• Title/Summary/Keyword: 반응차수

Search Result 154, Processing Time 0.028 seconds

Three-Dimensional Vibration Analysis of Thick Shells of Revolution (두꺼운 축대칭 회전쉘의 3차원적 진동해석)

  • 강재훈;양근혁;장경호
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.15 no.3
    • /
    • pp.399-407
    • /
    • 2002
  • A three-dimensional method of analysis is presented for determining the free vibration frequencies and mode shapes of hollow bodies of revolution (i.e., thick shells), not limited to straight line generators or constant thickness. The middle surface of the shell may have arbitrary curvatures, and the wall thickness may vary arbitrarily. Displacement components$U_\Phi, U_z, U_\theta$ in the meridional, normal and circumferential directions, respectively, are taken to be sinusoidal in time, periodic in$\theta$, and algebraic polynomials in the$\Phi$and z directions. Potential(strain) and kinetic energies of the entire body are formulated, and upper bound values of the frequencies are obtained by minimizing the frequencies. As the degrees of the polynomials are increased, frequencies converge to the exact values. Novel numerical results are presented for two types of thick conical shells and thick spherical shell segments having linear thickness variations. Convergence to four digit exactitude is demonstrated for the first five frequencies of both types of shells. The method is applicable to thin shells, as well as thick and very thick ones.

A Study on the Application and Grouting Effects of Akali-Silicasol Grout Material from Field Test (현장시험을 통한 알칼리성 실리카졸 주입재의 적용성 및 주입효과에 대한 연구)

  • Kim, Younghun;Lee, Jinkyu;Yang, Hyungchil;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
    • /
    • v.13 no.8
    • /
    • pp.5-13
    • /
    • 2012
  • This research have investigated the application and the injection effect of the alkaline silicasol grouting materia (which is) recently developed. To compare the engineering characteristics of the alkaline silicasol which is formed with 3D-gel and the sodium silicate, it have studied the strength and environmental effects through the laboratory test, and field application was investigated with a review of the injection effect and waterproof through the field test. As a result of the laboratory test, unconfined compression strength of alkaline silicasol was 5 times more than sodium silicate. As a result of the leaching test, a total amount of the eluviated elements was very small, it considered the environment-friendly material. As a result of the field test, considerable reduction of the coefficient of permeability at the hydraulic layer was confirmed, and it could secure that the coefficient of permeability showed a lower than standard value of $10^{-5}cm/sec$.

Screening of Zero-Valent Metal for the Removal of High Concentration PCE and 1,1,1 TCA (고농도 PCE 및 1,1,1 TCA 제거를 위한 영가금속 선정)

  • Kwon, Soo-Youl;Kim, Young
    • Journal of Wetlands Research
    • /
    • v.12 no.1
    • /
    • pp.23-31
    • /
    • 2010
  • Chlorinated aliphatic hydrocarbons (CAHs) such as tetrachloroethylene (PCE), 1,1,1-trichloroethane (1,1,1-TCA) are the contaminants most frequently found in soil and groundwater. They have a potential to be toxic to and persistent in environment. This study is focused on selection of zero-valent metal and ores for the removal of high concentration PCE or 1,1,1-TCA and mixture of two compound. For the screening of suitable metals, we measured dechlorination rate, removal capacities and economics by using batch reactor test. This results suggest that removal rate and dechlorination of high quality iron and zinc are higher than slag and nature ores like zinc and manganese. Among nature ores, zinc ores(64% purity) have highest removal capacities. And in economics zinc ores is 10 times better than high quality metal tested. We conclude zinc ore is most suitable metal for the removal of PCE or 1,1,1-TCA.

Analysis of the Physical and Mechanical Properties of Injected High-Density Polyurethane from Laboratory Experiments and Field Tests (실내실험 및 현장실험을 통한 고밀도 폴리 우레탄 공법의 물리·역학적 특성 분석)

  • Choi, Junyoung;Kim, Daehyeon
    • The Journal of Engineering Geology
    • /
    • v.31 no.1
    • /
    • pp.83-101
    • /
    • 2021
  • The high-density polyurethane method uses the instantaneous expansion pressure of injected material to stabilize soft ground, allowing reinforcement, restoration, and construction to be carried out in suboptimal ground conditions. Under normal and, even poor conditions, the method is easily applied because the working time is very short. The method is environmentally friendly and results have excellent durability. The purpose of this study was to verify the physical and mechanical properties of high-density polyurethane in the ground. Initial testing of strength, direct shear, and soil environment stability was followed by testing for permeability in order to address environmental concerns. The results of the experiments showed that the internal friction angle was about twice as high and the adhesion was about 2.5 to 3.5 times higher than for dense and hard clay, and that the permeability factor was significantly lower compared with the existing grouting method, within the range of 1.0 × 10-5.

Thermoluminescence Kinetics of LYGBO Crystal (LYGBO 단결정의 열형광 전자포획준위 인자)

  • Sunghwan, Kim
    • Journal of the Korean Society of Radiology
    • /
    • v.17 no.1
    • /
    • pp.17-23
    • /
    • 2023
  • In this study, the thermoluminescence kinetics of electron trap in Li6Y0.5Gd0.5(BO3)3 (LY0.5G0.5BO) scintillator for neutron detection composed of Li, Gd, and B with a high neutron response cross-section were investigated. The thermoluminescence glow curve of the LY0.5G0.5BO scintillation single crystal was measured and analyzed using the peak shape method, the initial rise method, and the machine learning algorithm to evaluate the physical parameters of the electron trap. The glow curve of the LY0.5G0.5BO scintillation single crystal consisted of a single peak. As a result of analyzing this peak, the activation energy, emission order, and frequency factor of the electron trap were 0.61 eV, 1.1, and 1.7×107 s-1, respectively. In addition, the possibility of thermoluminescence analysis of scintillators using machine learning was confirmed.

The Potential Energy Recovery and Thermal Degradation of Used Tire Using TGA (열분석법을 이용한 사용후 타이어의 열적 특성과 포텐셜 에너지의 회수)

  • Kim, Won-Il;Kim, Hyung-Jin;Hong, In-Kwon
    • Elastomers and Composites
    • /
    • v.34 no.2
    • /
    • pp.135-146
    • /
    • 1999
  • The thermal degradation kinetics of SBR and tire were studied using a conventional thermogravimetric analysis in the stream nitrogen at a heating rate of 5, 10, 15, $20^{\circ}C/min$, respectively. Thermogravimetric curves and their derivatives were analyzed using various analytical methods to determine the kinetic parameters. The degradation of the SBR and tire was found to be a complex process which has multi-stages. The Friedman method gave average activation energies for the SBR and tire of 247.53kJ/mol and 230.00kJ/mol, respectively. Mean-while, the Ozawa method Eave 254.80kJ/mol and 215.76kJ/mol. It would appear that either. Friedman's differential method or Ozawa's integral method provided satisfactory mathematical approaches to determine the kinetic parameters for the degradation of the SBR and tire. Approximately 86% and 55% of oil products were obtained at a final temperature of $700^{\circ}C$ and a heating rate of $20^{\circ}C/min$ for the SBR and tire respectively.

  • PDF

Correlation between Glycemic Index and in vitro Starch Hydrolysis of Cereals (곡류의 혈당지수와 전분 가수분해율과의 상관관계)

  • Lee, Jung-Sun;Shin, Hyun-Kyung
    • Korean Journal of Food Science and Technology
    • /
    • v.30 no.5
    • /
    • pp.1229-1235
    • /
    • 1998
  • To see the correlation between the rate of in vitro starch hydrolysis and the glycemic index, an in vitro digestion was carried out by incubating the cereal samples for 2 hours with ${\alpha}-amylase$ in dialysis tubing. Also the levels of blood glucose were measured over 2 hours after feeding healthy volunteers with 50 g carbohydrate portions. Hydrolysis area, hydrolysis index (HI) and the dialysate content of carbohydrate throughout the digestion time for barley was significantly below those for other cereals (p<0.05), and unpolished glutinous rice was significantly above (p<0.05). The GI-glucose of barley $(57%{\pm}7)$ to glucose as standard was significantly (p<0.05) lower than those of other cereals whereas the GI-glucose of glutinous rice $(110%{\pm}8)$ was significantly higher (p<0.05) than other cereals. The GI-rice values to rice as standard were $122%{\pm}4$ for glutinous sorghum, $116%{\pm}13$ for job's tear, $115%{\pm}13$ for glutinous millet, $106%{\pm}6$ for unpolished glutinous rice, $102%{\pm}7$ for glutinous rice, $100%{\pm}0$ for rice, $90%{\pm}12$ for unpolished rice, $85%{\pm}6$ for foxtail millet, $79%{\pm}5$ for buckwheat and $63%{\pm}6$ for barley. The GI-rice was significantly correlated to hydrolysis area and HI (r=0.75, p<0.01). It suggests that the in vitro starch hydrolysis offers good potential to predict the in vivo glycemic response of starch foods.

  • PDF

A Case Studty on the Ground Reinforcement and Waterproofing Effect of Weathering and Fault Zone by Special Injection Tip Equipment Using Microcement Type (특수주입선단장치에 의한 마이크로시멘트계 약액주입의 풍화대, 단층파쇄대의 지반보강 및 차수효과 사례연구)

  • Do, Jongnam;Jung, Jongju;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
    • /
    • v.10 no.2
    • /
    • pp.21-28
    • /
    • 2009
  • A grouting method has been widely used in construction of large-scale structure to reduce permeability and reinforce the ground. If cement and grout material were not mixed well in the injection tip equipment, an opposite flow and interception state of the chemical grouting can occur. McG (Multi-mixing counterflow prevented Grouting, McG) method installed a special grouting device to allow better mixing of the grouting material(above fineness $6,000cm^2/g$) and prevent backward flow. The block of nozzle also diversify powder rate of cement. YSS (Youngil Special Silicate, YSS) that lowers $Na_2O$ and thereby increases durability was developed by gel-forming reaction material. The seepage state and unconfined compressive strength of the injection material using the special injection tip equipment was tested in this study. The results of this study showed that the uniaxial compressive strength, permeability, N-value, TCR and RQD were improved by this method. Engineering characteristics obtained by the special injection tip method will be compared with those by the other method through various field tests from now on.

  • PDF

Removal of Aqueous Cyanide through the Utilization of Industrial By-products (산업부산물(제강 Sludge, 제강 Slag)을 이용한 시안 흡착 제거)

  • 이정원;현재혁;조재범
    • Journal of Korea Soil Environment Society
    • /
    • v.3 no.2
    • /
    • pp.89-99
    • /
    • 1998
  • Sorption of the aqueous cyanide onto steel mill sludge and steel mill slag, both of which are the by-products from the converter furnace, was studied. In the study, the influence of temperature, activation energy, concentration and pH on sorption of cyanide was investigated. Three different temperature($25^{\circ}C$ > $37^{\circ}C$> $50^{\circ}C$) was chosen to represent that of landfill leachate. Initial concentration was 1 mg/$\ell$ 5 mg/$\ell$, 10 mg/$\ell$, and 20 mg/$\ell$. In addition, pH was set to three different level, that is, 3, 7, and 11 respectively. As the result of batch mode experiment for cyanide adsorption, the removal rate was found to be proportional to the initial concentration of cyanide. The order of removal rate was 20 mg/$\ell$> 10 mg/$\ell$> 5 mg/$\ell$> 1 mg/$\ell$. Similarly the influence of pH was proportional because of the change in solubility of cyanide. The order of removal rate was pH 11 > pH 7 > pH 3. As the temperature increased, so did the removal rate. The reaction was endothermic and the value of activation energy(Ea) was 127.93 J/mole and 59.44 J/mole respectively at 1 mg/ιand 20 mg/ιof initial concentration. From the experiment, it can be postulated that the capability of steel mill by-products to attenuate aqueous cyanide is enough to be used as substitute for clay liner of landfill site in the aspect of pollutant removal.

  • PDF

Application of UV Curable Coating for the Surface Protection of Polymeric Materials: PVC and Polystyrene (고분자 물질의 표면 보호를 위한 자외선 경화 도료의 응용)

  • Moon, Myung-Jun;Park, Jin-Hwan;Lee, Gun-Dae;Suh, Cha-Soo;Kim, Jong-Rae
    • Applied Chemistry for Engineering
    • /
    • v.2 no.2
    • /
    • pp.175-184
    • /
    • 1991
  • Ultraviolet curable coatings are often used to protect the surface of polymer materials exposed to the ultraviolet radiation. However, the adhesion of epoxy acrylate on poly(vinyl chloride) and the UV curable coating on polystyren are poor. The objective of this work was to improve the adhesion of coating according to various formulations of the reactive diluents and finishing methods using the photografting of multifunctional acrylate and the surface activation on polymer surface impregnated a phtoinitiator. The addition of Tripropylene glycole diacrlate in the formulation of coating results in the improvement of adhesion of coating due to the flexibility. But the increase of the crosslinking density which results from the oxidation of surface during the exposure of UV radiation caused the loss of adhesion of coating exept the photografting method. In the trimethylolpropane triacrylate the improvement of adhesion are considerable due to the chemical bond between multifundtional acrylate and surface. From this work we expect to achieve the varity and functionality in the formulation of coating according to the photografting and surface activating of polymer.

  • PDF