• Title/Summary/Keyword: 마이크로 제조

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Enhancing the Performance of Polypropylene Fiber Reinforced Cementitious Composite Produced with High Volume Fly Ash (폴리프로필렌 섬유로 보강된 하이볼륨 플라이애시 시멘트 복합재료의 성능 향상 기법)

  • Lee, Bang Yeon;Bang, Jin Wook;Kim, Yun Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.3
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    • pp.118-125
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    • 2013
  • The synthetic fibers including Polyvinyl alcohol and Polyethylene fibers have been successfully used in the manufacture of high ductile fiber reinforced cementitious composites. Polypropylene (PP) fiber has also been used in composites, not for the purpose of achieving a high level of tensile ductility but to improve the fire resistance performance of concrete exposed to high temperatures. This paper discusses the method for enhancing the performance of composites supplemented with PP fiber. Five types of mixture proportions were designed with high volume fly ash for testing the performance of composites. Type I cement and fly ash F were used as binding materials. The water-to-binder ratio was 0.23~0.25, and the amount of PP fiber used was 2 vol%. Polystyrene bead were also used to increase the tensile ductility of composites. A series of experiments including slump, density, compression and uniaxial tension tests were performed to evaluate the performance of cementitious composites supplemented with PP fiber. From the test results, it was exhibited that the performance of composites supplemented with PP fiber can be enhanced by adopting the mechanics and statistics theory.

Fabrication of Honeycomb Adsorbents by Using the Ceramic Paper and Adsorption Characteristics of VOC (세라믹섬유지를 사용한 허니컴 흡착소자 제조 및 VOC 흡착특성)

  • Yoo, Yoon-Jong;Cho, Churl-Hee;Kim, Hong-Soo;Ahn, Young-Soo;Han, Moon-Hee;Jang, Gun-Eik
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1035-1041
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    • 2002
  • The adhesion characteristics of adsorbent during impregnation of Y-type and ZSM-5type zeolites into ceramic paper were analyzed, as the amount of silica sol in slurry for impregnation was varied. 31 wt% of zeolite particle, which is useful for VOC adsorption, was evenly dispersed and adhered on ceramic paper and original crystal structure of the zeolite remained unchanged even after binder application and heat treatment. Surface area of the impregnated ceramic paper was decreased compared with that of zeolite powder. And it was found to be attributed to the reduction of volume of mesopore while the volume of micropore under $20{\AA}$ was unchanged. Zeolite-impregnated honeycomb cylinder, whose diameter and length were 10 cm and 40 cm, respectively, was subjected to adsorption/desorption test with respect to toluene, MEK, cyclohexanone. All of the VOC's were removed by adsorption with efficiency higher than 97% and from the static adsorption test, $42 Nm^3/h$ of 300 ppmv-VOC-laden air was calculated be treated continuously, when the honeycomb was used in an adsorptive rotor system.

Effect of Trehalose on Moisture and Texture Characteristics of Instant Baekseolgi Prepared by Microwave Oven (트레할로스의 첨가가 마이크로웨이브 이용 즉석 백설기의 수분 및 조직감 특성에 미치는 효과)

  • Kang, Ho-Jin;Kim, Seung-Hee;Lim, Jae-Kag
    • Korean Journal of Food Science and Technology
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    • v.42 no.3
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    • pp.304-309
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    • 2010
  • Instant Baekseolgi containing 0, 1, 2, and 3% trehalose prepared using a microwave oven, after which quality characteristics were investigated over 24 hr. The sample was prepared to internal and external parts. The moisture content of Baekseolgi without trehalose (control) was not reduced. However, the presence of trehalose reduced moisture content of two different groups (p<0.05). Weight reduction of Baekseolgi was decreased with increased threhalose content (p<0.05). The hardness, and chewiness of Baekseolgi with trehalose was decreased with increased trehalose (p<0.05). However adhesiveness, springiness, and cohesiveness were not significantly changed. The results of sensory evaluation showed that moisture and hardness were reduced between the internal and external parts of the Baekseolgi with increased trehalose (p<0.05). This study shows that the addition of trehalose to Baekseolgi had a positive impact on quality characteristics, including moisture content, weight reduction, texture, and sensory properites.

Electrospray-assisted Preparation of Polymer Microparticles Containing Water-insoluble Bioactive Compounds (전기방사법을 이용한 유용성 생리활성성분을 포함한 고분자 마이크로입자 제조)

  • Hwang, Yoon Kyun;Jeong, Min Kuk;Cho, Sung Yeon;Park, Sung Il;Cho, Eun Chul
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.1
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    • pp.11-18
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    • 2017
  • An anti-aging compound ethyl (4-(2,3-dihydro-1H-indene-5-carboxyamido) benzoate) rapidly crystallizes in emulsion systems, and a flavonoid 3,5,7-trihydroxy-4'-methoxy-8-prenylflavone bearing a whitening function causes coloration of cosmetic compounds when mixed with metal oxides. In this study, an electrospray method was used to encapsulate water-insoluble bioactive compounds in polymeric microparticles. Poly (methyl methacrylate) and polycaprolactone were used to encapsulate ethyl (4-(2,3-dihydro-1H-indene-5-carboxyamido) benzoate) and 3,5,7-trihydroxy-4'-methoxy-8-prenylflavone, respectively. It was found that polymer concentration, the structure of electrospray nozzle, and compatibility between polymers and bioactive compounds were important factors in the preparation of the particles. Polycaprolactone particles encapsulating 3,5,7-trihydroxy-4'-methoxy-8-prenylflavone was effective in preventing coloration of a cosmetic compound when mixed with metal oxides.

Preparation of TiO2 Nanoparticles from Titanium Tetraisopropoxide Using an Aerosol Microreactor (에어로졸 마이크로반응기에 의한 Titanium Tetraisopropoxide로부터 TiO2 나노입자 제조)

  • Choi, Jae Gil;Park, Kyun Young
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.609-615
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    • 2005
  • $TiO_2$ particles, 30-300 nm in diameter, were prepared by thermal decomposition of titanium tetraisopropoxide (TTIP) using an aerosol microreactor, by which about $1{\mu}l$ of the liquid precursor is injected into an evaporator, 1 cc in volume, and vaporized precursor is then transported by nitrogen as a bolus to a tubular reactor 4 mm in diameter and 35 cm in length. Investigated were the effects of the reactor temperature and the concentration of TTIP vapor on the morphology, particle size distribution and crystalline structure of produced $TiO_2$ particles. With TTIP vapor concentration kept constant at 1 mol%, the reactor temperature was varied from 300 to 500 and $700^{\circ}C$. The primary particle size decreased with increasing the temperature, and the size distributions were mono-modal at 300 and $500^{\circ}C$, but bi-modal at $700^{\circ}C$. The TTIP vapor concentration was increased from 1 to 3.5 and 7 mol%, holding the reactor temperature at $700^{\circ}C$. The bi-modal distribution seen at the concentration of 1 mol% disappeared and the number of particles composing an agglomerate increased at the higher concentrations. These effects of the reactor temperature and the precursor concentration were discussed in comparison with experimental results reported earlier.

Fabrication of Thick Silicon Dioxide Air-Bridge and Coplanar Waveguide for RF Application Using Complex Oxidation Process and MEMS Technology (복합 산화법과 MEMS 기술을 이용한 RF용 두꺼운 산화막 에어 브리지 및 공면 전송선의 제조)

  • Kim, Kook-Jin;Park, Jeong-Yong;Lee, Dong-In;Lee, Bong-Hee;Bae, Yong-Hok;Lee, Jong-Hyun;Park, Se-Il
    • Journal of Sensor Science and Technology
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    • v.11 no.3
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    • pp.163-170
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    • 2002
  • This paper proposes a $10\;{\mu}m$ thick oxide air-bridge structure which can be used as a substrate for RF circuits. The structure was fabricated by anodic reaction, complex oxidation and micromachining technology using TMAH etching. High quality films were obtained by combining low temperature thermal oxidation ($500^{\circ}C$, 1 hr at $H_2O/O_2$) and rapid thermal oxidation (RTO) process ($1050^{\circ}C$, 2 min). This structure is mechanically stable because of thick oxide layer up to $10\;{\mu}m$ and is expected to solve the problem of high dielectric loss of silicon substrate in RF region. The properties of the transmission line formed on the oxidized porous silicon (OPS) air-bridge were investigated and compared with those of the transmission line formed on the OPS layers. The insertion loss of coplanar waveguide (CPW) on OPS air-bridge was (about 2dB) lower than that of CPW on OPS layers. Also, the return loss of CPW on OPS air-bridge was less than about -20 dB at measured frequency region for 2.2 mm. Therefore, this technology is very promising for extending the use of CMOS circuitry to higher RF frequencies.

Nonstoichiometry and Magnetic Property of the $Nd_{-x}Sr_{x}CoO_{3-y}$ System ($Nd_{-x}Sr_{x}CoO_{3-y}$계의 비화학양론 및 자기적 특성)

  • Chul Hyun Yo;Kwon Sun Roh;Sung Joo Lee;Kyu Hong Kim;Eung Ju Oh
    • Journal of the Korean Chemical Society
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    • v.35 no.3
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    • pp.211-218
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    • 1991
  • A series of samples in the $Nd_{-x}Sr_{x}CoO_{3-y}$ system (x = 0.00, 0.25, 0.50, 0.75 and 1.00) have been produced by heating the reactants at 1200${\circ}$C under atmospheric pressure. The solid solutions were analysed by X-ray diffraction spectra, thermal analysis, and SEM micrographs. X-ray powder diffraction assigns the compositions of x = 0.00, 0.25, 0.50 and 0.75 to the cubic system and the composition of x = 1.00 to the orthorhombic system. The reduced lattice volume is increased with increasing x values in the system. The mole ratio of $Co^{4+}$ or ${\tau}$ values are determined by the Iodometric titration method and are maximum at the composition of x = 0.50. The magnetic measurement shows that a ferromagnetism is appeared in the compositions of x = 0.00, 0.25, 0.50 and 0.75 and then an antiferromagnetism in the composition of x = 1.00. The measurement of the electrical conductivity shows that the semiconductivity is appeared in the composition of x = 0.00, 0.25 and 1.00 and the metallic conductivity in the composition of x = 0.50 and 0.75. The magnetic and electrical properties of the samples are discussed with the nonstoichiometric chemical formulas.

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A Study on Synthesis of CaCO3 & MgO/Mg(OH)2 from Dolomite Using the Strong Acidic Cation Exchange Resin (강산성 양이온 교환수지를 통한 백운석으로부터 CaCO3 및 MgO/Mg(OH)2 합성에 관한 연구)

  • Hwang, Dae Ju;Yu, Young Hwan
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.812-825
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    • 2019
  • Two dolomite samples mined from the different mines were calcined using a batch-type microwave kiln ($950/60min^{\circ}C$) to produce $CaO{\cdot}MgO$. The hydration of the $CaO{\cdot}MgO$ samples shows different reactivity. MgO was separated by reacting with a strong acid cation exchange resin using the reactivity of the hydration properties of light dolomite ($CaO{\cdot}MgO$). Calcium ($Ca-(R-SO_3)_2$) was separated from the prepared $CaO{\cdot}MgO$ by the cation exchange resin ($CaO{\cdot}MgO:R-SO_3H=1:12mass%$). High purity MgO (higher than 94 mass %) with unburned $CaCO_3$ (1~2 mass %) was obtained by the separation process. The separated MgO was heated at $950^{\circ}C$ for 60 minutes to afford high purity MgO with MgO content higher than 96%. And High-grade $CaCO_3$ was prepared from the reaction with calcium adsorbed resin ($Ca-(R-SO_3)_2$) and NaOH, $CO_2$ gas.

Fabrication and validation study of a 3D tumor cell culture system equipped with bloodvessle-mimik micro-channel (혈관모사 마이크로채널이 장착된 3D 종양 세포 배양 시스템의 제작 및 검증 연구)

  • Park, Jeong-Yeon;Koh, Byum-seok;Kim, Ki-Young;Lee, Dong-Mok;Yoon, Gil-Sang
    • Design & Manufacturing
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    • v.15 no.2
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    • pp.11-16
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    • 2021
  • Recently, three-dimensional (3D) cell culture systems, which are superior to conventional two-dimensional (2D) vascular systems that mimic the in vivo environment, are being actively studied to reproduce drug responses and cell differentiation in organisms. Conventional two-dimensional cell culture methods (scaffold-based and non-scaffold-based) have a limited cell growth rate because the culture cannot supply the culture medium as consistently as microvessels. To solve this problem, we would like to propose a 3D culture system with an environment similar to living cells by continuously supplying the culture medium to the bottom of the 3D cell support. The 3D culture system is a structure in which microvascular structures are combined under a scaffold (agar, collagen, etc.) where cells can settle and grow. First, we have manufactured molds for the formation of four types of microvessel-mimicking chips: width / height ①100 ㎛ / 100 ㎛, ②100 ㎛ / 50 ㎛, ③ 150 ㎛ / 100 ㎛, and ④ 200 ㎛ / 100 ㎛. By injection molding, four types of microfluidic chips were made with GPPS (general purpose polystyrene), and a 100㎛-thick PDMS (polydimethylsiloxane) film was attached to the top of each microfluidic chip. As a result of observing the flow of the culture medium in the microchannel, it was confirmed that when the aspect ratio (height/width) of the microchannel is 1.5 or more, the fluid flows from the inlet to the outlet without a backflow phenomenon. In addition, the culture efficiency experiments of colorectal cancer cells (SW490) were performed in a 3D culture system in which PDMS films with different pore diameters (1/25/45 ㎛) were combined on a microfluidic chip. As a result, it was found that the cell growth rate increased up to 1.3 times and the cell death rate decreased by 71% as a result of the 3D culture system having a hole membrane with a diameter of 10 ㎛ or more compared to the conventional commercial. Based on the results of this study, it is possible to expand and build various 3D cell culture systems that can maximize cell culture efficiency by cell type by adjusting the shape of the microchannel, the size of the film hole, and the flow rate of the inlet.

Study on Stabilization of Retinaldehyde using Drug-in-Cyclodextrinin-Liposome (DCL) for Skin Wrinkle Improvement (레틴알 안정화를 위한 사이클로덱스트린-리포좀에 관한 연구)

  • Ha, Ji Hoon;Choi, Hyeong;Hong, In Ki;Han, Sang-Kuen;Bin, Bum Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.48 no.1
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    • pp.77-85
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    • 2022
  • Retinaldehyde (RA), vitamin A derivative, is an intermediate between retinol and retinoic acid and has an excellent wrinkle improving effect. In this study, Drug-in-cyclodextrin-in-liposome (DCL) was used to enhance the stability and skin penetration of RA. The complex of RA and hydroxypropyl-beta-cyclodextrin (HP-β-CD) was prepared by the freeze-drying method, and the presence or absence of inclusion of retinal was confirmed by UV-Vis spectrometer, FT-IR and SEM images. RA was captured in HP-β-CD about 95.6% on 1 : 15 (w/w). The retinal-HP-β-CD complex was encapsulated in liposomes using a homomixer and microfluidizer, with an average particle size of 215 ± 4.2 nm and a zeta potential of -31.2 ± 0.5 mv. In the evaluation of the degradation stability of RA, degradation rate of RA-HP-β-CD-liposomes in water was 1.8% higher than RA-liposome (5.8%), RA-HP-β-CD complex (9.7%) and RA alone (37.6%). RA cream (0.05% RA) including RA-HP-β-CD-liposomes was prepared for clinical test with wrinkle-improving efficacy and skin dermis denseness evaluated for 2 or 4 weeks. RA cream showed a significant wrinkle improving effect without skin irritation. In conclusion, it was confirmed that the double stabilization technology using the DCL system contribu tes to the effect of improving skin wrinkles by increasing the stabilization of retinal.