ}C$로 증가한 경우 12.9$\AA$으로 거칠은 표면형상으로 변화되었다. $650^{\circ}C$로 열처리된 BLT 박막의 잔류분극 2Pr ($\pm$($P^{*}$ -$P^{ ^}$))값은 5V 인가전압에서 약 29.1 $\mu$C/$cm^2$을 나타내었다. 또한 $10^{10}$ 스위칭 cycles 가지 분극 스위칭을 반복한 후에도 뚜렷한 잔류분극의 변화를 발견할 수 없어서 우수한 피로특성을 나타내었다. 3V 전압에서 BLT 박막의 누설전류는 약 2.2$\times$$10^{-8}$ A/$cm^2$를 나타내었다.내었다.었다.

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Recognition of Seawater Intrusion Using Reference IP Technique (참조채널 유도분극탐사기술에 의한 해수침투대 인지)

  • Lee, Sang-Kyu;Hwang, Hak-Soo;Hwang, Se-Ho;Park, In-Hwa;Shin, Je-Hyun
    • Geophysics and Geophysical Exploration
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    • v.5 no.1
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    • pp.56-63
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    • 2002
  • Tracing the history of study, problems of seawater intrusion are commonly investigated with electrical techniques because seawater saturated zone is indicative of the low resistivity anomaly. There we, however, silt and mud layers in the western and southern coastal areas of Korea, so we may make a mistake in case we determine seawater intrusion only with resistivity survey. Hence, reference IP survey was carried out in Kimje, Jeollabuk-Do and Youngkwang, Jeollanam-Do in order to decide whether or not the area is under the influence of seawater intrusion. With the use of a electric field cable to minimize EM coupling, we obtained more accurate results by appling reference If technique measuring simultaneously wavelet of current as well as potential. With the aid of reference IP technique, it is possible that we can exactly evaluate seawater intrusion by discriminating seawater saturated area (no IP effect) from very highly conductive layer composed of clay mineral (high IP effect).

Polarization Characteristics of Thermal Sprayed Coating Layer (용사코팅층의 분극특성)

  • Ahn, S.H.;Kim, S.J.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.8 no.4
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    • pp.38-43
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    • 2004
  • Thermal spraying onto the metal substrate has been widely used as a technique of the surface treatment in the various industrial field. A wide range of thermal spray technologies exist and all rely on the fundamental process of fusing a metal feedstock, atomizing it and transporting it to the surface of a substrate. Specially, these methods have been taken into account as the protection method against the corrosion. In this study, the polarization characteristics were carried out on the thermal sprayed coating layer immersed in various pH of diluted aqueous solutions at $25^{\circ}C$. Aluminum, Zinc, Ni-base alloy, alumina and polyethylene powder were used with sprayed coating materials. From the polarization curves, the electrochemical corrosion potential($E_{corr}$) and the corrosion current density($I_{corr}$) were investigated.

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