• Title/Summary/Keyword: 물성저하

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Study on Type of Different Polyols for Physical Properties of Polyurethane Foam Under Sea Water (해수에서 폴리올 종류가 폴리우레탄 폼의 물성에 미치는 영향)

  • Kim, Sang-Bum
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.158-163
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    • 2011
  • Rigid polyurethane foam (PUF) was synthesized with different contents of aliphatic polyester polyol, aromatic polyester polyol and aliphatic polyether polyol to know change of properties under sea water. UTM(universal testing machine), DSC(differential scanning calorimetry), hardness meter and FT-IR(Fourier transform spectroscopy) were used to study the PUF`s physical properties under sea water. Compressive strength and hardness of PUF decreased with increasing the content of aromatic polyester polyol under sea water as aging. According to the results of IR spectral analysis, reduction of urethane and urea peak was found and allophanate and biuret peak increased. Although glass transition temperature of PUF increased, mechanical properties of PUF decreased under sea water, because PUF gets brittle when crosslink density increase.

Determination of Degraded Fiber Properties of Laminated CFRP Flat Plates Using the Bivariate Gaussian Distribution Function (이변량 Gaussian 분포함수를 적용한 CFRP 적층 평판의 보강섬유 물성저하 규명)

  • Kim, Gyu-Dong;Lee, Sang-Youl
    • Composites Research
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    • v.29 no.5
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    • pp.299-305
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    • 2016
  • This paper presents a method to detect the fiber property variation of laminated CFRP plates using the bivariate Gaussian distribution function. Five unknown parameters are considered to determine the fiber damage distribution, which is a modified form of the bivariate Gaussian distribution function. To solve the inverse problem using the combined computational method, this study uses several natural frequencies and mode shapes in a structure as the measured data. The numerical examples show that the proposed technique is a feasible and practical method which can prove the location of a damaged region as well as inspect the distribution of deteriorated stiffness of CFRP plates for different fiber angles and layup sequences.

Textural and Sensory Characteristics of Gamma Irradiated Porridges (감마선 조사된 시판 분말죽의 물성 및 관능특성)

  • 육홍선;이유석;이주운;오상희;김장호;김동수;변명우
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.2
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    • pp.427-432
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    • 2004
  • Effect of gamma irradiation on porridge viscosity was studied. Vegetable, beef and pine nut dry flour porridges were irradiated at 0, 2.5, 5, 7.5 and 10 kGy, and rheological characteristics and sensory qualities of irradiated porridge were evaluated. Hunter color lightness were decreased, while redness were increased in dry flour porridge with the increase of irradiation dose. Firmness, consistency, cohesiveness and viscosity of dry flour porridge were significantly decreased with the increase of irradiation dose (p<0.05). Vegetable, beef and pine nut dry flour porridges at dose of 10 kGy reduced the viscosity with 93%, 71% and 55%, respectively Irradiation greatly reduced the viscosity of porridges, probably by starch depolymerization. Irradiation increased the total solids and thus, can improve the calorie up to 30 ㎉. Gamma irradiation was effective in enhancing calorie value of porridge due to reduction of viscosity. As a result of sensory evaluation, overall acceptability and the quality characteristics of irradiated porridges (up to S kGy) were not significantly different from those of the control (p<0.05). In the vegetable porridge, the irradiated porridge at dose of 2.5 kGy was a significantly better overall acceptability than the non-irradiated porridge (p<0.05).

Improvement of Microwave Heating Properties of Frozen Starch by Spray of Surface Materials (Maltodextrin류의 표면도포에 의한 냉동전분의 Microwave 가열특성 개선)

  • Kim, Eun-Mi;Han, Hye-Kyung;Kim, In-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.7
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    • pp.1035-1040
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    • 2005
  • This study was conducted to investigate the surface spraying effect of materials on the rheological properties of frozen starch with microwave heating. Microwave helps reduce cooking time by high temperature, but swiftly snatches moisture from foods such as frozen starches (buns and noodles etc) and makes surface of foods harder. Four types of maltodextrin materials have been prepared for different concentration solutions and sprayed on surface doughs of sheet type. Sprayed dough samples were Quickly frozen at $-70^{\circ}C$ and wrapped with polypropylene film. All the treated samples were kept at 0, -20 and $-50^{\circ}C$, and then taken out periodically for measurement of the quality during storage. The quality attributes evaluated after heating with microwave energy include sensory quality retrogradation, texture, surface color and microstructure. The quality of frozen starches deteriorated with long term storage even at low temperatures of -20 and $-50^{\circ}C$, and the spray materials were found to improve the textural and physical properties of frozen starches in the microwave heating. Particularly, maltodextrin with D.E value of $9\~12$ had the most desirable effects of quality improvement.

Effects of the Addition Pro-oxidant on the Physical Properties and Degradation of the Petroleum- derived Plastic Film (산화촉진제 첨가가 플라스틱 필름의 물성과 분해에 미치는 영향)

  • Kihyeon, Ahn;Jae-Suk, Choi;Roun, Lee;Jung-Gu, Han;Tae-Hoon, Ro;Hyung Woo, Park
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.28 no.3
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    • pp.165-170
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    • 2022
  • If petroleum- derived plastic like a bio-based plastic was degradation, awareness like a global warming and environmental disasters will be decreased. Plastic film was produced by adding ferric ions according to concentration by using a pro-oxidant in polyolefin resin. Changes in tensile strength, elongation, and molecular weight were evaluated according to the UV irradiation time. Increasing the amount of ferric ions resulted in more significant declines of physical properties, and also resulted in greater changes in molecular weight. After 100 hours of UV irradiation, tensile strength declined significantly in the film containing pro-oxidant as compared to the control. A similar effect was also observed in terms of elongation. The film containing pro-oxidant showed a 73.8% decrease in molecular weight after 100 hours of UV irradiation. The appropriate use of pro-oxidant can not only degrade plastic film but also control the time of degradation at the petroleum-derived plastic films. Further studies are necessary to investigate the conditions of plastic film degradation.

Thermal Dispersion Method for a Medical Ultrasonic Phased Array Transducer (의료용 초음파 위상배열 트랜스듀서의 열 분산 방안)

  • Lee, Wonseok;Roh, Yongrae
    • The Journal of the Acoustical Society of Korea
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    • v.34 no.3
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    • pp.210-218
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    • 2015
  • When the driving voltage of an ultrasound transducer is increased to improve the quality of ultrasound images, heat is generated inside the transducer that can cause patient's skin burn and degradation of transducer performance. Hence, in this paper, a method to disperse the heat of the transducer has been studied. The phased array transducer having 3 MHz center frequency and 32 channels was selected for analyses of the thermal dispersion. First, mechanism of the heat generation was investigated in relation to the transducer operation through theoretical analysis, and material damping and sound pressure amplitude were confirmed to be influential on the heat generation. Further, we investigated the effects of the properties of the materials constituting the transducer on the thermal dispersion through finite element analysis. Based on the analysis results, we determined the thermal properties of the constituent materials that could facilitate the thermal dispersion inside the transducer. The determined thermal properties were applied to the finite element model, and the results showed that the maximum temperature at an acoustic lens contacting with a patient was decreased to 51 % of its initial value.

Thermal Aging Behavior of H-NBR/NBR Blend (H-NBR/NBR 블렌드의 열노화거동)

  • Choi, Won-Seok;Kim, Gun-Wan;Do, Je-Sung;Yoo, Myung-Ho;Ryu, Sung-Hun
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.132-137
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    • 2011
  • In the present investigation, thermal aging behavior of H-NBR/NBR blend with various H-NBR content was investigated. Mixture of dicumyl peroxide and sulfur were used as a curing agent. The influence of the thermal aging of the H-NBR/NBR blends on the solid state properties such as tensile strength, elongation at break, hardness and abrasion resistance was investigated. Tensile strength was increased with increasing H-NBR content, while abrasion resistance was decreased. Both elongation at break and hardness were not affected by the addition of H-NBR. The properties such as hardness, tensile strength and elongation at break of the aged samples were lower than unaged samples. However, the rate of deterioration of those properties was decreased by increasing the H-NBR content, which indicated that improved thermal aging behavior was obtained by the addition of H-NBR. Abrasion loss was increased with increasing aging time, but it became less by the addition of H-NBR addition.

Strength Prediction on Composite Laminates Including Material Nonlinearity and Continuum Damage Mechanics (재료 비선형과 연속체 손상역학을 고려한 복합 적층판의 강도 예측)

  • Park, Kook-Jin;Kang, Hee-Jin;Shin, Sangjoon;Choi, Ik-Hyun;Kim, Minki;Kim, Seung-Jo
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.11
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    • pp.927-936
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    • 2014
  • This paper presents development and verification of the progressive failure analysis upon the composite laminates. Strength and stiffness of the fiber-reinforced composite are analyzed by property degradation approach with emphasis on the material nonlinearity and continuum damage mechanics (CDM). Longitudinal and transverse tensile modes derived from Hashin's failure criterion are used to predict the thresholds for damage initiation and growth. The modified Newton-Raphson iterative procedure is implemented for determining nonlinear elastic and viscoelastic constitutive relations. Laminar properties of the composite are obtained by experiments. Prediction on the un-notched tensile (UNT) specimen is performed under the laminate level. Stress-strain curves and strength results are compared with the experimental measurement. It is concluded that the present nonlinear CDM approach is capable of predicting the strength and stiffness more accurately than the corresponding linear CDM one does.

백판지 Varnish Coating적성 개선에 대한 연구

  • 곽상효;황명동;이경현;박광만;이순용
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.04a
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    • pp.79-79
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    • 2001
  • 백판지는 포장용기로 사용되기 때문에 인쇄적성 이외에 다양한 후가공적성이 요구 된다. V Varnish Coating도 이러한 후가공적성 중의 하나로서 국내 인쇄소에서는 기계 코팅으로 불리 우며, 목적은 표면에 고분자수지 피막을 입힘으로써 인쇄물의 광택을 높여서 상품가치를 높이고 수운침투와 같은 외부환경의 변화로부터 상품을 안전하게 보관하기 위함이다. arnish C Coating은 인쇄기의 마지막 Unit에서 인쇄와 동일한 방식으로 진행되는데, 코팅액의 배합은 인쇄소와 인쇄물에 따라 상이하다. 본 연구는 Varnish Coating(OI하 기계코팅) 광택향상을 통 한 품질개선 목적으로 수행되었다. 기계 코팅의 특 성 을 파 악 하 기 위 해 서 Gas Chromatography / Mass Spectrometer와 FT -IR Sp e ectrometer를 사용하여 성문운석을 실시해본 결과 코팅액으로 사용되는 광택바니스는 아크 랄과 페놀수지를 툴루엔 계열의 용매에 녹인 용액이고, 흐$\mid$석제로 쓰이는 인쇄바니스는 스티 렌수지를 동일한 용매에 녹인 용액으로 조사되었다. 기계코팅광택 저하현상의 원인파악을 위해서 도공층의 공극구조를 Mercury Porosimeter를 이용하여 파악한 결과 기공의 부피가 상 대적으로 크게 나타났다. 위의 결과를 토대로 기계코팅광택 저하는 코팅액이 과도한 기공부피를 갖는 도공층 내부 로 대부분 홉수되고 표면에 적은 양만이 잔류하기 때문으로 판단하고 해결방안은 도공층의 기공부피를 줄이는 쪽으로 정하였다. Mayor Coater와 QC를 이용하여 Coating Color Formula t tion 번경실힘을 진행하여 도공지 물성을 분석하였다. 그 결과 Double Coating의 Top Color에 서 강력한 상호작용을 하는 Protein과 콜레이를 감량 하고 경질탄산칼숨을 배제하여 기공의 부피를 줄인 경우 기계코팅광택 향상효과가 두드러지게 나타났다. 이러한 Lab 실험을 바탕으로 결정된 Color Formulation에 대한 현장실험을 진행하였고 Lab 평가 및 실인쇄 평가 결과 원하는 수준의 기계코팅광택 향상을 얻을 수 있었다. 몇 차례의 현장실험과 Long-Run Test한 제품들에 대한 물성을 문석한 결과 기계코팅굉택은 인쇄 광택과 같은 경향을 나타냈으며 실협실적으로 간단하게 측정되는 물성 중에서 Air Permeability와 강한 음의 상관관계롤 보였다.

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Flame Retardancy and Mechanical Property of Polypropylene/ Nylon Nanocomposite Reinforced with Montmorillonite (몬모릴로나이트로 강화된 폴리프로필렌/ 나일론 나노복합재료의 난연특성 및 기계적 특성)

  • 이종훈;박호식;안인구;이윤희;김연수;이영관;남재도
    • Polymer(Korea)
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    • v.27 no.6
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    • pp.576-582
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    • 2003
  • When the halogenated flame retardant, decabromodiphenyl oxide, was added to the polypropylene/nylon blend, and was compounded with montmorillonite and compatibilizer, maleic anhydride polypropylene, the improvement of flame retardancy and mechanical properties was investigated. The degree of dispersion between polymer resin and inorganic nanoparticles was investigated, and the flame retardancy and mechanical properties was measured quantitatively. XRD results showed that the montrnorillonite was com-pletely exfoliated after polypropylen/nylon nanocomposites was mixed above twice. By compounding with montmorillonite, polypropylene/nylon blend system was overcome the deterioration of flame retardancy. The tensile strength and impact strength were slightly increased, and by compounding with montmorillonite, the additional increase in mechanical properties was obtained. Therefore, the flame retardancy of polypropylene / nylon blend was decreased by adding nylon, but by compounding with inorganic nanoparticle, improvement of the flame retardancy and mechanical properties was obtained.