• Title/Summary/Keyword: 밀도보정

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수용액중에서 모노에탄올아민의 CO2 흡수반응의 반응자유에너지의 밀도범함수 계산모델.

  • Jang, Yong-Hun;Kim, Yong-Jun;Wi, E-Hwan;Lee, Sang-Yeon
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.53-61
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    • 2014
  • 온실가스 증가로 인한 지구온난화 문제가 범세계적인 문제로 대두되고 있는 가운데, 특히 온실가스 중 약 76%이상을 차지하는 이산화탄소를 흡수하기 위한 흡수제 개발에 여러 국가들이 심혈을 기울이고 있다. 그 중 이산화탄소 흡수제로 가장 상용화 되어 있는 모노에탄올아민(monoethanolamine, MEA)은 분자량이 작아 몰 농도비에 따른 이산화탄소의 흡수에 유리하고 반응속도가 빠르다는 장점이 있으나, 재생에 필요한 에너지가 높다는 단점이 존재한다. 수용액중에서 MEA가 $CO_2$를 흡수하는 반응의 반응자유에너지는 반응메카니즘을 이해하는데 가장 기본적인 도구이다. 본 연구에서는 B3LYP, M06-2X의 밀도범함수를 이용하여 MEA의 $CO_2$ 흡수반응의 반응자유에너지를 계산하는 계산모델을 선정하였다. 수용액에서 MEA가 $CO_2$를 흡수하는 반응의 반응자유에너지를 밀도범함수를 이용하여 계산할 때는, 수용액상태에서 화학종의 분자구조를 최적화하는 것이 필요하였다. 또한 M06-2X 밀도범함수가 B3LYP 밀도범함수보다 좋은 결과를 주었으며, 분산보정을 하는 것이 보다 좋은 결과를 주었다.

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Measurement Method of Final Residual Radioactivity of Radioactive Metallic Waste for Clearance (규제해제 대상 방사성 금속 폐기물 최종잔류방사능 측정법)

  • Seo, Bumkyoung;Ji, Youngyong;Hong, Sangbum;Lee, Keunwoo;Moon, Jeikwon
    • Journal of Radiation Protection and Research
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    • v.38 no.4
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    • pp.228-233
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    • 2013
  • It has been continuously generated the requirement for the replacement of the main components such as a steam generator due to the deterioration of the nuclear power plant all around the world. Also, a large amount of radioactive metal was generated during the decommissioning in a short period. It is required to make an accurate measurement of the residual radioactivity for recycling the metal waste for releasing from regulatory control. In planning the measurement procedures, the influence of geometry, self-absorption, density and other relevant factors on the representativeness of the measurements should be considered for the decommissioning metal waste. In this study, the method for measurement procedures, the source term evaluation, the ways to secure representative samples, the measurement device for wide area and the self-absorption correction factors for different density were evaluated. The metal samples for measurement were prepared for securing the simple geometry and representative by melting process. The developed correction method for measuring the radioactivity a variety density of metal waste could improve the reliability of the evaluation results for clearance.

Treatment planning of Lung Cancer with Density corrected Computed Tomography (밀도를 입력한 CT planning을 이용한 Lung Cancer의 치료계획)

  • 김성규;김명세;신세원;홍정숙
    • Progress in Medical Physics
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    • v.4 no.2
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    • pp.19-25
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    • 1993
  • Treatment planning of lung cancer with density corrected Computed tomography. Eighty-seven patients with lung cnacer who had radiation therapy in Yeungnam University Medical Center between, April 1 1990 and Aug. 30 1993 were retrospectively evaluated total tumor dose, dose distribution, field correction, and loading change, compared with contour or CT image planning and density corrected CT planning. In dose distribution, higher dose was calculated in compare with density corrected CT planning less than 5% difference were found in 45 patient(52%), 5-10% in 25 patients (29%), 10-15% in 15 patients (17%) and over 15% in 2 patients (2%). Correction of treatment field was performed in 18 patients (21%) and changing of dose loading was given in 15 patients (17%). In conclusion, we emphasize that density corrected CT planning is the very important factor which contribute to increase therapeutic gain by exact selection of target volume, target dose, normal tissue dose and dose of critical organ.

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Determination of Neutron Absorption Fraction Factor in Manganese Sulfate Bath System (황산망간 용액조 장치의 중성자 흡수분율 보정인자 결정)

  • Lee, Kyung-Ju;Park, Kil-Oung;Hwang, Sun-Tae;Lee, Kun-Jai
    • Nuclear Engineering and Technology
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    • v.21 no.1
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    • pp.12-17
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    • 1989
  • The correction factor of neutron fraction absorbed by $^{55}$ Mn in the MnSO$_4$ bath was determined for the absolute measurement of neutron emission rate by using the solution circulation-type manganese sulfate bath system. For the determination of this correction factor, I/f, the atomic number desnsity and the effective neutron capture cross section data of Mn, S and impurity elements in the MnSO$_4$ solution were determined. For the atomic number density determination, the MnSO$_4$ solution concentration was determined by using the volumetric EDTA titration and gravimetric method. The impurity contents were analyzed by using the ICP method. For the calculation of effective neutron capture cross sections, a FORTRAN computer program EASCAL was developed in this study. in which Westcott's parameters and Axton's empirical relations are used.

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Evaluation and Determination of Air Void for Asphalt Concrete using a dielectric constant measurement (유전율 측정을 통한 아스팔트 콘크리트의 공극률 추정 연구)

  • Kim, Boo-Il;Kim, Yeong-Min;Cho, In-Sun
    • International Journal of Highway Engineering
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    • v.11 no.1
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    • pp.95-104
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    • 2009
  • This study was conducted to evaluate the relationship between the dielectric constant and air void of asphalt concrete. Standard specimens that have air voids of various range $(0%{\sim}20%)$ were used to measure the dielectric constant using parallel plate method that measures low frequency dielectric constant. From the tests, dielectric constant of asphalt concrete was tend to decrease as the frequency was increased, and the decrement slope was varied with the types of asphalt binders. Dielectric constant was decreased linearly as air void was increased from zero to twenty percent. Consequently, the effect of temperature and moisture content on dielectric constants of asphalt concrete was evaluated to develop the standard curve between dielectric constant and air void of asphalt concrete. The standard curve developed in this study can be used to calibrate or develop the algorithm of non-destructive density gauge.

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석회암지역에서 불연속면의 물리검층반응

  • Kim, Yeong-Hwa;Yang, Yeong-Geun;Kim, Jung-Yeol;Kim, Yu-Seong
    • Journal of the Korean Geophysical Society
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    • v.4 no.2
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    • pp.95-102
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    • 2001
  • As a basic study of characterizing fracture condition in bore hole, conventional geophysical well log data consisting of sonic, gamma-gamma and resistivity logs were compared with geological core log and acousic televiewer log in limestone geology. Discontinuities shown on the acoustic televiewer log and the core log show fairly good correlation. The conventional Geophysical log is also shown to bi effective in locating discontinities in limestone geology; sonic log shows the best result and resistivity shows the worst. Particularly, the combination method of density and sonic logs is shown to be the most effective in delineating discontinuities.

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Energy Efficient In-network Density Query Processing in Wireless Sensor Networks (무선 센서 네트워크에서 에너지 효율적인 인-네트워크 밀도 질의 처리)

  • Lee, Ji-Hee;Seong, Dong-Ook;Kang, Gwang-Goo;Yoo, Jae-Soo
    • Journal of KIISE:Computing Practices and Letters
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    • v.16 no.12
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    • pp.1234-1238
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    • 2010
  • In recent, there have been done many studies on applications that monitor the information of mobile objects using Wireless Sensor Networks (WSN). A density query that finds out an area spread by density that a target object requires in the whole sensing field is a field of object monitoring applications. In this paper, we propose a novel homogeneous network-based in-network density query processing scheme that significantly reduces query processing costs and assures high accuracy. This scheme is based on the possibility-based expected region selection technique and the result compensation technique in order to enhance the accuracy of the density query and to minimize its energy consumption. To show the superiority of our proposed scheme, we compare it with the existing density query processing scheme. As a result, our proposed scheme reduces about 92% energy consumption for query processing, while its network lifetime increases compared to the existing scheme. In addition, the proposed scheme guarantees higher accuracy than the existing scheme in terms of the query result.

Improved Density-Independent Fuzzy Clustering Using Regularization (레귤러라이제이션 기반 개선된 밀도 무관 퍼지 클러스터링)

  • Han, Soowhan;Heo, Gyeongyong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.24 no.1
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    • pp.1-7
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    • 2020
  • Fuzzy clustering, represented by FCM(Fuzzy C-Means), is a simple and efficient clustering method. However, the object function in FCM makes clusters affect clustering results proportional to the density of clusters, which can distort clustering results due to density difference between clusters. One method to alleviate this density problem is EDI-FCM(Extended Density-Independent FCM), which adds additional terms to the objective function of FCM to compensate for the density difference. In this paper, proposed is an enhanced EDI-FCM using regularization, Regularized EDI-FCM. Regularization is commonly used to make a solution space smooth and an algorithm noise insensitive. In clustering, regularization can reduce the effect of a high-density cluster on clustering results. The proposed method converges quickly and accurately to real centers when compared with FCM and EDI-FCM, which can be verified with experimental results.