• Title/Summary/Keyword: 미량 화학

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Importance of Extracellular Enzyme Activities in Northern Peatland Biogeochemistry-Possible Coupling with Trace Gas Emission and DOC Dynamics (북구 이탄습지의 생지화학적 반응에 있어서 체외효소의 중요성-미량기체 발생량 및 용존유기탄소 동태와의 연관성에 대하여)

  • Freeman, Chris;Park, Seok-Soon;Kang, Ho-Jeong
    • Korean Journal of Ecology and Environment
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    • v.39 no.4 s.118
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    • pp.435-444
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    • 2006
  • A suite of extracellular enzyme activities involved in organic carbon decomposition were determined in three northern peatlands (a bog, a fen, and a swamp) over a 12 month period along with trace gas ($CO_2$ and $N_2O$) flux and DOC dynamics in the wetlands. The activities varied $0.008-0.066\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.021\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.003-0.016\;{\mu}mole\;g^{-1}\;min^{-1}$, $0.004-0.047\;{\mu}mole\;g^{-1}\;min^{-1}$, for ${\beta}-glucosidase$, cellobiohydrolase, ${\beta}-xylosidase$, and N-acetylglucosaminidase, respectively. In general, the activities were highest in the forested swamp followed by the fen and the bog. When the data from three wetlands are combined, the enzyme activities exhibited significant positive correlations with trace gas emission and available carbon. Further, the average activity of 4 enzymes explained about 20-40% of the variations of trace gas emssion and available carbon. The results indicate that enzymes related to the mineralization of organic carbon may play an important role in trace gas flux and DOC dynamics in northern peatlands.

Assessment of Micro Organic Pollutants Removal Using Advanced Water Treatment Process and Nanofiltration Process (고도처리공정과 나노여과공정에서의 미량유해물질 제거 평가)

  • Kang, Joon-Seok;Choi, Yang-Hun;Kwon, Soon-Buhm;Yu, Young-Beom
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.8
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    • pp.579-587
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    • 2014
  • Various kinds of micro organic pollutants have frequently been detected from a water system. Therefore, it is considered to be very important part in the drinking water treatment system. And the research about removal process and processing efficiency have been being conducted briskly. In this study, the removal efficiency was evaluated using advanced water treatment process and nanofiltration process. The removal efficiency of nanofiltration process was very different according to physical and chemical characteristics of materials. The molecular weight of cutoff was the most influential factor in the removal efficiency. And when pKa value was higher than pH of raw water or Log Kow value was below 2, the removal efficiency of material was decreased. In case of oxidation reaction, the bigger the molecular weight of material was and the more hydrophobic a material was, the less oxidation reaction occurred. And the removal efficiency was decreased. Most unoxidized materials were removed by absorption. And the more actively oxidation reaction occurred by $H_2O_2$, the more absorption reaction increased.

Anatomical Characteristics and Trace Elements of Historical Papers and Cloths from Neunggasa Temple in Korea (능가사 출토 종이와 섬유의 해부학적 성질 및 미량원소 분석)

  • Wazny, Agnieszka Helman;Park, Won-kyu
    • Journal of Conservation Science
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    • v.10 no.1 s.13
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    • pp.1-9
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    • 2001
  • The objective of this study is to examine the characteristics of historical papers and cloths found at Neunggasa temple, Goheunggun, Chonnam Province, Korea, using light microscopy, image analysis and SEM-EDS for fiber morphology and trace metal composition. All papers were made from paper mulberry. Transparent membrane, which was separated from bast fiber, was unique in these fibers. The papers found on the wall of Daewungjun were most highly degraded and those of the books, which were excavated under Cheungwangmun, were relatively well preserved. The cloths found under the statue 'Dong-bangjiguk' were silk, very narrow fiber without any marks. In the analysis of SEM-EDS, high content of silica was detected. Also small content of calcium was taken into consideration. Content of iron and chlorine were discussed from the viewpoint of potentially harmful elements for the conservation of paper. The composition of trace elements could not be used to determine the origins of papers.

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Characteristics of Thin Film Electric Resistance Probe Prepared at Various Sputtering Condition (박막형 전기저항식 부식속도 측정 센서의 금속층 증착조건에 따른 전기화학적 특성 변화)

  • 방일환;원덕수;송홍석;장상엽;이성민;고영태;김지영
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.05a
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    • pp.95-95
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    • 1998
  • 현장에서 부식속도를 측정하는 방법의 하나인 전기저항 프로브(Electric Resistance Probe, ER probe)는 시편이 부식되는 양에 비례하여 저항이 증가하는 원리를 이용한 것으로 부식기구에 무관하게 직접적인 부식속도의 측정이 가능하다. 그러나, 와이어나 판형으로 기계 가공된 프로브로 제작되어 미량의 부식에는 저항변화폭이 작아 긴 측 정시간이 필요하고, 특히 국부 부식의 경우 부식이 상당히 진행되더라도 전체 저항변 화가 크지 않은 문제점이 있다. 박막형 전기저항프로브는 미량의 부식에서도 저항변화폭이 크게 나타나도록하기 위 하여 금속 박막을 스퍼터링으로 증착하여 동일 부식량에서 저항 변화율을 크게 향상 시킨 프로브이다. 이 프로브는 좁은 선폭(O.25-1mm)의 세선을 복수개 포함한 형상으로 프로브를 설계하여 핏팅이 발생하면 하나의 세선이 끊어지도록 하여 국부적인 부식이 일어날 경우에도 저항변화가 크게 나타나도록 고안되었다. 탄소강의 경우 일반적인 환경에서는 부식속도가 결정립의 크기, 가공경화의 정도등 에 민감하게 변화되지 않는 것으로 알려져 있으나, 박막으로 증착되었을 경우에는 별 크재료와는 전혀 다른 미세구조를 가지므로 벌크의 부식거동과는 다른 거동을 보일 수 있다. 이 연구에서는 증착조건을 달리하여 증착된 철 박막의 결정성, 비저항, 표면 상태, 조성등을 4 point 프로브, SEM, Auger spectroscopy등을 이용하여 조사하고 각각의 전위, 부식속도등과의 상관관계를 조사하였다. 증착된 박막의 비저항은 증착중 혼입된 산소의 양에 따라 매우 민감하게 변화하였다. 산소가 l0at%이상 함유된 철은 강의 알려진 비저항보다 수십배 높은 비저항을 보이며, 부식전위가 높아지고 실제 부식속도 또한 매우 낮게 나타났다. 박막의 부식거동은 미량 불순물에 의해서도 크게 변화하였는데 동일한 수준의 비저 항을 갖는 철 박막에서도 99.9% 순도의 철을 타켓으로 하여 증착된 막은 일반 저탄소 강을 타켓으로 하여 증착된 막보다 훨씬 낮은 부식속도를 보였다.

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A Study of the Effect on Fertilization Condition on the Several Essential Elements in 2 Lettuce Cultivas (상치의 시비조건에 따른 상치내 몇 가지 미량원소의 함량에 관한 연구)

  • Kwon, O-Dal;Chung, Keun-Hi;Lee, Jin-Hi
    • Korean Journal of Organic Agriculture
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    • v.7 no.1
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    • pp.147-159
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    • 1998
  • In order to study the effects of chemical fertilizer and organic fertilizer on the toxic mineral content in the absence or presence of the wood extraction, the lettuce an experiment of fatal 20 treatments was conducted far a peried of 10 weeks. The results obtained from the experiment are summarized as follows; 1. The mineral contents of the lettuce in the wood extraction-treated group and the wood extraction non-treated group showed no conspicious differenves. 2. These are no prominent differences in the mineal contents(Chromium, Nickel, Lead, and Aluminium) in the lettuce between the organic fertifized group and the lettuce raised in the chemical fertilized group. 3. Mercury was not detected in all samples of lettuces raised in all treatments.4. Cadmium contents in the lettuce samples were increased as the amount of organic fertilizer was increased from 25% to 100%.

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보은 지역의 온천 변성염기성암에 대한 암석.지구화학적 연구

  • 권성택;이동호
    • The Journal of the Petrological Society of Korea
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    • v.1 no.2
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    • pp.104-123
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    • 1992
  • We present petrography, mineral chemistry of amphibole and plagioclase, and major and trace element chemistry for the Ogcheon metabasites occurring in the Poun and Mungyong areas to understand metamorphism, and to define chemical characteristics of parental rocks and their implication for tectonic environment. The Ogcheon metabasites often preserve relict igneous textures, although no primary phases are observed. They are mainly composed of amphibole (actinolite+hornblende)+plagioclase+epidote+chlorite+sphene+opaque oxides, indicating epidote amphibolite facies metamorphism. Coarse-grained amphiboles frequently have actinolitic composition in the core, and hornblende along the margin and cleavage, which can be interpreted either as miscibility gap or as result of polymetamorphism. Although presumed polymetamorphic events in the Ogcheon supergroup favor the latter possibility, further metamorphic studies are necessary to solve the problem. Amphibole and plagioclase chemistries suggest greenschist (epidote-amphibolite, if miscibility gap is present) to amphibolite facies metamorphism of possibly medium pressure. The major and trace element data of whole rocks indicate that the Ogcheon metabasites are transitional to tholeiitic basalts belonging to within-plate environment. Absence of evidences indicating deep sea environment suggests that the Ogcheon metabasites emplaced in an intra-cratonic, possibly rift environment which failed to proceed to an oceanic rift. Chemical variation of the metabasites toward a granitic pluton indicates K loss closer to the pluton, suggesting that caution should be taken when K is involved in a discussion.

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Structure Elucidation of Minor Organic Constituents from Polyozellus multiflex (까치버섯 (Polyozellus multiflex)이 생산하는 미량 유기화합물의 화학구조)

  • Hwang, Ji-Sook;Ryu, Jong-Ha;Gu, Gyo-Cheol;Kwak, Ju-Yeon;Kim, Sang-In;Yoo, Ick-Dong;Song, Kyung-Sik
    • The Korean Journal of Mycology
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    • v.26 no.4 s.87
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    • pp.519-524
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    • 1998
  • Four minor compounds were isolated from fruiting bodies of Polyozellus multiflex by consecutive chromatographic separation. Their structures were identified as ergost-4,6,8,22-tetraen-3-one, 4-methoxy-6-methyl-2H-pyran-2-one, p-anisic acid, and p-hydroxybenzoic acid by spectral analysis. They could not inhibit prolyl endopeptidase nor acetylcholine esterase at the concentration up to 100 ppm.

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Field Effect Transistors for Biomedical Application (전계효과트랜지스터의 생명공학 응용)

  • Sohn, Young-Soo
    • Applied Chemistry for Engineering
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    • v.24 no.1
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    • pp.1-9
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    • 2013
  • As the medical paradigm is changing from disease treatment to disease prevention and an early diagonosis, the demand to develop techniques for the detection of minute concentrations of biomolecules is increasing. Among the various techniques to sense the minute concentration of biomolecules, the biosensors utilizing the matured semiconductor techniques are presented here. To understand such biosensors, the structure and working principle of a MOSFET (Metal-oxide-semiconductor field-effect transistor) which is the basic semiconductor device is firstly introduced, and then the ISFET (Ion sensitive FET), BioFET (Biologically modified FET), Nanowire FET, and IFET (Ionic FET) are introduced, and their applications to biomedical fields are discussed.

Scientific Study of Punch'ong and Whiteware from Ch'unghyodong Kwangju (I). Analysis of Chemical Compositon (광주 충효동 분청과 백자의 과학기술적 연구 (Ⅰ). 성분분석을 중심으로)

  • Lee, Young Eun;Koh, Kyong Shin
    • Journal of the Korean Chemical Society
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    • v.42 no.3
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    • pp.251-265
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    • 1998
  • Punch'ong and whiteware sherds excavated from four kilns located in Ch'unghyodong, Kwangju, Chollanamdo were analyzed for their body and glaze composition. They are classified into eight different groups by the site and layer from which they were collected. In principal component analysis of major composition, the punch'ong body separates out into several different groups. CHE2, made in early fifteenth century, has a higher aluminum and lower iron content compared to the later groups of lower grade. Whiteware body has a very high aluminum content of around 30 wt. in both soft type and hard type. Punch'ong glaze was determined to be lime type and whiteware alkali-lime type.

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Geochemical Study on the Mobility of Dissolved Elements by Rocks-$CO_2$-rich waters Interaction in the Kangwon Province (강원도 지역 탄산수와 암석간의 반응에 의한 용존 원소들의 유동성에 관한 지구화학적 연구)

  • 최현수;고용권;윤성택;김천수
    • Economic and Environmental Geology
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    • v.35 no.6
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    • pp.533-544
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    • 2002
  • In order to investigate the relative mobility (RM) of dissolved elements during processes controlling major and trace element content, the concentrations of major, minor and trace elements were reviewed from the previous data of $CO_2$-rich waters and granites from Kangwon Province. The relative mobility of elements dissolved in $CO_2$-rich waters is calculated from $CO_2$-rich water/granite ratio with normalizing by sodium. The results show that gaseous input of magmatic volatile metals into the aquifer is negligible in this study area, being limited by cooling of the rising fluids. Granite leaching by weakly acidic, $CO_2$-charged water is the overwhelming source of metals. Poorly mobile element (Al) is preferentially retained in the solid residue of weathering, while alkalis, alkaline earth and oxo-hydroxo anion forming elements (especially As and U) are mobile and released to the aqueous system. Transition metals display an intermediate behavior and are strongly dependent on either the redox conditions (Fe and Mn) or solid surface-related processes (adsorption or precipitation) (V, Zn and Cu).