• Title/Summary/Keyword: 반응시간 분석

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Synthesis of 2,2'-Iminodibenzoic Acid-Cellulose Adsorbent and Its Adsorptivity of Cu(II) and Pb(II) (2,2'-Iminodibenzoic acid-cellulose 흡착제의 합성과 Cu(II) 및 Pb(II)의 흡착에 관한 연구)

  • Shim, Sang-Kyun;Min, Byoung-Do
    • Analytical Science and Technology
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    • v.10 no.4
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    • pp.291-299
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    • 1997
  • 2,2'-iminodibenzoic acid-cellulose was prepared by reacting 2,2'-iminodibenzoic acid salt with cellulose-Cl obtained by chlorination of cellulose-OH which is the major component of sawdust. The adsorptivity of Pb(II) and Cu(II) was studied using the synthetic chelating adsorbent. The adsorption amounts of those ions increased with increasing pH and the optimum adsorption time of metal ion was about 1hr. The adsorptivity of Pb(II) was larger than that of Cu(II).

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Spectroscopic Studies on Crystallization of Na, TPA-ZSM-5 synthesized at Low Temperature and Atomospheric pressure (저온 상압에서 합성된 Na, TPA-ZSM-5의 결정화에 관한 분광학적 고찰)

  • Yun, Young Ja;Ha, Jae Mok
    • Analytical Science and Technology
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    • v.10 no.1
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    • pp.18-30
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    • 1997
  • Na, TPA-ZSM-5 with Si / Al mole ratio of about 130 was synthesized at low temperature and atmospheric pressure. These intermediate products were characterized by using XRD, XRF, FT-IR, NMR, and SEM. As a result, intermediate product were different from those that synthesized by autoclave method but spectroscopic characteristics of the final products showed to be in the typical ZSM-5 region. The defect sites were observed in the final product and removed by calcination at $540^{\circ}C$. Na, TPA-ZSM-5, aboveall, was synthesized at this condition within 48hr.

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Behavior Analysis in Love Model of Romeo and Juliet with Time Delay (시간지연을 갖는 로미오와 줄리엣의 사랑모델에서의 거동해석)

  • Huang, Linyun;Bae, Young-Chul
    • Journal of the Korean Institute of Intelligent Systems
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    • v.25 no.2
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    • pp.155-160
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    • 2015
  • We say that human have an animal of emotion. There are various kind in the emotion of human. One of among them, love has been studied in sociology and psychology as a matter of great concern. In this paper, we propose a novel love model with the delay time as response time for love. We also consider it in the Romeo and Juliet of love model to analyze their romantic behaviors. First we consider the Juliet only have a time delay, Romeo only have a time delay, and both Romeo and Juliet have a time delay. We represent their behaviors as time series and phase portrait, and we analyze their difference.

Similarity Model Analysis and Implementation for Enzyme Reaction Prediction (효소 반응 예측을 위한 유사도 모델 분석 및 구현)

  • Oh, Joo-Seong;Na, Do-Kyun;Park, Chun-Goo;Ceong, Hyi-Thaek
    • The Journal of the Korea institute of electronic communication sciences
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    • v.13 no.3
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    • pp.579-586
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    • 2018
  • With the beginning of the new era of bigdata, information extraction or prediction are an important research area. Here, we present the acquisition of semi-automatically curated large-scale biological database and the prediction of enzyme reaction annotation for analyzing the pharmacological activities of drugs. Because the xenobiotic metabolism of pharmaceutical drugs by cellular enzymes is an important aspect of pharmacology and medicine. In this study, we apply and analyze similarity models to predict bimolecular reactions between human enzymes and their corresponding substrates. Thirteen models select to reflect the characteristics of each cluster in the similarity model. These models compare based on sensitivity and AUC. Among the evaluation models, the Simpson coefficient model showed the best performance in predicting the reactivity between the enzymes. The whole similarity model implement as a web service. The proposed model can respond dynamically to the addition of reaction information, which will contribute to the shortening of new drug development time and cost reduction.

Characteristics of low temperature pyrolysis of LDPE, PS, ABS plastics (저온열분해조건에서 LDPE, PS, ABS의 열분해생성물 생성특성)

  • Cha, Wang-Seog;Jang, Hyun-Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.468-470
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    • 2008
  • 열중량반응기와 미분반응기를 이용하여 ABS의 열분해 및 생성물분포 특성을 연구하였으며 미분반응기를 이용한 실험의 열분해온도는 $410{\sim}450^{\circ}C$이었다. 각 상의 열분해생성물의 수율은 무게측정을 통해 얻었으며 액상생성물의 탄소수분포는 GC-SIMDIS 방법을 통해 측정하였다. 열중량 분석실험에서는 측정할 수 없었던 다량의 고상잔류물의 생성을 회분식 미분반응기실험을 통해 확인할 수 있었다. 반응온도와 시간이 증가할수록 액상생성물의 수율과 평균분자량은 감소하였으나 액상생성물 중의 스티렌모노머의 생성은 두드러지게 증가하였다. ABS 열분해 반응에서 말단절단의 속도계수인 활성화에너지 값은 54.1kcal/mole이었다.

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Reduction Rate of Electric Arc Furnace Dust with Solid Carbon (전기로 더스트의 고체탄소에 의한 환원반응속도)

  • 박병구;이광학;김영홍;신형기
    • Resources Recycling
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    • v.7 no.1
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    • pp.34-40
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    • 1998
  • This shdy was invcsligated on reduction rate of EAF dust wth solid carbon cantents. The rate equation for reduction ofEAF dust was obtaincd in the tempcrahlrc range cot 910-108O"C, and the ratio of zinc removal and metallization raho of ironoxides to thc reaction time was also analysed. From the XRD analysis for slag residues '||'&'||'er reaction, the cxistcncc DI themixture of Akemmite[Ca2MgSi2O.] and SiO, was identified.ed.

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The Unsupervised Learning-based Language Modeling of Word Comprehension in Korean

  • Kim, Euhee
    • Journal of the Korea Society of Computer and Information
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    • v.24 no.11
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    • pp.41-49
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    • 2019
  • We are to build an unsupervised machine learning-based language model which can estimate the amount of information that are in need to process words consisting of subword-level morphemes and syllables. We are then to investigate whether the reading times of words reflecting their morphemic and syllabic structures are predicted by an information-theoretic measure such as surprisal. Specifically, the proposed Morfessor-based unsupervised machine learning model is first to be trained on the large dataset of sentences on Sejong Corpus and is then to be applied to estimate the information-theoretic measure on each word in the test data of Korean words. The reading times of the words in the test data are to be recruited from Korean Lexicon Project (KLP) Database. A comparison between the information-theoretic measures of the words in point and the corresponding reading times by using a linear mixed effect model reveals a reliable correlation between surprisal and reading time. We conclude that surprisal is positively related to the processing effort (i.e. reading time), confirming the surprisal hypothesis.

Optimization of Enzymatic Synthesis Condition of Structured Lipids by Response Surface Methodology (반응표면분석에 의한 기능성 유지의 효소적 합성 조건 최적화)

  • Cho, Eun-Jin;Lee, Jong-Ho;Lee, Ki-Teak
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.531-536
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    • 2004
  • Synthesis conditions were optimized using response surface methodology for producing structured lipids (SL) by interesterification of DHA-enriched algae oil derived from microalgae, Schizochytrium sp. and corn oil. Reaction was performed fer 24 hr at $55^{\circ}C$ catalyzed by immobilized lipase from Rhizomucor miehei (RM IM) in shaking water bath. Major fatty acids of SL were palmitic (21.70 mol%), oleic (20.20 mol%), and linoleic (27.34 mol%) acids, and DHA (15.06 mol%). To separate newly synthesized SL-triglycerides (TG) species, HPLC with evaporative light scatting detector (ELSD) was used. Production conditions were optimized using central composite design with reaction temperature $(35-75^{\circ}C,\;X_1)$, reaction time $(2-42\;hr,\;X_2)$, and enzyme concentration $(2-14%,\;X_3)$ as variables. When variables were $70.28^{\circ}C\;(X_1),\;28.74\;hr\;(X_2),\;and\;11.30%\;(X_3)$, maximum content of selected three peaks of synthesized SL-TG species was predicted as 6.97 area%.

A Study on the Utilization of By-products from Honeyed Red Ginseng: Optimization of Total Ginsenoside Extraction Using Response Surface Methodology (홍삼정과 제조 부산물 이용에 관한 연구: 반응표면분석을 이용한 총 진세노사이드 추출조건의 최적화)

  • Lee, Eui-Seok;You, Kwan-Mo;Kim, Sun-Young;Lee, Ka-Soon;Park, Soo-Jin;Jeon, Byeong-Seon;Park, Jong-Tae;Hong, Soon-Taek
    • Food Engineering Progress
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    • v.21 no.1
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    • pp.79-87
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    • 2017
  • This study was carried out to extract ginsenosides in by-products from honeyed red ginseng. Response surface methodology (RSM) was used to optimize the extraction conditions. Based on D-optimal design, independent variables were ethanol (extraction solvent) concentration (30-90%, v/v), extraction temperature ($25-70^{\circ}C$), and extraction time (5-11 h). Extraction yield (Y1) and total ginsenosides (Y2) in the extract were analyzed as dependent variables. Results found that extraction yield increased with increasing extraction temperature and time, whereas it was decreased with increasing ethanol concentration. Similar trends were found for the content of ginsenosides in the extracts, except for ethanol concentration, which was increased with increasing ethanol concentration. Regression equations derived from RSM were suggested to coincide well with the results from the experiments. The optimal extraction conditions for extraction yield and total ginsenosides were an extraction temperature of $56.94^{\circ}C$, ethanol concentration of 57.90%, and extraction time of 11 h. Under these conditions, extraction yield and total ginsenoside contents were predicted to be 84.52% and 9.54 mg/g, respectively.

Highly dispersed $Ru/{\alpha}-Al_2O_3$ Catalyst development for selective CO oxidation reaction (선택적 CO 산화반응을 위한 고분산된 $Ru/{\alpha}-Al_2O_3$ 촉매개발)

  • Eom, HyunJi;Koo, KeeYoung;Jung, UnHo;Rhee, YoungWoo;Yoon, WangLai
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.228.1-228.1
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    • 2010
  • 선택적 CO 산화반응(PrOx)을 위한 Ru이 고분산 담지된 $Ru/{\alpha}-Al_2O_3$ 촉매를 증착-침전법(deposition-precipitation)으로 제조하였다. 용액의 pH와 aging 시간에 따른 Ru 입자의 크기 변화와 분산도의 영향을 살펴보았으며 함침법(impregnation)으로 비교 촉매를 제조하였다. 촉매의 특성분석은 BET, TPR, CO-Chemisorption분석을 수행하여 촉매의 비표면적, 환원특성, 분산도를 알 수 있었다. 특성분석결과, 증착-침전법으로 제조한 $Ru/{\alpha}-Al_2O_3$ 촉매가 함침법으로 제조한 촉매에 비해 분산도가 높았으며, pH별 촉매 제조에서는 pH6.5로 제조한 촉매가 22.06%로 가장 높은 분산도를 보였다. 또한, 담체의 비표면적 영향에 따른 Ru 입자의 분산도를 살펴보기 위해 ${\gamma}-Al_2O_3$${\alpha}-Al_2O_3$ 담체를 적용한 결과, 비표면적이 작은 ${\alpha}-Al_2O_3$ 담체 표면에서 Ru 분산도가 ${\gamma}-Al_2O_3$ 담체에 비해 높았다. 이는 기공이 발달하여 비표면적이 넓은 ${\gamma}-Al_2O_3$ 담체는 소량의 Ru을 고분산 담지 시 담체 표면보다는 기공 내에 담지 되는 양이 많아 실제 반응 시 반응에 참여하는 표면 활성 금속양이 적음을 알 수 있다. 특히, 선택적 산화반응과 같이 표면에서 빠른 반응이 일어나는 경우, 기공 내부의 활성금속이 반응에 참여하기 어려워 반응 활성이 낮음을 PrOx 반응실험을 통해 확인할 수 있었다. PrOx test 조건은 GHSV 250000~60000, 온도는 80~200도, 람다값은 2~4로 성능 비교하여 실험 하였다. PrOx의 성능평가 결과 담체를 ${\alpha}-Al_2O_3$를 사용하여 deposition-precipitation방법으로 제조한 pH6.5 촉매에서 $100{\sim}160^{\circ}C$에서 90%의 가장 높은 CO conversion을 가지고 18%의 선택도를 가졌다.

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