• Title/Summary/Keyword: 부식 높이

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Experimental Study on the Effect of Specimen Size on Electrical Resistivity Measurement (전기비저항 측정에서 실험체 크기의 영향에 대한 실험적 연구)

  • Lim, Young-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.164-169
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    • 2018
  • In this study, the effect of the size of the specimen on the apparent resistivity was investigated at the laboratory level for electrical resistivity. The specimens were measured for apparent resistivity by fabricating specimens with different sides and heights. Experimental results show that the apparent resistivity increases as the side and height of the specimen become smaller. Also, it was confirmed that the influence of the size of the specimen on the electrical resistivity measurement was not linear.

Super-Hydrophobic Coating and Plasma Electrolytic Oxidation for Anti-Corrosion Property of Magnesium Alloy (초발수 코팅 및 플라즈마 전해 산화를 이용한 마그네슘합금의 내식성 향상)

  • Ju, Jae-Hun;Kim, Dong-Hyeon;Kim, Gwon-Hu;Lee, Jeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.79-79
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    • 2018
  • 마그네슘은 나트륨, 알루미늄과 함께 지구상에서 가장 풍부한 금속 중 하나로서 밀도가 약 $1.74g/cm^3$으로서 구조용 금속재료 중 가장 가볍고 우수한 비강도를 지니고 있으며, 우수한 열전도도, 전기전도도, 전자파 차폐능을 지닌다. 최근 마그네슘 및 그 합금은 항공기, 자동차, 전자제품, 기계류 및 생활용품 등에 쓰이고 있으며, 사용량 및 적용범위가 매년 급격히 증가되고 있는 추세이다. 그러나 마그네슘합금은 매우 낮은 표준 환원전위와 치밀하지 못한 표면 산화막으로 인하여 부식에 대한 저항성이 매우 취약하다는 한계를 가지고 있다. 따라서 마그네슘합금의 표면처리 가운데 부식에 대한 저항성을 보완할 수 있는 방법은 활발한 마그네슘합금의 응용에 필수적이다. 이러한 마그네슘합금의 내식성을 향상시키고자 전기화학적 플라즈마 전해 산화처리 (Plasma Electrolytic Oxidation)를 하게 되는데, 아노다이징, 화성피막처리 등 과 같은 기존의 산업적 표면처리 방안으로는 불가능한 수준의 표면경도를 확보할 수 있을 뿐만 아니라 두꺼운 산화피막 형성을 통해 이들 합금이 가진 기본적 취약점인 내식성 문제를 보완할 수 있는 장점이 있지만, 다공성 산화피막 형성만으로 기대할 수 있는 내식성 향상 효과가 매우 크지는 못하다. 따라서 다공성의 양극산화피막의 단점, 즉 다공성 물질로 부식성 물질의 이동을 허용할 수 있는 공간을 가지는 구조를 개선시킬 수 있는 추가적인 처리를 필요로 한다. 본 연구에서는 발수성 표면처리를 이용하여 다공성 구조물의 표면이 물에 대한 저항성을 가지도록 함으로써 초발수성 표면을 구현하고자 하였다. 이러한 방법은 기존의 후처리 방법인 봉공처리로는 얻을 수 없었던 다공성 구조물로의 부식성 물질의 침투를 억제할 수 있었으며, 상당한 수준의 내식성 향상 효과를 보여주었다. 또한 물에 대한 반발성은 표면에 물의 이동성을 높이는 효과를 보여주며 이로 인하여 자기세척 효과도 보여주었다.

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Development of Corrosion Detection Method for Closed U-ribs in Steel Bridges Using Ultrasonic Velocity Method (초음파 속도법을 활용한 강교 부식 손상탐지법 개발)

  • Kim, Woo-Seok;Mun, Seong-Mo;Kim, Cheol-Min;Lee, Kang-Moon;Im, Seok-Been
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.254-261
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    • 2021
  • This study was intended to develop an inspection method to detect defects in closed-cell steel members in steel girder bridges. The ultrasonic pulse velocity method was selected as a rapid and effective method to identify thickness changes of steel specimens caused by corrsion. This study developed an algorithm to expedite the process and improve the accuracy in the prediction of steel plate thickness. Also, both static and continuous scanning methods were compared to each other to identify the difference in accuracy, but the results revealed that both methods produce almost the same results. This study also provided the idea to calculate the height of water contained in the closed-cell steel member and results of laboratory experimental results. The water heights which is thicker than the steel plate thickness were detectable and predicted using the idea suggested by this study, but the water heights lower than the steel plate thickness were not possible. However, the results showed whether the steel member contains water or not.

State Classification of the Corrosion of Pipes Using a Clustering Algorithm (클러스터링 알고리즘을 이용한 배관의 부식 상태 분류)

  • Cheon, Kang-Min;Shin, Geon-Ho;Hur, Jang-Wook
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.7
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    • pp.91-97
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    • 2022
  • Pipes transport and supply fuel in various categories; however, corrosion occurs because of the external environment, impurities are mixed in the fuel, and substances leak to the outside, which can lead to serious accidents. Therefore, in this study, inspection equipment using a laser scanner was manufactured to classify conditions according to the degree of corrosion of the outer wall of the pipe, and the corrosion height and maximum value of the pipe were obtained from the surface information. Using the k-means method, it was classified into four states, and the standard of the average height and maximum height of corrosion for each state was derived.

Cathodic Protection Characteristics and Effective Length of Protection Current of Concrete Pile using Zn-mesh Sacrificial Anode (아연 메쉬 희생양극을 이용한 콘크리트 파일의 음극방식 특성 및 방식전류 유효거리)

  • Kim, Ki-Joon;Jeong, Jin-A;Lee, Woo-Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.773-776
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    • 2008
  • The corrosion of steel in concrete is significant in marine environment. Marine bridges are readily deteriorated due to the exposure to marine environment. Salt damage is one of the most detrimental causes to concrete bridges and port structures. Especially, the splash and tidal zones around water line are comparatively important in terms of safety and life-time point of view. During the last several decades, cathodic protection (cp) has been commonly accepted as an effective technique for corrosion control in concrete structures. Zn-mesh sacrificial anode has been recently developed and started to apply to the bridge column cp in marine condition. The detailed parameters regarding Zn-mesh cp technique, however, have not well understood. This study is to investigate how much Zn-mesh cp influences along the concrete column at elevated temperature. About 100cm column specimens with eight of 10cm segment rebars have been used to measure the variation of cp potential with the distance from Zn-mesh anode at both 10$^{\circ}$C and 40$^{\circ}$C in natural seawater. The cp potential change and current diminishment along the column specimens have been discussed for the optimum design of cp by Zn-mesh sacrificial anode

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Corrosion Loss of the Shell and the Bulkhead Plates of the Oil Tankers According to Their Age (유조선의 선각외판 및 격벽 부식도의 선령별 변화)

  • Park, Jung-Hee;Park, Si-Jung
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.18 no.1
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    • pp.17-23
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    • 1982
  • The corrosion loss of the shell plates and the bulkead plates of the oil tankers, nationalities of which belong to korea are determined and analyzed. The thickness of the plates are determined by use of the ultrasonic thickness meters at the check points set along the fore and aft line and the perpendicular to it. Difference between the original thickness and the determined one are given as the corrosion loss at the present age. 1. On the shell plates (1) The total mean of the corrosion loss shows the greatest value on the load water line in every age classes of the vessels. (2) The total mean of the corrosion loss on the fore and aft line shows little difference, even though it is slightly greater at the fore part, in every age classes of the vessels. (3) The corrosion loss along the perpendicular grows greater in the order of upper bilge line, light water line, freeboard line and load water line at 16 ages of the vessels, and the loss changes in the order of light water line, upper bilge line, freeboard line and load water line at 20 ages of the vessels. (4) The total mean of the corrosion loss along the light water line and upper and lower water line shows the greatest value on the fore part. That along the freeboard line and the load water line shows the greatest value on the midship part and on the after part, respectively. 2. On the bulkhead plates (1) The total mean of the corrosion loss shows the greatest value on the top part at the every age classes of the vessels. (2)The corrosion loss along the perpendicular grows greater in the order of the lower, center and upper part at every age classes of the vessels. (3) The total mean of the corrosion loss at the top part grows greater in the order of the transverse bulkhead of the side oil tank, that of center oil tank, longitudinal bulkhead of center oil tank, and transverse bulkhead of side water tank at the 20 ages of the vessels.

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Tensile Strength Change of Circular Structural member with Artificial Sectional Surface Damage (인위적 표면 단면손상 수준에 따른 원형 부재의 인장성능 변화)

  • Ha, Min-Gyun;Kwon, Tae-Yun;Lee, Won-Hong;Ahn, Jin-Hee
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.3
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    • pp.100-109
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    • 2021
  • This study was examined the tensile strength change of a circular tubular member with artificial sectional damage on its surface to consider surface sectional damage by corrosion. The tensile strength tests were conducted using circular tubular specimens with artificial sectional damage considering sectional damaged height and width on its surface according to the corrosion level. From the tensile strength test results, it is confirmed that tensile strength of the circular tubular specimens was affected by the damaged circumference (damaged width), not damaged length (damaged height) and their tensile failures were appeared at the minimum section of the artificial sectional damage part. Nonlinear finite-element analyses were conducted considering equivalent sectional damage effect on sectional damaged part in tensile specimens to examine the change in the tensile strength of tubular specimens with artificial sectional damage since it is difficult to estimate the sectional damaged surface condition of the specimens clearly. From the nonlinear finite element analysis results for the tensile test specimens, tensile strengths of test specimens with irregular sectional damaged surface were relatively evaluated to be highly decreased than these of FE analysis model with equivalent sectional damage. Therefore, residual tensile strengths of tensile members with irregular sectional damage as local corrosion can be evaluated and predicted using correlation coefficient between tensile test results and FE analysis results with equivalent sectional damage.

Monitoring of Concrete Deterioration Caused by Steel Corrosion using Electrochemical Impedance Spectroscopy(EIS) (EIS를 활용한 철근 부식에 따른 콘크리트 손상 모니터링)

  • Woo, Seong-Yeop;Kim, Je-Kyoung;Yee, Jurng-Jae;Kee, Seong-Hoon
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.651-662
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    • 2022
  • The electrochemical impedance spectroscopy(EIS) method was used to evaluate the concrete deterioration process related to chloride-induced steel corrosion with various corrosion levels(initiation, rust propagation and acceleration periods). The impressed current technique, with four total current levels of 0C, 13C, 65C and 130C, was used to accelerate steel corrosion in concrete cylinder samples with w/c ratio of 0.4, 0.5, and 0.6, immersed in a 0.5M NaCl solution. A series of EIS measurements was performed to monitor concrete deterioration during the accelerated corrosion test in this study. Some critical parameters of the equivalent circuit were obtained through the EIS analysis. It was observed that the charge transfer resistance(Rc) dropped sharply as the impressed current increased from 0C to 13C, indicating a value of approximately 10kΩcm2. However, the sensitivity of Rc significantly decreased when the impressed current was further increased from 13C to 130C after corrosion of steel had been initiated. Meanwhile, the double-layer capacitance value(Cdl) linearly increased from 50×10-6μF/cm2 to 250×10-6μF/cm2 as the impressed current in creased from 0C to 130C. The results in this study showed that monitoring Cdl is an effective measurement parameter for evaluating the progress of internal concrete damages(de-bonding between steel and concrete, micro-cracks, and surface-breaking cracks) induced by steel corrosion. The findings of this study provide a fundamental basis for developing an embedded sensor and signal interpretation method for monitoring concrete deterioration due to steel corrosion at various corrosion levels.

송전선 철탑설계에 대하여

  • 김정부;홍부식
    • 전기의세계
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    • v.28 no.10
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    • pp.9-16
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    • 1979
  • 근래 우리나라의 국민소득이 높아짐에 따라 가전제품의 수요가 늘고, 중화학공업의 발달에 따라 전력수요가 급격히 증가하고 있다. 이에 반하여 석유가는 매년 증가하고 있으므로 기력발전소를 지양하고 대용량의 원자력, 양수발전소, 석탄발전소가 건설되고 있는 경향이 있다. 발전소는 입지조건상 해안 또는 강변에 위치하고 있으며 수요지와는 거리가 멀고 또는 계통의 안전도(Stability), 신뢰도(Reliability)를 높이기 위하여 154KV와 345KV 송전선으로 전계통을 연계하고 있다. 송전선의 전력운송능력을 증대시키기 위하여 복도체 또는 사도체로 하고 있으며 전선도 ACSR에서 TACSR로 하는 나라도 있다. 현재 미국에서는 765KV Canada에서는 735KV 송전선으로 운전되고 있으며 장차 1500KV 송전선도 곧 실용화된다고 한다. 이에 따라 송전선의 지지물인 철탑도 대형화되어가고 높이도 증가하게 되어 이의 제작및 건설비가 막대하게 들게되며 앞으로는 용지확보도 더욱 어렵게 되어 송전선의 회전수를 2 또는 4회선으로 건설하여야 될것이다. 송전선철탑설계는 종래에는 Cremona도식해법에 의하여 설계하였으나 이의 작도및 하중조건이 많아지면 부재의 정확한 설계하중을 산출하는 데는 많은 시간과 노력이 필요하다. 이러한 불편을 헤소하기 위하여 Ritter의 수치해석법(moment 방법)을 이용한 전산화 및 설계이론에 대하여 소개하고자 한다.

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수돗물 중 강력한 돌연변이유발물질인 MX에 대한 분석

  • 권오영;김희갑
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2002.10a
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    • pp.153-153
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    • 2002
  • 수돗물의 염소소독 과정에서 부식질의 초기 분해생성물인 MX(Mutagen X)는 수돗물의 전체 돌연변이유발성의 최고 60%까지 차지하는 것으로 알려져 있다. 그러나 존재하는 농도는 수 ng/L로 정량분석을 위해서는 resin을 사용하여 10 ~ 20L의 물을 농축하여야 한다. 이 연구에서 MX의 농축에 사용된 resin은 XAD-4와 XAD-7HP의 1:1 mixture이었으며, 사용 전에 Soxhlet extractor를 사용하여 ethyl acetate와 methanol로 각각 12시간씩 세척하였다. 15L의 물 시료는 37%의 염산으로 pH 2에 맞춘 후 직경 2cm의 유리관에 15cm의 높이로 채워진 resin을 40mL/min의 유속으로 통과시켰다. 유리관에 잔류하는 물은 질소가스로 대부분 불어 제거한 후 ethyl acetate 200mL를 가해 1mL/min의 유속으로 흘려주어 MX를 용출시킨 후 회전증발기로 5mL의 부피까지 농축시키고 10% H$_2$SO$_4$ in MeOH 0.1mL를 가하여 6$0^{\circ}C$에서 methyl ester화하였다. 과포화된 $Na_2$SO$_4$ 수용액 0.3ml를 가한 후 MTBE 0.3mL로 추출하고 GC/ECD로 분석하였다. MX의 회수율은 60% 이상이었으며 일부수돗물 시료에 대해 분석하였다.

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