• Title/Summary/Keyword: 물질 전달

Search Result 1,639, Processing Time 0.033 seconds

Mass Transfer of Citric and Acetic Acid by Reactive Extractant in Batch Extractor (회분식 추출기에서 반응추출제에 의한 구연산과 초산의 물질이동)

  • Lee, Han-Seob
    • Applied Chemistry for Engineering
    • /
    • v.5 no.2
    • /
    • pp.223-229
    • /
    • 1994
  • The effect of agitation speed on mass transfer coefficient in the extraction of citric acid from mixed aqueous solutions of citric and acetic acid with n-butylacetate solutions of di-isotridecylamine(DITDA) and 50% mixture of tri-n-octyl and try-n-hexyl phosphine oxide(MOHPO), were studied in batch extractor. Experimental results showed that the degree of extraction was higher with increasing agitation speed, and was best at 200rpm and 30 minutes in batch extractor. The higher degree of extraction was obtained in mixed solution of citric-acetic acid by using DITDA than MOHPO as an carrier. Mass transfer coefficient was proportional to the degree of extraction, and $K_r=1.254{\times}10^{-3}Re^{0.536}$ was found for she extraction of citric acid by DITDA.

  • PDF

Phospholipase C isozyme들과 조절물질 선별체계

  • 민도식;이영한;서판길;류성호
    • Proceedings of the Korean Society of Applied Pharmacology
    • /
    • 1993.04a
    • /
    • pp.63-63
    • /
    • 1993
  • Phospoinositide-specific phospholipase C (PLC)는 세포막의 phosphoinositide를 분해하여 inositol phosphates와 diacylglycerol을 전달하는데 핵심적인 효소이다. PLC는 분자량과 1차구조의 비교에 의하여 type (PLC-$\beta$, ${\gamma}$, $\delta$)로 구분되며, 각 type마다 2-4종의 subtype이 존재하고 PLC isozyme들에 대한 현재가지의 각종 신호 전달 및 조절에 대한 연구를 종합하면: (1) PLC-$\beta$ type은 G-protein과 연결되어 신호를 전달받고, (2) PLC-${\gamma}$ type은growth factor receptor tyrosine kinase에 의하여 인산화 되어 활성화됨으로, 세포의 성장 신호를 전달하며. (3) PLC-$\delta$ type에 대한 신호 전달이나 조절은 밝혀지지 않고 있다.

  • PDF

Analytical trends in mass spectrometry based metabolomics approaches of neurochemicals for diagnosis of neurodegenerative disorders (퇴행성신경질환의 진단을 위한 신경전달물질 대사체의 질량 분석법 동향)

  • Lee, Na-Kyeong;Jeon, Won-Jei;Jeong, Seung-Woo;Byun, Jae-Sung;Lee, Wonwoong;Hong, Jongki
    • Analytical Science and Technology
    • /
    • v.30 no.6
    • /
    • pp.355-378
    • /
    • 2017
  • Because neurochemicals are related to homeostasis and cognitive and behavioral functions in human body and because they enable the diagnosis of numerous neurodegenerative disorders, there has been increasing interest in the development of analytical platforms for neurochemical profiling in biological samples. In particular, mass spectrometry (MS)-based analytical methods combined with chromatographic separation have been widely used to profile neurochemicals in metabolic pathways. However, development of delicate sample preparation procedures and highly sensitive instrumental detection is necessary considering the trace levels and chemical instabilities of neurochemicals in biological samples. Therefore, in this review, analytical trends in MS-based metabolomics approaches to neurochemicals in multiple biological samples, such as urine, blood, CSF, and biological tissues, are discussed. This paper is expected to contribute to the development of an analytical platform to discover biomarkers that will aid diagnosis, prognosis, and treatment of neurodegenerative disorders.

Effect of S$iO_2$ Nano-sized particle on heat and mass transfer in ammonia-water absorption ($SiO_2$나노입자에 의한 암모니아-물 흡수용액의 열 및 물질전달 특성 연구)

  • 하종주;이찬호;김성현
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
    • /
    • 2002.05a
    • /
    • pp.161-165
    • /
    • 2002
  • 인류가 직면한 환경 및 에너지 문제를 타개하기 위한 많은 연구 중 흡수식 열펌프는 환경친화적인 자연냉매를 사용하는 열구동 시스템으로 다시 주목을 받고 있다. 흡수식 열펌프의 구성요소 중 흡수기는 암모니아의 흡수에 의한 열 및 물질전달 현상이 동시에 일어나는 곳으로 암모니아-물 열펌프 시스템의 성능 향상을 위해 가장 중요한 부분이다.(중략)

  • PDF

Importance of finite rate inter-phase mass transfer in gas/cloud interaction (공기/구름의 상호작용에서 물질전달 한계속도의 중요성)

  • 임종포;조석연
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2001.11a
    • /
    • pp.83-84
    • /
    • 2001
  • 액적화학은 SO4$^{-2}$ 생성에 중요한 역할을 할 뿐만 아니라 OH와 HO$_2$ 라디칼 생성에도 영향을 미친다. 따라서 기존 기상 광화학반응에 액적화학을 추가하여 산성비 모사를 하여왔다. 그러나 액적화학을 추가하기 위해서는 기액간의 물질전달을 포함하여야 하고 액적화학반응속도와 기상화학반응속도가 크게 다름으로써 수치적 풀이의 어려움이 가중되는 문제가 있다. 따라서 기존 연구에서는 기액간의 평형 및 시간 분리 등의 가정을 사용하여 액적화학 반응 추가에 따른 문제를 해결하여 왔다. 본 논문은 이러한 수치단순화의 정확도를 평가하려 한다. (중략)

  • PDF

A Study on the Fin Efficiency of Continuous Fin with Combined Heat and Mass Transfer (열과 물질 전달을 수반하는 연속휜의 휜효율에 관한 연구)

  • 정세환
    • Journal of Advanced Marine Engineering and Technology
    • /
    • v.22 no.4
    • /
    • pp.445-450
    • /
    • 1998
  • In the present paper the effects of combined heat and mass transfer on the fin efficiency were calculated. Sector method was used for calculating the fin efficiency of the continuous fin. The parameter Lewis No. and C which describe the combined heat and mass transfer is derived by using the heat and mass transfer analogy and effects of Lewis No. and C on the fin efficiencies were calculated.

  • PDF

Mathematical Modeling for Leaching and dissolution of Solidified Radioactive Waste in a Geologic Reposiory (지하 처분장에서의 방사성폐기물 고화체의 용출 및 용해에 대한 수학적 모형 분석)

  • Kim, Chang-Lak;Park, Kwang-Sub;Cho, Chan-Hee;Kim, Jhinwung;Suh, In-Suk
    • Nuclear Engineering and Technology
    • /
    • v.20 no.2
    • /
    • pp.120-131
    • /
    • 1988
  • A souce term model describes mathematically the source of radionuclides as they begin slow migration and decay in deep groundwater. Various source term models based on mass-transfer analysis and measurement-based source term models are reviewed. Ganerally, two processes are involved in leaching or dissolution: (1) chemical reactions and (2) mass transfer by diffusion. The chemical reaction controls the dissolution rates only during the early stage of exposure to groundwater. The exterior-field mass transfer may control the long term dissolution rates from the waste solid in a geologic repository. Mass-transfer analyses re3y on detailed and careful application of the governing equations that describe the mechanistic processes of transport of material between and within phases. If used correctly, source term models based on mass-transfer theory are valuable and necessary tools for developing reliable predictions.

  • PDF

Carbon Dioxide Absorption in a Packed Column Using Guanidine-based Superbase Solution (구아니딘계 초염기 흡수제에 의한 충진탑에서의 이산화탄소 포집 특성)

  • Choi, Young Min;Hong, Yeon Ki;You, Jong Kyun
    • Korean Chemical Engineering Research
    • /
    • v.54 no.5
    • /
    • pp.648-652
    • /
    • 2016
  • The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.

Ion Exchange Kinetics for Cs and Sr in a Batch Zeolite System (회분식 제올라이트계에서 Cs 및 Sr의 이온교환속도 연구)

  • Lee, Eil-Hee;Yoo, Jae-Hyung;Park, Hyun-Soo
    • Applied Chemistry for Engineering
    • /
    • v.4 no.4
    • /
    • pp.739-745
    • /
    • 1993
  • The characteristics of mass transfer in an inorganic ion exchange system where Cs and/or Sr are separated by means of zeolites was investigated. Experimental work to separate Cs or Sr was carried out for Cs-AW300 and CS-AW500 systems in case of Cs whereas for Sr-4A and Sr-13X systems in case of Sr. The experimental conditions were chosen as follows in the batch type separation : temperature $25^{\circ}C$, agitation speed 300rpm, amount of zeolite 4g, volume of solution $0.5{\ell}$, and concentrations of solution 1000ppm, 2000ppm, respectively. As a result, it was found that the mass transfer rate is controlled mainly by the liquid film diffusion. The mass transfer coefficients in the film were found to be in the range of $10^{-4}{\sim}10^{-3}cm/sec$, while the apparent diffusivity inside the particles was found to be in the order of $10^{-8}cm^2/sec$.

  • PDF