• Title/Summary/Keyword: 반응고성형

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The Characterization of High Performance Electrode in Phosphoric Acid Fuel Cell Long-run Operation (인산형 연료전지 장기운전을 통한 고성능 전극의 특성 연구)

  • 이창엽;설용건;양재춘;김건택;노중석
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.11a
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    • pp.85-88
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    • 1999
  • 대용량 발전 시설의 개발을 목표로, 연구에 대한 많은 관심이 집중되어 온 인산형 연료전지는 이미 전 세계적으로 연구의 선두에 있는 국가들에서 수백 KW급 규모로 상용화단계에 진입해 있는 상태이고 미국 등지에서는 전력회사 등을 통하여 MW급 규모의 응용이 이루어지고 있다. 다른 연료전지에서와 마찬가지로 인산형 연료전지에서도 산소의 환원반응이 느린 점과 산소의 환원시 높은 과전압으로 인한 성능이 감소가 한계요인으로 되고 있어 이의 극복을 위한 많은 연구가 있어 왔으며 최근의 개발 방향은 발전시스템의 고성능화와 전지의 수명연장, 그리고 경제성 확보 등의 측면에서 이루어지고 있다.(중략)

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A Study on the Cutting Characteristics of Al Alloy in End Milling for Various Hardnesses(I) (경도변화에 따른 Al합금의 밀링가공시 가공 특성에 관한 연구(I))

  • Kim Seong-Il
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.1
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    • pp.82-87
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    • 2006
  • The cutting tests of aluminum alloy with heat treatmented various hardnesses after rheo-fonning were carried out using CNC milling machine. The surface roughness(Ra, Rmax) of cut surface and cutting forces are measured at various cutting conditions such as low spindle speed, feed speed and hardness. In the CNC end-milling, the surface roughness increases as feed speed increases and decreases as spindle speed increases. However, the bulit-up edge has occurred on in case of low hardness and low feed speed. In experimental conditions, as the hardness of aluminum alloy increases, the surface roughness(Ra, Rmax) decreases

A Fundamental Study for a Photocatalytic Reactor Design (광촉매 반응치 설계를 위한 기초 연구)

  • 손건석;윤승원;고성혁;김대중;송재원;이귀영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.2
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    • pp.40-47
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    • 2002
  • Because UV wavelength lights can activate photocatalysts, plasma is used as a light source of a photocatalytic reactor. Even though plasma has good intensity for photo reaction, substrate of catalyst coating was limited by the geometry of plasma generator. Usually bead type substrate was used for a pack bed type reactor. Honeycomb monolith type substrate was used with UV lamps instead plasma, due to the light penetration the honeycomb monolith length was too short to show good activity In this study a photocatalytic reactor, which is using a honeycomb monolith substrate, was investigated with plasma as an activation light source. As a parametric study the effects of 1311owing factors on plasma generation and power consumption are examined; supply voltage, substrate length, environment condition, catalyst loading and ratio. Using the test results, the practicability test was done with simulated synthetic gases representing bad smells and automotive exhaust gases.

A Study of Non-thermal Plasma Generation on a Photocatalytic Reactor Using a Ceramic Honeycomb Monolith Substrate (세라믹 벌집형 담체를 사용한 광촉매 반응기의 플라즈마 생성에 관한 연구)

  • 손건석;윤승원;고성혁;김대중;송재원;이귀영
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.2
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    • pp.48-54
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    • 2002
  • Since photocatalysts are activated by lights of UV wavelengths, plasma is alternatively used as a light source for a photocatalytic reactor. Light intensity generated by plasma is proportional to the surface area of catalytic material, and this, in many practical applications, is prescribed by the geometry of a plasma generator. Thus, it is crucial to increase the surface area far sufficient light intensity for photocatalytic reaction. For example, in a pack-bed type reactor, multitudes of beads are used as a substrate in order to increase the surface area. Honeycomb monolith type substrate, which has very good surface area to volume ratio, has been difficult to apply plasma as a light source due to the fact that light penetration depth through the honeycomb monolith was too short to cover sufficient area, thus resulting in poor intensity for photocatalytic reaction. In this study, nonthermal plasma generation through a photocatalytic reactor of honeycomb monolith substrate is investigated to lengthen this short penetration depth. The ceramic honeycomb monolith substrate used in this study has the same length as a three way catalyst used fur automotive applications, and it is shown that sufficient light intensity for photocatalytic reaction can also be obtained with honeycomb monolith type reactor.

A Study on the Isomerization Reactions of Tricyclopentadiene Derivatives Using Aluminum Chloride(AlCl3) Catalyst(I) (알루미늄클로라이드 촉매를 이용한 Tricyclopentadiene 유도체의 이성화 반응 연구(I))

  • Jo, Hyun-Hye;Kwon, Tae-Soo;Park, Chang-Sun;Han, Jeong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.2
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    • pp.17-24
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    • 2012
  • Tetrahydrotricyclopentadiene(below THTCPD) isomer is a good candidate materials for the high performance liquid fuel component because of its high density and heat of combustion value. The object of this study was to find out the proper reaction condition to improve the fluidity of THTCPD which is solid state at room temperature. Therefore, we have carried out isomerization reactions using aluminum chloride in the varying reaction condition such as reaction temperature and solvents. The results showed that when using aluminum chloride catalyst, THTCPD isomerization reaction was more active in the polar halogenated reaction media such as dichloromethane(methylene chloride: MC), 1,2-dichloroethane(ethylene chloride: EC) and chloroform than in non-polar hydrocarbon media such as n-Hexnae and toluene and was effected by reaction temperature variation.

Classifications of Ecological Districts for Estuarine Ecosystem Restoration; Examples of Goseong Bay Estuaries, South sea, Korea (하구 생태 복원을 위한 생태구역 구분; 남해 고성만 고성천 인근 하구의 예)

  • An, Soon-Mo;Lee, Sang-Yong;Choi, Jae-Ung
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.16 no.2
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    • pp.70-80
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    • 2011
  • Estuarine ecosystem responds sensitively to natural and anthropogenic perturbations. lt is necessary to identify the direction of the change when the perturbation occurs as well as to understand the structure and functioning of estuarine ecosystem for a proper management of the area. In this study, the estuarine habitats were classified into different ecological districts so as to the switch from one district to another district could be related to the environmental change due to the perturbations. Total 16 ecological districts was defined according to the presence of barrage, salinity and vegetation characteristics. The defined ecological districts were applied to small estuaries in Goseong bay, south sea of Korea (Baedun, Guman, Maam, Goseong) to distinguish different regions which might have characteristic bottom topography, inclinations of river bottom, sediment characteristics, salinity structure and area of vegetation. Total 7 out of 16 ecological district was identified in this region; NFB (natural, fresh, bare), NHB (natural, high salinity, bare), NLV (natural, low salinity, vegetated) in natural (without barrage) estuaries and CFB (closed, fresh, bare), CFV( closed, fresh vegetated), CLV (closed, low salinity, vegetated), CHB (closed, high salinity, bare) in closed (with barrage) estuary. A comparison of environmental factors and biota between CHB and CLV demonstrated the effect of barrage on estuarine ecosystem. The height and sediment characteristics of CHB and CLV were similar but the average salinity was lower in CLV than in CHB due to the barrage, which produced favorable condition for the Phragmites australis in CLV. Information regarding the ecological districts in various sizes and location could be useful for predicting the ecosystem change due to natural and anthropogenic perturbations and for preparing management actions.

Catalytic Cracking of Pyrolysed Waste Lube-oil Into High Quality Fuel Oils Over Solid Acid Catalysts (고체산 촉매를 이용한 페윤활유 열분해유의 고급연료유화 특성 연구)

  • 박종수;윤왕래;고성혁;김성현
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.248-255
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    • 1999
  • Catalytic cracking of pyrolysed waste lubricating oil over solid acid catalysts (HY zeolite, ${\beta}$-zeolite, HZSM-5) has been carried out in a micro-fixed bed system. The feed oil for catalytic activity tests has been prepared by thermal cracking of waste lubricating oil under the reaction conditions of 480$^{\circ}C$, 60 min. Optimum reaction conditions for the maximum light oil yields($\_$21/) were WHSV(weight hourly space velocity)=1 at 375$^{\circ}C$. The amounts of total and strong acid sites appeared to be the largest in ${\beta}$-zeolite as determined by NH$_3$, TPD. It is seen that the catalytic activity order, in terms of the light fuel oil ($\_$21/) production, were HY zeolite)${\beta}$-zeolite>HZSM-5. Also, coke formation followed the same order. The highest activity in HY zeolite may be attributed from the fact that it has supercages facilitating the easy diffusion of larger molecules and also the effectiveness of the acid sites for cracking within the pore. This fact could be confirmed by the coke formation characteristics.

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Microelectromechnical system 소자를 위한 박막형 2차 전지용 TEX>$SnO_2$ 음극 박막의 충, 방전 특성 평가

  • 윤영수;전은정;신영화;남상철;조원일
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.50-50
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    • 1999
  • 마이크로 공정을 이용한 초소형 정밀 기계는 공정 기술과 재료 기술의 발전에 의하여 더욱 소형화되고 있으며 특히 기능을 갖는 부분과 이 부분을 제어하는 주변회로의 on-chip화의 요구가 증가되기 시작하였다. 이와 같은 추세에 있어서의 문제점은 초소형 정밀기계 부품 소자의 구동을 위한 에너지원의 개발이다. 즉, 소자의 크기가 작아진 것에 부합되는 초소형의 전지가 필요하게 된 것이다. 따라서 보다 완전한 초소형 정밀 기계 및 마이크로 소자의 구현을 위하여 마이크로 소자와 혼성 (Hybrid) 되어 이용될 수 있는 고성능 및 초소형의 전지의 개발이 필수적이다. 초소형 전지의 구현을 위하여 Li계의 2차 전지를 선택하여 이를 박막화하고 반도체 공정을 도입할 수 있다. 이러한 전지를 박막형 2차 전지 또는 박막형 마이크로 전지(thin film Secondary Battery : TFSB or Thin Film Micro-Battery : TFMB)라 하며 이러한 2차 전지는 일반적인 벌크 전지와 동일하게 cathode/Electolyte/Anode의 구조를 갖는다. 박막의 특성상 전해질은 고상의 물질을 사용하는 것이 벌크형 2차 전지와 다른 점이다. TFSB의 성능은 주로 cathode에 의하여 결정되며 지금까지 많은 cathode 물질에 대한 연구 보고가 발표되고 있다. 반도체 공정을 이용한 TFMB의 제작시 무엇보다 중요한 점은 우수한 고상 전해질 및 anode 물질의 선택에 있다. 최근에 2차 전지를 위한 carbon계 anode를 대체할 수 있는 SnO에 대한 보고가 있는데 이는 한 개의 Sn 원자당 2개 이사의 Li가 반응하여 높은 용량을 갖는 전지의 제작이 가능하기 때문이다. Sno2의 anode는 매우 높은 충전용량을 갖는데 첫 번째 방전시에 Li2O를 생성하여 비가역적 반응을 나타내고 계속되는 충방전 동안 Li-Sn 합금이 생성되어 2차전지의 가역적 반응을 가능하게 한다. SnO2 는 대기중에서 Li 금속보다 안정하기 때문에 전지의 제작 공정 및 사용 면에서 매우 우수한 물질이지만 아직까지 SnO2 구조적 특성과 전지의 충, 방전 특성에 대한 관계의 규명을 위한 정확한 정설은 제시되고 있지 못하다. 본 연구에서는 TFSB anode 물질로써 SnOx박막을 상온에서 여러 전도성 콜렉터 위에 증착하여 그 충, 방전 특성을 보고하였다. 증착된 SnOx박막의 표면은 SEM, AFM으로 분석하였으며 구조의 분석은 XR와 Auger electron spectroscope로 하였다. 충, 방전 특성을 분석하기 위하여 리늄 foil을 대극과 참조 전극으로 하여 EC:DMC=1:1, 1M LiPF6 액체 전해질을 사용한 Half-Cell를 구성하여 100회 이상의 정전류 충, 방전 시험을 행하였다. Half-Cell test 결과 박막의 구조, 콜렉터의 종류 및 Sn/O비에 따라 서로 다른 충, 방전 거동을 나타내었다.

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