• Title/Summary/Keyword: 리튬배터리

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Development of Online Battery Management System for Uninterruptible Power Supply (무정전 전원공급장치용 온라인 배터리 관리시스템 개발)

  • Nam Jong-ha;Choi Jin-Hong;Kim Seung-Jong;Kim Jae-Woong
    • Proceedings of the KIPE Conference
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    • 2004.07b
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    • pp.830-833
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    • 2004
  • UPS 시스템에서 정전시 안정적인 전력공급을 방해하는 요소의 대부분은 배터리의 불량이 차지하고 있다. 일반적으로 UPS 시스템에 적용되는 배터리는 일정시간이 경과되면 전체를 교체하는 관리시스템을 가지며, 주기적인 방전시험을 실시하지만 교체기준에 대한 명확한 방안이 마련되어 있지 않다. 일부에서는 배터리의 내부저항 혹은 임피던스를 측정하여 배터리의 교체여부를 판단하는 기준으로 삼고 있지만 배터리의 비선형적 특성으로 인하여 그 오차범위는 크다고 할 수 있다. 또한 배터리는 부동충전시에는 정상적인 특성을 보이지만 방전시 불량 특성이 나타나는 경우가 많고, 리튬-이온 배터리의 경우 내부저항은 수십$[m\Omega]$의 비교적 큰 값을 가지지만 UPS에 적용되는 납축전지의 경우 수$[m\Omega]$ 정도의 아주 낮은 내부저항을 가져 측정오차에 의해 불량 여부를 명확히 판단하지 못하는 경우가 있다. 본 논문에서는 이러한 문제점에 착안하여 평상시에는 배터리의 개별셀 전압, 온도, 전체전압 및 보관함의 온도, 충방전 전류, SOC(State of Charge)를 현장 및 원격지의 모니터링 PC로 전송하여 사용자에게 보여주며, 정전으로 인한 방전시에는 내부저항과 개별셀의 용량을 계산하고 이를 통해 교체시기를 결정할 수 있도록 구성되어 있으며, 실험을 통해 타당성을 확인하였다.

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Nanoscale Pattern Formation of Li2CO3 for Lithium-Ion Battery Anode Material by Pattern Transfer Printing (패턴전사 프린팅을 활용한 리튬이온 배터리 양극 기초소재 Li2CO3의 나노스케일 패턴화 방법)

  • Kang, Young Lim;Park, Tae Wan;Park, Eun-Soo;Lee, Junghoon;Wang, Jei-Pil;Park, Woon Ik
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.83-89
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    • 2020
  • For the past few decades, as part of efforts to protect the environment where fossil fuels, which have been a key energy resource for mankind, are becoming increasingly depleted and pollution due to industrial development, ecofriendly secondary batteries, hydrogen generating energy devices, energy storage systems, and many other new energy technologies are being developed. Among them, the lithium-ion battery (LIB) is considered to be a next-generation energy device suitable for application as a large-capacity battery and capable of industrial application due to its high energy density and long lifespan. However, considering the growing battery market such as eco-friendly electric vehicles and drones, it is expected that a large amount of battery waste will spill out from some point due to the end of life. In order to prepare for this situation, development of a process for recovering lithium and various valuable metals from waste batteries is required, and at the same time, a plan to recycle them is socially required. In this study, we introduce a nanoscale pattern transfer printing (NTP) process of Li2CO3, a representative anode material for lithium ion batteries, one of the strategic materials for recycling waste batteries. First, Li2CO3 powder was formed by pressing in a vacuum, and a 3-inch sputter target for very pure Li2CO3 thin film deposition was successfully produced through high-temperature sintering. The target was mounted on a sputtering device, and a well-ordered Li2CO3 line pattern with a width of 250 nm was successfully obtained on the Si substrate using the NTP process. In addition, based on the nTP method, the periodic Li2CO3 line patterns were formed on the surfaces of metal, glass, flexible polymer substrates, and even curved goggles. These results are expected to be applied to the thin films of various functional materials used in battery devices in the future, and is also expected to be particularly helpful in improving the performance of lithium-ion battery devices on various substrates.

Upstream Risks in Domestic Battery Raw Material Supply Chain and Countermeasures in the Mineral Resource Exploration Sector in Korea (국내 배터리원료광종 공급망 업스트림 리스크와 광물자원탐사부문에서의 대응방안)

  • Oh, Il-Hwan;Heo, Chul-Ho;Kim, Seong-Yong
    • Economic and Environmental Geology
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    • v.55 no.4
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    • pp.399-406
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    • 2022
  • In line with the megatrend of 2050 carbon neutrality, the amount of critical minerals used in clean-energy technology is expected to increase fourfold and sixfold, respectively, according to the Paris Agreement-based scenario as well as the 2050 carbon-neutrality scenario. And, in the case of Korea, in terms of the battery supply chain used for secondary batteries, the midstream that manufactures battery materials and battery cell packs shows strength, but the upstream that provides and processes raw materials is experiencing difficulties. The Korea Institute of Geoscience and Mineral Resources has established a strategy to secure lithium, nickel, and cobalt and is conducting surveys to respond to the upstream risk of these types of battery raw materials. In the case of lithium, exploration has been carried out in Uljin, Gyeongsangbuk-do since 2020, and by the end of 2021, the survey area was selected for precision exploration by synthesizing all exploration data and building a 3D model. Potential resources will be assessed in 2022. In the case of nickel, the prospective site will be selected by the end of 2022 through a preliminary survey targeting 10 nickel sulfide deposits that have been prospected in the past. In the case of cobalt, Boguk cobalt is known only in South Korea, but there is only a record that cobalt was produced as a minor constituent of hydrothermal deposit. According to the literature, a cobalt ore body was found in the contact area between serpentinite and granite, and a protocol for cobalt exploration in Korea will be established.

Analysis of the Effect of Alternating Current Ripple on Electrical State of Health Degradation of 21700 Lithium-ion Battery (교류 리플이 21700 리튬 이온 배터리의 전기적 건강 상태 열화에 미치는 영향 분석)

  • Bongwoo Kwak
    • Journal of IKEEE
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    • v.27 no.4
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    • pp.477-485
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    • 2023
  • In this paper, the effect of AC ripple on the lifetime of lithium-ion batteries is experimentally analyzed. Bidirectional power conversion system(PCS) is used to increase the efficiency of energy storage systems (ESS). When connected to the grid, a current ripple with a frequency twice the grid frequency is applied to the battery due to its structure. Therefore, to analyze the effect of AC ripple on Li-ion battery aging, cycle life test are performed by applying charge/discharge profiles of DC current and DC+AC current ripple specifications. Based on the experimental results, direct current internal resistance (DCIR), incremental capacitance (IC), and surface temperature were analyzed. As a result, it is confirmed that AC ripple does not directly affect degradation and that battery degradation slows down after a certain cycle. These results can serve as a guideline for optimizing filters to reduce ripple on the battery side in applications where AC ripple occurs.

Leaching of Smelting Reduced Metallic Alloy of Spent Lithium Ion Batteries by the Mixture of Hydrochloric Acid and H2O2 (과산화수소를 혼합한 염산용액으로 폐리튬이온배터리의 용융환원된 금속합금의 침출)

  • Moon, Hyun Seung;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.30 no.5
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    • pp.25-31
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    • 2021
  • Smelting reduction of spent lithium-ion batteries results in the production of metallic alloys in which reduced cobalt, nickel and copper coexist. In this study, we investigated the leaching of the metallic alloys containing the above three metals together with iron, manganese, and silicon. The mixture of hydrochloric acid and hydrogen peroxide as an oxidizing agent was employed, and the effect of the concentration thereof, the reaction time and temperature, and pulp density was investigated to accomplish the complete leaching of cobalt, nickel, and copper. The effect of the hydrogen peroxide concentration and pulp density on the leaching was prominent, compared to that of reaction time and temperature, especially in the range of 20 to 80℃. The complete leaching of the metals present in metallic alloys, except silicon, was accomplished using 2 M HCl and 5% H2O2 with a pulp density of 30 g/L for 150 min at 60℃.

An Analysis for 18650 Li-Ion Cell Electrical Characteristics of Vibration and Shock Test (18650 리튬이온 셀의 진동 및 충격 시험 기반 전기적 특성 분석)

  • Yoon, Chang-O;Kim, Jong-Hoon;Jang, Min-ho
    • Proceedings of the KIPE Conference
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    • 2016.07a
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    • pp.313-314
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    • 2016
  • 본 논문에서는 리튬이온(Li-Ion) 배터리 셀(Cell)의 Shock test와 Vibration test 기반 18650 원통형 셀 내부 전기적 특성 변화를 분석하였다. 전류적산법을 기반으로 방전 용량을 측정하였고, OCV(Open Circuit Voltage) 측정 및 HPPC(Hybrid Pulse Power Characterization) test를 기반으로 내부 저항을 측정하고 진동 및 충격 시험 전 후의 파라미터를 비교 분석하였다.

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Extractive Metallurgy of Lithium (리튬의 제련기술)

  • Sohn, Ho-Sang
    • Resources Recycling
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    • v.31 no.3
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    • pp.3-15
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    • 2022
  • Lithium is the lightest metal and the first metal in the periodic table. Lithium is used in a variety of applications, including the production of organolithium compounds, as an alloying addition to aluminum and magnesium, and as the anode in rechargeable lithium ion batteries especially for electronic devices and electric vehicles. Therefore, lithium is indispensable metal in our daily lives. The use of lithium continues to rise and has increased from about 14,000 tonnes per year worldwide in the 2000 to about 82,200 tonnes in the 2000. However, lithium is a representative rare metal and ranks 32nd among the abundant elements in the earth's crust. This study reviews the current status of the lithium extraction processes as well as the trend in production amount and use. Lithium is extracted by a various methods depending on the type of resources. These extraction methods are essential for the development of new recycling processes that can extract lithium from secondary lithium resources.

Research for Recharging Braking Power Circuit of Electric Regenerative Auxiliary Brake for Hybrid Commercial Vehicles (하이브리드 상용차용 전기식 회생 보조 브레이크의 전력회수회로에 대한 연구)

  • Kim, Yoon-jae;Yoo, Chang-hee;Kwon, Sun-man;Lee, Jun-young
    • Proceedings of the KIPE Conference
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    • 2016.07a
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    • pp.191-192
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    • 2016
  • 본 논문은 전기식 회생 보조 브레이크의 넓은 범위의 입력전압을 가진 전기에너지를 받아서 넓은 범위의 출력전압을 가진 리튬이온 배터리에 충전할 수 있도록 Buck-boost 토폴로지를 제안하고, 배터리와의 절연을 위해 출력 효율이 좋은 LLC 토폴로지를 제안한다. 제안된 2단 구성 회로의 유효성은 실험을 통해 검증되었다.

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