• Title/Summary/Keyword: 물 전기분해

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Controlling Water Splitting Characteristics of Anion-Exchange Membranes by Coating Imidazolium Polymer (이미다졸륨 고분자 코팅을 통한 음이온교환막의 물분해 특성 제어)

  • Kim, Do-Hyeong;Park, Jin-Soo;Kang, Moon-Sung
    • Membrane Journal
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    • v.25 no.2
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    • pp.152-161
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    • 2015
  • In this study, novel pore-filled anion-exchange membranes (PFAEMs) with low electrical resistance, high permselectivity, and low water-splitting flux property under a concentration polarization condition have been developed for the enhancement in the efficiency of electrochemical water treatment processes. The base membranes have been prepared by filling a copolymer containing quaternary ammonium groups with an excellent ion-exchange capability into a porous polyolefin substrate, showing a high performance superior to that of a commercial membrane. In addition, it was confirmed that the electrochemical membrane performances are preserved while the water-splitting flux is effectively controlled by coating an imidazolium polymer onto the surface of the base membrane. The prepared PFAEMs revealed remarkably low electrical resistances of about 1/6~1/8 compared to those of a commercial membrane, and simultaneously low water-splitting flux comparable with that of cation-exchange membranes under a concentration polarization condition.

Proteinase activity in the isolates of Trichomonas vaginalis according to their pathogenicity (질트리코모나스의 병원성과 단백 분해 효소와의 상관성)

  • 심영기;박경희
    • Parasites, Hosts and Diseases
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    • v.31 no.2
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    • pp.117-128
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    • 1993
  • Ten axonic isolates of Trichomonns uaginolis were subcutaneously injected to the BALB/c mice in order to assess their pathogenicity by means of so-called "mouse assay" method. All the isolates revealed neutral and acid proteinase activities both in their Iysates and in culture media, but the specific activities of both proteinases in the severely pathogenic group were significantly higher than the mildly pathogenic group (p < 0.05). In the SDS-PAGE system in which the electrophoretic gels contained 0.4% gelatin as the substrate, five different handing patterns of trichomonal proteinases were detected, and the patterns were closely related with the pathogenicity of the isolates of T. vosinalis. All five bands might be regarded as cysteine proteinases group in the inhibitor assays. The cytotoxicity of the Iysates of T. vaginalis to the target Chinese hamster ovarian (CHO) cell line was also significantly different according to the pathogenicity of the isolates, and generally lower in the Iysates treated with cysteine proteinase inhibitors than in the control Iysates. In summarizing the results, it might be considered that the proteinases of T.vaginalis showing five electrophoretic banding patterns are closely related with the pathogenicity and cytotoxicity of the isolates of T. voginolis.

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Antifungal effect of electrolyzed hydrogen water on Candida albicans biofilm (Candid albicans 바이오필름에 대한 전기분해 수소수의 항진균 효과)

  • Pyo, Kyung-Ryul;Yoo, Yun Seung;Baek, Dong-Heon
    • Journal of Dental Rehabilitation and Applied Science
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    • v.31 no.3
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    • pp.212-220
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    • 2015
  • Purpose: Candida albicans can cause mucosal disease in many vulnerable patients. Also they are associated with denture-related stomatitis. Electrolyzed water is generated by electric current passed via water using various metal electrodes and has antimicrobial activity. The aim of this study was to investigate antifungal activity of electrolyzed water on C. albicans biofilm. Materials and Methods: C. albicans was cultured by sabouraud dextrose broth and F-12 nutrient medium in aerobic and 5% $CO_2$ condition to form blastoconidia (yeast) and hyphae type, respectively. For formation of C. albicans biofilm, C. albicans was cultivated on rough surface 6-well plate by using F-12 nutrient medium in $CO_2$ incubator for 48 hr. After electrolyzing tap water using various metal electrodes, the blastoconidia and hyphal type of C. albicans were treated with electrolyzed water. C. albicans formed blastoconidia and hyphae type when they were cultured by sabouraud dextrose broth and F-12 nutrient medium, respectively. Results: The electrolyzed water using palladium electrode (EWP) exhibited antifungal effect on blastoconidia of C. albicans. Also, the EWP significantly has antifungal activity against C. albicans biofilm and hyphae. In the electrolyzed water using various metal electrodes, only the EWP have antifungal activity. Conclusion: The EWP may use a gargle solution and a soaking solution for prevention of oral candidiasis and denture-related stomatitis due to antifungal activity.

Electrochemical Behaviors of Copper-1-(2-pyridylazo)-2-naphthol Complex in Acetonitrile (아세토니트릴 용매 중에서 Copper-1-(2-pyridylazo)-2-naphthol 착물의 전기화학적 성질)

  • Zun-Ung Bae;Sang-O Oh;Hee-Bong Song;Tae-Myung Park
    • Journal of the Korean Chemical Society
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    • v.37 no.10
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    • pp.888-894
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    • 1993
  • The electrochemical behaviors of copper-1-(2-pyridylazo)-2-naphthol(Cu-PAN) complex in acetonitrile (AN) solution have been investigated by the use of cyclic voltammetry, DC-polarography, controlled potential coulometry and UV-Vis spectroscopy. Cu-PAN complex in acetonitrile exhibit three reduction waves at -1.27 V, -1.64 V and -2.08 V vs. Ag/AgNO$_3$(AN). The numbers of electron involved in each reduction step was calculated with controlled potential coulometry, and reduction product was identified with UV-Vis spectrum. As the result, we proposed the reduction mechanism of the Cu-PAN complex in acetonitrile.

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Oxygen Evolution Characteristics of Non-Noble Metal Electrochemical Catalysts for Water Electrolysis (비귀금속 전기화학 촉매의 수전해 산소 발생 특성)

  • Park, Yu-Se;Choe, Seung-Mok;Lee, Gyu-Hwan;Kim, Yang-Do
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.168.1-168.1
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    • 2017
  • 화석연료를 대체하기 위한 에너지원으로서 수소에너지에 대한 연구가 활발히 진행되고 있다. 수전해는 무한 청정한 물을 전기분해하여 수소를 생산하는 기술로써 대표적으로 알칼리 수전해(alkaline water electrolysis, AWE)와 고분자 전해질막 수전해(polymer electrolyte membrane water electrolysis, PEMWE)가 있다. 그 중, AWE는 알칼리 분위기에서 물분해 반응이 진행되어 촉매의 부식 위험성이 비교적 낮기 때문에 상대적으로 저렴한 비귀금속 산화물 촉매를 사용할 수 있다는 장점이 있다. 본 연구에서는 비귀금속인 Cu, Co를 이용하여 $CuCoO_4$를 합성한 후 산소 발생 촉매 물질로 활용하여 산소 발생 반응(Oxygen Evolution Reaction, OER)특성을 고찰하였다.

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Evaluation of Angiotensin -I- Converting Enzyme Inhibitory Activity and Protein Changes of Enzymatic Hydrolysate Extracted from Hanwoo Loin and Round Myosin B (한우 등심과 우둔에서 추출한 Myosin B의 효소적 가수분해물의 단백질 변화와 Angiotensin -I- Converting Enzyme(ACE) 저해효과)

  • Kim, Y.J.;Chin, Koo-Bok
    • Journal of Animal Science and Technology
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    • v.49 no.1
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    • pp.129-136
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    • 2007
  • This study was performed to determine the protein profiles using sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) and Angiotensin-I-converting enzyme(ACE) inhibitory activity (IC50) as affected by the various meat cuts, digestion times with pepsin. Hydrolysates having the protein concentration of 10 ug/mL had approximately 36∼39% ACE inhibitory activities, regardless of meat cut and digestion time. Protein concentration and ACE inhibitory activity of the diluted hydrolysate increased after 1-hr digestion. In original hydrolysates, ACE inhibitory activities of loin had higher than those of round (P<0.05). In addition, non-heated hydrolysates had higher ACE inhibitory activities than heated counterparts. When myosin B was digested by pepsin more than 1 hr, improved ACE inhibitory activities were observed as compared to the non-digested control.

Hydration Properties of High Volume Cement Matrix Using Blast Furnace Slag and Alkaline Aqueous by Electrolysis (고로슬래그 및 전기분해한 알칼리 수용액을 사용한 하이볼륨 시멘트 경화체의 수화특성)

  • Kim, Sun-A;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.8-13
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    • 2017
  • This experimental study is purposed to analyze the effect of alkaline aqueous solution by electrolysis on strength development in order to develop high volume cement matrix using industrial by-products. Blast furnace slag was used a binder, and an alkaline aqueous solution obtained by electrolyzing pure water was used as an alkali activator. The hydration properties of these specimens were then investigated by compressive strength test, XRD and observation of micro-structures using SEM. As a result, we found that compressive strength increased with the addition of alkaline aqueous solution which cement matrix incorporating blast furnace slag. But those strength decreased reversely when replacing ratio of blast furnace slag was increased. It is judged that results of engineering properties evaluation on the binder and alkaline aqueous solution are useful as a basic data for mixtures design and evaluation properties of high volume cement matrix using by-products.

Electrochemical Synthesis and Properties of Polyanilines (Polyanilines의 전기화학적 합성과 그들의 성질)

  • Choi, Shin June;Park, Su Moon
    • Journal of the Korean Chemical Society
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    • v.42 no.3
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    • pp.355-365
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    • 1998
  • 전도성 고분자들 중의 하나인 polyaniline(PAn)의 전기화학적 합성법과 그 성질을 개관한다. 전기화학적 합성은 aniline(An)을 산성용액에서 전기화학적으로 산화시킴으로써 이루어지는데, 그 중간 생성물로서는 전기화학반응의 첫 단계에서 얻어지는 라디칼 양이온으로부터 몇 단계를 거쳐 생성되는 nitrenium 양이온이 중요하다. 그리고 고분자의 성장 과정에 고분자 자신이 연관되어 있음이 반응동력학적 측정으로부터 밝혀져 자체 촉매 메카니즘에 의함이 알려졌다. PAn의 분해반응 역시 반응동력학적 측정으로부터 Schiff 염기의 가수 분해 반응과 매우 흡사하게 진행됨이 밝혀지고 그 최종 생성물은 p-benzoquinone임이 증명되었다. PAn은 최소한 3개의 분광학적으로 다른 상태를 가지며, 이들은 모두 다른 유동성 전자 상태를 가지므로 각기 다른 전도도를 가진다. PAn의 적절한 유도체를 사용하여 self-doped 고분자를 얻을 수 있으며, 이에 관한 최근의 연구를 개관한다.

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전기분해를 이용한 오염퇴적물 처리

  • 이용화;김평중
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2000.05a
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    • pp.206-207
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    • 2000
  • 해저퇴적물은 수생생물들의 주거공간을 제공하여 수생생태계에서 중요한 역할을 담당한다. 그러나 오염된 해저퇴적물은 수계에서 축적되는 양보다 퇴적물에서 수계로 용출되는 양이 많아 수계의 오염을 가중시키는 가장 끈 원인이 된다. 오염도가 높은 퇴적물에서는 특정종의 서식을 불가능하게 하거나 서식이 가능하다 할지라도 서식생물의 체내에 오염물이 농축되어 이는 먹이사슬을 통하여 수중서식생물들에게 축적되게 되어 궁극적으로 인간들에게도 나쁜 영향을 미치게 된다. (중략)

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Neutral Electrolyzed Water for Prevention of Dental Caries (기존 구강청결제를 대체할 수 있는 치아우식 예방을 위한 전기분해수)

  • Lee, Kyam
    • Journal of the korean academy of Pediatric Dentistry
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    • v.43 no.3
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    • pp.306-312
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    • 2016
  • Gargle solution has typically been used for the prevention of oral infectious disease such as dental caries and periodontitis. However, the use of most gargle solutions is controversial in application for children because some gargle solutions have harmful side effects. Electrolyzed water is generated by passed an electric current and has antimicrobial activity. The purpose of this study was to investigate and compare the efficacy of electrolyzed water in various conditions for eliminating cariogenic bacteria. Electrolyzed water was generated by a platinum electrode in the presence of sodium chloride at various concentrations. Streptococcus mutans and Streptococcus sobrinus were cultivated into a brain heart infusion broth. After harvesting planktonic bacteria, the pellets were treated with the electrolyzed water and commercial gargle solutions and plated on a mitis-salivarius agar plate. Also, the anti-biofilm activity of the electrolyzed water and commercial gargle solutions was investigated after biofilm formation of S. mutans and S. sobrinus. The bacteria in the biofilm were plated onto a mitis-salivarius agar plate. The plates were incubated, and the colony forming unit was measured. The electrolyzed water containing sodium chloride showed significant antibacterial activity against S. mutans and S. sobrinus as well as some gargle solutions. Furthermore, the electrolyzed water had more disruptive effect on the biofilm of S. mutans and S. sobrinus and killed more bacteria in the biofilm than commercial gargle solutions. The results demonstrate that electrolyzed water may be a useful gargle solution for prevention of dental caries.