• Title/Summary/Keyword: 물리적 풍화

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Effects of Evaporation on the Weathering Rate and Chemical Composition of Iranian Heavy Crude Oil (이란산 원유의 증발에 따른 풍화율 및 화학적 성상 변화)

  • Kim, Beom;Kim, Gi-Beum;Sim, Won-Joon;Yim, Un-Hyuk
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.3
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    • pp.238-246
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    • 2012
  • Once oil is spilled into marine environment, it experiences various weathering processes among which evaporation is the most dominant process in the initial stage of weathering. This study aimed to elucidate the effects of evaporation on the physicochemical properties of spilled oil using standardized laboratory experiments. Laboratory evaporation process was successfully reproduced using controlled rotary evaporation method. In case of Iranian Heavy crude (IHC), evaporation rate after 48 hours was $29.3{\pm}0.4%$ (n=40, p<0.001). Evaporation was simulated using ADIOS2 weathering model and the result was in agreement with laboratory experiment. Chemical composition changes of petroleum hydrocarbons including alkanes, polycyclic aromatic hydrocarbons (PAHs) and biomarkers by evaporation rate were also analyzed. As oil evaporated, low molecular weight alkanes and PAHs decreased, while biomakers showed conservative characteristics. Among biomarkers, $17{\alpha}(H)$, $21{\beta}(H)$-hopane was used for calculation of weathering rates, which matched with evaporative mass losses. Weathering rate calculation using hopane showed that stranded oils of weathering stage I (28.9%) and mesocosm oil weathering experiment till 5 days (26.5%) were mainly affected by evaporation process.

Surface Geophysical Survey for Delineation of Weathered Zone of Chojeong Area and Investigation of Fault Fracture Zones (초정지역의 풍화대 조사 및 단층파쇄 지역의 불연속면 조사를 위한 지표물리탐사)

  • Kim, Ji-Soo;Han, Soo-Hyung
    • The Journal of Engineering Geology
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    • v.17 no.4
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    • pp.517-523
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    • 2007
  • Geophysical surveys(seismic refraction, electrical resistivity, and ground penetrating radar) were performed to delineate the weathering zone associated with vadose water in Chojeong area and investigate the fault related fracture zones. On the basis of seismic velocity structures, weathering layer for the southwestern part is interpreted to be deeper than for the northeastern part. The depth to bedrock(i.e., thickness of weathered zone) from seismic refraction data attempted to be correlated with drill-core data and groundwater level. As for the investigation of geological discontinuities such as fault related fracture zone, seismic refraction, electrical resistivity, and ground penetrating data are compositely employed in terms of velocity and resistivity structures for mapping of surface boundary of the discontinuities up to shallow depth. Surface boundaries of fracture zone are well indicated in seismic velocity and electrical resistivity structures. Accurate estimation of weathered zone and fracture zone can be successfully available for mapping of attitude of vadose water layer.

Climate Change Impact on Korean Stone Heritage: Research Trends and Prospect (국내 석조유산의 기후변화 영향: 연구동향과 미래전망)

  • Kim, Jiyoung
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.437-448
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    • 2016
  • Studies on vulnerability of cultural heritage and adaptation strategy to worldwide climate change have been actively carried out in advanced countries since the late 20th century, and this established a valid research methodology and piled up climate and deterioration dataset in the field of climate change. Meanwhile, we still have tasks to acquire related scientific data despite referencing political researches in Korea. Applying Korean future climate to impact analysis, deterioration of Korean stone heritage is likely prospected to change into complexity in terms of physical, chemical and biological weathering that may bring impacts on conservation business and administrative field of cultural heritage. Further studies will ensure detailed implication of climate change impact on Korean stone heritage by means of down-scaling analysis of areas to local scale and dataset frequency to an hour. It is important to sort out capability and vulnerability of the stone heritage to future environment, and to make an adaption and prevention strategies.

Formation of Salty Materials on Granite Surface by Environmental Pollutants - Effects of TiO2 - (환경오염물질에 의한 화강암 표면에서의 염의 생성에 관한 연구 - TiO2의 영향을 중심으로 -)

  • Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1754-1759
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    • 2010
  • Because the stone cultural properties located outdoors, they have been altered and deteriorated in external appearance due to environmental factors such as acid rain, extreme change in temperature, and salts. Damage to stone cultural properties is accelerated particularly due to recent industrial development and environmental pollution. An experimental study was conducted to evaluate the effect of environmental contaminants(sea water and air pollutants such as, $SO_2$, NO, $CO_2$) on the weathering of granite. And as part of the developing of conservation method, $TiO_2$ catalyst was prepared and tested. After expose a granite to sea water and air pollutants, the mineral compositions of the tested granite surface were lower then that of the fresh granite. And absorption capacity of the weathered granite was steadily increased. From these results, it was expected that granite could be weathered by sea water and air pollutants. For the $TiO_2$ coated granite, absorption capacity was slightly enhanced compared to the $TiO_2$ non-coated granite. Therefore, the $TiO_2$ coating method tested in this study considered to be a viable method to assist in the conservation of granite from environmental contaminants.

Comparison of Physicochemical Characteristics of Topsoil and Subsoil for Soil Conservation and Management (토양 보전 및 관리를 위한 표토와 심토의 물리화학적 특성 비교)

  • Lee, So-Jin;Choo, Chang-Oh;Kim, Jong-Tae;Jeong, Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.731-739
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    • 2021
  • This research aimed to analyze the characteristics of topsoil for soil conservation and promote the process of turning subsoil into topsoil. The physicochemical characteristics of topsoil and subsoil of different types of soil were compared, and their quantitative differences were examined. 204 soil samples were collected from a total of 102 areas according to rock types. These samples were tested to measure grain size, water content, and unit weight, along with XRF and XRD analyses. The topsoil and subsoil of the soil samples were also analyzed. The results of this research showed that the topsoil and subsoil had different physical characteristics, and that the chemical alteration index of the topsoil was higher than that of the subsoil. This would imply that the topsoil was high in clay minerals since it was directly affected by weathering more than the subsoil. In particular, vermiculite, one of the final products generated from weathering, was common in the topsoil.

Lithological Characteristics and Deterioration Diagnosis of Dosolammaaebulsang (Rock-carved Buddha Statue of Dosolam) in the Seonunsa Temple, Gochang, Korea (고창 선운사 도솔암마애불의 암석학적 특성과 손상도 진단)

  • Park, Sung-Mi;Ryu, Keong-Seok;Choi, Hee-Soo;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.27 no.1
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    • pp.101-114
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    • 2011
  • The rock-carved Buddha statue at Dosolam (Korea Treasure No. 1200) of the Seonunsa temple in Gochang is unique style sculptured on natural rock cliff of 13.0m height. The Buddha statue is composed of volcanic complex with tuff, dacitic tuff breccia, tuff bereccia and lithic tuff. Especially, the Buddha statue is characterized by hydrothermal alteration and fragmentation on the upper and lower part. As a result of damage diagnosis, exfoliation and detachment of physical weathering are high of 11.3% and 9.3%, respectively. Infrared thermography analysis, exfoliation and micro-cracks occurred in the measuring parts that have not been confirmed by naked eyes. Chemical index of alteration and weathering potential index of host rock for the Buddha statue are 55.16 to 64.01 and 6.14 to 9.92 which are represented within highly weathering degree. In surface, dark black, reddish brown and white discoloration are observed prominently in the lower. Brown discoloration 6.9% is highest. According to the P-XRF measurements, high concentration of Fe in common, in part of dark black discoloration was Mn, white and brown discoloration in part of S and Ca content were higher. Biological weathering that yellowish brown and dark gray crustoes lichenes appeared by 20.8% and 13.3%, respectively. Therefore, comprehensive deterioration rate of Buddha statue show physical damage by 21.2%, discoloration for inorganic contaminants by 10.8% and biological damage by 39.4%. Ultrasonic velocity measurement carried out of Buddha statue on the surface by 555 points. Measured value of ultrasonic velocity was about 2,273m/s(1,067 to 3,215m/s, and weathering coefficient is 0.5(0.4 to 0.8) that progress on MW(moderately weathered) to HW(highly weathered) grade of rocks.

Geophysical Investigation of the Subsurface in the Dok-do Island (물리탐사를 이용한 독도 지반조사)

  • Kim, Chang-Ryol;Park, Sam-Gyu;Bang, Eun-Seok;Kim, Bok-Chul
    • 한국지구물리탐사학회:학술대회논문집
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    • 2008.10a
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    • pp.125-130
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    • 2008
  • Electrical resistivity and seismic refraction surveys were conducted to investigate geologic structures and geotechnical characteristics of the subsurface in Dok-do island, along with rock physical properties. The resistivity results in Seo-do island show that the fault adjacent to the fisherman's shelter is a normal fault and extended towards the NW direction. Bedded Rapilli Tuff in the downstream was more severely influenced in depth by weathering and erosion than Trachy Andesite II in the upstream area. The physical properties of the rocks illustrate that Trachyte and Trachy Andesite are hardest, Massive Tuff Breccia is next, and Tuffs are the most soft rocks in Dok-do island.

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Salt Weathering Characteristics and Mechanism Interpretation of the Five-Storied Stone Pagoda in Tapri-ri, Uiseong (의성 탑리리 오층석탑의 염풍화 특성과 메커니즘 해석)

  • Lee, Mi Hey;Lee, Myeong Seong;Lee, Jae Man;Chun, Yu Gun
    • 보존과학연구
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    • s.33
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    • pp.57-67
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    • 2012
  • The Uiseong Tapriri Five-Storied stone pagoda has occurred exfoliation, granular disintegration and discoloration by physical and chemical weathering factors with the major deterioration occurring due to efflorescence by salt. According to the results of SEM-EDS and X-ray diffraction analysis, salts consists of gypsum, taranakite. Artificial salt weathering tests were carried out using the same type of rocks as those in the stone pagoda. The test results showed that efflorescence occurred on the surface of the rock, and that exfoliation and granular disintegration occurred inside the rock due to salt crystallization.

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Classification of Weathering for the Granite and Granite Gneiss in Okcheon Belt-Jecheon${\cdot}$Geumsan${\cdot}$Gimcheon in Korea (옥천대지역 -제천${\cdot}$금산${\cdot}$김천 - 에 분포하는 화강암 및 화강 편마암의 풍화분류에 관한 고찰)

  • Woo, Ik;Park, Hyuk-Jin
    • Economic and Environmental Geology
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    • v.37 no.3
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    • pp.355-364
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    • 2004
  • A study on the weathering grade classification has been performed for granite and granite gneiss in Korea. The qualitative classification criteria of weathering were reviewed and then modified with field studies for the weathered rock masses. The thin section observations and XRD analyses for the different weathering grades rock samples showed the petrographical and petrophysical difference with respect to the weathering : the proportion of weathering-resistant minerals suck at quartz and orthoclase has a tendency to increase with the development of weathering, but that of weathering-sensible minerals such as anorthite and biotite is decreased. The ranges of physical and mechanical rock properties for different weathering grades were obtained from the laboratory rock tests and field tests for the studied rocks. And then, along with $RDI_{sq}$(Fookes et al., 1988), the weathering index $I_{a}$, (Woo, 2003) has been developed in this study to demarcate the weathering grade. Those two indices rely mainly on the water absorption ratio of rock and on the different rock strength. The range of these weathering indices have been determined with the physical and mechanical rock properties that can be obtained from simple field or laboratory tests in 4 grades $I_{a}$> 7 for F, 3.5 < $I_{a}$ < 10 for SW, 1.0 $I_{a}$< 6.0 for MW and $I_{a}$< 2.5 for HW. Consequently, the weathering index could be utilized to classify quantitatively the rock weathering grade, especially for the studied granites and the granite gneiss in Korea.

Characterization of Freezing-Thawing on the Artificial Weathering of $TiO_2$ Loaded Granite and Their Physical Property ($TiO_2$가 담지된 화강암의 인공풍화에 미치는 수분의 동결-융해의 평가와 물리적 성질)

  • Shon, Byung-Hyun;Jung, Jong-Hyeon;Kim, Hyun-Gyu;Choung, Young-Hean;Cho, Ki-Chul;Oh, Kwang-Joon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.183-190
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    • 2006
  • An experimental study was conducted to evaluate the effect of freezing-thawing and air pollutants on the weathering of $TiO_2$ loaded granite. And the granite was coated with $TiO_2$ catalyst and tested. After freezing-thawing and air pollutants experiments the mineral compositions of the granite surface were lower then that of the fresh granite. Density of the weathered granite was steadily decreased from $2.60g/cm^3\;to\;2.55{\sim}2.56g/cm^3$, but absorption ratio and porosity were slightly increased. From these results, it was expected that granite could be weathered by freezing-thawing md air pollutants. In the case of $TiO_2$ was coated to the granite, the compressive strength and absorption ratio were slightly enhanced compared to the $TiO_2$ non-coated granite. Therefore, the $TiO_2$ coating method tested in this study considered to be a viable method to assist in the conservation of granite from environmental contaminants.