• 한국가스학회:학술대회논문집
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• 2003.10a
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• pp.65-72
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• 2003

현행 가스법상 지상식 LNG 저장탱크에 있어서 일정 용량의 저장탱크 주위에는 액상의 가스가 누출된 경우에 그 유출을 방지할 수 있는 방류둑(Dike) 또는 이와 동등 이상의 효과가 있는 시설을 설치하도록 규정하고 있어, 실제로 모든 지상식 LNG 저장탱크에 대해서 별도의 방류둑 설치를 의무화하고 있다. 또한, 예외규정으로 국제기준(international codes and standards)에 의해 설계되는 저장탱크는 심의를 통해 방류둑 기능을 인정할 수 있도록 하고 있다. 외국의 경우 LNG 저장탱크는 일반적으로 자국내 법령보다는 국제기준에 의해 건설됨으로써 1차 탱크로부터 일정거리의 둘레에 방류둑이 필요한 단일방호식 저장탱크 이외에 이중방호식, 완전방호식(full-containment) 및 멤브레인식(membrane) 저장탱크의 경우 외부(콘크리트, 강재)탱크가 방류둑 기능을 가지고 있어 별도의 방류둑이 필요없는 구조로 규정하고 있다. 멤브레인 LNG 저장탱크의 경우 프랑스, 일본 및 한국이 설계기술을 보유하고 있고, 최근 프랑스 및 한국에서 별도의 방류둑 없는 지상식 멤브레인 저장탱크 건설이 추진되고 있으나 양국 모두 자국법의 방류둑 규정에 의해 건설의 장애요소로 작용하고 있다. 따라서 지상식 멤브레인 LNG 저장탱크의 방류둑 기능에 대한 각 국의 법령 및 기준을 조사하고, 방류둑 일체형 저장탱크(완전방호식 및 멤브레인 저장탱크)의 형식별 안전성 평가 자료를 비교 검토함으로써 방류둑 일체형 멤브레인 저장탱크의 국내 도입의 타당성을 검토하고자 하였다. 조사결과 유럽, 미국 및 일본에서는 이중벽 LNG 저장탱크의 경우 콘크리트 외부탱크가 방류둑 기능을 가지는 것으로 규정하고 있으며, 특히 EN 1473과 제정중인 prEN 265002에서는 멤브레인 저장탱크의 경우 내부 멤브레인 탱크 누출시 단열시스템과 함께 외부 콘크리트 탱크가 액밀성 및 기밀성을 동시에 가지는 것으로 별도의 방류둑이 불필요함을 규정하고 있다. 프랑스 및 일본의 방류둑 일체형 LNG 저장탱크에 대한 위험성 평가 결과를 검토한 결과 멤브레인 저장탱크와 완정방호식 저장탱크는 안전성 차원에서 거의 동일한 것으로 나타났다. 따라서 국내에서 개발한 지상식 멤브레인 LNG 저장탱크 설계모델에 대한 안전성 제고 및 안전성 평가 등을 통해 객관적인 안전성 근거가 확보된다면 동 탱크의 경우에도 완전방호식 LNG 저장탱크와 같이 외부콘크리트 저장탱크의 방류둑 기능인정이 가능할 것으로 판단된다.

• Membrane Journal
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• v.32 no.1
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• pp.1-12
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• 2022

Graphene oxide (GO) has been considered as a promising membrane material, because of its easy processability and distinct properties, including controllable pore size distribution and diffusion channels. Particularly, the feasibility has been proposed a number of simulation results and proof-of-concept experimental approaches towards GO membranes. That is, GO already shows many outstanding intrinsic properties suitable for promising membrane platforms, such as the minimum membrane thickness and the ability to generate nanopores in the two-dimensional lattices or to create slit-like nanochannels between adjacent sheets. This review will be addressed the important experimental development in GO-based membranes for gas and ion separations, emphasizing on intrinsic transport phenomena, and critical issues for practical applications.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.33 no.11
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• pp.15-23
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• 2005

In this paper, the static and dynamic behavior of partly wrinkled membrane was studied. Membrane finite elements were used in the analysis and the wrinkling in the element was accounted for by a penalty-parameter material modeling which was implemented as a user subroutine to ABAQUS. The wrinkle algorithm was applied to a corner-loaded square membrane to investigate the effect of wrinkling on the static and dynamic behavior.

• Membrane Journal
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• v.27 no.6
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• pp.519-527
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• 2017

Membrane fouling is the main issue hindering the expansion of low pressure membrane processes for surface water treatment. Therefore, applying periodic hydraulic cleaning for fouling control should be well optimized. Better understanding of membrane fouling associated with periodic hydraulic cleaning would be useful to optimize membrane cleaning strategies. By comparing experimental permeability data with the classical Hermia blocking laws, this study aims at analyzing membrane fouling and understanding dominant fouling mechanisms occurring when filtering a synthetic surface water solution with a pressurized membrane process during six filtration cycles of 30 min each, separated with cyclic cleaning of 1 min by backwashing and forward flushing separately and combined. When applying single cleaning technique, membrane fouling during the first cycles was controlled by complete blocking mechanism while the last cycles were dominated by cake formation. Nevertheless, when combining cleaning technique better membrane regeneration was obtained and fouling was mainly due to cake formation.

• Membrane Journal
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• v.31 no.5
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• pp.327-332
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• 2021

The use of membranes for MBRWG (Membrane Bioreactor for Waste Gas) treatment can provide highly selective separation of a waste gas stream followed by effective biological removal. MBRWG have several potential advantages, among which the most distinctive one is separation of gas and liquid phases at each side of membrane potentially allowing the optimal biomass control toward effective biodegradation of target gases as well as biofilm activation. This advantage becomes especially favorable for removal of hydrophobic toxic gases, such as xylene, by MBRWG systems, because the mass transfer, the toxicity, and thereby the biodegradation of hydrophobic gas treatment requires sensitive handling of liquid stream and water control near biofilm. Among various membranes for MBRWG treatment, PDMS-hollow fiber membranes provide the high gas mass transfer. Despite lower specific surface areas, capillary type membranes are also applied current MBRWG studies. In addition to the main application of membranes as biofilm supporter in MBRWG systems, there can be another application of membranes in a posterior process for removal of residual gases or dusts emitted from conventional biological waste gas treatment processes.

• Proceedings of the Membrane Society of Korea Conference
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• 2002.07a
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• pp.149-165
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• 2002

고도정수 멤브레인공정, 멤브레인의 특성분석방법, 자연유기물질(NOM) 용질의 멤브레인 표면 혹은 막공에서의 이동현상, 그리고 막오염(fouling)현상에 대한 연구경향을 살펴보았으며, 이와 관련 되어 이루어진 연구결과를 개략적으로 요약함으로써 고도정수 멤브레인에 대한 일반적인 이해를 돕고자 하였다.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.144-150
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• 2013

Hybrid ceramic membrane (HCM) processes that combined ozonation with a ceramic membrane (CM) or a reactive ceramic membrane (RM), an iron oxide nanoparticles (IONs) incorporated-CM were investigated for membrane fouling control. Alumina disc type microfiltration and ultrafiltration membranes doped with IONs by sintering method were tested under varying mass fraction of IONs. Scanning electron microscope (SEM) images showed that IONs were well-doped on the CM surface and doped IONs were approximately 50 nm in size. Change in the pure water permeability of RM was negligible compared to that of CM. These results indicate that IONs incorporation onto CM had little effect on CM performance in terms of the flux. Natural organic matter (NOM) fouling and fouling recovery patterns during HCM processes confirmed that the RM-ozonation process enhanced the destruction of NOM and reduced the extent of fouling more than the CM-ozonation process by hydroxyl radical formation in the presence of IONs on RM. In addition, analyses of NOM in the feed water and the permeate showed that the efficiency of membrane fouling control results from the NOM degradation during HCM processes; leading to removal and transformation of relatively high contents of aromatic, high molecular weight and hydrophobic NOM fractions.

• Membrane Journal
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• v.22 no.4
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• pp.235-242
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• 2012

Ammonium perchlorate (AP) is primarily derived from the process of liquid incineration treatment when dismantling a solid rocket propellant. A series of batch dead-end nanofiltration (NF) and reverse osmosis (RO) membrane experiments were conducted to explore the retention mechanisms of AP under various hydrodynamic and solution conditions. Low levels of silicate type of siloxane had been detected through the GC/MS and FTIR analysis of liquid solutions extracted from solid ammonium perchlorate composite propellant (APCP). It is indicated that NF/RO membranes fouling in the presence of APCP was mainly attributed to the AP interactions because the concentration of silicate type of siloxane was negligible compared to that of AP. The osmotic pressure of AP was presumably resulted in the flux declines ranging from 13 to 17% in the case of the application of low-pressure (551 and 896 kPa for NF and RO) compared to those in application of high-pressure. The retention of AP by NF/RO membranes significantly varied from approximately 10 to 70% for NF and 26 to 87% for RO, depending on the operating and solution water chemistry conditions. The results suggested that retention efficiency of AP was fairly increased by reducing concentration polarization (i.e. application of low-pressure and stirring speed of 600 rpm) and increasing the pH of a solution. The result of this study was also consistent with the previous modeling of 'solute mass transfer of NF/RO membranes' and demonstrated that hydrodynamic and solution water chemistry conditions are to be a key factor in the retention of AP by NF/RO membranes.

• Journal of Energy Engineering
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• v.21 no.4
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• pp.339-345
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• 2012

RMembrane LNG storage tanks have been recently investigated to replace full-containment LNG storage tanks because of safety and cost aspects. Quantitative Risk Analysis (QRA) and Finite Element Method (FEM) were used to evaluate safety of membrane LNG storage tanks. In this study, structural safety evaluation results via FEM analysis showed that both membrane type and full-containment type cryogenic LNG storage tanks with 140,000 $m^3$ capacity were equivalently safe in terms of strength safety and leakage safety of a storage tank system. Also, Fault Tree Analysis (FTA) was used to improve the safety of membrane LNG storage tanks and membrane LNG tanks were modified by adding three safety equipments: impact absorber structure for the low part of the membrane, the secondary barrier to diminish the thermal stress of the corner part of the outer tank, and a pump catcher in case of falling of a pump. Consequently, the safety of the modified membrane LNG storage tanks were proved to be equivalent to that of full-containment LNG storage tanks.

• Membrane Journal
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• v.28 no.4
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• pp.252-259
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• 2018

An acidic, real metal-plating wastewater was treated by a fluidized bed membrane reactor introduced with granular activated carbon (GAC) as fluidized media. With GAC fluidization, there was no increase in suction pressure with time at each flux set-point applied. At neutral solution pH, much less fouling rate was observed than acidic pH under GAC fluidization. Higher solution pH resulted in the increase in particle size in metal-finishing wastewater, thus producing a less dense cake structure on membrane. More than 95% of chemical oxygen demand was observed from the fluidized bed membrane reactor under GAC fluidization. Total suspended solid concentration in membrane permeate was near zero. At the raw wastewater pH, no removal of copper and chromium by the fluidized bed membrane reactor was observed. As the pH was increased to 7.0, removal efficiency of copper and chromium was increased considerably to 99 and 94%, respectively. Regardless of solution pH tested, more than 95% of cyanide was removed possibly due to the strong adsorption of organic-cyanide complex on GAC in fluidized bed membrane reactor.