• Title/Summary/Keyword: 부피 변화

Search Result 1,090, Processing Time 0.034 seconds

College Students' Misconception about the Volume Change of Solution during Acid/Base Titration: Partial Molar Volume of Salt (산·염기 적정에서 용액의 부피 변화에 대한 대학생들의 오개념 연구)

  • Jang, Nak Han
    • Journal of Science Education
    • /
    • v.33 no.2
    • /
    • pp.317-320
    • /
    • 2009
  • I investigated Korean college students' conception about the volume change of solution when they detected the equivalence point during acid/base titration experiment using method of volume measurement. According to this study, most college students had a misconception that the volume increment was due to the formation of water by neutralization during acid/base titration. However, this is not enough to explain the volume change, neglecting contribution of a salt in solution. I calculated the partial molar volume of NaCl formed to explain the volume increment of solution during HCl/NaOH neutralization. Comparing the result of experiment with the calculation of partial molar volume, I elucidated that the main effect of volume increment was due to the partial molar volume of NaCl formed during HCl/NaOH neutralization. Here I propose to introduce college students to the concept of partial molar volume of the salt formed to reduce misconception about the volume change of solution during acid/base neutralization.

  • PDF

Free-Volume Theory for Diffusion (자유 부피 확산 이론)

  • 홍성욱
    • Membrane Journal
    • /
    • v.8 no.1
    • /
    • pp.1-10
    • /
    • 1998
  • 액체 상태에서 물질이 확산되는 현상을 자유 부피의 개념으로 해석하고자 하는 노력은 1959년에 Cohen과 Turnbull에 의해서 시작되었다. 그들은 액체의 부피를 두 부분으로 나누었는데, 하나는 분자가 차지하고 있는 점유 부피(Occupied volume)이고, 다른 하나는 자유 부피(Free-volume)로서 무작정한 열적 유동에 의해서 재분배된다. 온도의 변화에 의해 부피가 변하는 것은 이 자유 부피의 변화때문이며, 점유 부피는 온도에는 무관함 것으로 갖주하였다. 분자가 액체 상태에서 이동하려면 이웃에 충분한 크기의 자유 부피 공간이 존재해야한다. 따라서, 분자의 확산은 분자가 이들 자유 부피 공간들로 도약하는 것이다. Cohen-Turnbull의 이론에서는 순수한 액체의 자기 확산 계수(Self-diffusion conefficient)는 자유 부피의 무작정한 유동에 의하여 임계 크기의 공간이 생성되는 확률과 관련이 있다. Cohen-Turnbull 자유 부피 이론은 그 후 많은 사람들에 의해서 수정되었고, 그중에서 현재 가장 널리 사용되는 것은 Fujita의 이론과 Vrentas-Duda의 이론이다. 두 이론 모두 확산 데이터를 correlation하는데는 문제가 없으나, Vrentas-Duda의 이론만이 확산계수를 예측할 수 있는 능력이 있다. 또한, 고분자와 용매의 도약 단위의 몰 질량이 같을때에 Vrentas-Duda의 이론은 Fujita의 이론과 같아지므로, Fujita의 이론은 Vrentas-Duda의 이론의 특수한 경우라고 할 수 있다. 따라서, 본 논문에서는 Vrentas-Duda 자유 부피 이론만을 다루기로 하겠다.

  • PDF

Volume difference in upper central incisor preparation according to the changes of restorative design and marginal location (상악 중절치 삭제 시 수복 디자인과 변연부 위치에 따른 부피 변화)

  • Kim, Chong-Hyun;Park, Young-Bum;Kim, Sung-Tae;Lee, Keun-Woo
    • The Journal of Korean Academy of Prosthodontics
    • /
    • v.49 no.2
    • /
    • pp.152-160
    • /
    • 2011
  • Purpose: The aim of this study was to evaluate the volumetric change of teeth after preparation for various designs and margin locations through Micro CT analysis (Skyscan 1076: SKYSCAN, Konitch, Belgium). Materials and methods: The 36 artificial teeth were used to determine reduction volume of upper central incisor. According to the restorative design these 36 teeth were divided into 4 groups and according to the marginal location each group was divided into 3 subgroups. The volume of unprepared teeth was obtained by using Micro CT and the volume of prepared teeth was obtained in the same method. The CT scanned images before and after preparation were superimposed. Results: The volume difference was significantly increased as follows: traditional laminate veneer < full laminate veneer < all ceramic crown < metal ceramic crown. One-way ANOVA and Tukey multiple comparison analyses were used to analyze the data in this study. In each group the volume difference was significantly increased as follows: 1 mm above CEJ < CEJ < 1 mm below CEJ (P<.05). The % volume difference of all ceramic crown and metal ceramic crown was 31 - 48% and that of laminate veneer was 14 - 30%. The volume difference of the traditional laminate veneer was 1/3 of that of metal ceramic crown. The full laminate (1 mm below CEJ) and all ceramic crown (1 mm above CEJ) showed a similar volume difference. Metal ceramic crown showed 13.7% more volume difference than all ceramic crown. Conclusion: There exists the difference in volumetric change according to designs of restoration and margin locations of preparation.

A Study on the Volumetric Expansion Ratio of Rock Mass for Subsidence Behavior Analysis II (지반침하 거동특성 분석을 위한 암반의 부피팽창률에 관한 연구 II)

  • Lee, Seung-Joong;Jung, Yong-Bok;Choi, Sung-O.
    • Tunnel and Underground Space
    • /
    • v.18 no.6
    • /
    • pp.436-446
    • /
    • 2008
  • The volumetric expansion ratio of rock mass on the subsidence occurrence area can explain why the depth of the surface subsidence is lower than the height of an opening; it is because the empty space of the gangway is filled with the broken rock. But, until now, when the surface subsidence mechanism is studied without consideration of the volumetric expansion ratio, it is usually overlooked that the amount of subsidence occurrence can be overestimated. Therefore, in this study, the authors researched the subsidence occurrence mechanism with a new theoretical approaching method. The volumetric expansion ratio obtained from this method has been applied to the numerical simulations. The authors adopted the UDEC(Universal Distinct Element Code) for their discontinuum numerical analysis, because this program has an advantage for analyzing the behavior of rock discontinuities.

Neural Network Modeling for Bread Baking Process (제빵 굽기 공정의 신경회로망 모형화)

  • Kim, Seung-Chan;Cho, Seong-In;Chun, Jae-Geun
    • Korean Journal of Food Science and Technology
    • /
    • v.27 no.4
    • /
    • pp.525-531
    • /
    • 1995
  • Three quality factors of bread during baking process were measured to develop neural network models for bread baking process. Firstly, volume and browning changes during bread baking process were measured using image processing technique and temperature changes inside the bread during process were measured by K-type thermocouples. Relationships among them showed nonlinearity. Secondly, multilayer perception structure with error back propagation learning was used to construct neural network models. Three neural network models for volume, browning, and bread temperature were developed respectively. Developed models showed good performance with predictive error of 4.62% for volume and browning changes after 30 seconds, 7.38% for volume and browning changes after 2 minutes, and 1.09% for temperature change inside the bread respectively.

  • PDF

Study on the Density and Volume Change Property of Petroleum Products according to Temperature Variation (석유제품의 온도 변화에 따른 밀도 및 부피 변화 특성 연구)

  • Hwang, In-ha;Doe, Jin-woo;Kang, Hyung-kyu;Sung, Sang-rae;Ha, Jong-han;Na, Byung-ki
    • Journal of the Korean Applied Science and Technology
    • /
    • v.34 no.4
    • /
    • pp.1112-1120
    • /
    • 2017
  • Petroleum products are composed of various types of hydrocarbon compounds. Like other types of liquids, they presented the variation of density and volume according to temperature change. The method of measuring the density of petroleum products in a liquid phase is based on experimental data obtained mainly for each fractionally distilled petroleum product. In this study, the density and volume changes of kerosene and automotive diesel according to temperature change were measured and the property of change were analyzed. The conversion values were calculated using the density volume conversion table proposed by international standard ASTM. In addition, we analyzed the differences between the reference values and the measured values for the temperature changes specified in the domestic metering law.

0차원 모델을 이용한 공정장비 Scale Up 연구

  • Kim, Dong-Hwan;Lee, Yeong-Gwang;Bang, Jin-Yeong;Jeong, Jin-Uk
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.518-518
    • /
    • 2012
  • 공정 수율 향상을 위한 웨이퍼의 대면적화는 공정 반응용기의 부피변화를 수반한다. 반응용기의 부피가 커지면 플라즈마 내의 전자와 이온이 손실되는 면적이 증가하게 되고, 그 결과 공정결과에 직접적으로 영향을 미치는 전자온도와 전자밀도가 떨어지게 된다. 이렇게 변화된 플라즈마 변수들을 원래의 값으로 되돌리기 위해서는 인가전력, 실험압력, 유량과 같은 외부변수들이 조절되어야 하는데, 공간 평균 모델(global model) 식을 이용하여 외부변수들의 변량을 계산할 수가 있다. 본 연구에서는 부피가 다른 두 반응용기에서의 플라즈마 변수 진단을 통해서 부피가 커진 환경에서의 전자온도와 전자밀도가 떨어지는 현상을 관찰하였고, 공간 평균 모델로 계산된 외부변수들의 변량을 적용하였을 때 원래의 값으로 가까워 지는 경향을 볼 수가 있었다. 이렇게 같은 공정 결과를 얻기 위한 외부변수들의 변량을 간단히 계산함으로써 대면적화가 되었을 때 외부변수들을 얼마나 변화시켜야 하는지에 대한 일반적인 방향을 제시해 줄 수 있다.

  • PDF

Manufacturing and Characterization of SiC/AI Metal Matrix Composite by Modified Gas Metal Arc Welding Process ; Manufacturing and Microstructure (개조된 GMA용접공정을 이용한 SiC/AI 복합재료의 제조 및 특성)

  • Kim, Gwang-Su
    • Korean Journal of Materials Research
    • /
    • v.6 no.11
    • /
    • pp.1090-1098
    • /
    • 1996
  • 개조한 가스 금속 아아크 용접공정을 이용하여 SiC/AI 금속기 복합재료를 제조하고 그 특성을 조사하였다. AI 모재위에 강화입자의 크기와 부피분율을 변화하여 다양한 SiC/AI 복합재료층을 제조하였고, 만들어진 복합재료층의 특성은 미세조직관찰과 미소경도시험을 통하여 이루어졌다. 복합재료층의 두께는 약 7-8mm로 측정되었고 균일한 강화입자의 분포도를 얻을 수 있었다. 분산입자의 부피분률은 Ar가스의 유량에 의하여 조절하였고 분산입자의 부피분률이 증가하고 크기가 작아짐에 따라 기지의 수지상 응고조직은 더욱 미세화되었다. 복합재료의 부피경도는 분산입자의 부피분률이 감소함에 따라 낮아졌으나 입자 크기에는 크게 변화가 없는 것으로 나타났다.

  • PDF

The Change of Facial Contouring after Facial Massage (안면 수기 마사지 후 안모의 변화)

  • Im, Eun-Jin;We, Soo-Young;Jung, Da-Woon;Kim, Seong-Taek
    • Journal of Dental Rehabilitation and Applied Science
    • /
    • v.28 no.1
    • /
    • pp.103-108
    • /
    • 2012
  • This study was carried out to qualitatively examine the effect of hand massage on facial contour treatment. In the research, the hand massage was carried out to do facial treatments 2 times a week, total 20 times for 10 weeks on women in their 20s~40s. 3D Laser Scanner was used to analyze. The change of facial volume decreased by $731mm^3$ (p>.05), the thickness of cheekbone area decreased by 0.40mm(p<.05) and the thickness of mastication area decreased by 0.44mm after hand massage(p<.05) By above-mentioned findings, hand massage is likely to be an effective treatment for the reduction of facial volume, the thickness of cheekbone area and mastication area to be basic data of establishing facial line treatment methods.

A Study on the Variation of Explosion Characteristics by the Block in Closed Vessel (밀폐 공간내 Block에 의한 폭발특성 변화에 관한 연구)

  • Oh Kyuhyung;Kim Jongbok;Lee Seungeun;Kim Hong;Lee Youngchul;Park Sungsu
    • Journal of the Korean Institute of Gas
    • /
    • v.3 no.3 s.8
    • /
    • pp.23-28
    • /
    • 1999
  • Variation of explosion characteristics by the blocks in closed vessel was investigated to analyse the effect of the block volume(volume blockage) and the surface area of the blocks(ratio of block surface area to vessel volume). Volume and surface area of blocks in explosion vessel were changed by the combination of blocks. The volume of explosion vessels was 270 liter, and the LPG-air or NG-air mixtures were ignited by the electric spark. Explosion pressure was measured with the strain type pressure transducer. From the experimental results, explosion pressure was decreased by the increase of the volume blockage and the block surface area. And the decrease of explosion pressure was more affected by the volume blockage than the surface area.

  • PDF