• Title/Summary/Keyword: 로랑분해

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Optimization for Maillard Reaction Substrate Conditions of Ribose and Hydrolyzed Wheat Gluten Solution Using Response Surface Methodology (반응표면분석법을 이용한 Ribose와 소맥 글루텐 산 가수분해물의 마이얄 반응기질 조건 최적화)

  • Moon, Ji-Hye;Choi, Hee-Don;Choi, In-Wook;Kim, Yoon-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.3
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    • pp.458-465
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    • 2011
  • Response surface methodology (RSM) was applied to optimize substrate conditions of ribose and hydrolyzed wheat gluten solution for Maillard reaction. Independent variables were NaCl concentration of hydrolyzed wheat gluten ($X_1$), concentration of ribose ($X_2$) and concentration of hydrolyzed wheat gluten ($X_3$), while the dependent variables of the central composite design (CCD) were browning index (absorbance 420 nm), DPPH radical scavenging activity (DF) and sensory preference (score). Optimum substrate conditions at $140^{\circ}C$, 30 min reaction were 3% NaCl concentration of hydrolyzed wheat gluten, 6.2% concentration of ribose and 13.27% concentration of hydrolyzed wheat gluten. The coefficients of determination ($R^2$) were 0.975, 0.960 and 0.854, the model fit was very significant (p<0.001). DPPH radical scavenging activities and sensory preferences were predicted as 700 (DF) and 8.42 (score), respectively. The model solution increased more browning and DPPH radical scavenging activities with increasing ribose and hydrolyzed wheat gluten concentration. Especially hydrolyzed wheat gluten concentration was the most influential factor, while NaCl concentration of hydrolyzed wheat gluten hardly affected the responses. Sensory preference was increased with rising wheat gluten concentration and decreasing NaCl concentration of hydrolyzed wheat gluten.

Destruction of Spent Organic ion Exchange Resins by Ag(II)-Mediated Electrochemical Oxidation (Ag(II)매개산화에 의한 폐 유기이온교환수지의 분해)

  • Choi Wang-Kyu;Nam Hyeog;Park Sang-Yoon;Lee Kune-Woo;Oh Won-Zin
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.183-189
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    • 1999
  • A study on the destruction of organic cation and anion exchange resins by electro-generated Ag(II) as a mediator was carried out to develop the ambient-temperature aqueous process, known as Ag(II)-mediated electro-chemical oxidation (MEO) process, for the treatment of a large quantity of spent organic ion exchange resins as the low and Intermediated-level radioactive wastes arising from the operation, maintenance and repairs of nuclear facilities. The effects of controllable process parameters such as applied current density, temperature, and nitric acid concentration on the MEO of organic ion exchange resins were investigated. The cation exchange resin was completely decomposed to $CO_2$. The current efficiency increased with a decrease in applied current density while nitric acid concentration and temperature on the MEO of cation exchange resin did not affect the MEO. On the other hand, anion exchange resins were decomposed to CO and $CO_2$. The ultimate conversion to CO was about $10\%$ regardless of temperature. The destruction efficiencies to $CO_2$ were dependent upon temperature and the effective destruction of anion exchange resin could be obtained above $60^{\circ}C$.

Current Status on Gold Smelting Technology (금제련(金製鍊) 기술(技術)의 현황(現況))

  • Kim, Byung-Su;Kim, Chi-Kwon;Sohn, Jeong-Soo
    • Resources Recycling
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    • v.16 no.3 s.77
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    • pp.3-11
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    • 2007
  • Presently, most of gold is smelted from gold concentrates and anode slimes. Anode slimes are by-products of nonferrous smelters such as lead and copper. In addition, gold is recovered from waste dental and medical materials, waste gold coating solution, and waste printed circuit boards (waste PCBs). The smelting method of gold from gold concentrates and various wastes containing high concentration of gold is largely divided into chlorination, cyanidation, and amalgamation methods. For the anode slimes, electrolysis method is usually used, which largely consists of roasting, high temperature melting and electrolysis processes. Also, various wastes containing low concentration of gold are mainly treated by pyrometallursical processes. In the paper, current status on gold smelting technology is reviewed, and a novel process for gold smelting which is researched in the recent is briefly introduced.

Sonolysis of Trichloroethylene in a Continuous Flow Reactor with the Multi Ultrasound Irradiation (연속식 다중 초음파 반응조에서 TCE의 초음파 분해)

  • Lee, Min-Ju;Oh, Je-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.6
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    • pp.419-427
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    • 2009
  • To test applicability for continuous flow treatment of ultrasound technology, sonolysis of TCE aqueous solution using 584 kHz multi irradiation reactor was performed under batch and continuous flow conditions. Under batch condition (3 and 4 sides irradiation, 600 W), first order degradation rate constant of TCE was higher under 4 sides than 3 sides irradiation conditions, while the generation of $H_2O_2$ and chloride was similar under both irradiation conditions. Under continuous flow condition with 4 sides irradiation, removal efficiencies of TCE in steady-state were decreased from 83 to 48% with increasing flow rate from 67 to 300 mL/min at 600 W, and were increased from 14 to 75% with increasing acoustic power from 100 to 600 W at 100 mL/min. Removal efficiency of TCE in groundwater was decreased 10% compared to in distilled water at 100 mL/min and 600 W.

Enantioconvergent Hydrolysis of Racemic Epoxides for Production of Enantiopure Epoxides and Vicinal Diols using Epoxide Hydrolases (에폭사이드 가수분해효소에 의한 광학수렴반응을 이용한 광학활성 에폭사이드 및 Vicinal Diol 제조)

  • Lee, Eun-Yeol
    • KSBB Journal
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    • v.22 no.3
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    • pp.123-128
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    • 2007
  • One drawback of conventional kinetic resolution of racemic epoxides by epoxide hydrolase (EH) is that the theoretical yield can never exceed 50%. This 50% limitation can be overcome by using enantioconvergent process, in which both enantiomers of the racemic epoxide are transformed via stereochemically matching pathways into a single enantiopure diol as the sole product in 100% theoretical yield. In order to make a single enantiopure vicinal diol, the two enantiomers of the racemic epoxide must be hydrolyzed with retention and inversion of configuration each other. The EHs should be enantio- and regiospecific at the same time. The enantioconvergent hydrolysis with EHs and relevant biotransformation for preparing enantiopure epoxides and vicinal diols with a high yield are reviewed.

Solubilization of Tofu-Residue Using Multienzyme Derived from Aspergillus niger CF-34 (Aspergillus niger CF-34 효소를 이용한 두부 또는 두유비지의 가용화)

  • Kim, Kang-Sung;Park, Eun-Ha;Choi, Yeon-Bae;Kim, Kyo-Chang;Lee, Sang-Hwa;Sohn, Heon-Soo
    • Korean Journal of Food Science and Technology
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    • v.26 no.5
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    • pp.484-489
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    • 1994
  • Solubilization of plant ceil wall(tofu-residue) using enzyme complex obtained by Aspergillus niger CF-34 was attempted. The hydrolysis reaction was done at pH 4.0, $50^{\circ}C$, which were optimum pH and temperature of the enzyme, respectively. At the enzyme dosage of 2.5% (in terms of solid content of tofu-residue) and reaction time of 3 hr, the solubilizing percent of protein and carbohydrate were 62% and 50% respectively. Homogenization prior to enzyme reaction did not have much effect on tofu-residue solubilization. To improve solubility of tofu-residue, additional treatment such as alkali with 0.1% NaOH solution was found to be useful. The results showed that tofu-residue, which mainly consists of cell wall component of cellulose and hemicellulose, was not accessible to enzyme reaction and some prior treatment is required to enhance enzyme hydrolysis.

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CAH degradation characteristics under mixed conditions (혼합조건에서의 CAH 화합물 분해 특성에 관한 연구)

  • 김종호;배우근;심호재;신언빈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.214-217
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    • 2001
  • 자연계에서는 오염물질이 단일물질로 존재하기보다는 혼합물로 존재하는 것이 대부분이다. 본 연구에서는 지하수 오염물질 chlorinated aliphatic hydrocarbon(CAH)들 중 trichloroethylene(TCE), vinyl chloride(VC)에 대해서 Fe$^{\circ}$와 함께 미생물, 활성탄을 이용하여 단일물질 및 혼합물질상태에서 그 분해특성을 살펴보았다. 실험은 120$m\ell$ serum bottle을 이용하여 단일물질 및 혼합물질상태에서 그 분해특성을 살펴보았다. 실험은 120$m\ell$ serum bottle을 이용하였고 headspace 50${\mu}\ell$를 GC에 주입하여 각 오염물질 농도를 분석하였으며, Fe$^{\circ}$, Fe$^{\circ}$+ cell, Fe$^{\circ}$+ 활성탄 3가지 조건에서 TCE (25${\mu}\ell$)가 단일화합물 또는 VC(10$\mu\textrm{m}$)와 혼합화학물로 존재시 분해특성을 조사하였다. 단일화합물로 존재시 2시간후 TCE농도 측정 결과 Fe$^{\circ}$만을 이용하였을 때보다 활성탄, Cell을 함께 이용하였을 경우 그 분해율이 각각 1.6배, 1.8배 높게 나타났다. 그러나, VC와 혼화합물로 존재시 TCE 분해율은 단일 화합물로 존재시와 비교 Fe$^{\circ}$, Fe$^{\circ}$+ 활성탄, Fe$^{\circ}$+ cell 조건에서 각각 63%, 28%, 5%로 나타났다. VC는 Fe$^{\circ}$만으로는 분해가 되지 않았지만 cell에 의해 완전분해 되었으며, 함께 존재시 TC는 Fe$^{\circ}$만으로는 분해가 되지 않았지만 cell에 의해 완전분해 되었으며, 함께 존재시 TCE분해에 저해작용을 미치는 것으로 나타났다.

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Korean Compound Nouns Decomposition Suitable for Embedded Systems (임베디드 시스템에 적합한 한국어 복합명사 분해)

  • Choi, Min-Seok;Kim, Chang-Hyun;Cheon, Min-Ah;Park, Ho-Min;Namgoong, Young;Yoon, Ho;Kim, Jae-Hoon
    • Annual Conference on Human and Language Technology
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    • 2018.10a
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    • pp.316-320
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    • 2018
  • 복합명사는 둘 이상의 말이 결합된 명사를 말하며 문장에서 하나의 단어로 간주된다, 그러나 맞춤법 및 띄어쓰기 검사나 정보검색의 색인어 추출, 기계번역의 미등록어 추정 등의 분야에서는 복합명사를 구성하는 개별 단어를 확인할 필요가 있다. 이 과정을 복합명사 분해라고 한다. 복합명사를 분해하는 방법으로 크게 규칙 기반 방법, 통계 기반 방법 등이 있으며 본 논문에서는 규칙을 기반으로 최소한의 통계 정보를 이용하는 방법을 제안한다. 본 논문은 4개의 분해 규칙을 적용하여 분해 후보를 생성하고 분해 후보들 중에 우선순위를 정하여 최적 후보를 선택하는 방법을 제안한다. 기본 단어(명사)로 트라이(trie)를 구축하고 구축된 트라이를 이용하여 양방향 최장일치를 적용하고 음절 쌍의 통계정보를 이용해서 모호성을 제거한다. 성능을 평가하기 위해 70,000여 개의 명사 사전과 음절 쌍 통계정보를 구축하였고, 이를 바탕으로 복합명사를 분해하였으며, 분해 정확도는 단어 구성비를 반영하면 96.63%이다. 제안된 복합명사 분해 방법은 최소한의 데이터를 이용하여 복합명사 분해를 수행하였으며 트라이 자료구조를 사용해서 사전의 크기를 줄이고 사전의 검색 속도를 개선하였다. 그 결과로 임베디드 시스템과 같은 소형 기기의 환경에 적합한 복합명사 분해 시스템을 구현할 수 있었다.

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The Product properties of Bituminous Coal in Two-Stage Pyrolysis (유연탄의 이단 열분해에 따른 생성물의 특성)

  • 송광섭;이상남;윤형기;김상돈
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.208-214
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    • 1993
  • Pyrolysis of bituminous coal has been carried out in a two-stage fixed bed reactor to produce high heating value gas(7000 kcal/N㎥) for industrial or town gas usage. The effects of coke catalyst, pyrolysis temperature (468∼565$^{\circ}C$), and catalytic cracking temperature (700∼850$^{\circ}C$) on the product gas properties from pyrolysis of bituminous coal have been determined. From pyrolysis of Dong Jin coal with coke, the carbon deposition on catalyst is found to be less than 5% of product tar and approximately 15% of total energy iii the parent coal can be recovered as high heating value gas. Oil composition in the product tar from the two-stage pyrolysis is higher than that from low-temperature pyrolysis. The tar produced from pyrolysis below 516$^{\circ}C$ can be easily catalytically cracked but, the tar produced above 565$^{\circ}C$ cannot be cracked easily with catalyst. From the product gas analysis, the catalytic cracking temperature should be maintained below 800$^{\circ}C$ since cracking speed of ethylene increases remarkably with the cracking temperature above 800$^{\circ}C$.

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Degradation Characteristics of Ligninsulfonate by Laccase and Mn-peroxidase (Laccase와 Mn-peroxidase에 의한 Ligninsulfonate의 분해 특성)

  • Bae, Hyeun-Jong;Kim, Yoon-Soo;Mun, Sung-Phil
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.4
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    • pp.27-32
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    • 1995
  • To understand whether ligninolytic enzyme catalyze polymerization or depolymerization of the high molecular weight (HMW) lignin, the action of laccase and Mn-peroxidase (MnP) towards commercial ligninsulfonates (LS) was examined in various conditions of pH and cosubstrates. Polymerization occurred when LS was incubated with laccase at pH 6.0. In contrast, the high molecular weight portions were significant1y reduced at pH 4.5, especially when glucose was added. When LS was treated with MnP at pH 4.5, compounds of low molecular weight were produced. In particular, when cellobiose was added to Mn-P reaction mixture, the breakdown of LS was observed. In conclusion, degradation of LS by laccase and MnP occurred primarily at pH 4.5 where-as polymerization of LS was dominant at pH 6.0. Color index, however, was not greatly changed in the degradation mixtures of LS.

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