• Title/Summary/Keyword: 보론

Search Result 231, Processing Time 0.028 seconds

Characterization of Aluminum Coated Layer in Hot Press Forming of Boron Steel (고온 프레스성형시 보론강 알루미늄 코팅층 거동특성)

  • Jang, Jeong-Hwan;Joo, Byeong-Don;Lee, Jae-Ho;Moo, Young-Hoon
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.21 no.4
    • /
    • pp.183-188
    • /
    • 2008
  • Hot press forming allows geometrically complicated parts to be formed from sheet and the rapid cooling hardens them to extremely high strength. The main purpose of this research is to characterize Al coated layer in Al coated boron steel during hot press forming. For the hot press hardening experiment, test specimens were heated up to $810{\sim}930^{\circ}C$ and held for 3, 6 and 9 minutes, respectively. And then, some specimens were press hardened and others were air-cooled without any pressing for the comparison purpose. Al coated layer shows four distinct micro-structural regions of interest; diffusion zone, Al-Fe zone(I) low-Al zone(LAZ) and Al-Fe zone(II). Band-like LAZ is clearly shown at temperature ranges of $810{\sim}870^{\circ}C$ and sparsely dispersed at temperature higher than 900oC. The micro-cracking behavior in the Al coated layer during forming were also analyzed by bending and deep drawing tests. The strain concentration in softer LAZ is found to be closely related with micro-cracking and exfoliation in coated layer during forming.

Effect of Hot-stamping Heat Treatment on the Microstructure of Al-Segregated Zone in TWB Laser Joints of Al-Si-coated Boron Steel and Zn-coated DP Steel (Al-Si 도금된 보론강과 Zn 도금된 DP강 TWB 레이저 용접부내의 Al-편석부 미세조직에 미치는 핫스탬핑 열처리의 영향)

  • Jung, Byung Hun;Kong, Jong Pan;Kang, Chung Yun
    • Korean Journal of Metals and Materials
    • /
    • v.50 no.6
    • /
    • pp.455-462
    • /
    • 2012
  • Al-Si coated boron steel and Zn coated DP steel plates were laser-welded to manufacture a Tailor Welded Blank (TWB) for a car body frame. Hot-stamping heat treatment ($900^{\circ}C$, 5 min) was applied to the TWB weld, and the microstructural change and transformation mechanism were investigated in the Al-rich area near the bond line of the Al-Si coated steel side. There was Al-rich area with a single phase, $Fe_3(Al,Si)$, which was transformed to ${\alpha}-Fe$ (Ferrite) after the heat treatment. It could be explained that the $Fe_3(Al,Si)$ phase was transformed to ${\alpha}-Fe$ during heat treatment at $900^{\circ}C$ for 5 min and the resultant ${\alpha}-Fe$ phase was not transformed by rapid cooling. Before the heat treatment, the microstructures around the $Fe_3(Al,Si)$ phase consisted of martensite, bainite and ${\alpha}-Fe$ while they were transformed to martensite and ${\delta}-Fe$ after the heat treatment. Due to the heat treatment, Al was diffused to the $Fe_3(Al,Si)$ and this resulted in an increase of Al content to 0.7 wt% around the Al-rich area. If the weld was held at $900^{\circ}C$ for 5 min it was transformed to a mixture of austenite (${\gamma}$) and ${\delta}-Fe$, and only ${\gamma}$ was transformed to the martensite by water cooling while the ${\delta}-Fe$ was remained unchanged.

Effect of cooling rate on the hot ductility of boron bearing steel during continuous casting (Study for prevention of corner crack on continuous casting slab) (보론 첨가강에서 연주 냉각속도가 고온연성에 미치는 영향 연구 (주편 코너 크랙 발생 방지 방안 확보 연구))

  • Cho, Kyungchul;Koo, Yangmo;Park, Joongkil
    • Korean Journal of Metals and Materials
    • /
    • v.46 no.6
    • /
    • pp.329-337
    • /
    • 2008
  • During the continuous casting of boron-bearing steel, the corner cracks on the slab are formed by deformation with low strain rate and rapid cooling at the unbending temperature within the range of 800- $1000^{\circ}C$. Especially, the rapid cooling in the corner of slab during the continuous casting leads to as corner cracking. Therefore, in this study, the hot tensile tests applied to the different cooling rates were taken into account in order to study the effect of cooling rate on the hot ductility of boron-bearing steel. The results revealed that increasing cooling rate deteriorate the hot ductility of boron- bearing steel. Rapid decreasing of the hot ductility is caused by formation of a film-like ferrite and precipitate at the austenite grain boundaries. The morphology of the precipitates in the boron-bearing steel was monitored by PTA (Particle Tracking Autoradiography) and TEM, we observed MnS and BN compound and their morphology was quite different depending on the cooling rates. When the cooling rate is increased, rodshape MnS and BN precipitates can be formed along the austenite grain boundaries. It can cause that weakening the boundary region and decreasing the hot ductility of boron-bearing steel.

Theory of Jeong, Sin-bo(鄭臣保論) - With regard to the Introduction of Neo-Confucianism to Korean Dynasty from Southern Song Dynasty (정신보론(鄭臣保論) - 남송 성리학의 고려 전래와 관련하여 -)

  • Choi, Young-song
    • The Journal of Korean Philosophical History
    • /
    • no.36
    • /
    • pp.7-42
    • /
    • 2013
  • This article is on the introduction and origin of Korean Neo-Confucianism. In this article, it is verified and clarified that a scholar named Jeong, Sin-bo (鄭臣保) from Southern Song settled on today's Seosan Ganwoldo (看月島) in the year of 1237 (24th year of the king Gojong in Korean Dynasty) and he introduced the Neo-Confucianism both by Jeong, Myung-do (程明道) and Jeong, Yi-cheon (程伊川) who are also called Double Jeong to Korean scholars. Based on these facts, it overturns the history that Anhyang (安珦) first introduced Neo-Confucianism to Korean Dynasty in the year of 1290 even with 35 years ahead. When this gains official approval by the academia, the history of Neo-Confucianism seems to be rewritten. This article first examines changes in history of Korean Neo-Confucianism with three stages and then concentrates on the life of Jeong, Sin-bo. It presents that Jeong, Sin-bo was a descendant of a Southern Song's noble family named Pogang Jeong (浦江鄭氏) and he committed to Chunqiu thoughts (春秋思想) and spirit of loyalty (義理精神) naturally as the posterity of Pogang Jeong. Lastly, it also infers the transmission of Jeong, Sin-bo's scholastic mantle and his influence on the posterity.

Effect of Vanadium and Boron on Microstructure and Low Temperature Impact Toughness of Bainitic Steels (베이나이트강의 미세조직과 저온 충격 인성에 미치는 바나듐과 보론의 영향)

  • Huang, Yuanjiu;Lee, Hun;Cho, Sung Kyu;Seo, Jun Seok;Kwon, Yongjai;Lee, Jung Gu;Shin, Sang Yong
    • Korean Journal of Materials Research
    • /
    • v.31 no.3
    • /
    • pp.139-149
    • /
    • 2021
  • In this study, three kinds of bainitic steels are fabricated by controlling the contents of vanadium and boron. High vanadium steel has a lot of carbides and nitrides, and so, during the cooling process, acicular ferrite is well formed. Carbides and nitrides develop fine grains by inhibiting grain growth. As a result, the low temperature Charpy absorbed energy of high vanadium steel is higher than that of low vanadium steel. In boron added steel, boron segregates at the prior austenite grain boundary, so that acicular ferrite formation occurs well during the cooling process. However, the granular bainite packet size of the boron added steel is larger than that of high vanadium steel because boron cannot effectively suppress grain growth. Therefore, the low temperature Charpy absorbed energy of the boron added steel is lower than that of the low vanadium steel. HAZ (heat affected zone) microstructure formation affects not only vanadium and boron but also the prior austenite grain size. In the HAZ specimen having large prior austenite grain size, acicular ferrite is formed inside the austenite, and granular bainite, bainitic ferrite, and martensite are also formed in a complex, resulting in a mixed acicular ferrite region with a high volume fraction. On the other hand, in the HAZ specimen having small prior austenite grain size, the volume fraction of the mixed acicular ferrite region is low because granular bainite and bainitic ferrite are coarse due to the large number of prior austenite grain boundaries.

A Study on Quenching Speed Prediction Method of Specimen for Evaluating the Oxide Layer of Uncoated Boron Steel Sheet (비도금 보론강판 산화층 평가용 시편의 퀜칭속도 예측기법 연구)

  • Lee, J.H.;Song, J.H.;Bae, G.H.
    • Transactions of Materials Processing
    • /
    • v.31 no.1
    • /
    • pp.17-22
    • /
    • 2022
  • Hot stamping is widely used to manufacture structural parts to satisfy requirements of eco-friendly vehicles. Recently, hot forming technology using uncoated steel sheet is being studied to reduce cost and solve patent problems. In particular, research is focused on process technology capable of suppressing the generation of an oxide layer. To evaluate the oxide layer in the hot stamping process, Gleeble testing machine can be used to evaluate the oxide layer by controlling the temperature history and the atmosphere condition. At this time, since cooling by gas injection is impossible to protect the oxide layer on the surface of a specimen, research on a method for securing a quenching speed through natural cooling is required. This paper proposes a specimen shape design method to secure a target quenching speed through natural cooling when evaluating the oxide layer of an un-coated boron steel sheet by Gleeble test. For the evaluation of the oxide layer of the un-coated steel sheet through the Gleeble test, dog-bone and rectangular type specimens were used. In consideration of the hot stamping process, the temperature control conditions for the Gleeble test were set and the quenching speed according to the specimen shape design was measured. Finally, the quenching speed sensitivity according to shape parameter was analyzed through regression analysis. A quenching speed prediction equation was then constructed according to the shape of the specimen. The constructed quenching speed prediction equation can be used as a specimen design guideline to secure a target quenching speed when evaluating the oxide layer of an un-coated boron steel sheet by the Gleeble test.

Fabrications and Analysis of Schottky Diode of Silicon Carbide Substrate with novel Junction Electric Field Limited Ring (새로운 전계 제한테 구조를 갖는 탄화규소 기판의 쇼트키 다이오드의 제작과 특성 분석)

  • Cheong Hui-Jong;Han Dae-Hyun;Lee Yong-Jae
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.10 no.7
    • /
    • pp.1281-1286
    • /
    • 2006
  • We have used the silicon-carbide(4H-SiC) instead of conventional silicon materials to develope of the planar junction barrier schottky rectifier for ultra high breakdown voltage(1,200 V grade). The substrate size is 2 inch wafer, Its concentration is $3*10^{18}/cm^{3}$ of $n^{+}-$type, thickness of epitaxial layer $12{\mu}m$ conentration is $5*10^{15}cm^{-3}$ of n-type. The fabticated devices are junction barrier schottky rectifier, The guard ring for improvement of breakdown voltage is designed by the box-like impurity of boron, the width and space of guard ring was designed by variation. The contact metals to rectify were used by the $Ni(3,000\:{\AA})/Au(2,000\:{\AA})$. As a results, the on-state voltage is 1.26 V, on-state resistance is $45m{\Omega}/cm^{3}$, maximum value of improved reverse breakdown voltage is 1180V, reverse leakage current density is $2.26*10^{-5}A/CM^{3}$. We had improved the measureme nt results of the electrical parameters.

The Study of Water Characteristics of Drinking Underground Water in the West Gyeong-Nam (서부경남지역 음용 지하수의 수질특성에 관한 고찰)

  • Park, Hyun Geoun;Jung, Youn Ho
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.36 no.3
    • /
    • pp.192-197
    • /
    • 2014
  • Water analyses were conducted on 1,525 underground water laid in the western district of Korea's South Gyeongsang Province, from January 2007 until July 2010, according to sections, factors, fountainheads and inter-factor correlativities. The following are the results. 1. As a result of local incongruity rate, 18.2% in inland areas, coastal areas and 24.5% showed a high value comparatively. Costal areas showed high incongruity rate. 2. As a result of local incongruity rate, they were found that the total colony count and general bactria 39.9%, 42.6% showed a high in costal areas. 3. As a result of local factorial inspection, it was found that the turbidity content counted up to 0 to 0.2 NTU in 59.4% in inland areas, 60.2% in costal areas of sections, and in other 12.6%, 14.0%, it exceeded 0.5 NTU. As a result of local factorial inspection, it was found that the nitrate-nitrogen content counted up to 0 to 10 mg/L in 98.2% in inland areas, 97.6% in costal areas of sections, and in other 1.8%, 2.4%, it exceeded 10 mg/L. As regards chloride in coastal areas, water quality standards for chloride 250 mg/L exceeds the 1.4% higher then in inland areas. 4. Hardness in inland areas was closely correlated with total solids (r = 0.910), sulfate ion (r = 0.819). Also, total solids and boron (r = 0.600) showed high correlativities. On the other hand hardness in coastal areas was closely correlated with total solids (r = 0.919), chloride (r = 0.829). Also sulfate ion was closely correlated with hardness (r = 0.599), turbidity and aluminum (r = 0.635) showed high correlativities in this research.

Controlling the Work Functions of Graphene by Functionalizing the Surface of $SiO_2$ Substrates with Self-assembled Monolayers

  • Jo, Ju-Mi;Kim, Yu-Seok;Cha, Myeong-Jun;Lee, Su-Il;Jeong, Sang-Hui;Song, U-Seok;Kim, Seong-Hwan;Jeon, Seung-Han;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.08a
    • /
    • pp.400-401
    • /
    • 2012
  • 그래핀(Graphene)은 열 전도도가 높고 전자 이동도(200 000 cm2V-1s-1)가 우수한 전기적 특성을 가지고 있어 전계 효과 트랜지스터(Field effect transistor; FET), 유기 전자 소자(Organic electronic device)와 광전자 소자(Optoelectronic device) 같은 반도체 소자에 응용 가능하다. 그러나 에너지 밴드 갭이 없기 때문에 소자의 전기적 특성이 제한되는 단점이 있다. 최근에는 아크 방출(Arc discharge method), 화학적 기상 증착법(Chemical vapor deposition; CVD), 이온-조사법(Ion-irradiation) 등을 이용한 이종원자(Hetero atom)도핑과 화학적 처리를 이용한 기능화(Functionalization) 등의 방법으로 그래핀을 도핑 후 에너지 밴드 갭을 형성시키는 연구 결과들이 보고된 바 있다. 그러나 이러한 방법들은 표면이 균일하지 않고, 그래핀에 많은 결함들이 발생한다는 단점이 있다. 이러한 단점을 극복하기 위해 자가조립 단층막(Self-assembled monolayers; SAMs)을 이용하여 이산화규소(Silicon oxide; SiO2) 기판을 기능화한 후 그 위에 그래핀을 전사하면 그래핀의 일함수를 쉽게 조절하여 소자의 전기적 특성을 최적화할 수 있다. SAMs는 그래핀과 SiO2 사이에 부착된 매우 얇고 안정적인 층으로 사용된 물질의 특성에 따라 운반자 농도나 도핑 유형, 디락 점(Dirac point)으로부터의 페르미 에너지 준위(Fermi energy level)를 조절할 수 있다[1-3]. 본 연구에서는 SAMs한 기판을 이용하여 그래핀의 도핑 효과를 확인하였다. CVD를 이용하여 균일한 그래핀을 합성하였고, 기판을 3-Aminopropyltriethoxysilane (APTES)와 Borane-Ammonia(Borazane)을 이용하여 각각 아민 기(Amine group; -NH2)와 보론 나이트라이드(Boron Nitride; BN)로 기능화한 후, 그 위에 합성한 그래핀을 전사하였다. 기판 위에 NH2와 BN이 SAMs 형태로 존재하는 것을 접촉각 측정(Contact angle measurement)을 통해 확인하였고, 그 결과 NH2와 BN에 의해 그래핀에 도핑 효과가 나타난 것을 라만 분광법(Raman spectroscopy)과 X-선 광전자 분광법(X-ray photoelectron spectroscopy: XPS)을 이용하여 확인하였다. 본 연구 결과는 안정적이면서 패턴이 가능하기 때문에 그래핀을 기반으로 하는 반도체 소자에 적용 가능할 것이라 예상된다.

  • PDF

A Study on Effective Relations between China's Cancellation of the Export Rebate of VAT tax and Chinese Steel Export to Korea. (중국의 수출 증치세 환급 취소가 중국산 철강재의 대한국 수출에 미치는 영향)

  • Lee, Seoung Taek
    • International Commerce and Information Review
    • /
    • v.19 no.3
    • /
    • pp.83-105
    • /
    • 2017
  • I tried to analyze export relation of influence in Chinese H beam(common steel), Hot Rolled Steel(common steel), Plate(common steel) which could be influenced immediately by China's cancellation of the export rebate of value added tax in 2010 through the statistic methods such as cointegration, Granger causality, impulse response and variance decomposition. In the first period they mutually influenced each other in export to Korea but in the second period, this relation of influence was lessoned. Due to production expansion of Hot Rolled Steel(common steel), Plate(common steel) in Korea, the change of import trend, the market change of steel users' industries and China's expedient export of boron steel to Korea, mutual influence among these products was greatly declined. Ever since Hyundai Steel's production expansion involving blast furnace facilities, there is need for the industry to concentrate on developing new markets for its facilities' output in Korea. Therefore, Korea's steel industry desperately needs strength of de-jure standards such as unique quality standards and related certifications, efficient distribution management, as well as export promotion strategy through its global trading network to effectively address its structural supply-demand imbalances.

  • PDF