• Title/Summary/Keyword: 미세기공

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Preparation of Asymmetric Ceramic Membrane by Coating-Pyrolysis Process (도포-열분해법을 이용한 비대칭 세라믹 분리막 제조)

  • Ryu, Hyun-Wook;Kim, Byung-Hoon
    • Journal of the Korean Ceramic Society
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    • v.39 no.12
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    • pp.1153-1157
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    • 2002
  • The fabrication of a three-layered asymmetric ceramic membrane was performed by slip casting of the porous alumina support and dip coating of the alumina intermediate layer using high purity ${\alpha}-Al_2O_3$ powders that have different particle size, followed by screen printing-pyrolysis of the $Tio_2$ layer as an ultrafilteration membrane using Ti-naphthenate solution. The bending strength, porosity and mean pore size of the alumina support were 231 kg/$cm^2$s, 30.26% and 0.19 ${mu}m$, respectively. The thickness of the intermediate layer was 30 ${mu}m$ and the mean pore size of that was 0.063 ${mu}m$. Also, the top layer was 0.5 ${mu}m$ thick and micropores with about 20 nm size were formed uniformly.

Preparation and characterization of nanoporous monolith with high thermal insulation performance (나노 기공성 단열 실리카 모노리스 제조 및 특성 연구)

  • Choi, Hyun-Muk;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.83-91
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    • 2014
  • In this study, we synthesized two different silica monoliths by using sol-gel, solvent exchange, surface modification, ambient pressure drying processes, and surfactant-based templating technique followed by calcination process. All of the prepared two silica monoliths showed crack-free appearance with fairly good transparency, and furthermore were confirmed to have extremely high porosity, specific surface area, and mean pore size below 30 nm. The silica aerogel sample exhibited finer and more homogeneous nano-sized pore structure due to spring back effect caused by surface modification, which resulted in better thermal insulation performance. Based on measured thermal conductivities and theoretical relationship, multi-layered glass window system in which silica monolith prepared in this study was inserted as a middle layer was revealed to have superior thermal insulation performance compared to conventional air-inserted glass window system.

Fabrication of porous titanium oxide-manganese oxide ceramics with enhanced anti-static and mechanical properties (우수한 대전방지 및 기계적 성질을 가지는 다공성 산화티탄-산화망간 세라믹스 제조)

  • Yu, Dongsu;Hwang, Kwang-Taek;Kim, Jong-Young;Jung, Jong-Yeol;Baik, Seung-Woo;Shim, Wooyoung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.6
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    • pp.263-270
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    • 2018
  • Recently, porous ceramic materials with anti-static performance are urgently needed for semiconductor and OLED/LCD display manufacturing industry. In this work, we fabricated porous titanium manganese oxide ceramics having the surface resistivity of $10^8-10^{10}$ ohm and enhanced mechanical strength by partial sintering method using nanosized titanium oxide. By addition of nano-sized titanium oxide in the matrix, neck formation between grains was strengthened, which remarkably increased flexural strength up to 170 MPa (@porosity: 15 %), 110 MPa (@porosity: 31 %), compared to 80 MPa (@porosity: 26 %) for pristine titanium manganese oxide ceramics. We evaluated the performances of our ceramics as air-floating module for OLED flexible display manufacturing devices.

Fabrication of nanoporous ceramic membrane for water treatment (수처리용 나노스케일 다공성 세라믹 멤브레인 제조)

  • Han, Hyuk Su;Lee, Ho Jun;Ryu, Jeong Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.2
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    • pp.77-81
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    • 2019
  • Recently, as the problem of environmental pollution emerges, various methods of eco-friendly water treatment method are being developed. Polymer membranes, which are currently leading the market, are inexpensive, but have many problems in terms of chemical resistance and durability. Thus, ceramic membrane has been attracted great attention as high-efficiency water treatment due to excellent durability and chemical resistant. In this study, ceramic membranes were developed via pore structure, size control, and surface treatment. The pore size of the membrane was controlled through the formation of $ZrO_2$ and $TiO_2$ coating films. Tape casting and sol-gel process were used to form a ceramic coating film with nanopores on the surface of the membrane. Microstructure analysis of ceramic membrane and pore size analysis of the coating film were conducted and the change of water treatment characteristics was observed.

Manufacturing and Application of Activated Carbon and Carbon Molecular Sieves in Gas Adsorption and Separation Processes (가스 흡착 및 분리공정용 활성탄소와 탄소분자체의 제조 및 응용)

  • Jeong, Seo Gyeong;Ha, Seongmin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.488-495
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    • 2022
  • Activated carbon (AC) and carbon molecular sieve (CMS) have attracted attention as porous materials for recovery and separation of greenhouse gases. The carbon molecular sieve having uniform pores is used for collecting and separating gases because it may selectively adsorb a specific gas. The size and uniformity of pores determine the performance of the CMS, and chemical vapor deposition (CVD) is widely used to coat the surface with a predetermined thickness in order to control the CMS's micropores. This CVD method can be used to control the size of pores in CMS manufacturing, but it must be optimized because of its various experimental variables. Therefore, in order to produce AC and CMS for gas adsorption and separation, this review focuses on various activation processes and pore control technologies by CVD and surface treatment.

An on-line process information system for nano-fiber webs (나노 파이버웹의 온.인 공정 정보 시스템)

  • 김주용;임대영;변성원
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.143-145
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    • 2003
  • 전기방사에 의해 제조되는 나노 파이버웹은 섬유가 매우 가늘고, 기공이 미세하며 비표면적이 매우 커서 필터 및 전극재료에 적합한 산업용 소재이다. 나노 웹의 구조는 방사 용액의 농도, 방사 온도, 압력, 전압등 여러 변수들에 의해 영향을 받으며, 이 변수들의 구조에 미치는 영향들이 이론적, 실험적으로 많이 연구, 보고되어 있다 [1]. 그러나, 공정의 분석 및 제어에 대한 연구는 매우 드물며, 특히 대량 생산하에서의 품질 관리 시스템에 대한 연구는 전무한 실정이다. (중략)

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Study on the Hindered Diffusion Within Disordered-Fibrous Membrane and Gels(I) (불규칙 섬유상(disordered-fibrous) 멤브레인이나 젤(gel)에서의 제한적 확산(hindered diffusion) 현상에 관한 연구(I))

  • 전명석;김재진
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.139-140
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    • 1997
  • 1. 서론 : 한외 및 정밀여과의 분리메카니즘에 연관된 물리적 현상에 대해 현재까지 진행된 많은 연구들은, 막기공이 갖는 복잡하고 불규칙한 구조를 단순하고 규칙적인 well-defined 구조인 실린더형이나 슬릿형 기공으로 가정하여 문제를 전개하고 있다. 본래, 다공성 매질(porous media)에서의 유체흐름을 다루는 이론 및 실험연구자들에 의해 제안된 섬유상 매질(fibrous media)에 대한 해석은 계의 미세구조(microstructure)에 추계적 개념을 적용시키려는 최근의 추세에 따라 점차 관심이 높아가고 있다.(생략)

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졸-겔 법에 의한 알루미나 한외여과막의 제조 및 특성에 관한 연구

  • 최양희;김은옥;최재호;이용택
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.40-42
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    • 1991
  • 최근에 분리 농축 그리고 정제 등의 분야에서 세라믹 분리막은 내열성, 내약품성 및 우수한 기계적 강도와 같은 특성으로 인해 기존의 유기고분자막으로는 사용할수 없던 영역까지 그 응용 범위를 확대시키고 있다. 이러한 세라믹 분리막 중 기공크기가 0.1-0.001 $\mu$m 정도로 미세한 한외여과막의 경우, 최근에는 주로 졸-겔법을 이용하여 제조되는 것으로 보고되고 있는데, 이는 졸-겔법이 기존 분리 공정과 비교하여 볼대 다음과 같은 장점이 있기 때문이다.

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InfluenceofPre-TreatmentontheFormationofOrderedNano-SizedPoresFabricatedbyAluminumAnodizationMethod (전처리공정이알루미늄얌극산화법에의해제조된규칙적인나노급미세기공의형성에미치는영향)

  • Lee Jae-Hong;Lee Byung-Wook;Kim ChangKyo;Hong Chinsoo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.6
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    • pp.239-244
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    • 2005
  • Nano-sizedporearrayswerepreparedbytheself-organizationprocessesoftheanodicoxidationusingthealuminumplatewith99.999$\%$purity.Sincethealuminumplatehasaroughsurface,thealuminumplateof1mmthicknesswasanodizedafterthepre-treatmentsofpressing,mechanicalpolishing,thermaloxidation,chemicalpolishing,andelectrochemicalpolishing.Thediameterofthenano-sizedporesandthethicknessofbarrierlayercanbecontrolledbyappliedvoltage.Thethicknessofaluminamembranecanalsobecontrolledbytheanodizingcurrent.Thenano-sizedporeswithdiameterof60$\~$120nm,thedistancebetweenthenearestporesof30$\~$60nm,andthethicknessof6$\~$7Wwereobtainedbytheanodicoxidationprocess.Theporewideningprocesswasemployedforobtainingtheone-channelwithflatsurfacebecausetheporesofthealuminamembranepreparedbythefixedvoltagemethodshowsthestructureoftwo-channelwithroughsurface.