• Title/Summary/Keyword: 보론

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3-D Atom Probe Tomography and Secondary ion Mass Spectroscopy techniques for the microstructure and atomic scale investigation on the state of Boron in Steels (3차원 원자 침 분석기 (3-DAPT)와 이차이온 질량분석기 (SIMS)을 이용한 보론 첨가 강의 미세구조와 보론의 원자 단위 분석)

  • Seol, J.B.;Kang, J.S.;Yang, Y.S.;Park, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.91-94
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    • 2008
  • Newly developed Atom Probe Tomography (APT) technique can provide the highest available spatial resolution, 3D tomography imaging and quantitative chemical analysis in a sub-nm scale. As a complementary technique to APT, Nano-secondary ion Mass Spectroscopy (SIMS) also provides the boron distribution in micro-scale. Therefore, the exact behavior of boron at either grain boundary or grain interior in steels can be investigated by the combination of APT and SIMS techniques from the sub-nanometer scale to the micrometer scale. The results obtained by both APT and SIMS revealed that the boron atoms were mainly segregated to the grain boundaries rather than to the grain interior in the steels containing 50ppm and 100ppm boron. It also found that carbon atoms were segregated at the boron enriched regions, which were thought to be retained austenite phase due to the chemical composition of carbon atoms.

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Combustion Behavior in a Solid Fuel Ramjet Combustor (고체 램제트 추진기관 연소실에서의 연소 현상)

  • Lee, T. H.
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.3
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    • pp.25-30
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    • 1999
  • An experimental investigation was conducted to explore the effects of air mass flux on the combustion efficiency and particle size distributions in a solid fuel ramjet using a fuel grain highly loaded with boron carbide. Particle distributions were measured at the grain exit and at the nozz1e entrance using a Malvern 2600 HSD. Combustion efficiency increased with decreasing air mass flux. In general, the particle distribution was trimodal or quadrimodal with node peaks at approximately 4, 15, and 25$\mu\textrm{m}$ and possibly one at less than 2$\mu\textrm{m}$. The larger particles were the result of surface agglomeration, primarily within the recirculation region. Higher inlet air temperature produced higher combustion efficiencies, apparently the result of enhanced combustion of the larger boron carbide particles that burn in a diffusion controlled regime.

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Application and Verification of Virtual Manufacturing to Hot Press Forming Process with Boron Steel (보론강 핫 프레스 포밍 공정에 대한 가상생산 응용 및 검증)

  • Suh, Yeong-Sung;Ji, Min-Wook;Lee, Kyung-Hoon;Kim, Young-Suk
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.2
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    • pp.61-66
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    • 2010
  • A virtual manufacturing system that is composed of JMatPro, a material modeler and $DEFORM^{TM}$-HT, a finite element package is applied to the hot press forming process: high temperature material properties for each phase such as flow stress, elastic modulus, Poisson's ratio, thermal expansion coefficient, in addition to TTT curve are predicted by JMatPro and taken into $DEFORM^{TM}$-HT to predict the material behavior considering phase transformation and heat transfer simultaneously. In order to verify the accuracy of computation, the residual stress and the springback were compared with the experimental measurements. Both the predicted and measured principal residual stresses and amount of springback were in good agreement. It was also found that the residual stresses generated from hot press forming are not negligible as it has been generally assumed, although the springback deformation is quite small.

A Study on the Characteristics of Laser Processing in the DLC Thin Film according to Boron Doped Content (보론 도핑 여부에 따른 DLC 박막의 레이저 가공 특성 변화 연구)

  • Son, Ye-Jin;Choi, Ji-yeon;Kim, Tae-Gyu
    • Journal of the Korean Society for Heat Treatment
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    • v.32 no.4
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    • pp.155-160
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    • 2019
  • Diamond Like Carbon (DLC) is a metastable form of amorphous carbon that have superior material properties such as high mechanical hardness, chemical inertness, abrasion resistance, and biocompatibility. Furthermore, its material properties can be tuned by additional doping such as nitrogen or boron. However, either pure DLC or doped DLC show poor adhesion property that makes it difficult to apply contact processing technique. Therefore we propose ultrafast laser micromachining which is non-contact precision process without mechanical degradation. In this study, we developed precision machining process of DLC thin film using an ultrafast laser by investigating the process window in terms of laser fluence and laser wavelength. We have also demonstrated various patterns on the film without generating any microcracks and debris.

Removal of Aqueous Boron by Using Complexation of Boric Acid with Polyols: A Raman Spectroscopic Study (폴리올과 붕산의 착화합물 형성원리를 이용한 수용액 중의 보론 제거에 관한 라만 분광학 연구)

  • Eom, Ki Heon;Jeong, Hui Cheol;An, Hye Young;Lim, Jun-Heok;Lee, Jea-Keun;Won, Yong Sun
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.808-813
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    • 2015
  • Boron is difficult to be removed from seawater by simple RO (reverse osmosis) membrane process, because the size of boric acid ($B(OH)_3$), the major form of aqueous boron, is as small as the nominal pore size of RO membrane. Thus, the complexation of boric acid with polyols was suggested as an alternative way to increase the size of aqueous boron compounds and the complexation behavior was investigated with Raman spectroscopy. As a reference, the Raman peak for symmetric B-O stretching vibrational mode both in boric acid and borate ion (${B(OH)_4}^-$) was selected. A Raman peak shift ($877cm^{-1}{\rightarrow}730cm^{-1}$) was observed to confirm that boric acid in water is converted to borate ion as the pH increases, which is also correctly predicted by frequency calculation. Meanwhile, the Raman peak of borate ion ($730cm^{-1}$) did not appear as the pH increased when polyols were applied into aqueous solution of boric acid, suggesting that the boric acid forms complexing compounds by combining with polyols.

Assessment of River Water Quality Contaminated by Abandoned Mine and Hot-Spring using Principal Component Analysis (주성분분석기법을 적용한 온천 및 폐광산 오염원에 대한 하천수질평가)

  • Lee Jae-Young;Sato Yuko;Kang Meea;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.15 no.4 s.42
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    • pp.381-390
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    • 2005
  • S City depends on the T River as source water for water supply. Arsenic and boron from the hot-spring waste-water discharged from the hot-spring spa resort and emerging from the fractures of bedrock of the river have been prevalent contaminant of the T River water. This research was conducted to propose the simple and quick surrogate parameter for water quality management easily. And through making hexa-diagram of principal ions in the water samples, existing state of the water and influence of the human activity or geological origin can be figured out. As a results of characteristics of the T River water quality using principal component analysis, the contributory percentages of the 1st, 2nd and 3rd principal components were $40.80\%,\;21.40\%\;and\;11.31\%$, respectively. Therefore it was clarified that the quality of the T River water could be explained by these three principal components. Concentration of the chloride ion, which is one of the characteristics of the hot-spring water, was well correlated to both arsenic and boron concentrations. Hence concentrations of the arsenic and boron in the raw water of the water reatment plant can be predicted by the measurement of concentration of the chloride ion.

Formal Synthesis of Lespedezol $A_1$ via Versatile Palladium-Catalyzed Cross-Coupling of Diazochromanone with Arylboronic Acid (디아조크로마논과 보론산의 팔라듐 촉매하 결합반응을 이용한 Lespedezol $A_1$의 합성)

  • Han, Young Taek
    • YAKHAK HOEJI
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    • v.57 no.5
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    • pp.357-361
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    • 2013
  • A formal synthesis of Lespedezol $A_1$ has been accomplished. The key feature of this synthesis involves an efficient and powerful palladium-catalyzed cross coupling reaction of diazocarbonyl compound with bis(benzyloxy)phenylboronic acid for the key 3-aryl-chromen-4-one intermediate, which was difficult to be prepared by Suzuki coupling reaction in the previous study. The versatile and efficient synthetic procedure would facilitate synthesis of pterocarpenes and their derivatives.