• Membrane Journal
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• v.10 no.4
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• pp.186-191
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• 2000

The recovery of three ethyl esters (aroma model compounds; ethyl acetate, ethyl propionate. ethyl butyrate) from aqueous solutions was studied for vapor permeation with surface-modified hydrophobic alumina membrane, Although the driving force of ethyl butyrate is the highest, the ethyl butyrate concentration in permeate is lower than those of propionate and acetate. Since the solubility of aroma compounds for water is very low, phase separation occurred in permeate, and we could obtain pure ethyl esters. The experimental results showed that the porous hydrophobic alumina membrane had high selectivity and permeation flux on the ester-model compounds.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1992.10a
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• pp.81-86
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• 1992

원자력발전소 1차 계통 내의 건전성 감시를 위한 설비로는 음향누설 감시계 통(Acoustic Leak Monitoring System: ALMS), 금속파편 감시계통(Loose Parts Monitoring System: LPMS) 및 원자로내부구조물 진동감시계통 (Internals Vibration Monitoring System: IVMS)등이 있다. 현재, 국내의 여 러 원전에는 이들중 일부 계통들이 선택적으로 설치되어 운전중이며, 영광 3,4호기에서는 국내 최초로 이들 3개의 계통을 종합한 핵증기공급계통 건전 성감시계통(Nuclear Steam Supply System Integrity Monitoring System: NIMS)을 설계하였다. 특히, 영광 3,4호기 NIMS에서는 각 계통에 의해 감지 된 1차 계통 내의 이상상태를 하나의 분석컴퓨터(Analysis Computer)를 사 용하여 해석하는 종합결함 탐지해석 기법을 도입하였다.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.05a
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• pp.177-182
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• 1999

감압증발의 효율을 향상시키기 위한 방법으로 액주내의 기포생성에 의한 자기 미립화를 수반하는 과열액분류의 증발을 분사 감압증발이라고 하며, 특히 적절한 방법으로 액체내에 기포핵을 공급하는 경우에는 매우 좋은 증발성능이 얻어 진다는 것이 보고되어 있다. 따라서 본 연구에서는 온배수를 감압증발시켜 저온저압의 증기를 제조하여 MVR로부터 승온승압에 의해 고온의 증기를 얻기위한 것이 연구의 목적이므로, 증발효율향상을 위해 기포핵 공급용 전해전류장치를 설치하고, 감압증발용의 노즐을 원통형 튜브로 대체하기위해 튜브형 노즐로 부터 과열액을 급격히 감압시켜 자기미립화에 의한 증발을 유도하여 전해전류가 증발효율에 미치는 영향을 실험적으로 연구하고자 작동액체로써 물을 사용하고, 액체온도, 액체유량, 과열도 및 기포핵 공급용의 전해전류량을 변화시켜 실험을 수행하였다.(중략)

• Journal of Energy Engineering
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• v.11 no.3
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• pp.237-246
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• 2002

If the safety depressurization system of APR-1400, the Korean next generation reactor, is in operation, water, air and steam are successively discharging into a in-containment refueling water storage tank through spargers. Among the phenomena occurring during the discharging processes, the air bubble clouds produce a low-frequency and high-amplitude oscillatory loading, which may result in the most significant damages to the submerged structures if the oscillation frequency is the same or close to the natural frequency of the structures. The involved phenomena are so complicated that most of the prediction of frequency and pressure loads has been resorted to experimental work and computational approach has been precluded. This study deals with a numerical simulation on the behavior of air bubble clouds discharging into a water pool through a sparger, by using a commercial thermal hydraulic analysis code, FLUENT, version 4.5. Among the multiphase flow models, the VOF (Volume Of Fluid) model was selected to simulate the water, air and steam flows. A satisfactory result was obtained comparing the analysis results with the ABB-Atom test results which had been performed for the development of sparser.

• Journal of Korea Soil Environment Society
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• v.5 no.1
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• pp.13-23
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• 2000

The effects of operating condition of soil vapor extraction system and the characteristics of site on the remediation of oil contaminated soil were investigated. Thorough investigation showed that the site was contaminated with gasoline leaked from underground storage tank and the maximum concentration of BTEX and TPH were 1,081 ppm and 5,548 ppm respectively. The leaked gasoline were diffused to 6m deep and the area and volume of the polluted soil were assumed to 170$m^2$ and 1,000$\textrm{m}^3$respectively. The site were consisted of three different vertitical layers, the top reclaimed sandy soil between the earth surface and 3~4m deep, middle silty sand between 3~4m and 6m deep, and the bottom bedrock below the 6m deep. The air pemeability of soil was measured to 1.058-1.077$\times$10$^{-6}$ $\textrm{mm}^2$ by vacuum pump tests. The groundwater which level was 3~4m deep was observed in some areas of this site. The soil vapor extraction system which had 7.5 HP vacuum pump and 8 extraction wells was constructed in this site and operated at 8 hrs/day for 100 days. The BTEX was removed with above 90% efficiency where no groundwater and silty sand were observed. On the contrary, the efficiency of BTEX and TPH were dramatically decreased where groundwater and silty sand were observed. The flow rate of soil air induced by soil vapor extraction system was reduced in deeper soil.

• Economic and Environmental Geology
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• v.46 no.5
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• pp.425-444
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• 2013

This study was carried out in order to determine the remediation of total petroleum hydrocarbons (TPHs), trichloroethylene (TCE), perchloroethylene (PCE), benzene, toluene, ethylbenzene and xylenes (BTEX) compounds for non-aqueous phase liquids (NAPLs) using in-situ air sparging (IAS) / vapor extraction (VE) with the marine sediments of Mandol, Hajeon, Sangam and Busan, South Korea. Surface sediment of Mandol area had sand characteristics (average particle size, 1.789 ${\Phi}$), and sandy silt characteristics (average particle size, 5.503 ${\Phi}$), respectively. Sangam surface sediment had silt characteristics (average particle size, 5.835 ${\Phi}$). Sediment characteristics before experiment in the Busan area showed clay characteristics (average particle size, 8.528 ${\Phi}$). TPHs level in the B1 column of Mandol, Hajeon, Sangam, and Busan sediments were 2,459, 6,712, 4,348, and 14,279 ppm. B2 (3 L/min) to B5 (5 L/min) columns reduced 99.5% to 100.0% of TCE and 93.2% to 100.0% of PCE. Removal rates of TCE, PCE, and BTEX are closely correlated (0.90-0.99) with particle sizes and organic carbon concentrations. However, TPHs (0.76) and benzene (0.71) showed the poorer but moderate correlations with the same parameters.

• Applied Biological Chemistry
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• v.40 no.1
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• pp.71-75
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• 1997

Important physicochemical properties of captafol [N-(1,1,2,2-tetrachloro-ethylthio)cyclohex-4-ene-1,2-dicarboximide], water solubility, vapor pressure, hydrolysis and octanol/water partition coefficient(Kow) were measured based on the standard EPA and OECD methods. Water solubility of the chemical was 2.24 ppm at $25^{\circ}C$. Half-life by hydrolysis at $25^{\circ}C$ in the buffer solution of pH 3.0, pH 7.0, and pH 8.0 was 77.8 hr, 6.54 hr and 0.72 hr, respectively, demonstrating instability in alkaline solution. The half-life in acid condition was not significantly different by temperature change, however, that in neutral or alkaline solution became shorter at $40^{\circ}C$. Hydrolysis study with a reference compound, diazinon, proved that the experimental method of the present study is reliable. Vapor pressure of captafol, $8.27{\times}10^{-9}$ torr at $20^{\circ}C$, was calculated from the equation, log P=6.94-(4401.6/T) plotted on the experiment results under different temperature conditions, 40, 50, and $60^{\circ}C$. pressure of captafol, the contamination of captafol would not happen easily in environment by vaporization. High Kow value of 1,523 was observed and this might result in bioconcentration through food chain when captafol was exposed. However, affecting human health through aquatic bioaccumulation is not likely to occur due to its rapid hydrolysis in the environment.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2006.06a
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• pp.21-22
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• 2006

디젤엔진에서 배출되는 배기가스 중의 주요 오염물질 중의 하나인 NOx(질소산화물)는 대부분 고온의 연소 과정에서 발생하고, 발생량은 연소온도에 따라 결정되는 것으로 알려져 있다. 또한 연료의 연소 중에 물이 첨가되면 연소공기의 비열 증가에 의하여 연소온도가 감소하여 NOx 발생량이 급격하게 감소하게 되는데, 연소실에 물을 첨가하는 방법으로는 유화연료, 직접물분사, 흡기가습 등이 있다. 이중 흡기가습은 구조가 간단하면서 NOx 저감효율이 가장 높은 것으로 알려져 있다. 본 연구는 당사 고유모델 중형엔진인 힘센엔진에 흡기가습 기술을 적용하여 연소성능 및 NOx 저감효과 등을 시험하고, 흡기가습 시스템의 상용화 모델 개발을 위한 기초 데이터를 확보하기 위해 수행되었다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.472-475
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• 2010

Theoretical consideration on the combustion behavior of nano-aluminum and water mixture was conducted. The regions are divided into; 1)water+aluminum 2)steam+aluminum 3)reaction zone. Latent heat of vaporization was considered as a function of pressure in case of phase change of water. Also, pressure exponent was studied of various sized nano particles within the range of 0.1MPa ~ 10MPa.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2014.11a
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• pp.118-119
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• 2014

원전 운전 중 2차계통 구성재료가 부식되어 철 산화물이 증기발생기 내부로 유입된다. 유입된 철산화물은 고온고압의 환경에서 침적되어 슬러지가 된다. 침적된 슬러지는 증기발생기 전열관 재료에 응력부식균열(SCC)을 일으키는 주원인으로 원전에서는 철 산화물의 유입을 최소화하기 위해 기동전 2차계통을 순환 세정하고 있다. 해외 원전에서는 고분자 아크릴산(Polyacrylic Acid)을 순환세정시 주입함으로써 2차계통 철 산화물 제거 효율을 높인 사례가 있었다. 이에 우리 원전에서도 기동전 순환세정시 고분자 아크릴산을 주입 적용하였다. 고분자 아크릴산 주입 전 필수적으로 이뤄져야할 연구는 고분자 아크릴산이 재료에 미치는 영향평가이다. 본 연구에서는 고분자 아크릴산 농도(1, 10, 100 ppm)에 따라 2차계통 구성재료인 SA106 Gr.B와 Alloy 690의 건전성에 미치는 영향를 수행하였다. 평가방법으로는 전기화학 분극실험, 시편을 침지시켜 실험 전, 후 무게 감량을 이용한 부식률 측정, 표면 상태분석등을 이용하여 종합적으로 평가하였다. 전기화학 분극실험과 부식률 측정결과, 고분자 아크릴산 농도가 높을수록 부식은 증가하였고 고분자 아크릴산 농도 100 ppm일 때 최대 부식률이 0.037 mils로 계산되었다. 이는 부식허용 기준치(5.8 mils)보다는 100배이상 낮았으며 표면분석 결과 고분자 아크릴산으로 인한 pitting 부식은 발생하지 않았다. 이와 같은 결과로 기동시 환경에서 고분자 아크릴산 농도 100 ppm까지는 재료 건전성에 미치는 영향은 거의 없는 것으로 판단된다.