Browse > Article
http://dx.doi.org/10.4191/KCERS.2002.39.12.1153

Preparation of Asymmetric Ceramic Membrane by Coating-Pyrolysis Process  

Ryu, Hyun-Wook (Department of Ceramic Engineering, Chonnam National University)
Kim, Byung-Hoon (Department of Ceramic Engineering, Chonnam National University)
Publication Information
Journal of the Korean Ceramic Society / v.39, no.12, 2002 , pp. 1153-1157 More about this Journal
Abstract
The fabrication of a three-layered asymmetric ceramic membrane was performed by slip casting of the porous alumina support and dip coating of the alumina intermediate layer using high purity ${\alpha}-Al_2O_3$ powders that have different particle size, followed by screen printing-pyrolysis of the $Tio_2$ layer as an ultrafilteration membrane using Ti-naphthenate solution. The bending strength, porosity and mean pore size of the alumina support were 231 kg/$cm^2$s, 30.26% and 0.19 ${mu}m$, respectively. The thickness of the intermediate layer was 30 ${mu}m$ and the mean pore size of that was 0.063 ${mu}m$. Also, the top layer was 0.5 ${mu}m$ thick and micropores with about 20 nm size were formed uniformly.
Keywords
$TiO_2$ membrane; Porous alumina; Ti-naphthenate; Pyrolysis process;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 K. K. Chan and A. M. Brownstein, 'Ceramic Membranes Growth Prospects and Opportunities,' Am. Ceram. Soc. Bull., 70 [4] 703-07 (1991)
2 R. J. R. Uhlhom, M. H. B. J. Huis In't Veld, K. Keizer and A. J. Burggraaf, 'Synthesis of Ceramic Membranes, Part I Synthesis of Non supported and Supported $\gamma$Alumina Membranes without Defects,' J. Mater. Sci., 27 527-37 (1992)   DOI
3 M. A. Alvin, T. E. Lippert and J. E. Lane, 'Assessment ofPorous Ceramic Materials for Hot Gas Filteration Appli-cation,' Am. Ceram. Soc. Butt., 70 [9] 1491-98 (1991)
4 J. S. Kim, C. K. Cho and H. K. Ha, 'Environmental Pollution Protection Technologies by Ceramic Membrance,'Bull. Kor. Ceram. Soc., 10 [3] 231-37 (1995)
5 A. J. Burggraaf and K. Keizer, Inorganic Membranes; Chap. II, Edited by R. R. Bhave, Van Nistrand, New York, 1991
6 S. H. Hyun, M. A. Anderson and S. P. Yoon, 'Development of Ceramic Composite Membranes for Gas Separation: I. Coating Characteristics of Nanoparticulate SiO$_2 Sols,' J. Kor. Ceram. Soc., 29 [6] 496-504 (1992)
7 K. Kato, 'Photocatalytic Property of TiO$_2$ Anchored on Porous Alumina Ceramic Support by the Alkoxide Methode,' J. Ceram. Soc. of Jpn., 101 [3] 245-49 (1993)   DOI
8 J. K. You and E. S. Lee, 'A Study on Preparation of Alu-mina Membranes(I),' J. Kor. Ceram. Soc., 30 [7] 589-97 (1993)
9 J. H. Lee, S. C. Choi and K. S. Han, 'Microstructural Change of Doped-alumina Membrane,' J. Kor. Ceram. Soc., 36 [10] 1040-47 (1999)
10 A. Kakimi, S. Okamura, Y. Yagi, K. Mori and T. Tsukamoto, 'Fabrication of Ferroelectric Bi$_{4}Ti_{3}Oi_{2}$ Thin Films by Dipping Pyrolysis of Metal Naphthenates and Micropatternsby an Electron Beam,' Jpn. J. Appt. Phys., 33 [9B] Pt.l 5301-04 (1994)   DOI
11 H. W. Ryu and K. S. Hwang, 'Atomic Force Microscopy Study of Epitaxial Bi$_{4}Ti_{3}O_{12}$ Thin Films Formed using a Dipping-pyrolysis Process,' J. Kor. Phys. Soc., 40 [3] 493-96 (2002)
12 K. S. Hwang, H. M. Lee and B. H. Kim, 'Preparation of Bi$_{4}Ti_{3}O_{12}$ Films by Dipping-pyrolysis Process,' J. Kor. Ceram. Soc., 35 [9] 1002-05 (1998)
13 K. S. Hwang and B. H. Kim, 'Preparation of Epitaxial Bi$_{4}Ti_{3}O_{12}$ Thin Films on MgO(100) Substrates,' Kor. J. Ceram., 4 [1] 33-6 (1998)
14 Y. Gu and G. Meng, 'A Model for Ceramic Membrane Formation by Dip Coating,' J. Eur. Ceram. Soc., 19 1961-66 (1999)   DOI   ScienceOn
15 J. Luyten, J. Cooymans, C. Smolders, S. Vercauteren, E. F. Vansant and R. Leysen, 'Shaping of Multilayer Ceramic Membranes by Dip Coating,' J. Eur. Ceram. Soc., 17 273-79 (1997)   DOI   ScienceOn