• Title/Summary/Keyword: 박리결함

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Characterizations on the Thermal Insulation of SiC Coated Carbon-Carbon Composites (탄화규소로 코팅된 탄소-탄소 복합재료의 단열 특성)

  • Seo, Hyoung-IL;Lim, Byung-Joo;Sihn, Ihn Cheol;Bae, Soobin;Lee, Hyung-Ik;Choi, Kyoon;Lee, Kee Sung
    • Composites Research
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    • v.33 no.3
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    • pp.101-107
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    • 2020
  • This study investigates the characterization on the thermal insulation properties of silicon carbide coating on the Cf-C composites. The silicon carbide coatings by chemical vapor deposition on the C/C composites are prepared to evaluate thermal resistance. Firstly, we perform the basic insulation test by thermal shock at 1350℃ in air on the C/C composite and SiC-coated C/C composite. We also performed the burner tests on the surface of the composites at high temperatures such as 1700 and 2000℃, and the weight change after burner tests are measured. The damages on the surface of C/C composite and SiC-coated composite are observed. As a result, the SiC coating is beneficial to protect the C/C composite from high temperature even though damages such as defoliation, crack and voids are observed during burner test at 2000℃.

Understanding Interfacial Charge Transfer Nonlinearly Boosted by Localized States Coupling in Organic Transistors (유기트랜지스터 내부 편재화 준위간 커플링에 의한 계면 전하이동의 비선형적 가속화 현상의 이해)

  • Han, Songyeon;Kim, Soojin;Choi, Hyun Ho
    • Journal of Adhesion and Interface
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    • v.22 no.4
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    • pp.144-152
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    • 2021
  • Understanding charge transfer across the interface between organic semiconductor and gate insulator gives insight into the development of high-performance organic memory as well as highly stable organic field-effect transistors (OFETs). In this work, we firstly unveil a novel interfacial charge transfer mechanism, in which hole transfer from organic semiconductor to polymer insulator was nonlinearly boosted by localized states coupling. For this, OFETs based on rubrene single crystal semiconductor and Mylar gate insulator were fabricated via vacuum lamination, which allows stable repetition of lamination and delamination between semiconductor and gate insulator. The surfaces of rubrene single crystal and Mylar film were selectively degraded by photo-induced oxygen diffusion and UV-ozone treatment, respectively. Consequently, we found that the interfacial charge transfer and resultant bias-stress effect were nonlinearly boosted by coupling between localized states in rubrene and Mylar. In particular, the small number of localized states in rubrene single crystal provided fluent pathway for interfacial charge transport.

Development of Heterogeneous Damage Cause Estimation Technology for Bridge Decks using Random Forest (랜덤포레스트를 활용한 교량 바닥판의 이종손상 원인 추정 기술 개발)

  • Jung, Hyun-Jin;Park, Ki Tae;Kim, Jae Hwan;Kwon, Tae Ho;Lee, Jong-Han
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.1
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    • pp.19-32
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    • 2024
  • An investigation into the detailed safety diagnosis report indicates that domestic highway bridges mainly suffer from defects, deterioration, and damage due to physical forces. In particular, deterioration is an inevitable damage that occurs due to various environmental and external factors over time. In particular, bridge deck is very vulnerable to cracks, which occur along with various types of damages such as rebar corrosion and surface delamination. Thus, this study evaluates a correlation between heterogeneous damage and deterioration environment and then identifies the main causes of such heterogeneous damage. After all, a bridge heterogeneous damage prediction model was developed using random forests to determine the top five factors contributing to the occurrence of the heterogeneous damage. The results of the study would serve as a basic data for estimating bridge maintenance and budget.

Evaluation of Shear Bond Strength and Adhesive Bond Durability of Mixed Species Structural Glued Laminated Timber (이수종 구조용집성재의 전단접착력 및 접착내구성 평가)

  • Shim, Sangro;Yeo, Hwanmyeong;Shim, Kugbo
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.1 s.129
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    • pp.87-96
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    • 2005
  • This study was carried out to evaluate the shear bond strength and adhesive bond durability of structural glued laminated timber (glulam) manufactured with mixed species lumber of Korean red pine, Korean pine and Japanese larch, using resorcinol adhesive and water-based polymeric-isocyanate adhesive (WPI). Each board used as a glulam lamina was graded by visual inspection. The visual lumber grade of the all species was very low due to the large size and number of knots and the steep slope of grain. In view of the results, appropriate pruning, sawing and drying processes might be needed to produce high grade lamina lumber with small knot size and drying defect free. Shear bond strength of every tested glulam specimen ranged between 7.9 and $9.9N/mm^2$, and much higher than the Korean Standard (KS) for glulam shear bond strength, $7.1N/mm^2$. There was not much shear bond strength difference between wood/resorcinol and wood/WPI. The resorcinol adhesive bond durability exceeded KS requirements. However, delamination on the end-grain surfaces of WPI glulam submerged in both room temperature and boiling water severely occurred, and its durability did not meet KS requirements. Further investigations may be required, and special care should be taken, to ensure long service life of WPI glulam used for exterior application. Results of this study are expected to be useful for improvement of mechanical properties and structural performance of mixed species glulam.

Fabrication and Electrical Insulation Property of Thick Film Glass Ceramic Layers on Aluminum Plate for Insulated Metal Substrate (알루미늄 판상에 글라스 세라믹 후막이 코팅된 절연금속기판의 제조 및 절연특성)

  • Lee, Seong Hwan;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.39-46
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    • 2017
  • This paper presents the fabrication of ceramic insulation layer on metallic heat spreading substrate, i.e. an insulated metal substrate, for planar type heater. Aluminum alloy substrate is preferred as a heat spreading panel due to its high thermal conductivity, machinability and the light weight for the planar type heater which is used at the thermal treatment process of semiconductor device and display component manufacturing. An insulating layer made of ceramic dielectric film that is stable at high temperature has to be coated on the metallic substrate to form a heating element circuit. Two technical issues are raised at the forming of ceramic insulation layer on the metallic substrate; one is delamination and crack between metal and ceramic interface due to their large differences in thermal expansion coefficient, and the other is electrical breakdown due to intrinsic weakness in dielectric or structural defects. In this work, to overcome those problem, selected metal oxide buffer layers were introduced between metal and ceramic layer for mechanical matching, enhancing the adhesion strength, and multi-coating method was applied to improve the film quality and the dielectric breakdown property.

Stabilization of cubic-BN/hexagonal-BN Mixed Films by Post-Annealing (후 열처리에 의한 cubic-BN 상과 hexagonal-BN상 혼합 막의 안정성 향상)

  • 박영준;최제형;이정용;백영준
    • Journal of the Korean Vacuum Society
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    • v.9 no.2
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    • pp.155-161
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    • 2000
  • BN films composed of c-BN(70%) and h-BN(30%) phases have been synthesized by the ion beam assisted deposition (IBAD) process and stabilized by post-annealing. Boron was e-beam evaporated at 1.2 $\AA$/sec and nitrogen was ionized and accelerated at about 100 eV by the end-hall type ion gun. Substrates were negatively biased by DC 400 and 500 V, respectively, and heated at $700^{\circ}C$. Synthesized BN films were in-situ post-annealed at 700 or $800^{\circ}C$, respectively, for 1 hr without breaking vacuum. BN films without post-annealing were peeled off from substrates immediately when they were exposed to the air while those with post-annealing at $800^{\circ}C$ were stabilized. Post annealing reduced the film stress from 4.9 GPa to 3.4 GPa, but no considerable stress release in the c-BN phase was observed, contrary to previous reports that the stress relaxation in the c-BN phase is the main mechanism for the stabilization. Structural and chemical relaxation of non c-BN phase is supposed to be responsible for the film stress reduction and, in turn, stabilization, especially when the c-Bn content of the film is not high.

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Study on the Crack and Thermal Degradation of GFRP for UPE Gelcoat Coated Underground Pipes Under the High Temperature Water-Immersion Environment (고온 수침 환경에서 UPE 겔코트 코팅된 지중 매설 파이프용 GFRP의 열화 및 크랙 발생 특성에 관한 연구)

  • Kim, Daehoon;Eom, Jaewon;Ko, Youngjong;Lee, Kang-Il
    • Journal of the Korean Geosynthetics Society
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    • v.17 no.4
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    • pp.169-177
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    • 2018
  • Glass fiber reinforced polyester (GFRP) composites are widely used as structural materials in harsh environment such as underground pipes, tanks and boat hulls, which requires long-term water resistance. Especially, these materials might be damaged due to delamination between gelcoat and composites through an osmotic process when they are immersed in water. In this study, GFRP laminates were prepared by surface treatment of UPE (unsaturated polyester) gelcoat by vacuum infusion process to improve the durability of composite materials used in underground pipes. The composite surface coated with gelcoat was examined for surface defects, cracking, and hardness change characteristics in water-immersion environments (different temperatures of $60^{\circ}C$, $75^{\circ}C$, and $85^{\circ}C$). The penetration depth of cracks was investigated by micro CT imaging according to water immersion temperature. It was confirmed that cracks developed into the composites material at $75^{\circ}C$ and $85^{\circ}C$ causing loss of durability of the materials. The point at which the initial crack initiated was defined as the failure time and the life expectancy at $23^{\circ}C$ was measured using the Arrhenius equation. The results from this study is expected to be applied to reliability evaluation of various industrial fields where gelcoat is applied such as civil engineering, construction, and marine industry.

Petrological Characteristics and Nondestructive Deterioration Assessments for Foundation Stones of the Sebyeonggwan Hall in Tongyeong, Korea (통영 세병관 초석의 암석학적 특성 및 비파괴 손상평가)

  • Han, Doo Roo;Kim, Sung Han;Park, Seok Tae;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.54 no.2
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    • pp.199-212
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    • 2021
  • The Sebyeonggwan Hall (National Treasure No. 305) is located on the Naval Headquarter of Three Provinces in Tongyeong, and it has partly undergone with several rebuilding, remodeling, repairing and restorations since it's the first establishment in Joseon Dynasty (AD 1605) of ancient Korea. This study focuses on 50 foundation stones that comprise the Sebyeonggwan. These stones are made of six rock types and currently have various shapes of the surface damages. As the foundation stones, the dominant rock type was dacitic lapilli tuffs, and provenance-based interpretation was performed to supply alternative stones for conservation. Most of the provenance rocks for foundation stones showed highly homogeneity with their corresponding stones of petrography, mineralogy and magnetic susceptibility. According to surface deterioration assessments, the most serious damages of the stones were blistering and scaling. The deterioration mechanism was identified through the analysis of inorganic contaminants, and the primary reason is considered salt weathering caused by sea breeze and other combined circumstances. Based on the mechanical durability of the stones, there was no foundation stone that required the replacement of its members attributed to the degradation of the rock properties, but conservation treatment is considered necessary to delay superficial damage. The foundation stones are characterized by a combined outcome of multiple petrological factors that caused physical damage to surfaces and internal defects. Therefore, it's required to diagnosis and monitoring the Sebyeonggwan regularly for long-term preservation.

Recent Developments in Quantum Dot Patterning Technology for Quantum Dot Display (양자점 디스플레이 제작을 위한 양자점 패터닝 기술발전 동향)

  • Yeong Jun Jin;Kyung Jun Jung;Jaehan Jung
    • Journal of Powder Materials
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    • v.31 no.2
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    • pp.169-179
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    • 2024
  • Colloidal quantum dot (QDs) have emerged as a crucial building block for LEDs due to their size-tunable emission wavelength, narrow spectral line width, and high quantum efficiency. Tremendous efforts have been dedicated to improving the performance of quantum dot light-emitting diodes (QLEDs) in the past decade, primarily focusing on optimization of device architectures and synthetic procedures for high quality QDs. However, despite these efforts, the commercialization of QLEDs has yet to be realized due to the absence of suitable large-scale patterning technologies for high-resolution devices., This review will focus on the development trends associated with transfer printing, photolithography, and inkjet printing, and aims to provide a brief overview of the fabricated QLED devices. The advancement of various quantum dot patterning methods will lead to the development of not only QLED devices but also solar cells, quantum communication, and quantum computers.