• Title/Summary/Keyword: 박리 저항성

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Long Term and Cyclic Oxidation Behavior of Th-45at%AI-1.6at%Mn Intermetallic Compounds (Ti-45at%AI-1.6at%Mn 금속간화합물의 장시간 및 반복산화특성)

  • Kim, Young-Jin;Choi, Moon-Ki;Kim, Mok-Soon
    • Korean Journal of Materials Research
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    • v.8 no.1
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    • pp.45-51
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    • 1998
  • Ti-45at%AI-1.6at%Mn 조성을 갖는 금속간화합물의 장시간 및 반복산화 거동을조사하기 위하여 반응소결법 및 플라즈마 아크 용해법으로 제조한 시편에 대하여 80$0^{\circ}C$에서는 반응소결재와 용제재 모두 등온 및 반복산화에 대하여 우수한 저항성을 나타내었다. 90$0^{\circ}C$에서는 반응소결재의 경우에는 등온 및 반복산화에 대하여 우수한 저항성을 보였으며, 중량변화와 산화피막의 박리는 극히 적었다. 이에 비해 용제재의 경우에는 등온 및 반복산화에 의해 중향이 크게 변하였으며 피막의 박리도 극심하였다. 90$0^{\circ}C$에 있어서 두 재료간의 이러한 산화거동 차이는 기지/산화물 계면 부근에 형성된 산화층의 차이에 기인하는 것으로 간주하였다. 반응소결재의 경우에는 계면 부근에 연속적인 AO$_{3}$O$_{3}$층이 형성되며, 이러한 층이 산화에 대한 보호막으로 작용하는데 비하여 용제재에 있어서는 계면 부근에 AO$_{3}$O$_{3}$와 TiO$_{2}$의 혼합층이 형성되었다. 용제재의 반복산화시에 보여진 피막의 박리는 냉각시에 TiO$_{2}$와 기지간의 열팽창계수 차이에 기인하여 발생하는 열응력을 TiO$_{2}$가 견디지 못하고 박리를 초래한 것으로 해석하였다.

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An Evaluation of Resistances in Porous Asphalt Concrete Mixtures due to Repeated Cyclic Freeze-Thawing (배수성 아스팔트콘크리트 혼합물의 반복 동결융해 저항성 평가)

  • Jo, Shin Haeng;Kim, Nakseok
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1D
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    • pp.33-39
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    • 2012
  • More and more pavements are suffering from damage these days due to the below-zero winter temperatures and frequent snowfalls. From this research, the freeze-thawing mechanisms of pavements will be observed, and the freeze-thawing resistance of porous asphalt concrete mixture is to be evaluated according to various assessment methods. The investigation was conducted through applying rigid and flexible pavements to freeze-thawing resistance experiments, which include various experiments such as deformation rate measurements, Lottman tests, repeated cyclic freeze-thawing experiments, stripping resistance tests and so on. Test results revealed that the porous asphalt concrete had less deformations according to temperatures compared to dense-graded asphalt concrete due to the 20% void gap. In addition, according to the freeze-thawing repetition experiments which are effected by moisture, the porous asphalt concrete mixture showed superior resistance to repeated cyclic freeze-thawing compared to other asphalt concrete mixtures due to the drainage and the voids within the specimen.

Evaluation of Moisture Susceptibility on Asphalt Mixtures mixing Anti-Stripping Agent (박리방지제의 첨가에 따른 아스팔트 혼합물의 수분민감성 평가)

  • Yang, Sung-Lin;Hwang, Sung-Do;Kim, Yeong-Min;Jeong, Kyu-Dong
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.41-52
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    • 2008
  • This study is to evaluate the property for the moisture susceptibility of asphalt mixtures using anti-stripping agent. Asphalt mixtures using lime, hydrated lime and liquid anti-stripping agent are evaluated through the three types of modified moisture conditioning($H_c$, V_s$, F-T). Indirect Tensile Test, that is recommended by AASHTO TP-9, which includes creep test, resilient modulus test and strength test is used to estimate moisture susceptibility. Analysis method through Energy Ratio(ER) that is proposed by Roque at University of Florida is used to evaluate moisture susceptibility and moisture resistance effects of asphalt mixtures using anti-stripping agent. As a test result, material property of asphalt mixtures was changed by moisture conditioning methods and the types of anti-stripping agent. Also, cracking resistance of accumulated moisture damage was changed by moisture conditioning methods and the types of anti-stripping agent. Based on test result, it was found that cracking resistance using Energy Ratio was differed from 10% to 30%.

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Evaluation of Stripping and Rutting Properties of CRM Modified Asphalt Mixtures (CRM 개질아스팔트 혼합물의 소성변형 및 박리저항 특성)

  • Doh, Young-S.;Park, Tae-W.;Kim, Hyun-H.;Kim, Kwang-W.
    • International Journal of Highway Engineering
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    • v.9 no.4
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    • pp.149-158
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    • 2007
  • Evaluation of the asphalt mixture modified with crumb rubber modifier(CRM) was performed to estimate possibility of using it as a paying material. OACs(optimum asphalt content) of CRM modified asphalt mixtures by dry process and wet process were determined by Marshall mix design and Wheel tracking test and moisture susceptibility test by freezing and thawing were carried out with CRM modified asphalt mixtures at OACs. The results from these tests, resistance of permanent deformation of CRM modified asphalt mixtures were superior to one of AP-5 while showing very low resistance of moisture sensitivity by freezing and thawing. This means that CRM modified asphalt mixtures are very sensitive to freezing and thawing. However, CRM modified asphalt mixture with anti-stripping material showed high improvement to resistance of moisture susceptibility by freezing and thawing. Therefore, it is recommended that when CRM mixtures were used in domestic, CRM modified asphalt mixtures should be with prevention against freezing and thawing resistance by moisture susceptibility.

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Synthesis and Characteristics of Organo-Layered Silicate as an Filler of Polymeric Nanocomposites from $delta-Na_2Si_2O_5$ ($delta-Na_2Si_2O_5$ 로부터 고분자 나노복합 소재용 유기 층상 실리케이트 합성 및 특성)

  • 김윤섭;고형신
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.226-226
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    • 2003
  • 일반적으로, 고분자 매트릭스에 층상 점토광물이 분산되어 얻어지는 복합재료는 세가지 형태를 이룬다. 첫째 통상의 복합재료는 고분자 매트릭스 내에 점토입자가 고루게 분산된 상태를 말하며, 둘째 점토 층 사이에 고분자 모노머나 올리고머가 일부분 삽입된 삽입형 복합재료(intercalated composite)이며, 셋째 점토 층 사이에 삽입된 모노머나 올리고머의 경화 또는 중합반응을 통해 점토내의 한층 한층 균일하게 매트릭스 내에 분산된 박리형 나노복합소재(exfoliated nanocomposite) 이다. 이들 복합재료들 중 박리형 나노복합소재는 적은 양의 점토가 단위 층으로 고분자 매트릭스에 완전히 분산되어 다양한 물성의 향상이 기대되는 재료이다. 따라서 최근 고분자의 기계적 강도, 팽윤 저항성 그리고 차폐특성 둥 전반적인 물성을 향상시키는 방법으로 층상 점토광물의 층 사이에 다양한 유기물을 삽입하여 층간거리를 확장시킨 유기 점토광물을 제조하고 이를 고분자 소재에 첨가하여 박리형 나노복합소재를 제조하는 방법이 많은 연구가 수행되고 있다.

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Oxidation Behaviors of Metallic Interconnectors for Solid Oxide Fuel Cells (고체산화물 연료전지용 금속접속자의 산화거동)

  • 김상우;이병호;김긍호
    • Journal of the Korean Ceramic Society
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    • v.37 no.9
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    • pp.894-899
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    • 2000
  • 중온형 고체산화물 연료전지용 금속접속자로서의 적용가능성을 알아보기 위하여 Ducrolloy 및 Ferritic 스틸의 산화거동을 연구하였다. Ducrolloy는 고온저항이 주기적인 증감을 보이며 산화크롬막의 형성에 의해 신간에 따라 더 이상의 저항증가가 없어 장기 산화안정성을 보였다. 반면, Ferritic 스틸은 고온산화에 의해 형성된 표면 산화철막의 박리가 일어날뿐 아니라 저항이 크게 증가함을 보여 금속접속자로 응용을 위해서는 내산화코팅이 필요하였다.

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The Fractural-Mechanical Properties and Durability of Lightweight Concrete Using the Synthetic Lightweight Aggregate (합성경량골재(SLA)를 사용한 경량콘크리트의 파괴, 역학적 특성 및 내구성)

  • Jo Byung-Wan;Park Seung-Kook;Park Jong-Bin;Daniel C. Jansen
    • Journal of the Korea Concrete Institute
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    • v.17 no.1 s.85
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    • pp.19-25
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    • 2005
  • Recycling of waste materials in the construction Industry is a useful method that can cope with an environment restriction of every country. In this study, synthetic lightweight aggregates are manufactured with recycled plastic and fly ash with 12 percent carbon. Nominal maximum-size aggregates of 9.5 mm were produced with fly ash contents of 0, 35, and $80\%$ by the total mass of the aggregate. An expanded clay lightweight aggregate and a normal-weight aggregate were used as comparison. Gradation, density, and absorption capacity are reported for the aggregates. Five batches of concrete were made with the different coarse aggregate types. Mechanical properties of the concrete were determined including density, compressive strength, elastic modulus, splitting tensile strength, fracture toughness, and fracture energy. Salt-scaling resistance, a concrete durability property, was also examined. Compressive and tensile strengths were lower for the synthetic aggregates; however, comparable fracture properties were obtained. Relatively low compressive modulus of elasticity was found for concretes with the synthetic lightweight aggregate, although high ductility was also obtained. As nv ash content of the synthetic lightweight aggregate increased, all properties of the concrete were improved. Excellent salt-scaling resistance was obtained with the synthetic lightweight aggregate containing 80 percent fly ash.

Evaluation of Environment Friendly High Performance Ternary Cement Concrete Deck Overlay Pavement by Experimental Construction (시험시공을 통한 친환경 고성능 3성분계 시멘트 콘크리트 교면 포장의 성능 평가)

  • Choi, In-Hyeok;Kim, Dae-Seong;Lee, Jun-Ho
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.85-93
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    • 2011
  • This study experimented to evaluate the environment friendly high performance ternary cement concrete deck overlay pavement using mineral admixture such as fly ash and ground granulated blast-furnace slag. It was measured to find best binder mixing according to replacement rate of mineral admixture with compressive strength and flexural strength. After finding best binder, it is also experimented to evaluate durability on chloride penetration resistance, freezing- thawing resistance, scaling resistance of deicing chemicals, abrasion resistance, alkali-silica reactivity test and bonded environment friendly high performance ternary cement concrete deck overlay pavement experimented to evaluate bonded old deck and new concrete overlay pavement using special polymer cement mortar. In additions, bonded environment friendly high performance ternary cement concrete deck overlay pavement by experimental construction was evaluated at interchange bridge of North Yeoju. Result, examination was indicated better binding with binder replacement of cement 70%, ground granulated blast-furnace slag 15% and fly ash 15%. And special polymer cement mortar used in old deck and new overlay concrete was indicated better bonding both laboratory and construction.