• Title/Summary/Keyword: 바이오디젤연료

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Esterification of Indonesia Tropical Crop Oil by Amberlyst-15 and Property Analysis of Biodiesel (인도네시아 열대작물 오일의 Amberlyst-15 촉매 에스테르화 반응 및 바이오디젤 물성 분석)

  • Lee, Kyoung-Ho;Lim, Riky;Lee, Joon-Pyo;Lee, Jin-Suk;Kim, Deog-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.324-332
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    • 2019
  • Most countries including Korea and Indonesia have strong policy for implementing biofuels like biodiesel. Shortage of the oil feedstock is the main barrier for increasing the supply of biodiesel fuel. In this study, in order to improve the stability of feedstock supply and lower the biodiesel production cost, the feasibility of biodiesel production using two types of Indonesian tropical crop oils, pressed at different harvesting times, were investigated. R. Trisperma oils, a high productive non-edible feedstocks, were investigated to produce biodiesel by esterification and transesterification because of it's high impurity and free fatty acid contents. the kindly provided oils from Indonesia were required to perform the filtering and water removal process to increase the efficiency of the esterificaton and transesterification reactions. The esterification used heterogeneous acid catalyst, Amberlyst-15. Before the reaction, the acid value of two types oil were 41, 17 mg KOH/g respectively. After the pre-esterification reaction, the acid value of oils were 3.7, 1.8 mg KOH/g respectively, the conversions were about 90%. Free fatty acid content was reduced to below 2%. Afterwards, the transesterification was performed using KOH as the base catalyst for transesterification. The prepared biodiesel showed about 93% of FAME content, and the total glycerol content was 0.43%. It did not meet the quality specification(FAME 96.5% and Total glycerol 0.24%) since the tested oils were identified to have a uncommon fatty acid, generally not found in vegetable oils, ${\alpha}$-eleostearic acid with much contents of 10.7~33.4%. So, it is required to perform the further research on reaction optimization and product purification to meet the fuel quality standards. So if the biodiesel production technology using un-utilized non-edible feedstock oils is successfully developed, stable supply of the feedstock for biodiesel production may be possible in the future.

Spray Characteristics of Biodiesel Fuel by Blending Bioethanol and Diesel Fuel in a Common Rail Injection System (커먼레일 분사시스템에서 바이오에탄올 및 디젤연료 혼합 바이오디젤의 분무 특성)

  • Park, Su-Han;Suh, Hyun-Kyu;Kim, Hyung-Jun;Lee, Chang-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.2
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    • pp.82-89
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    • 2009
  • In order to investigate the spray characteristics according to diesel and bioethanol blending with biodiesel fuel, macroscopic spray characteristics were analyzed from the comparison of the effect of the injection pressure, ambient pressure and density on the spray tip penetration and spray cone angle. In addition, spray atomization characteristics were studied with local and overall Sauter mean diameter (SMD) and the contour map of SMD distribution at various injection conditions. It was revealed that the spray tip penetration of biodiesel fuels blended with diesel and ethanol was shorter than that of an undiluted biodiesel fuel at low injection pressure. However, the difference of spray tip penetration among three test fuels reduces at a high injection pressure. Increase of the ambient gas density leads to the decrease of the spray tip penetration of three test fuels. When diesel and ethanol fuels add to an undiluted biodiesel fuel, spray cone angle increases due to the decrease of the fuel density at the same ambient pressure condition. On the other hand, the droplet mean diameter decreases due to the reduction of the kinematic viscosity and surface tension.

Characteristics of Exhaust Emissions and Particle Size Distribution using Biofuel Blended Diesel Fuel in CRDI Diesel Engine with CPF (CPF를 장착한 CRDI 디젤엔진에 바이오 혼합연료 사용에 따른 배출가스 특성 및 입자수분포 특성)

  • Kim, H.N.;Sung, Y.H.;Kim, T.J.;Choi, B.C.;Lim, M.T.;Suh, J.J.
    • Journal of Power System Engineering
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    • v.12 no.1
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    • pp.5-12
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    • 2008
  • We measured emission characteristics of CRDI diesel engine equipped with a commercial CPF. Experimental parameters adopted a neat diesel fuel, a blend of diesel fuel with 20% biodiesel, a blend of diesel fuel with 15% biodiesel and 5% ethanol. The experiments were carried out to measure the emission and engine performance according to ESC 13-mode cycles. The maximum torque with biodiesel blend fuel is slightly lower than that of neat diesel fuel in the entire the 13-mode cycles, and 5% ethanol and 15% biodiesel blend fuel is slightly higher than that of neat diesel fuel. THC and CO emissions of the biofuel blended diesel fuel were slightly increased and decreased, and mean conversion efficiencies of THC and CO on the commercial CPF were achieved about 70$\sim$87% in the ESC 13-mode. From the measurement by the Scanning Mobility Particle Sizer(SMPS), the total number and mass of nano-sized particles by a commercial CPF were decreased about 97.8% and 96.8 % in the range of the nano-size from 10.6 to 385nm, respectively.

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Effects of Biodiesel Fuel on Exhaust Emission Characteristics in Diesel Engine(Using Soybean Oil) (디젤기관에서 바이오디젤 연료가 배기배출물 특성에 미치는 영향(대두유를 중심으로))

  • Lim, Jae-Keun;Choi, Soon-Youl;Cho, Sang-Gon
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.1
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    • pp.27-32
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    • 2008
  • Recently, we have a lot of interest in alternative fuels to provide energy independence from oil producing country and to reduce exhaust emissions for air pollution prevention. Biodiesel, which can be generated from natural renewable sources such as new or used vegetable oils or animal fats, may be used as fuel in diesel engine of compression ignition engine. In this paper, the test results on specific fuel consumption and exhaust emissions of neat diesel oil and biodiesel blends(10 vol.% biodiesel and 20 vol.% biodiesel) were presented using four stroke, direct injection diesel engine, especially this biodisel was produced from soybean oil at our laboratory. This study showed that Soot and CO emission were decreased as the blending ratios of biodiesel to diesel oil increased, on the other hand NOx emission was slightly increased because of the oxygen content in biodiesel. Also, the biodiesel blends yielded slightly higher specific fuel consumption than that of diesel oil because of lower heating value of biodiesel.

Analysis of Combustion Characteristics of Bio Diesel Fuel in a DI Diesel Engine Using PXI and LabVIEW (PXI와 LabVIEW를 이용한 직접 분사식 디젤기관의 바이오 디젤유 연소특성 분석)

  • Jung, S.H.;Kim, M.S.;Jang, S.H.;Koh, D.K.;Ahn, S.K.
    • Journal of Power System Engineering
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    • v.8 no.2
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    • pp.18-23
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    • 2004
  • Recently many researchers have been studying the development of alternative energy due to serious environmental pollution and drying up fossil energy. Among various alternative fuels, authors investigated the physical and combustion characteristics of the bio diesel fuel(BDF) which was made from the wasted vegetable oil. In this study, PXI and LabVIEW, which is a novel measuring instrument and online analysis, was used to investigate the combustion characteristics of BDF in a DI diesel engine.

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The Characteristics of Emission on Simultaneous Application with Biodiesel, Oxygenated Fuel(EGBE) and EGR in a DI Diesel Engine (DI 디젤기관에서 바이오디젤유와 함산소연료(EGBE) 동시적용 및 EGR에 의한 배기배출특성)

  • Choi, Seung-Hun;Oh, Young-Taig
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.3
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    • pp.143-148
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    • 2010
  • In this study, the potential possibility of biodiesel fuel(BDF) and oxygenated fuel(ethylene glycolvmono-n-butyl ether; EGBE) was investigated as an effective method of decreasing the smoke emission. The smoke emission of blending fuel (BDF and EGBE 0~20 vol-%) was reduced in comparison with diesel fuel and it was reduced approximately 64% at 2000 rpm, full load in the 20% of blending rate. But torque and brake specific energy consumption( BSEC) didn't have no large differences. Also, the effects of exhaust gas recirculation(EGR) for the reduction of NOx emission has been investigated. Consequently, It was found that simultaneous reduction of smoke and NOx emission was achieved with BDF(90 vol-%) and EGBE(10 vol-%) blended fuel and cooled EGR method(5~10%).

Energy Consumption of Biodiesel Production Process by Supercritical and Immobilized Lipase Method (초임계와 Lipase 고정화에 의한 바이오디젤 생산 공정의 에너지소비량)

  • Min, Eung-Jae;Lee, Euy-Soo
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.257-263
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    • 2012
  • Biodiesel is a renewable energy which is nontoxic and acting as a replacement for conventional diesel which derived from fossil fuel. Classified biodiesel producing way such as acid, base, supercritical and enzyme methods, this study focused on eco-friendly production of biodiesel using supercritical and immobilized enzyme process. Assuming a plant with a production rate of 10,000 tons a year, a PRO II simulator program was used to simulate the product conversion rate and total energy consumption. The product conversion in supercritical process and immobilized enzyme was found to be 91.17% (including 0.9% glycerol) and 93.18% (including 1.0% glycerol) respectively. The result shows that the efficiency of immobilized enzyme process is higher compared to supercritical process but having lower end product purity. From the energy consumption point of view, supercritical process consume about 8.9 MW while immobilized enzyme process consume much lower energy which is 3.9 MW. Consequently, this study certifies that energy consumption of supercritical process is 2.3 times higher than immobilized enzyme process.

A Study on Characteristics of Rice Bran Oil as an Alternative Fuel in Diesel Engine(I) (디젤기관의 대체연료로서 미장유의 특성 연구(I))

  • 오영택;최승훈;김승원
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.2
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    • pp.15-22
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    • 2002
  • Lately, our world is faced with very serious problems related to the increased air pollution of the exhaust emissions from automobiles. In particular, the exhaust emissions of diesel engines are recognized as a main cause which strongly influence environment. Lots of researchers have attempted to develop various alternative fuels to reduce these harmful emissions in diesel engine. The purpose of this investigation is to evaluate the possibility of esterfied rice bran oil for diesel fuel substitution in a naturally aspirated D. 1. diesel engine, and also find means to reduce smoke emissions in esterfied rice bran oil combustion. The smoke emission of esterfied rice bran oil is reduced remarkably in comparison with commercial gas oil, that is, it was reduced approximately 58.2% at 2500rpm. But, power, torque and brake specific energy consumption didn't have no large differences. It was concluded that esterfied rice bran oil can utilize effectively as an alternative and renew- able fuel fur diesel engine.

Power and Emission Characteristics of DI Diesel Engine with a Soybean Bio-diesel Fuel (바이오디젤유를 사용한 직접분사식 디젤엔진의 출력성능 및 배출가스 특성)

  • Choi, B.C.;Lee, C.H.;Park, H.J.
    • Journal of Power System Engineering
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    • v.6 no.3
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    • pp.11-16
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    • 2002
  • This paper describes the power performance and emission characteristics of the high speed direct injection diesel engine (2.9 litter displacements) driven by soybean oil asknown a bio diesel fuel. The results were compared to diesel fuel with blending bio diesel fuels. The soybean bio diesel fuel was added in the diesel fuel in concentration varying from 25% to 75% volume rates. We measured the emissions according to ECE 13 mode and full load, fixedengine speed. When the 25% bio diesel fuel was used, NOx emission at the ECE 13 mode test slightly decreased compared with diesel base engine. Over engine speed of 2000 rpm, the level of unburned hydrocarbon(HC) and carbon monoxide(CO) were the same to the diesel engine. Smoke emission decreased asthe blending bio diesel fuel rate increased.

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