• Title/Summary/Keyword: 반사분광법

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Mid-infrared Cavity Ringdown Spectrometer Using Difference - frequency Generation (차주파수 생성을 이용한 중적외선 공동 광자감쇠 분광장치)

  • 이동훈;윤일선;이용훈;김봉수
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.02a
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    • pp.204-205
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    • 2003
  • 미량기체의 흡수스펙트럼을 높은 감도로 측정하는 공동 광자감쇠 분광법(cavity ringdown spectroscopy; CRDS)을 나노초 레이저 펄스의 차주파수 생성(difference-frequency generation; DFG)을 광원으로 이용하여 파장 3 ~ 4 $\mu\textrm{m}$ 영역에서 구현하였다. CRDS는 고반사율 거울로 이루어진 광학적 공동에 단일 파장의 빛을 가두었다가 그 에너지의 시간적 감소율을 측정하여 공동 속 기체의 흡수율을 알아내는 방법이다. (중략)

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Surface Structure Analysis of Solids by Impact Collision Ion Scattering Spectroscopy(2): Atomic Structure of Semiconductor Surface (직충돌 이온산란 분광법(ICISS)에 의한 고체 표면구조의 해석(2): 반도체 재료의 표면구조 해석)

  • Hwang, Yeon
    • Korean Journal of Crystallography
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    • v.19 no.1
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    • pp.7-13
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    • 2008
  • 고체 표면의 구조해석 방법에는 LEED(저에너지 전자선 회절법)나 RHEED(반사 고에너지 전자선 회절법) 등과 같이 표면의 2차원적 회절상을 해석하는 방법이 있고(역격자 공간의 해석), 또는 ISS(이온산란 분광법), RBS(러더포드 후방산란법) 등과 같이 표면 원자의 실공간에 대한 정보를 직접 얻는 방법이 있다. 실제로는 두 가지 종류의 분석법을 상호 보완적으로 조합하여 효율적인 구조해석을 수행한다. 본고에서는 직충돌 이온산란 분광법(ICISS: Impact Collision Ion Scattering Spectroscopy)에 대한 원리, 장치, 측정방법 등을 소개한 전고에 이어서 이를 이용한 반도체 표면구조 해석에 관하여 기술하고자 한다. 표면의 원자구조를 알아내기 위해서는 산란된 입자의 강도를 입사각도와 출사각도에 대하여 조사하여야 하는데, 이온이 원자와 충돌하여 산란될 때 원자의 후방으로 형성되는 shadow cone에 의하여 생성되는 집속 효과(focusing effect) 및 가리움 효과(blocking effect) 중에서 ICISS는 집속 효과만을 고려하여 해석하면 실공간에서의 원자구조를 해석할 수 있다. 본 고에서는 ICISS를 이용하여 금속 또는 절연체 물질이 반도체 표면 위에서 흡착 또는 성장될 때 초기의 계면 구조 해석, 금속/반도체 계면에서 시간에 따른 동적변화 해석, III-V족 반도체의 표면구조 해석, 반도체 기판 위에서 박막 성장 과정 해석 등에 관한 연구 사례를 소개하고자 한다.

Spectral Mixture Analysis in forest using Landsat-7 ETM+ (Landsat-7 ETM+영상을 이용한 산림지역의 혼합화소분석)

  • 이지민;이규성
    • Proceedings of the Korean Association of Geographic Inforamtion Studies Conference
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    • 2003.04a
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    • pp.157-162
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    • 2003
  • 중저해상도 광학영상의 순간시야각(instantaneous filed of view -IFOV)에 포함되는 공간에는 반사특성이 상이한 두 개 이상의 지표물이 존재하는 경우가 대부분이다. 영상분류와 같은 기존의 영상처리기법에서는 하나의 화소가 단일의 지표물을 대표한다는 가정에서 접근하였으나, 최근 화소의 혼합정도를 세분하는 분광혼합분석(spectral mixture analysis)기법이 개발되고 있다. 분광혼합분석법을 이용하여 혼합된 화소에 포함된 지표물을 분해(unmixing) 하고 그 효과를 분석하고자 하여 경기도 광릉국립수목원의 시험림 지역을 대상으로 Landsat-7 ETM+영상을 이용하여 선형혼합 모델을 적용하였고, 그 결과 각각의 화소를 6개의 End-member의 혼합비로 구분하였다. Endmember의 비율을 나타낸 영상을 분석하여 점유비율에 따른 활엽수와 침엽수의 구분을 할 수 있었고, 각 임상별의 특징도 얻을 수 있었다. 특히 침엽수의 경우 그림자의 효과가 높다는 특성도 파악 할 수 있었다. 분광혼합분석법은 기존의 전통 분류방법과는 달리 다양한 산림의 정보를 추출해 낼 수 있다.

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Analysis of patterned ITO layer of PDP thin films using spectroscopic ellipsometry (분광타원법을 이용한 PDP용 ITO 박막의 패턴 분석)

  • 윤희삼;김상열
    • Korean Journal of Optics and Photonics
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    • v.14 no.3
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    • pp.272-278
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    • 2003
  • We studied patterned ITO layers of PDP thin films on glass substrates using spectroscopic ellipsometry. The optical property of ITO is expressed with the optical model based on two Lorentz oscillators. The effect of patterned ITO is calculated by taking the weighted average of reflectance in proportion to ITO coverage. The relative coverage of ITO is determined by using the model analysis of spectroellipsometric data. The difference of ITO coverage obtained by the best-fit model analysis of ellipsometric spectra to the expected one is critically examined and suggestions are made to minimize the observed discrepancy.

Optical Structures of Multilayer Coatings of Antireflection Lenses and their Transmission Characteristics (무반사 렌즈용 다층박막의 광학적 구조 및 광투과 특성)

  • 김상열;최성숙
    • Korean Journal of Optics and Photonics
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    • v.6 no.4
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    • pp.259-265
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    • 1995
  • Antireflection coatings on optical lenses commertially available in domestic market are optically analyzed. Transmission spectra and reflection spectra are collected using spectrophotometers. The apparent absorption spectra around the absorption band edge are dominated by the substrate absorption. The reflection spectra and the apparent absorption spectra at visible region between 400nm and 700nm show very strong correlation to each other except a couple samples. The discrepency observed in the latters are due to an increased absorption in visible region by the substrate, which is negative effect of these samples. An antireflection coating consisted of $SiO_2/TiO_2/SiO_2/ZrO_2/Cr$ is made on c-Si substrate for spectroscopic ellispometry analysis. A film-by-film coating is accomplished and between each film deposition, ex-situ spectroscopic ellipsometry measurements are made. The analysis of the spectroscopic ellipsometry data reveals that the average film densities of $ZrO_2$ and $TiO_2$ reach only 80% of their respective packing densities and thick films are inhomogeneous along film growth direction. Discussions are made toward in-situ, real-time monitoring of the film growth so that a real-time feedback is possible to achieve a post-correction to minor deviations occured in the previous step. step.

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Integrated Cavity Output Spectroscopy Using an External Cavity Diode Laser for the Density Absorption Measurement of Trace Gases (미량 기체의 밀도 측정을 위한 외부 공진기 반도체 레이저 광학공동 적분 투과 분광법)

  • Ryoo Hoon Chul;Yoo Yong Shin;Lee Jae Yong;Hahn Jae Won
    • Journal of the Korean Vacuum Society
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    • v.15 no.1
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    • pp.24-30
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    • 2006
  • Integrated cavity output spectroscopy(ICOS) is a simple, non-intrusive absorption measurement technique that can detect and quantify trace-level gas species. The spectral absorbance of a gas is quantified from the integrated optical output of the modulated high-finesse cavity containing the sample which is irradiated by a wavelength-swept laser source. We constructed an experimental setup by using a tunable single mode external cavity diode laser operating at the wavelength near 765 nm and a Fabry-Perot cavity with length modulation achieved by a piezoelectric transducer where one of the cavity mirrors sat on. In the experiment performed on minute oxygen gas at the wave-length near 764.5nm, we demonstrated the minimum detectable absorption of $8.45\times10^{-8}cm^{-1}$.

A Reproduction algorithm of nighttime road-image for visibility evaluation of headlamps (헤드램프의 시계성 평가를 위한 야간도로 영상 재현 알고리즘)

  • Lee, Cheol-Hui;Ha, Yeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.38 no.6
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    • pp.630-639
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    • 2001
  • This study proposes a new calculation method for generating real nighttime lamp-lit images. In order to improve the color appearance in the prediction of a nighttime lamp-lighted scene, the lamp-lit image is synthesized based on spectral distribution using the estimated local spectral distribution of the headlamps and the surface reflectance of every object. The Principal component analysis method is introduced to estimate the surface color of an object, and the local spectral distribution of the headlamps is calculated based on the illuminance data and spectral distribution of the illuminating headlamps. HID and halogen lamps are utilized to create beam patterns and captured road scenes are used as background images to simulate actual headlamp-lit images on a monitor. As a result, the reproduced images presented a color appearance that was very close to a real nighttime road image illuminated by single and multiple headlamps compared to the conventional graphic-based algorithm.

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The Optical Properties of SiO2/TiO2/ZrO2 Broadband Anti-reflective Multi-layer Thin Films Prepared by RF-Magnetron Sputtering (SiO2/TiO2/ZrO2 광대역 반사방지막의 제작 및 광학적 특성 분석)

  • Kang, M.I.;Ryu, J.W.;Kim, K.W.;Kim, C.H.;Baek, Y.K.;Lee, D.H.;Lee, S.R.
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.138-147
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    • 2008
  • $SiO_2/TiO_2/ZrO_2$ broadband anti-reflective multi-layer thin films were prepared at room temperature by RF sputtering system. Optical constants and structural properties on each layer of films were analyzed by spectroscopic ellipsometer and transmittance spectra of the films were measured by $UV-V_{is}$ spectrophotometer in the range of 300$\sim$900 nm. To evaluate the films, we compared the measured and analyzed spectra with designed spectra. We investigated influence of discrepancy of thickness and refractive indices of each layer on changes of the transmittance spectra. It was found that refractive indices and shape of dispersion of deposition materials are more contributed to changes of the transmittance spectra than thickness of layer.

Studies on the Near Infrared Diffuse Reflection Spectroscopy for Meat Components (근적외선 반사분광분석법에 의한 정육 및 그 구성성분의 반사 spectra에 관한 연구)

  • Oh, Eun-Kyong;Grossklaus, Dieter
    • Korean Journal of Food Science and Technology
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    • v.24 no.5
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    • pp.404-407
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    • 1992
  • This study was conducted to determine the effect of the physical and chemical factors on the absorbance when the chemical component of food was rapidly and effectively analyzed with near infrared reflection spectrophotometer. The absorbance was measured within the wavelength range of 1100 and 2500m and at the various sample temperatures. The absorbance was greatly increased with the rising sample temperature. When the grinding time of samples prolonged, the absorbance was decreased. The absorption peaks occurring in the near infrared spectra of meat, meat protein, pork fat and water were attributed to the overtone and combination vibration of C-H, N-H, O-H or C=O bond within the macromolecules of each sample. The absorbance was lower for meat protein than other meat components. Pork fat was characterized by the ${\cdot}CH_2{\cdot}$ absorption peak at the wavelength of 1700 and 2300 nm and water by the relatively high absorption peak at the wavelength of 1450 and 1930 nm. As a result, the absorbance of near infrared reflection spectrum of meat was affected mainly by fat and water in meat.

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SWIR Application for the Identification of High-Grade Limestones from the Upper Pungchon Formation (풍촌층 상부 층준의 고품위 석회석 동정을 위한 SWIR 적용)

  • Kim, Yong-Hwi;Kim, Gyoo Bo;Choi, Seon-Gyu;Kim, Chang Seong
    • Economic and Environmental Geology
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    • v.49 no.5
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    • pp.335-347
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    • 2016
  • The mineralogical and geochemical characteristics of diverse carbonate rocks can be investigated by using VNIRSWIR(visible near infrared-short wavelength infrared) spectroscopic analysis as a rapid, nondestructive, and inexpensive tool. Comparing whole rock analysis to VNIR-SWIR spectroscopic analysis, the analytical method was investigated to estimate CaO contents, mud impurity, and whiteness of carbonate rocks involved in high-grade limestones in the field. We classify typical carbonate rocks in the upper Pungchon Formation in high-grade limestone mine area such as the Gangweon, Chungmu and Baegun mine in the Jeongseon area. The results show that powdered specimen has much higher reflectance than cutted specimen between the same sample. Whiteness is highly correlated with reflectance(0.99) for powdered specimen. The absorption of mineral mixtures shifts in position as a result of the mass ratio of calcite and dolomite in the Chungmu mine by changing to 75:25, 50:50, and 25:75. The absorption peak position in carbonate mixtures is highly correlated with CaO contents(0.98~0.99). Based on color system, the carbonate rocks are grouped into (milky) white, light grey, light brown, grey, and dark grey. The absorption peak position shifts from 2340 nm to 2320 nm as CaO contents decrease from 55.86 wt.% to 29.71 wt.%. We confirmed that absorption peak position shifts depending on the amount of Ca, which is bonded to $CO{_3}^{-2}$, Mg, and Fe contents replacing Ca. This result suggests that CaO contents in carbonate rocks can be considered to quantitative analysis in the field by spectroscopic analysis.