• Resources Recycling
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• v.16 no.2 s.76
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• pp.48-55
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• 2007

A low-priced catalyst for pyrolysis of LDPE has been synthesized. Fly ash, which is waste material generated from coal-fired power plants was used as silica and alumna sources for solid acid catalyst. Amorphous silica-alumina catalysts (FSAs) were pre-pared by dissolution of silica and alumina from fly ash, followed by co-precipitation of the dissoluted ions. A series of LDPE pyrolysis were carried out in a thermogravimetric analyzer to investigate the effects of synthesis conditions such as NaOH/fly ash weight ratio and activation time one catalytic performance of FSAs. The physical properties of FSAs were examined and related to their catalytic performances. FSA(1.2-8) synthesized with NaOH/fly ash weight ratio of 1.2 and the activation time of 8 hours showed the best catalytic performance. The catalytic performance of FSA(1.2-8) was comparable with that of commercial catalysts and it was concluded that the FSA could be a good candidate for catalytic use in the recycling of waste polyolefins.

• Journal of the Korean Recycled Construction Resources Institute
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• v.5 no.4
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• pp.114-121
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• 2010

Portland cement production is under critical review due to high amount of CO2 gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. However, most study deal only with alkali-activated ground granulated blast furnace slag or fly ash, as for the combined use of the both, little information is reported. In this study, we investigated the influence of mixture ratio of fly ash/ blast furnace slag tand curing condition on the flowability and compressive strength of mortar in oder to develop cementless alkali-activated concrete. In view of the results, we found out that the mixture ratio of fly ash/blast furnace slag always results to be significant factors. But the influence of curing temperature in the strength development of mortar is lower than the contribution due to other factors. At the age of 28days, the mixture 50% fly ash and 50% ground granulated blast furnace slag activated with 1:1 the mass ratio of 9M NaOH and sodium silicate, develop compressive strength of about 65 MPa under $20^{\circ}C$ curing.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.37 no.2
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• pp.497-505
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• 2017

TDF (Tire derived fuel) Fly ash is an industrial by-product when scraped tire was used a fuel source at the power plant. TDF Fly ash has been classified as domestic waste at the workplace so far and has not been appropriately utilized. We conducted a fundamental physical property test of asphalt mixture to investigate the possibility of using TDF Fly ash as a mineral filler of asphalt mixture for exploring new usage strategies. TDF Fly ash meets KS F 3501 asphalt mixture mineral filler criteria. And the optimal asphalt binder amount was determined to be 4.5% by Marshall design. Mineral filler content was determined at 3% and analyzed by comparing using mineral filler as stone powder. The basic physical property test of the asphalt mixture was evaluated to the provision indicated in "Production and Construction Guidelines for Asphalt Mixture" published by the Ministry of Land, Infrastructure and Transport. In the test, Marshall stability test, dynamic immersion test, tensile strength ratio test, wheel tracking test were carried out. As a result of the experiment, Marshall stability and dynamic stability satisfied the standards, and confirmed the stability and Dynamic immersion and tensile strength ratio test that TDF Fly ash is more effective for scaling and moisture resistance than stone dust. Therefore, in this research, it is expected that multilateral utilization of TDF Fly ash, and a positive effect can be also expected.

• Journal of the Korean GEO-environmental Society
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• v.13 no.3
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• pp.53-58
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• 2012

In general, sand compaction pile(SCP) method and gravel compaction pile(GCP) method have been mainly used to reinforce soft soils such as soft clay or loose sandy ground. But the sand compaction pile method has problems such as lack of sand supply and destroying the nature while collecting sand, the gravel compaction pile method has a problem such as decreased permeability of the drainage material due to clogging. Recently, the study to replace sand with bottom ash which has similar engineering properties with sand is in active. As a fundamental research on bottom ash mixture compaction pile utilizing bottom ash, its behavioral characteristics depending on granular materials and replacement ratio has been simulated numerically. In particular, Settlement Reduction Ratio(SRR) according to the distance from the center of pile was calculated. The main findings were as follows. Change values of Mixture Compaction Pile's SRR according to granular materials showed similar patterns and stiffness of the composite soil is increased depending on the replacement ratio so SRR showed decreased patterns. Especially, when the replacement ratio is in 20~40%, it increase significantly. When the replacement ratio is over 40%, it increase slowly. When considering the economics, 30~40% replacement ratio is appropriate.

• Journal of the Korea Concrete Institute
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• v.23 no.3
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• pp.311-320
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• 2011

Fly ash (FA), byproduct from power plant has been actively used as mineral admixture for concrete. However, since bottom ash (BA) is usually used for land reclaim or subbase material, more active reuse plan is needed. Pond ash (PA) obtained from reclaimed land is mixed with both FA and BA. In this study, 6 PA from different domestic power plant are prepared and 5 different replacement ratios (10%, 20%, 30%, 50%, and 70%) for fine aggregate substitutes are considered to evaluate engineering properties of PA as fine aggregate and durability performance of PA concrete. Tests for fine aggregate of PA for fineness modulus, density and absorption, soundness, chloride and toxicity content, and alkali aggregate reaction are performed. For PA concrete, durability tests for compressive strength, drying shrinkage, chloride penetration/diffusion, accelerated carbonation, and freezing/thawing are performed. Also, basic tests for fresh concrete like slump and air content are performed. Although PA has lower density and higher absorption, its potential as a replacement material for fine aggregate is promising. PA concrete shows a reasonable durability performance with higher strength with higher replacement ratio. Finally, best PA among 6 samples is selected through quantitative classification, and limitation of PA concrete application is understood based on the test results. Various tests for engineering properties of PA and PA concrete are discussed in this paper to evaluate its application to concrete structure.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.1
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• pp.63-71
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• 2011

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of a by-products such as fly ash and ground granulated blast-furnace slag to partially replace the cement in concrete are gathering momentum. But most of by-products is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. In this study, we investigated the influence of alkali activator and superplasticizer on the flowability and compressive strength of the alkali-activated mortar in oder to develop cementless alkali-activated concrete using blast furnace slag. In view of the results, we found out that the type and mixture ratio of alkali activator, the type and adding order of superplasticizer results to be significant factors. When cementless alkali-activated mortar using blast furnace slag manufactured with 1:1 the mass ratio of 9M NaOH and sodium silicate, and added superplasticizer before alkali activator in the mixer, we can be secured workability with 180 mm of flow during 1 hours and compressive strength of about 50 MPa under $20^{\circ}C$ curing condition at age of 28days.

• Resources Recycling
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• v.18 no.2
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• pp.39-50
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• 2009

Portland cement production is under critical review due to high amount of $CO_2$ gas released to the atmosphere. Attempts to increase the utilization of fly ash, a by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the source of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effective in the reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in order to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.267-274
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• 2018

Though the wet bottom ash has been used as a type of lightweight aggregate, dry bottom ash, new type bottom ash from coal combustion power plant, has scarcely researched. It is excellent lightweight aggregate in the view point of construction material. This study is performed to check the applicability of dry bottom ash as a fine aggregate in lightweight aggregate concrete, by analyzing various properties of fresh and hardened concrete. We get results that the slump of concrete is within the target range at less than 75% replacement rate of dry bottom ash, the air content is not affected by the replacement rate of dry bottom ash, the bleeding capacity is less than $0.025cm^3/cm^2$ at 75% under of the replacement rate of dry bottom ash, and the compressive strength of concrete show 90% or more comparing the base mix while initial strength development is a little low. Oven dry unit weight of concrete is reduced by 8.9% when replaced 100% dry bottom ash, and dry shrinkage tends to decrease depending on increase of replacement rate of dry bottom ash. Modulus of elasticity of concrete shows no decease at 50% over of the replacement rate of dry bottom ash, while modulus of elasticity of concrete decreases when the replacement rate increases further. The dry bottom ash, when used as a fine aggregate in lightweight concrete, can be used effectively without any deterioration in quality.

• Tunnel and Underground Space
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• v.31 no.6
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• pp.623-646
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• 2021

As the demand for electric power increases with acceleration of electrification at home and abroad, the needs for coal-fired electrical power plant are accordingly increased. However, these coal-fired electrical power plants induce also many environmental problems such as increase of air pollutants, increase of possibility of land contamination by reclamation of coal ash, even though these power plants have a good economical efficiency. In case of a by-product of coal-fired electrical power plants, only 70% of them are recycled and the remaining 30% of by-product are fully buried in surrounding ground. Consequently, this study deals with coal ash backfilling mechanism in abandoned mine openings for the purposes of increasing the coal ash recycling rate as well as securing the mine area stability. In order to analyze the backfill and ground reinforcement by interaction between rock mass and backfills, the copying samples of discontinuous surface with different roughnesses were produced for bond strength tests and direct shear tests. And statistical analysis was also conducted to decide the characteristics of bond and shear behavior with joint roughness and their curing day. Numerical simulations were also analyzed for examining the effect of interface behavior on ground stability.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.373-380
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• 2023

This study investigated the carbonation of concrete brick cured in a CO₂ environment for the utilization of CO₂ captured in power plants. Concrete brick specimens were produced with electric arc furnace reducing slag (ERS) and electric arc furnace oxidizing slag (EOS), and cured for 3 days in a CO₂ chamber with a concentration of 20 % or in a constant temperature and humidity chamber. The weight change, compressive strength, flexural strength and carbonation depth of concrete bricks were measured. From the results, it was found that when subjected to CO₂ curing, CO₂ was absorbed at the level of 2.4 % of the weight of the specimen. The specimen incorporating ERS showed the highest carbonation depth, and satisfied KS F4004 standards for the concrete brick. Therefore, it is expected that the captured CO₂ can be utilized in the CO₂ curing process of concrete brick.