• Proceedings of the Korean Fiber Society Conference
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• 2002.04a
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• pp.159-162
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• 2002

고분자 재료로써의 Poly(ethylene terephthalate)는 섬유, 필름, 용기등 다양한 용도로 널리 이용되고 있으며, 이 용도는 대부분 변형 및 배향 결정화의 응용에 그 근거를 두고 있다. 그러나 등방성 고분자의 결정화 과정에 대한 연구에 비해 배향에 의해 유도되는 결정화 과정의 경우 그 명확한 메카니즘이 밝혀지지 않았으며, 최근 고속방사 기술의 개발과 더불어 배향 결정화 과정에 대한 관심이 집중되고 있다. (중략)

• Polymer(Korea)
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• v.39 no.1
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• pp.174-179
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• 2015

Alignments of photo-reactive mesogen were induced using bare glass substrates without a polymer alignment layer. It was found by using polarized FTIR spectroscopy, polarized microscopy, and birefringence measurement experiments that the reactive mesogen could be aligned along the rubbing direction although the glass substrate without an alignment layer was used. The induction mechanism of the rubbed bare glass is ascribed to that polymers from rubbing clothes are coated on the glass substrate along the rubbing direction and lead the alignment of liquid crystals through intermolecular interactions.

• Journal of Adhesion and Interface
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• v.17 no.4
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• pp.131-135
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• 2016

We investigated the specific gravity and mechanical property changes of solid-state extruded polypropylene (PP)/talc composites before and after orientation. The specific gravity of the composites increases with increasing the filler contents. The specific gravity of the oriented specimen containing filler in PP matrix is found to be much smaller than that of pre-specimen due to the formation of more micro-voids. It was found that the tensile properties of the composites are increased up to the talc content of 10 wt%, but after the contents exceeding 10 wt%, the tensile properties are decreased. For oriented specimens, the tensile strength of the composites showed monotonously decrease with increasing talc contents. When the contents of talc is 10 wt%, the theoretical values according to Halpin-Tsai equation are close to the experimental values but over 20 wt% of talc contents, the deviation of the experimental values from the theoretical prediction becomes higher. The maximum flexural strength and modulus were observed for PP/talc composites when the talc contents was 10 wt% for both pre-specimen and oriented specimen.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.22 no.6
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• pp.587-596
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• 2009

The fiber bridging model is the crucial factor to predict or analyze the tensile behavior of fiber reinforced cementitious composites. This paper presents the fiber bridging constitutive law considering the distribution of fiber inclined angle and the number of fibers in engineered cementitious composites. The distribution of fiber inclined angle and the number of fibers are measured and analyzed by the image processing technique. The fiber distribution are considerably different from those obtained by assuming two- or three-dimensional random distributions for the fiber inclined angle. The simulation of the uniaxial tension behavior was performed considering the distribution of fiber inclined angle and number of fibers measured by the sectional image analysis. The simulation results exhibit multiple cracking and strain hardening behavior that correspond well with test results.

• The Korean Journal of Rheology
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• v.8 no.1
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• pp.49-57
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• 1996

단섬유 강화복합재료의 가공공정에 있어서 유동 중에 일어나는 섬유 배향상태를 정 확히 예측하고 제어하는 일은 대단히 중요하다. 본 연구에서는 섬유현탁액의 거동을 살펴보 기 위하여 뉴톤유체를 매질로하는 섬유현탁액을 대상으로 하여 유변학적 해석을 하였다. 이 를 위해 섬유간 상호계수는 섬유배향상태의 함수의 섬유간 평균거리를 이용하여 계산하였는 데, 섬유간 평균거리는 변형된 Doi-Edwards의 방법을 이용하였다. 축대칭 압출팽창 문제를 예로 수치모사를 하여 본 저자들이 앞서 행한 결과와 비교하였다. 유동장을 축대칭 이차원 으로 하고 섬유배향을 삼차원 모두 고려하여 구한 수치모사의 결과는 실험과 잘 일치하였 다. 진한 섬유현탁액의 경우 섬유간 상호계수는 중요한 인자로서 이것을 섬유 배향상태에 의존하는데 이섬유간 상호계수를 섬유간 거리와 섬유배향상태의 함수로 나타내는 방법을 사 용하여 보다 실제적인 해석을 할수 있었다.

• Electrical & Electronic Materials
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• v.9 no.7
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• pp.733-744
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• 1996

본 논문에서는 최근 LCD소자에 있어서 큰 이슈로 등장한 표면 액정배향기술 및 광시야각 기술에 관하여 설명하였다. 표면 액정배향기술에 있어서는 종래의 러빙법에 대신하여 편광된 자외선을 조사하여 액정분자를 배열시키는 광배향제어법이 큰 기대를 모으고 있으며, 이 기술은 프리틸트 각 발생제어기술과 신뢰성이 과제로 남아있다. 광시야각 기술에 있어서는 최근까지 여러 방식이 제안되어왔으며 그 중에서도 현재로는 광학보상법, IPS방식 등이 실용화가 진행되고 있다. 그러나 향후 다른 방식의 기술발전 여부에 따라 상황이 변화될 것으로 예상된다. 각각의 방식에 따라 서로 장단점을 지니고 있어 향후 이용분야에 따라 용도를 나누어서 응용될 것으로 기대되어진다. LCD소자는 이러한 기술개발의 결과로 평판디스플레이 소자 중에서 더욱 확고한 위치를 확보할 것이며 더 많은 시장성을 점유할 것으로 전망된다. 이상으로 본 논문에서는 LCD소자의 표면액정 배향기술 및 광시야각 기술에 관하여 해설하였으며 표면액정 배향기술에 관하여는 간단히 소개하였으나 이 내용에 관하여는 다음 기회에 상세히 소개하기로 한다.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.1
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• pp.62-68
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• 1993

During compression molding of fibre-reinforced thermoplastics, the two main problems such as the fibre-matrix separation and the fibre orientation are produced by the flow state. As the molded product tends to be nonhomogeneous and anisotropic due to the separation and the orientation, it is necessary to clarify these in relation to the molding process variables and the fibre structure (fibre entanglement). If the entanglement of fibre structure is strong, the separation increases and the orientation is not easily aligned. Namely, these are inseparably related to each other. The correlation between the separation and the orientation have to be clarified for designing the fibre structure. In this paper, the degree of nonhomogeneity which is a measure of the separation is obtained using one-dimensional rectangular shaped part compression molding. And the orientation function is defined and measured by the image processing using soft X-rayed photograph and image scanner. Correlation between the degree of nonhomogeneity and the orientation function is discussed.

• Journal of Adhesion and Interface
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• v.14 no.4
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• pp.175-182
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• 2013

In this work, we aim to investigate the specific gravity, thermal, and mechanical property changes of solid-state extruded polypropylene (PP)/calcium carbonate composites before and after orientation. For this work, we prepared $PP/CaCO_3$ composites having two different sizes (OM-1 and OM-10). On increasing the filler content, the specific gravity of the composites increases. The specific gravity of the oriented specimen containing filler in PP matrix is found to be much smaller than that of pre-specimen due to the formation of more microvoids. The presence of microvoids in case of oriented composite specimen significantly affected the tensile and flexural properties of the composites. It was observed that the effect of orientation on both flexural strength and modulus is much stronger than the effect of filler contents, regardless of the filler particle size.

• Polymer(Korea)
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• v.29 no.4
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• pp.413-417
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• 2005

Orientations of liquid crystal molecules on a surface of a film of photoreactive polyvinylcinnamate were investigated in order to apply as an alignment layer of LCD. When the polyvinylcinnamate film was exposed to linearly polarized W light, optical anisotropy was induced in the film through a selective photoreaction. Liquid crystal molecules on a surface of the film was aligned along the oriented polymer chain direction through intermolecular interactions. Thermal and light stability of the photoaligned LC cell were studied by investigating LC alignment changes after the alignment layer was treated with heat and W light. When the film was exposed with linearly polarized UV several times, the LC alignment was induced only along the final UV exposure direction.

• Polymer(Korea)
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• v.26 no.2
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• pp.209-217
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• 2002

We studied the mechanism of orientation of polyimide molecules which were irradiated by polarized UU (PUV) using polarized Fourier transform infrared (FT-IR) spectroscopy and ultraviolet (UV) spectroscopy, According to the measured UV spectra, we found PI films mainly absorb UV light less than 350 nm wavelength, therefore, UV light less than 360 nm induces photochemical reaction of PI. PUV irradiation of PI films caused decrease of all peak intensities in the FT-IR spectra. except the newly formed broad peak at $3244 cm^{-1}$, due to degradation of the PI molecules. The remaining PI molecules after photo-degradation showed predominantly perpendicular molecular orientation to the irradiated PUV polarization direction, due to the preferential degradation of PI molecules parallel to irradiated PUV polarization direction. However the rubbing of PI films induced reorientation of the PI molecules parallel to the rubbing direction. We also investigated the alignment of the liquid crystal by rubbing or PUV irradiation. Liquid crystals align perpendicular to the PUV polarization direction and parallel to the rubbing direction.