• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.236-242
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• 2005

Membrane fouling by protein mixtures during microfiltration has been investigated for binary mixtures of bovine serum albumin (BSA), casein, lysozyme, pepsin, and ovalbumin. Filtration experiments were carried out using $0.2{\mu}m$ polycarbonate track-etched (PCTE) membrane in a stirred cell under constant transmembrane pressure (14 kPa) and concentration of hydrogen ion (pH=11) to study the effect of mixture composition on filtrate flux decline. Flux decline data were analyzed using a pore blockage-cake formation model developed recently. It was found that the model is in a good agreement with the experimental data. Fouling parameters such as the rate of pore blockage(${\alpha}$), the initial resistance of the protein deposit ($R_{po}$) and the increasing rate of the protein layer resistance(${\beta}$) were used to evaluate the rate of filtrate flow by membrane fouling in the binary mixture system. Generally, the trend of ${\alpha}$ is comparable with that of filtrate flux decline. It was also found that fast flux decreasing was observed over the binary mixture containing casein. The result is due to high value of the initial resistance of the protein deposit ($R_{po}$) over casein.

• Membrane Journal
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• v.33 no.4
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• pp.191-200
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• 2023

Polyethersulfone (PES) is a widely employed membrane material for water and industrial purification applications owing to its hydrophilicity and ease of phase separation. However, PES membranes and filters prepared using the nonsolvent induced phase separation method often encounter significant flux decline due to pore clogging and cake layer formation on the dense membrane surfaces. Our investigation revealed that tight microfiltration or loose ultrafiltration membranes can be subject to physical fouling due to the formation of a dense skin layer on the bottom side caused by water intrusion to the gap between the shrank membrane and the substrate. To investigate the effect of the bottom surface porosity on membrane fouling, two membranes with the same selective layers but different sub-layer structures were prepared using single and double layer casting methods, respectively. The double layered PES membrane with highly porous bottom surface showed high flux and physical fouling tolerance compared to the pristine single layer membrane. This study highlights the importance of physical optimization of the membrane structure to prevent membrane fouling.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.151-151
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• 2013

최근 반도체 및 디스플레이 산업에서의 플라즈마 공정의 중요성은 점점 증대되고 있다. 특히, 반도체/LCD 제조공정에서의 Dry Etch공정은 디스플레이용 유리 위에 형성된 산화막, 금속입자, 박막, 및 Polymer와 같은 불순물들을 플라즈마를 이용하여 제거하는 공정이다. 플라즈마 공정을 진행하는 동안 몇 가지 문제점들이 이슈가 되고 있다. Etch공정에서는 활성 부식가스를 많이 사용하고 장시간 플라즈마에 노출되기 때문에, 진공부품들은 플라즈마에 의해서 물리적인 이온충격(Ion Bombardment)과 화학적인 Radical 반응에 의한 부식이 진행된다. 부식영향에 의해 챔버를 구성하고 있는 부품에서 균열이 발생하거나 오염입자들이 떨어져 나오게 된다. 발생한 오염입자들은 산업용 플라즈마 공정에서 매우 심각한 문제가 되고 있다. 본 연구에서는 산화막의 부식 저항특성을 측정할 수 있는 평가방법에 대하여 고찰하였고, 표준화된 데이터로 비교분석할 수 있도록 평가기준과 규정화된 피막평가방법을 연구하였다. 또한, 산화막의 특성에 따른 플라즈마 상태, 오염입자 발생 등 플라즈마 공정을 진단하여 부품재료의 수명을 예측하고, 신뢰성 있는 평가방법에 관한 연구를 하였다.

• Membrane Journal
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• v.19 no.3
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• pp.194-202
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• 2009

In this study periodic water-back-flushing using permeate water was performed to minimize membrane fouling and to enhance permeate flux in advanced water treatment by tubular ceramic ultrafiltration membrane for Gongji stream in Chuncheon city. The back-flushing period (FT, filtration time) 2 min with periodic water-back-flushing of 15 sec showed the highest value of dimensionless permeate flux (permeate flux vs. initial permeate flux), and the lowest value of resistance of membrane fouling. Also in the results of BT effect at fixed FT 10 min, BT (back-flushing time) 20 sec showed the lowest value of resistance of membrane fouling and the highest value of dimensionless permeate flux, and we could be obtained the highest total permeate volume of 107.3 L. Consequently FT 10 min and BT 20 sec could be the optimal condition in Gongji stream water treatment, which was the exactly same results of our previous tubular alumina microfiltration. Then the average rejection rates of pollutants by our tubular ceramic UF system were 97.0% for turbidity, 32.1 % for chemical oxygen demand by manganese method, 28.8% for ammoniac nitrogen and 54.4% for T-P.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.6
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• pp.581-589
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• 2005

Recently, membrane processes have been replacing the conventional processes for waste water treatment to produce better quality of effluent and to meet more stringent regulations because of water shortage. However, using membrane processes for water treatment has confronted with fouling and difficulty in treating dissolved organic pollutants. In this study, membrane process equipped with crossflow microfiltration is combined with coagulation process using alum and PAC to improve permeability and treatment efficiency. The effects of coagulant dosage and optimum membrane operating conditions were investigated from measurement of permeate flow, cumulative volume, total resistance, particle size, dissolved organic pollutant, dissolved aluminium and quality of effluent. Characteristic of PAC coagulation was compared with that of alum coagulation. PAC coagulation reduced membrane fouling because of forming larger particle size and increased permeate velocity and cumulative volume. Less dissolved organic pollutants and dissolved aluminum made decreasing-rate of permeate velocity being lowered. At using $0.2\;{\mu}m$ membrane, cake filtration observed. At using $0.45\;{\mu}m$ membrane, there was floc breakage due to shear stress occurred born circulating operation. It made floc size smaller than membrane pore size, which subsequently to decrease permeate velocity and to increase total resistance. The optimum coagulation dosage was $300{\pm}50\;mg/L$ for both alum and PAC. PAC coagulation was more efficiently used with $0.2\;{\mu}m$ membrane, and the highest permeate flux was in using $0.45\;{\mu}m$membrane. The greatest efficiency of treatment was as follows; turbidity 99.8%, SS 99.9%, $BOD_5$ 94.4%, $COD_{Cr}$ 95.4%, T-N 54.3%, T-P 99.8%.

• Membrane Journal
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• v.28 no.1
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• pp.1-20
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• 2018

Fresh water is an important resource for humans, and pressure-driven membrane technology has been widely known as an energy-efficient method to obtain water resource. However, membrane fouling phenomenon, which is one of the major issue during operation, deteriorates membrane permeability. These fouling is usually affected by interaction between surface of membrane and various foulants, therefore, modification of membrane's surface is one of the methods to improve fouling-resistance. This review focuses on the method to modify surface of pressure-driven membranes such as microfiltration (MF), ultrafiltration (UF), nanofiltration (NF), and reverse osmosis (RO). Specifically, there are two different surface modification methods: (1) adsorption and coating as the physical modification methods, (2) cross-linker, free radical polymerization (FRP), atom transfer radical polymerization (ATRP), plasma/UV-induced polymerization as the chemical modification methods. This review introduces the physico - chemical surface modification methods reported in recent papers and suggests research directions for membrane separation which can increase membrane fouling resistance.

• Membrane Journal
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• v.13 no.4
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• pp.219-228
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• 2003

This study was carried to investigate the effect of humic acid and kaloin which cause the turbidity and organic substance component for optimization of drinking water treatment process using the membrane separation. Also we were ovserved the optimum operating condition which flux was stabilized, while specific resistance value in membrane was minimized. As the result, the membrane separation was operated at low specific resistance value with the increase of the pressure. And then, cake load decreased by high velocity with the increase of the linear velocity, and the tendency in which specific resistance value and flux increased. Therefore, we confirmed the optimum operating condition as pressure $2.0 kgf/cm^2,$ 0.92 m/sec linear velocity.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.3
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• pp.523-533
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• 2000

A two-phase anaerobic reactor with submerged membrane system was developed for increasing acidogen concentration and methane recovery. The membrane used was mixed esters of cellulose of $0.5{\mu}m$ pore size and $0.8m^2$ of effective surface area. The methanogenic reactor comprised of UASB (Upflow Anaerobic Sludge Blanket) and AF (Anaerobic Filter). COD removal efficiency was 70~80% and the methane content in the biogas increased up to 90% for the submerged membrane system in the anaerobic reactor. As the cake resistance of membrane caused a serious problem, stainless steal prefilters (40, 53, $63{\mu}m$) and air backwashing methods were applied to minimize the cake resistance effectively. Among the tested prefilters. the $63{\mu}m$ prefilter showed the best performance for reduction of cake resistance and a successful long-tern operation. By cleaning with alkali first and acidic solution later. the permeate flux decreased by long term operation was recovered to 89% of that with a new membrane.

• Membrane Journal
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• v.8 no.3
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• pp.130-137
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• 1998

Membrane fouling characteristics in the membrane-coupled activated sludge system were investigated. The influence of the floc size variation on the filtration resistance was analyzed using resistance-in-series model and mixed liquor was fractionated into three components to verify which component would give rise to a major contribution to the total resistance. The microbial floc size was rapidly reduced during the initial 4~6 hours of operation, and then decreased slightly but steadily, followed by leveling off at the size of 20 $\mu$m. The specific resistance of activated sludge increased with operation time, and measured values of specific resistance were matched well with the values estimated on the basis of the mean particle size in the mixed liquor. The contribution of soluble organics and cells to the total resistance was relativdy small compared with that of the supematant. Colloidal particles in the supematant showed much higher specific resistance than that of microbial floc, and played the most important role in the cake resistance.

• Membrane Journal
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• v.13 no.2
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• pp.88-100
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• 2003

A change of filtrate flux in Taylor vortex flow filtration was investigated experimentally by rotating speed of inner cellulose ester membrane cylinder (average pore size: 1.2 ${\mu}m$), slurry concentration, and particle size. The filtrate flux was a direct proportion relation with TMP, but an inverse relation with resistances. A change of cake resistance with time was examined by rotating speed, slurry concentration, and particle size. Initial resistance increased dramatically as raising slurry concentration, and the pseudo-steady state was maintained at high resistance value. However, times to reach the pseudo-steady state did not depend on slurry concentration. The resistance was larger as smaller particle size, because possibility of pore blocking inside membrane could be higher and shear effect should be lower as smaller particle size. A model equation suggested in this study was composed of particle deposition and removal terms, and could confirm well experimental data using average values of experimental coefficients.