• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.11
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• pp.5357-5364
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• 2011

The objective of this study is development of carbon recycle technology which convert carbon dioxide captured from flue gas to carbon monoxide or carbon and reuse in industrial fields. Since carbon dioxide is very stable and difficult to decompose, metal oxide was used as activation agent for the decomposition of carbon dioxide at low temperature. Metal oxides which convert $CO_2$ to CO or carbon were prepared using Ba-ferrite by solid and hydrothermal synthesis. TPR/TPO and TGA were used in this study. The results of TPR by H2 and TPO by $CO_2$ showed that Ba-ferrite powders synthesized by hydrothermal method were better than those by solid method. TGA showed contrary results that reduction of Ba-ferrite powders synthesized using solid method by $H_2$ was 21.96 wt%, oxidation by $CO_2$ was 21.24 wt% and 96.72 wt% of $CO_2$ decomposition efficiency showing excellent oxidation-reduction characteristics at $500^{\circ}C$.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.555-561
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• 2011

The objective of this study is the development of carbon recycle technology which converts $CO_2$ captured from flue gas to CO or carbon and reuse in industrial fields. Since $CO_2$ is very stable and difficult to decompose, metal oxide was used as an activation agent for the decomposition of $CO_2$ at low temperature. Metal oxides which convert $CO_2$ to CO or carbon at $500^{\circ}C$ were prepared using Zn-ferrite by the solid state reaction and hydrothermal synthesis. The behaviors of $CO_2$ decomposition were studied using temperature programmed reduction/oxidation (TPR/TPO) and thermogravimetric analyzer (TGA). Zn-ferrite containing 5 wt% ZnO showed the largest reduction and oxidation. Reduction by $H_2$ was 26.53 wt%, oxidation by $CO_2$ was 25.73 wt% and 96.98% of adsorbed $CO_2$ was decomposed to $CO_2$ and carbon with excellent oxidation-reduction behaviors.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.179-179
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• 2012

국내에는 나노 분말 제조를 위한 RF 열플라즈마 시스템 제조 기술이 확보되어 있지 않고, 또한 나노 파우더 제조를 위한 공정 기술 역시 외국 업체에 전적으로 의존하고 있다. 본 연구에서는 나노 분말 제조를 위한 RF 열 플라즈마 토치 시스템 개발과 고품질의 나노 파우더 합성 공정 기술을 확립하여 필요 기관에 제공하는데 있다. 80 kW RF Plasma torch system의 설계 및 제작을 위해 플라즈마 Simulator인 CFD-ACE+를 이용하여 플라즈마 토치 및 반응로 내의 온도 분포, 유체 유동, 열전달 등의 해석을 통해 플라즈마 토치 및 반응로의 반경 및 길이, 구조의 설계 값을 도출하여 반응로를 설계하여 RF 파워, RF 플라즈마 토치(Torch), 반응기(Reactor), 사이클론(Cyclone), 포집부(Collector), 열교환기 및 진공배기 시스템으로 구성하였다. Si 나노 소재의 경우, 이차전지 음극재에 적용이 가능한 대표적인 소재로서 높음 비용량과 충/방전시 부피팽창을 감소시킬 수 있어 이차전지의 고용량 구현을 위해서는 가장 중요한 소재중 하나로 많은 관심 재료로 평가 받고 있다. 따라서 본 연구에서는 상용화된 Si 원료 powder를 사용하여 고상 분체 공급 장치를 통하여 고온의 플라즈마를 통과시켜 기상화 및 결정화과정을 통해 Si 나노분말을 제조하였다. 공정 변수로서 공정압력 및 플라즈마 power, Gas의 변화량에 따른 나노 분말의 제조 특성에 대한 실험을 진행한 후 제조된 나노 분말을 비표면적측정(BET) 및 SEM 측정 결과 분석을 통하여 시스템 특성을 파악하였으며 제조된 Si 나노 파우더는 이차전지 음극재로서 770 mAh/g의 용량과 93%@50 cycle 수준의 유지율을 나타내었다.

• Plant Journal
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• v.15 no.4
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• pp.30-35
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• 2019

To meet both increasing social demand for reduction of fine dust and the strengthened air pollutant emission standards, this paper indicated performance enhancement of FGD with structural constraints in 500 MW coal fired thermal power plant's. Through modifying internal facilities for flue gases to make swirl in the absorption tower, it made turbulence and increased the efficiency of material transfer, the reaction area and time with the limestone slurry. Therefore, it could reduce dust and enhance the performance of collecting the SO₂. As a result, desulfurization efficiency was improved from 91.61% to 98.43% and dust removal efficiency was improved from 77.4% to 87.08%. Emission density is 7.85 ppm of SO₂ and 4.67 mg/㎥ of dust. This is a level that satisfies emission limit of 25 ppm of SO₂ and 5 mg/㎥ of dust which are the air pollutant emission standards of 2023. The performance enhancement method of this study is expected to be effectively applied to other coal-fired power plants with similar constraints.

• Korean Journal of Agricultural Science
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• v.37 no.3
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• pp.501-508
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• 2010

A swirl chamber type diesel engine attachable to 18 kW agricultural tractors was improved to reduce exhaust emissions. Compression ratio and throat area ratio of the combustion chamber were varied to determine optimum combustion conditions. Tests were composed of full load and 8-mode emission tests. Compression ratio was fixed as 21, but the swirl chamber volume was increased by 3.8%. Output power, torque, specific fuel consumption, exhaust gas temperature, and smoke level were not considerably different for compression ratios of 21.5 (reference condition) and 21 (test condition), while NOx, HC, CO and PM levels for the compression ratio of 21 were decreased by 11%, 46%, 28%, 11%, respectively, from those for the compression ratio of 21.5. The tests were also conducted with a compression ratio of 22 and 4.3% increased chamber volume. Output power, torque, exhaust gas temperature and smoke level were greater, while specific fuel consumption was less for the compression ratio of 22 than those for the compression ratio of 21.5. Increase of compression ratio decreased HC and CO levels by 24%, 39%, but increased NOx and PM levels by 24%, 39%. Based on these results, a compression ratio of 21 was selected as an optimum value. Then, full load tests with the selected compression ratio of 21 were carried out for different throat ratios of 1.0%, 1.1%, 1.2%. Output power and torque were greatest and smoke was lowest when throat area ratio was 1.1%, which satisfied the target values of specific fuel consumption (less than 272 g/$kW{\cdot}h$) and exhaust gas temperature (less than $550^{\circ}C$). Therefore, a throat area ratio of 1.1% was selected as an optimum value.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1093-1096
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• 2008

This study investigated the bond behavior between recycled coarse aggregate (RCA) concrete and deformed reinforcing bars. The position (i.e., vertical, horizontal) and the location (i.e., 375mm, 225mm and 75 mm) of deformed bar were considered as a main test parameter in this paper. From the test results, it was found that maximum bond strength of top reinforcement was decreased compared with that of bottom reinforcement. Also bar embedded horizontally 225mm above from base could not satisfy bond strength requirement provided in CEB-FIP code. It was caused by the fact that bonded area at the bottom of horizontal reinforcement was significantly reduced by the poring water and laitance. In this specimen, the bond strength provided by bearing stress and wedging action of concrete was not fully observed.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.3
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• pp.291-298
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• 2010

A conventional EGR cooler, which is used in an EGR system of an automobile diesel engine, has a low heat-exchange efficiency. To maximize the heat transfer between the exhaust gas and coolant, dimples are formed on the surface of heat exchange tubes. When designing the dimpled EGR cooler, the net heat transfer areas in the conventional and dimpled tube-type EGR coolers are compared. Structural integrity evaluations are also performed by combining finite element analysis with a homogenization method. Subsequently, the process of manufacturing the dimpled tube, i.e., the formation of dimples, edge bending, center v-notch bending, compression, and plasma welding, is established and carried out. Thus, the dimpled EGR cooler is developed, and its performance is verified.

• Journal of the Korean Vacuum Society
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• v.19 no.3
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• pp.190-198
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• 2010

Asymmetric model for plasma uniformity by Ar and $CF_4$ was modeled by the antenna structure, the diameter of chamber, and the distance between source and substrate for the development of plasma equipment for 450 mm wafer. The aspect ratio of chamber was divided by diameter, distance from substrate, and pumping port area. And we found the condition with the optimized plasma uniformity by changing the antenna structure. The drift diffusion and quasi-neutrality for simplification were used, and the ion energy function was activated for the surface recombination and etching reaction. The uniformity of plasma density on substrate surface was improved by being far of the distance between substrate wall and chamber wall, and substrate and plasma source. And when the antenna of only 2 turns was used, the plasma uniformity can improve from 20~30% to 4.7%.

• Journal of Energy Engineering
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• v.25 no.2
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• pp.21-28
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• 2016

This research was conducted for the optimal design of large commercial gas oven system. Equivalent ratio was determined through a numerical analysis and experiments on the combustion condition of the combustor. After reviewing the supply capacity of burner(20,000 kcal) and control method of convection fan, two types of heat exchangers designed. In order to maintain a uniform temperature inside the oven is required convection fan braking system. The center temperature in the oven rises more rapidly when the convectional fan is rotated in the counterclockwise direction than the counter-clockwise direction. And The efficiency of the system by installing a large heat transfer area was higher.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.22-27
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• 2013

HCNG engine is performed as a future engine because of high combustion efficiency and eco-friendly property, and is predicted to a brdge of hydrogen vehicles. As EURO-6 regulagion is due to be applied in 2014, consolidated regulations of methane gas that is exhausted from CNG and HCNG vehicles will come into effect. In this studies, methane oxidation catalyst is introduced to remove methane gas from HCNG emissions. Methane oxidation efficiency on catalyst was studied when it is driven long time. And characterization like metal dispersion, surface area was performed to investigate the correlation of catalyst efficiency and characteristics.