• Journal of the Korean Crystal Growth and Crystal Technology
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• v.3 no.1
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• pp.66-74
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• 1993

Potassium-Graphite Intercalation Compounds(K-GICs) have been prepared from purified natural graphite by transformed two-bulb method with variations of reaction temperature ($T_g:450^{\circ}C$, $400^{\circ}C$, $350^{\circ}C$, $300^{\circ}C$, $250^{\circ}C$).Prepared K-GICs were identified to stage transition process by X-ray diffraction data. At these results, d values of (00l) diffraction at 1 stage and 2 stage were corresponded to $5.35\AA$ and $8.73\AA$ respectively. The stage stability and energy states of K-GlCs were obtained by UV /VIS Spectrophotometric data. We found that the minimum value of reflectance was 2.67 eV(465nm) at $250^{\circ}C$and it's moved to higher energy than original graphite's. And X-ray diffraction and UV /VIS spectrophotometric datas suggest that K-GICs were formed lower stage and many charge carriers exist between C atoms of graphite. And then, these results also provide informations on the electrical and other physical properities of K-GICs.Especially, according to studied reports, d values differ from them of each author, but accurate values were established through this study.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.2
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• pp.121-141
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• 2017

The thermal analysis of an underground power conduit for electrical cables is essential to determine their current capacity with an increasing number of demands for high-voltage underground cables. The temperature rises around a buried cable, caused by excessive heat dissipation, may increase considerably the thermal resistance of the cables, leading to the danger of "thermal runaway" or damaging to insulators. It is a key design factor to develop the mechanism on thermal behavior of backfilling materials for underground power conduits. With a full-scale field test, a numerical model was developed to estimate the temperature change as well as the thermal resistance existing between an underground power conduit and backfill materials. In comparison with the field test, the numerical model for analyzing thermal behavior depending on density, moisture content and soil constituents is verified by the one-year-long field measurement.

• Journal of the Korean Chemical Society
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• v.55 no.1
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• pp.98-103
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• 2011

This study was done for the preparation of macromolecular material with UV-blocking features by adding the benzophenone group that is commonly used as a UV-absorbent and $TiO_2$ which is known to be a very stable material in chemical and physical aspects. Also, we compared the level of UV absorbency of the polymer produced from polymerization with previous materials and measured basic properties such as water content, refractive index and optical transmittance of produced contact lenses. The results of the measurement showed that the refractive index and water content of the contact lens with added UV-absorbent was 1.430~1.440 and 35.0~45.0% respectively, which was similar to that of previous contact lenses. Also, for optical transmittances of each wave length, contact lenses without the UV-absorbent was 89%, 88% and 89% respectively for UV-A, UV-B and visible light, indicating that the UV transmittance is very high though contrary with cases of contact lenses with added 2-hydroxy-4-methoxy-benzophenone and 2,4-dihydroxy-benzophenone which showed transmittances of 0% and 6% respectively for UV-A and UV-B showing a UV-blocking effect. Meanwhile, contact lenses with added $TiO_2$ showed transmittance of 6% and 51% respectively for UV-A and UV-B also showing a UV-blocking effect. The visible transmittance was 77~89% showing that it satisfies the visible transmittance required for ophthalmological materials.

• Journal of Adhesion and Interface
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• v.2 no.3
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• pp.25-32
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• 2001

Ethyl cyanoacrylate (ECA) is used as an instant adhesive, and it can be readily polymerized by moisture in air without any initiator and applied for industrial products and ohome use. However, pure ECA monomer is low-viscosity liquid at room temperature that flows into substrate surface. To thicken the instant adhesive, poly(methyl methacylate)(PMMA) is often added in it commercially. Another disadvantage of instant adhesive polymer is its brittleness In this study, functional polymers including PMMA for an additive of ECA were prepared to increase viscosity of the monomer and flexibility of the adhesive atthe same time The additives, P(MMA-VAc-EVE), were synthesized by radical copolymerization of MMA with VAc and EVE having low glass transition temperature (Tg). The additives were added to ECA to get functional instant adhesives. The chemical structures of the additives and ECA polymers were confirmed by $^1H$ NMR and FTIR, and their physical and mechanical properites were also evaluated. The Tg of the obtained additives decreased with increasing the content of VAc or VAc-EVE, indicating more improved flexibility. In addition, functional instant adhesive containing the additives showed higher bonding strength than that of the existing one.

• Elastomers and Composites
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• v.42 no.1
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• pp.20-31
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• 2007

Material characteristics and lifetime evaluation are very important in design procedure to assure the safety and reliability of the rubber components. In this paper, the NBR compound was prepared by sulfur-cure system, and was used in predicting the lifetime of rubber gasket made by the compound. The accelerated material aging was investigated at different temperatures at 120, 140 and $160^{\circ}C$ and aging time from 3 hours to 600 hours at 5, 6, 7 vol %. of $H_2SO_4$ concentrations The rubber strips were placed in acid solution using pyrex g1ass tube. Both ends of pyrex g1ass tube were sealed to avoid evaporation of solution during heating at given time. The material test and accelerated acid-heat aging test were carried out to predict the useful life of NBR rubber gasket for a fuel cell stack. In order to investigate the effects of acid-heat aging on the properties of the NBR, tensile strength, elongation at break, hardness and crosslink-density were measured. The tensile strength decreases as the $H_2SO_4$ concentrations and temperature increase. Results were evaluated using Arrhenius equation.

• Land and Housing Review
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• v.1 no.1
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• pp.35-42
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• 2010

Most of the dredged sand generated from the sewage pipe maintenance project and the government's four-river project are disposed depending on abandonment and filling-up. This is caused by the lack of related recycling technology using dredged sand appropriately and high absorption rate and micro-particles of dredged sand producted from existing sand production system. Thus, this study carried out a quality assessment for the dredged sand produced through the optimum washing and sorting system supplementing problems of existing dredged sand production system as a part of research to examine performance of removing micro-particles and foreign substances. As a result of the assessment, the dredged sand produced through the cleaning and sorting system showed a wide quality improvement effect in absorption rate, 0.08 mm sieve pass amount, clay lump volume and organic impurity content, and it turned out to satisfy both the quality standards of this study, KS F 2573(recycled aggregate for concrete) and KS F 2526(aggregate for concrete) so it could be confirmed that it would be able to be used as an aggregate for concrete in the future.

• Food Science and Preservation
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• v.13 no.1
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• pp.30-36
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• 2006

Milk protein-gum conjugates were prepared by Maillard reaction and added to dough to investigate the possibile use of them as anti-staling agents in bread Four different types of conjugates were added to dough, i.e., $casein-\kappa-carrageenan$ (CK), casein-sodium alginate (CA), $whey-\kappa-carrgeenan$(WK) and whey-sodium alginate (WA). Their addition to flour increased the gelatinization temperature, water absorption and development time of the dough. Extensogram showed the increased resistance to extension of the doughs resulting from the addition of the conjugates. Moisture content of the breads decreased during storage at $5^{\circ}C$ for 4 days. The breads added with conjugates had lower extents of the decreases than non-treated degrees and maintained higher moisture content than non-treated bread after 3 freeze-thaw cycles. The storage degrees at $5^{\circ}C$ for 4 days affected the increased bread hardness, but, addition of WA conjugate decreased extents of the increases. Therefore, milk protein-gum conjugates, especially WA conjugate, contributed to retarding staling of breads

• Korean Journal of Food Science and Technology
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• v.44 no.6
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• pp.722-727
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• 2012

In order to improve the physical properties of brown rice by hydration and cooking, the amount of water absorption, hardness, reducing sugar, and minerals were measured for rice (NR), brown rice (NBR), and scratched brown rice (SBR). The amounts of water absorption were present in the order of NBR<0.07 SBR<0.20 SBR=NR after 210 min. The moisture contents of gelatinization rice were significantly different by degree of milling and scratch. The hardness of gelatinization rice were present in the order of NR<0.20 SBR<0.07 SBR

• Membrane Journal
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• v.26 no.5
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• pp.337-350
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• 2016

Lithium-ion rechargeable batteries (LIBs) have garnered increasing attention with the rapid advancements in portable electronics, electric vehicles, and grid-scale energy storage systems which are expected to drastically change our future lives. This review describes a separator membrane, one of the key components in LIBs, in terms of porous structure and physicochemical properties, and its recent development trends are followed. The separator membrane is a kind of porous membrane that is positioned between a cathode and an anode. Its major functions involve electrical isolation between the electrodes while serving as an ionic transport channel that is filled with liquid electrolyte. The separator membranes are not directly involved in redox reactions of LIBs, however, their aforementioned roles significantly affect performance and safety of LIBs. A variety of research approaches have been recently conducted in separator membranes in order to further reinforce battery safeties and also widen chemical functionalities. This review starts with introduction to commercial polyolefin separators that are currently most widely used in LIBs. Based on this understanding, modified polyolefin separators, nonwoven separators, ceramic composite separators, and chemically active separators will be described, with special attention to their relationship with future research directions of advanced LIBs.

• Korean Journal of Construction Engineering and Management
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• v.10 no.5
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• pp.67-75
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• 2009

While the trend of all industries recently lies in combination, construction industry is much interested in enhancing efficiency and competitiveness in the aspect of site control by adopting RFID. Though RFID has been applied to diverse areas thus far, it cannot be easily applied to construction industry due to diverse physical, chemical and use-environmental properties of construction materials. Furthermore, it is rarely applied to the site because of many problems in its application. It is required to prepare RFID code issuance and system that can systematically control the code as well as to research the standardization of frequency, specification, protocol, package method, recognition method, etc in order to apply RFID to construction industry. In this research, RFID code issuance and management program are proposed as a part of program research to apply RFID. Furthermore, the restricted matters of existing RFID tag are drawn to produce pilot product of RFID tag that can solve it so as to perform site application test. According to the experiment, effective recognition distance varies depending on material/environmental property and control efficiency changes depending on attachment method and application method. Thus, preparing diverse restrictive factors and solutions by systematically analyzing control method(medium, process) of current architecture materials and applying it to construction site can be the way to successfully apply RFID.