• Title/Summary/Keyword: 물성 향상

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The PSA Properties of n-Butyl Acrylate/Acrylic Acid Copolymer and Tackifier Resins with Influence of Miscibility (n-Butyl Acrylate/Acrylic Acid 공중합체와 점착부여제간의 상용성과 점착물성)

  • 민경은;김호겸;최관영;곽기호
    • Polymer(Korea)
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    • v.24 no.4
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    • pp.469-476
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    • 2000
  • The miscibility between acrylic copolymers and tackifier resins influenced on adhesion properties of PSA. PSA with high molecular weight and narrow molecular weight distribution of acrylic copolymers showed systemical modification of adhesion properties of PSA by tackifier resins only in case of miscible system. It is concluded that the investigation of the miscibility between two Components is very important to adhesion properties of PSA.

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Application of the BWRS equation of state of polar halocarbons (극성 할로겐 탄화수소 화합물 물성 예측에 BWRS 상태 방정식의 응용)

  • 이태종;김부웅
    • Journal of Energy Engineering
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    • v.2 no.3
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    • pp.315-322
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    • 1993
  • The generalized 23 constants of the Benedict-Webb-Rubin-Starling (BWRS) equation of state were modified to achieve accurate predictions of thermo-physical properties for polar halocarbons. Multiproperty analysis was employed to obtain an optimum set of 23 constants for individual halocarbons. The overall average absolute deviations of predicted properties for those halocarbons using the 23 constants optimized for each halocarbon with use of either an acentric factor or orientation parameters are 0.41% for density, 0.33 Kcal/kg for enthalpy and 0.39% for vapor pressure. These results show a remarkable improvement in predicting properties over the ones obtained by use of the generalized constants for all the ten halocarbons tested here.

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Influence of Ultrasonic Treatment and Nano-Clay content on the Properties of Nano-Clay/Polyurethane Foam (초음파 처리와 나노클레이 농도가 나노클레이/폴리우레탄 폼의 물성에 미치는 영향)

  • Her, Kiyoung;Lim, Soonho;Kim, Daeheum
    • Korean Chemical Engineering Research
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    • v.47 no.2
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    • pp.208-212
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    • 2009
  • The nano-clay is widely used in polymer-nanocomposites due to the high aspect ratio, heat resistance and nano-scale dimension. In recent researches, the thermal and mechanical properties of polyurethane foam were improved with introducing the nano-clay. In this study, we describe the influence of ultrasonic treatment and content of nano-clay on properties of polyurethane foam. The nano-clay/polyurethane foam were characterized using their recovery time, compressive deflection, cell morphology and tensile test. The ultrasonic treatment was very effective for dispersion of nano-clay. Moreover, we found that introducing over 3 wt% of nano-clay bring the decrease of properties due to the poor dispersion. Expecially, ultrasonically treated 20A/polyurethane foam(1 wt%) showed greatly improved properties, such as homogeneous cell size and good dimension stability. We expect that our results could be applied to insulating materials for construction.

Enhancement of Mechanical Properties of 2K Polyurethane Adhesives via Forming Ionic Bonds (이온결합 형성에 따른 이액형 폴리우레탄 접착제의 기계적 특성 향상)

  • Kwon, Haeun;Kim, Doo Hun;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.22 no.4
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    • pp.128-135
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    • 2021
  • In this study, the acid polyols containing acid groups were synthesized, the novel polyurethane adhesive was developed by introducing the acid polyol by content. The acid polyols were introduced, the mechanical properties showed the maximum value when the acid content was 0.1 to 0.3 wt%, and it was confirmed that the mechanical properties and adhesive strength decreased at the content higher than 0.5 wt%. As the acid group, carboxylic acid and sulfuric acid were introduced to compare properties, and carboxylic acid showed stronger hydrogen bonding potential than sulfuric acid and improved mechanical properties. In addition, the correlation between particle size and mechanical properties was confirmed by introducing ZnO and CaCO3. When ZnO and CaCO3 were introduced, an ionic bond was formed with an acid group, and it was confirmed that mechanical properties were increased.

Investigation of the Effect of Seaweed Nanofibers in Jute Fiber-reinforced Composites as an Additive (해초 나노섬유가 황마섬유 강화 복합재료의 기계적 물성에 미치는 영향)

  • Kim, Jae-Cheol;Lee, Dong-Woo;Song, Jung-Il
    • Composites Research
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    • v.31 no.6
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    • pp.398-403
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    • 2018
  • Recently, environmental pollution caused by plastic waste, ecosystem disturbance of micro-plastics and human body accumulation are becoming big problems. In order to replace the traditional plastic, eco-friendly resin and natural fiber-based composite materials have been developed, but they have a disadvantage that their mechanical properties are significantly lower than those of synthetic fiber-based composites. In this study, eco - friendly nanofiber was extracted from seaweed and used as an additive in order to improve the mechanical properties of jute fiber-reinforced composites. Through the hand lay-up process, the composites were fabricated, and it was confirmed that the nanofiber was effective in improving the mechanical properties of natural fiber composites through tensile, bending and drop weight impact tests.

Effect of Compatibilizers on the Morphological, Mechanical and Rheological Properties of PP/PCL and TPO/PCL Blends (상용화제의 첨가에 따른 PP/PCL 블렌드와 TPO/PCL 블렌드의 기계적 물성 모폴로지 및 유변학적 물성)

  • Lee, Yun-Kyun;Kim, Min-Soo;Kim, Woo-Nyon
    • Korean Chemical Engineering Research
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    • v.49 no.3
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    • pp.342-347
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    • 2011
  • The effects of compatibilizers on the mechanical and rheological properties of PP/PCL and TPO/PCL blends have been studied. The thermoplastic polyolefin (TPO) consists of PP (80 wt%), EPDM (15 wt%) and Talc (5 wt%). Maleic anhydride grafted polypropylene (PP-g-MAH) and maleic anhydride grafted styrene-(ethylene-co-butene)-styrene copolymer (SEBS-g-MAH) were used as compatibilizers. In mechanical properties of PP/PCL and TPO/PCL blends, tensile strength was increased when PP-g-MAH was used as a compatibilizer, and impact strength was increased when SEBS-g-MAH was used as a compatibilizer. From the results of SEM morphology of PP/PCL blend, PCL droplet size was decreased by the addition of PP-g-MAH. From the results of rheological property, complex viscosity of the PP/PCL and TPO/PCL blends did not change appreciably when the compatibilizers were added. From the results of mechanical, morphological and rheological properties of the blends, PP-g-MAH acted as a compatibilizer to increase the tensile strength of the PP/PCL and TPO/PCL blends. While SEBS-g-MAH acted as a impact modifier to increase the impact strength of the PP/PCL and TPO/PCL blends.

Effect of Surfactant on Rheological and Electrical Properties of Latex-Blended Polystyrene/Single-Walled Carbon Nanotube Nanocomposites (계면활성제가 라텍스 블렌딩 폴리스티렌/단일벽 탄소나노튜브 나노복합재료의 유변학적, 전기적 물성에 미치는 영향)

  • Kang, Myung-Hwan;Noh, Won-Jin;Woo, Dong-Kyun;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.364-371
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    • 2012
  • Polystyrene/single-walled carbon nanotube (PS/SWCNT) nanocomposites were prepared by latex technology and the effect of surfactant (SDS) on nanotube dispersion, rheological and electrical properties was investigated. The nanocomposites were prepared through freeze-drying after mixing PS particles and aqueous SWCNT/SDS suspension. As the SDS content increased, the storage modulus and complex viscosity of the nanocomposites were increased due to enhanced dispersion of nanotubes, but if the content excessively increased, the modulus and viscosity began to decrease due to low molecular weight of SDS. The electrical conductivity sharply increased with the addition of SDS, and then did not show significant changes. This result is speculated to be the competition between the increased dispersion of nanotubes and the deterioration of electrical conductivity by SDS adsorption. An optimal ratio of SDS to SWCNT for improving electrical conductivity and end-use properties was 2. With this ratio, the electrical percolation threshold of SWCNT was less than 1 wt%.