• Title/Summary/Keyword: 물성저하

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Effects of fluoride release and solubility of resin modified glass ionomer with surface coating agents (표면 코팅제의 레진 강화형 글라스아이오노머 불소 유리량 및 용해도에 대한 효과)

  • Yoon, Taewan;Yoo, Seunghoon
    • Journal of Dental Rehabilitation and Applied Science
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    • v.35 no.2
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    • pp.81-89
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    • 2019
  • Purpose: This study aimed to investigate the correlation between the solubility and the amount of fluoride release when a resin surface coating agent is applied to RMGIC. Materials and Methods: To measure the fluoride release and solubility, Fuji II $LC^{(R)}$and $Filtek^{TM}$ Z350XT without a surface coating, Fuji II $LC^{(R)}$ with G coat $plus^{TM}$ and Fuji II $LC^{(R)}$ with $Permaseal^{(R)}$ were prepared. And the amount of fluoride release and solubility were measured. Results: There was no significant difference in the daily fluoride release between the surface coating agents. The cumulative fluoride release was significantly different between the groups using RMGIC at 56 days (P < 0.05). In the solubility measurement, RMGIC without surface coating was significantly different only on the 7th day compared to the other three groups (P < 0.05). Conclusion: Surface coating agents can prevent the degradation of properties by the initial solvent in RMGIC. Therefore, fluoride is preserved inside the restorative material and the effect of surface coating after the addition is reduced, so that the effect on fluoride release and storage is also reduced.

A Study on the Effect of Pile Surface Roughness on Adfreeze Bond Strength (말뚝표면 거칠기에 따른 동착강도 변화에 관한 연구)

  • Choi, Changho
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.12
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    • pp.79-88
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    • 2011
  • Adfreeze bond strength develops upon freezing of pore water within soil and at foundation surface. It has been reported that various factors like temperature, soil type, and pile surface roughness affect adfreeze bond strength. Especially, pile surface roughness has been considered as a primary factor to design pile foundation in frozen ground. It has usually been estimated with fixed correction factors for pile materials. However, even if the pile foundation material is the same, the surface roughness could vary depending on the production circumstances. In this study, laboratory test was carried out to quantitatively analyze the effects of surface roughness on the adfreeze bond strength, and fractal dimension was used as a measure for surface roughness. Test results showed that adfreeze bond strength increased with decreasing temperature, increasing vertical stress and surface roughness. The adfreeze bond strength varies sensitively with surface roughness in the early freezing section of $-2^{\circ}C$, but its sensitivity decreased in the temperature ranging between $-2^{\circ}C$ to $-5^{\circ}C$. The results conclude that the roughness highly affects the frictional resistance of pile surface in frozen ground; however, the roughness does not affect considerably when the temperature drops below about $-2^{\circ}C$.

Characteristics of Flexuarl-Shear Behavior of Beam Using Demonstrated CFRP Rod (국내 시범 생산 CFRP rod를 적용한 보 부재의 휨-전단 특성)

  • Choi, So-Yoeng;Kim, Il-Sun;Choi, Myoung-Sung;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.86-94
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    • 2022
  • Replacement of FRP rod as steel reinforcement has been attracted significantly to prevent the degradation of the concrete structure due to corrosion. So, the technology development to extend the structure's service life by improving FRP properties has been proceeded worldwide. Accordingly, it is necessary to develop Korea's CFRP rod and CFRP grid, including the manufacturing techniques to improve the properties of high-strength and high-stiffness. Moreover, the research should be conducted to evaluate the structural behavior of the beams using the CFRP rod or grid. This study investigates the flexural and shear behavior of reinforced concrete beam using demonstrated CFRP rod as reinforcement according to the reinforcement ratio and shear span to depth ratio. From the results, when the reinforcement ratio is out of a specific range, it is seemed that the effect on performance improvement of the beam using CFRP rod is cancelled or not significant. Meanwhile, when the CFRP rod was used as reinforcement, the possibility of shear failure occurred, even steel stirrups were installed in the beam with CFRP rod as tensile reinforcement according to the Korean Design Standard. Therefore, when the CFRP rod is used as tensile reinforcement in a beam, it should be prepared that a specific limitation of reinforcement ratio and an investigation against shear failure. Also, the ductility of the beam using the CFRP rod is determined by the deformation energy evaluation method. So, the ductility should be investigated by applying the deformation energy evaluation method that reflects the structural behavior of the beam.

A Study on the Improvement of the Electrochemical Performance of Graphite Anode by Controlling Properties of the Coating Pitch (코팅 피치의 물성제어를 통한 흑연 음극재의 전기화학 성능 향상 연구)

  • Kim, Bo Ra;Kim, Ji Hong;Kang, Seok Chang;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.459-465
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    • 2022
  • A pitch coating method was proposed for the purpose of improving the electrochemical properties of natural graphite. The synthesis conditions of pitch coating were optimized via measuring electrochemical properties of pitch-coated graphite anodes. As the synthesis temperature increased, the thermal stability was improved in addition to an increase in the softening point and residual carbon weight. However, the synthesis temperature of 430 ℃ resulted in the synthesis of a large amount of NI (NMP Insoluble) due to excessive condensation reaction. As the surface uniformity and coating thickness increased due to high thermal stability, the initial coulombic efficiency and rate capability of the pitch-coated graphite were improved. However, the graphite coated with the pitch containing excessive NI showed lower electrochemical properties than the uncoated graphite. NI had low dispersibility and formed spheres after heat treatment, so it formed the heterogeneous and thicker SEI layer. The optimum conditions for forming a uniform surface and an appropriate coating layer were investigated.

Carrageenan-Based Liquid Bioadhesives for Paper and Their Physical Properties (카라기난 기반 액상형 바이오 종이 접착제의 제조 및 물성에 관한 연구)

  • Oh, Seung-Jun;Han, Won-Sik;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.541-548
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    • 2020
  • There is a growing demand for natural materials to replace adhesives based on volatile organic compounds (VOCs). However, the exclusion of VOCs from the manufacturing process leads to difficulties in manufacturing, and reduction in productivity and preservability. In this paper, we report the manufacture of natural bioadhesives using the carrageenan component of seaweed. λ-carrageenan, isolated from the extracted total carrageenan, was used to prepare a highly stable adhesive for paper. The resulting composition was 52.0 ± 1.0% λ-carrageenan, 30.5 ± 0.5% Polyvinylpyrrolidone, 1.0 ± 0.05% ethylhexylglycerin, 1.5 ± 0.05% glycerin, 13.5 ± 0.5% dextrine, and 0.6 ± 0.05% food-grade antifoam emulsion. The viscosity was found to be 1.13 ± 0.07 × 105 cP (25℃), UV degradation occurred at pH6.22, drying rate was 15min, △b* was -10.79, and △E* ab was 8.18. The bioadhesive showed an excellent adhesion strength of 44.63 kgf/cm2. Thus this adhesive showed excellent fungal resistance and good adhesive persistence, without the presence of total volatile organic compounds (TVOC), formaldehyde (HCHO), and heavy metals.

Petrological Characteristics and Nondestructive Deterioration Assessments for Foundation Stones of the Sebyeonggwan Hall in Tongyeong, Korea (통영 세병관 초석의 암석학적 특성 및 비파괴 손상평가)

  • Han, Doo Roo;Kim, Sung Han;Park, Seok Tae;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.54 no.2
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    • pp.199-212
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    • 2021
  • The Sebyeonggwan Hall (National Treasure No. 305) is located on the Naval Headquarter of Three Provinces in Tongyeong, and it has partly undergone with several rebuilding, remodeling, repairing and restorations since it's the first establishment in Joseon Dynasty (AD 1605) of ancient Korea. This study focuses on 50 foundation stones that comprise the Sebyeonggwan. These stones are made of six rock types and currently have various shapes of the surface damages. As the foundation stones, the dominant rock type was dacitic lapilli tuffs, and provenance-based interpretation was performed to supply alternative stones for conservation. Most of the provenance rocks for foundation stones showed highly homogeneity with their corresponding stones of petrography, mineralogy and magnetic susceptibility. According to surface deterioration assessments, the most serious damages of the stones were blistering and scaling. The deterioration mechanism was identified through the analysis of inorganic contaminants, and the primary reason is considered salt weathering caused by sea breeze and other combined circumstances. Based on the mechanical durability of the stones, there was no foundation stone that required the replacement of its members attributed to the degradation of the rock properties, but conservation treatment is considered necessary to delay superficial damage. The foundation stones are characterized by a combined outcome of multiple petrological factors that caused physical damage to surfaces and internal defects. Therefore, it's required to diagnosis and monitoring the Sebyeonggwan regularly for long-term preservation.

The Development of Biodegradable Fiber Tensile Tenacity and Elongation Prediction Model Considering Data Imbalance and Measurement Error (데이터 불균형과 측정 오차를 고려한 생분해성 섬유 인장 강신도 예측 모델 개발)

  • Se-Chan, Park;Deok-Yeop, Kim;Kang-Bok, Seo;Woo-Jin, Lee
    • KIPS Transactions on Software and Data Engineering
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    • v.11 no.12
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    • pp.489-498
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    • 2022
  • Recently, the textile industry, which is labor-intensive, is attempting to reduce process costs and optimize quality through artificial intelligence. However, the fiber spinning process has a high cost for data collection and lacks a systematic data collection and processing system, so the amount of accumulated data is small. In addition, data imbalance occurs by preferentially collecting only data with changes in specific variables according to the purpose of fiber spinning, and there is an error even between samples collected under the same fiber spinning conditions due to difference in the measurement environment of physical properties. If these data characteristics are not taken into account and used for AI models, problems such as overfitting and performance degradation may occur. Therefore, in this paper, we propose an outlier handling technique and data augmentation technique considering the characteristics of the spinning process data. And, by comparing it with the existing outlier handling technique and data augmentation technique, it is shown that the proposed technique is more suitable for spinning process data. In addition, by comparing the original data and the data processed with the proposed method to various models, it is shown that the performance of the tensile tenacity and elongation prediction model is improved in the models using the proposed methods compared to the models not using the proposed methods.

Liquefaction Evaluation of Reclaimed Sites using an Effective Stress Analysis and an Equivalent Linear Analysis (유효응력해석과 등가선형해석을 이용한 매립지반의 액상화 평가)

  • Park, Sung-Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2C
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    • pp.83-94
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    • 2008
  • In this study an effective stress analysis was performed to evaluate liquefaction potential and ground settlement for reclaimed sites. The effective stress model can simulate the stiffness degradation due to excess pore pressure and resulting ground deformation. It is applicable to a wide range of strain. An equivalent linear analysis suitable for low strain levels was also carried out to compare the effective stress analysis. Shear stress ratio calculated from an equivalent linear analysis was used to determine SPT blow count to prevent liquefaction. Depending on the magnitude of potential earthquake and fine contents, the SPT blow count was converted into an equivalent cone tip resistance. It was compared with the measured cone tip resistance. The measured elastic shear wave velocity and cone tip resistance from two reclaimed sites in Incheon were used to perform liquefaction analyses. Two liquefaction evaluation methods showed similar liquefaction potential which was evaluated continuously. The predicted excess pore pressure ratio of upper 20 m was between 40% and 70%. The calculated post-shaking settlement caused by excess pore pressure dissipation was less than 10 cm.

Carbon Nanosphere Composite Ultrafiltration Membranes with Anti-Biofouling Properties and More Porous Structures for Wastewater Treatment Using MBRs (분리막 생물반응기를 활용한 폐수처리를 위한 생물오염방지 특성 및 다공성 구조를 가진 탄소나노구체 복합 한외여과막)

  • Jaewoo Lee
    • Membrane Journal
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    • v.34 no.1
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    • pp.38-49
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    • 2024
  • Wastewater treatment using membrane bioreactors has been extensively used to alleviate water shortage and pollution by improving the quality of the treated water discharged into the environment. However, membrane biofouling persistently holds back an MBR process by reducing the process efficiency. Herein, we synthesized carbon nanospheres (CNSs) with many hydrophilic oxygen groups and utilized them as an additive to prepare high-performance ultrafiltration (UF) membranes with hydrophilicity and porous pore structure. CNSs were found to form crescent-shaped pores on the membrane surface, increasing the mean surface pore size by about 40% without causing significant defects larger than bubble points, as the CNS content increased by 4.6 wt%. In addition, the porous pore structure of CNS composite membranes was also attributable to the CNS's isotropic morphologies and relatively low particle number density because the aforementioned properties contributed to preventing the polymer solution viscosity from soaring with the loading of CNS. However, too porous structure compromised the mechanical properties, such that CNS2.3 was the best from a comprehensive consideration including the pore structure and mechanical properties. As a result, CNS2.3 showed not only 2 times higher water permeability than CNS0 but also 5 times longer operation duration until membrane cleaning was required.

Analysis of grout injection distance in single rock joint (단일절리 암반에서 그라우팅 주입거리 분석)

  • Ji-Yeong Kim;Jo-Hyun Weon;Jong-Won Lee;Tae-Min Oh
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.25 no.6
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    • pp.541-554
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    • 2023
  • The utilization of underground spaces in relation to tunnels and energy/waste storage is on the rise. To ensure the stability of underground spaces, it is crucial to reinforce rock fractures and discontinuities. Discontinuities, such as joints, can weaken the strength of the rock and lead to groundwater inflow into underground spaces. In order to enhance the strength and stability of the area around these discontinuities, rock grouting techniques are employed. However, during rock grouting, it is impossible to visually confirm whether the grouting material is being smoothly injected as intended. Without proper injection, the expected increases in strength, durability, and degree of consolidation may not be achieved. Therefore, it is necessary to predict in advance whether the grouting material is being injected as designed. In this study, we aimed to assess the injection performance based on injection variables such as the water/cement mixture ratio, injection pressure, and injection flow using UDEC (Universal Distinct Element Code) numerical program. Additionally, numerical results were validated by the lab experiment. The results of this study are expected to help optimize variables such as injection material properties, injection time, and pump pressure in the grouting design in the field.