• Title/Summary/Keyword: 레이저 산란

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Changes of the Flame Temperature and OH Radical in the Unsteady Extinction Process (비정상 소화 과정에서의 화염 온도 및 OH 라디칼의 변화)

  • Lee, Uen-Do;Lee, Ki-Ho;Oh, Kwang-Chul;Shin, Hyun-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1557-1566
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    • 2004
  • A flame extinction phenomenon is a typical unsteady process in combustion. Flame extinction is characterized by various physical phenomena, such as convection, diffusion, and the production of heat and mass. Flame extinction can be achieved by either increasing the strain rate or curvature, by diluting an inert gas or inhibitor, or by increasing the thermal or radiant energy loss. Though the extinction is an inherently transient process, steady and quasi-steady approaches have been used as useful tools for understanding the flame extinction phenomenon. Recently, unsteady characteristics of flames have been studied by many researchers, and various attempts have been made to understand unsteady flame behavior, by using various extinction processes. Representative parameters for describing flame, such as flame temperature, important species related to reactions, and chemi-luminescence of the flame have been used as criterions of flame extinction. In these works, verification of each parameter and establishing the proper criterions of the extinction has been very important. In this study, a time-dependent flame temperature and an OH radical concentration were measured using optical methods, and the instantaneous change of the flame luminosity was also measured using a high-speed ICCD (HICCD) camera. We compare the unsteady extinction points obtained by three different methods, and we discuss transient characteristics of maximum flame temperature and OH radical distribution near the extinction limit.

Am Experimental Study on Measurement of Number Density and Temperature Distributions in $C_3H_8/O_2$ Flame by UV Laser Rayleigh Scattering (UV Laser Rayleigh Scattering을 이용한 $C_3H_8/O_2$ 화염에서 가스 성분의 농도 및 온도 분포 계측에 관한 실험적 연구)

  • Jin, S. H;Nam, G. J.;Kim, H. S.;Chang, N. K.;Park, S. H.;Kim, U.;Park, K. S.;Kim, G. S.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.2
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    • pp.60-68
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    • 1997
  • Rayleigh Scattering Cross Sections($\sigma$i) of various gases and the temperature distributions of premixes C3H8/O2 flame are measured by high power KrF(248nm) Exci- mer laser and ICCD camera. Results show that $\sigma$i of O2 and Propane(C3H8) gases agree well in the 5% error range, but of H2 has the more or less difference from the calcul- ated value by other groups. This is attributed to the low RS signal of H2 to Nosie level(S/N ratio). The temperature distributions of flame range out between 300K in the air and about 2000K in the burned area. In this temperature range, out system has the about 250K temperature resolution. Because low RS signals in the reaction area with high temperature are affected highly by noises, temperature uncertainty of this area is relatively high to another part of flame. Experimental results show that UV Rayleigh Scattering can be used for the measurement of mixing ratio of mixed gases and the temperature distributions of flame. Especially, this technique can be applied for the measurement of the mixing ratio of air/fuel before the ignition and the flame structure after the ignition inside the Engine.

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Flocculation Characteristics of the Polycondensate of 1-Butylamine and Epichlorohydrin(PBE) (1-부틸아민과 에피클로로히드린의 축합체인 PBE의 응집작용 특성)

  • Kim, Hag-Seong;Joo, Duk-Jong
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.569-573
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    • 1998
  • A water soluble polymer, polycondensate of 1-butylamine and epichlorohydrin (PBE), was synthesized by condensation of 1-butylamine and epichlorohydrin. The characteristics of PBE were determined by IR spectroscopy, low angle light scattering measurement, and $\zeta$ potential measurement. Its interactions with colloidal bentonite particles in aqueous medium were also studied. The results of the studies are as follows : PBE is a cationic polyelectrolyte carrying tertiary ammonium ions on its backbone. The average molecular weight of PBE is found to be about 1,600. The adsorption of PBE on the colloidal bentonite particles are well described with Langmuir adsorption isotherm. As the amounts of PBE adsorbed on the bentonite particles increase, the $\zeta$ potential of the particles changes its sign from negative to positive. This inversion of charge confirms that PBE is cationic in nature. The adsorption of PBE onto the bentonite particles was found to occur through cation exchange reaction. It has been shown that PBE has flocculation effects on the colloidal suspension of bentonite. It has also enhanced effects of filtrability on the digested sludge.

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The Spray Characteristics of Swirl and Slit Injector to DISI Engine Using LIEF and Mie-scattering Method (LIEE와 Mie 산란 방법을 이용한 직분식 가솔린 엔진의 스월 및 슬릿 인젝터의 분무 특성)

  • Lee Kihyung;Hwang Kyumin;Lee Changhee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.3 s.234
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    • pp.356-367
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    • 2005
  • The spray characteristics of DISI injector have a great role in gasoline engine efficiency and emission. Thus, many researchers have studied to investigate the spray characteristics of swirl and slit injectors that are used in a DISI engine. In this study, we tried to provide spray parameters, which affect on the spray characteristics such as injection pressure, ambient pressure and ambient temperature. In addition, we calculated $t_{b}\;and\;t_{c}$ to investigate the break up mechanism of test injectors and obtained $C_{v}$ to evaluate the spray characteristics. As the ambient pressure increases in case of slit injector, $C_{v}$ decreases. The laser-induced exciplex fluorescence (LIEF) technique, which is based on spectrally resolved two-color fluorescent emissions, has applied to measure the liquid and vapor phases for on evaporating spray simultaneously. The TMPD/naphthalene proposed by Melton is used as a dophant to detect exciplex signal. The temporal and spatial distribution of liquid and vapor phases during the mixture formation process was measured by this technique. In the LIEF technique, the vapor phase is detected by the monomer fluorescence while the liquid phase is tracked by the exciplex fluorescence. From this experiment, we found that the spray area of the vapor phase is increased with elapsed time after injection and the area of liquid is decreased when the ambient pressure is 0.1MPa. However, the area tends to increase until the end of injection when the ambient pressure is 1.0MPa.

적층형 박막 실리콘 태양전지 효율의 한계 및 돌파구

  • Myeong, Seung-Yeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.27-27
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    • 2010
  • 최근에 고유가와 지구온난화로 인하여 에너지가 향후 인류의 50년을 좌우할 가장 큰 문제로 대두되고 있어서 지구의 모든 에너지의 근원인 태양광을 이용하는 태양광 발전은 무한한 청정 에너지로 각광받고 있다. 빛을 흡수하여 전기에너지로 변환하는 태양전지는 풍력, 수소연료전지, 조력, 바이오에탄올 등의 신재생에너지 기술 중에서 상품성은 가장 뛰어나지만 발전단가가 가장 높은 것이 단점이다. 태양광 발전단가를 줄여서 기존의 화석에너지를 이용한 발전단가와 견줄 수 있는 그리드 패러티(grid parity)를 달성하려면 태양전지 모듈의 고효율화와 동시에 저가화가 반드시 이루어져야 한다. 현재 태양광 모듈 시장의 90%는 효율이 12-16% 정도로 높은 단결정(single crystalline or monocrystalline) 실리콘이나 다결정(polycrystalline or multicrystalline) 실리콘 등의 벌크(bulk)형 결정질 실리콘 모듈이 차지하고 있으나 원재료인 실리콘 웨이퍼의 제조단가의 50%를 차지하고 있어서 저가화가 어렵다. 반면, 원료가스를 분해하여 대면적 기판에 증착하는 박막(thin-film) 실리콘 태양전지의 경우는 차세대 태양전지로 각광받고 있다. 박막 실리콘 모듈은 매우 적은 실리콘 원재료를 소비한다. 단결정이나 다결정 실리콘 웨이퍼의 두께가 $180-250\;{\mu}m$ 정도인 것에 비해서 박막 실리콘의 두께는 $0.3-3\;{\mu}m$ 수준이다. 더불어, 유리, 플라스틱 등의 저가 기판에 저온 대면적 증착이 가능하여 저가양산화에 유리하다. 박막 실리콘 모듈은 벌크형 실리콘 모듈(-0.5%/K) 대비 낮은 온도계수[비정질 실리콘(amorphous silicon; a-Si:H)의 경우 -0.2%/K]와 빛의 세기가 약한 산란광에서도 동작하여 평균발전시간이 증가하므로 외부환경에서 우수한 발전성능을 보이고 있다. 태양전지 모듈은 상온에서의 안정화 효율을 기준으로 가격이 책정되어($/$W_p$) 판매되기 때문에 벌크형 실리콘 모듈에 비해서 박막 실리콘 모듈은 가격대 성능비가 우수하다. 따라서 박막 실리콘 모듈은 벌크형 결정 실리콘 모듈의 대안으로 떠오르고 있으며, 레이저 기술을 이용하여 수려한 투광형 건물일체형(building integrated photovoltaic; BIPV) 모듈을 제작할 수 있는 장점도 있다. 이러한 장점에도 불구하고 기존의 양산화된 단일접합 비정질 실리콘 태양광 모듈은 효율이 6-7%로 낮아서 설치면적 및 설치 모듈의 증가가 성장의 걸림돌이 되고 있다. 박막 실리콘 태양전지의 고효율화를 도모하기 위해서 적층형 탄뎀셀로 양산 트렌드가 변화하고 있다. 이에 적층형 박막 실리콘 태양전지 효율의 한계 및 돌파구에 대해서 논의한다.

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The Status and prospect of Pohang Synchrotron Light Source at PAL on its 25th Anniversary

  • Jo, Mu-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.61.2-61.2
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    • 2013
  • 우리나라 최초의 거대과학 장치인 포항방사광가속기(PLS)는 지난 16년(1994~2010) 동안 국내외 이용자에게 제3세대 방사광을 제공했다. 최초 2기의 빔라인을 시작으로 꾸준하게 빔라인 증설과 성능개선을 위해 노력해 왔다. 지속해서 늘어나는 방사광 이용자 수와 더욱더 좋은 수준의 방사광 요구에 부응하기 위하여 2009년부터 3년 동안 가속장치의 성능향상사업(PLS-II)을 마쳤다. PLS-II는 PLS 대비에너지와 빔전류는 3 GeV, 400 mA로 늘리는 반면 빔의 크기는 크게 줄이고 빔안정성을 개선한 고품질 X-선 방사광 발생장치이다. 2012년부터 16기의 삽입장치 빔라인을 포함한 30기의 빔라인을 가동하여 이용자 지원을 하고 있으며 초전도케비티 설치를 포함한 목표 성능의 확보에도 많은 노력을 기울이고 있다. 현재는 6 nm-rad의 빔에 미턴스, 3-GeV전자빔, 약 0.5 ${\mu}m-rms$ 빔안정도를 가진 200 mA Top-up 운전으로 빔을 제공 하고 있으며 2014년 말에는 저장전류 400 mA급의 PLS-II 목표치로 운전할 계획이다. 본 발표에서는 포항가속기의 25년 역사를 돌아보고 가속장치의 건설에 얽힌 이야기, 중요장치 그리고 운전과 빔제공에 관한 내용, 특히 핵심 운전가치인 빔안정성을 개선하고 유지하기 위한 노력을 빔운전 측면과 진공을 포함한 엔지지어링 측면에서 언급하고자 한다. PLS 건설부터 현재 운용 중인 30기의 빔라인에서 수행된 연구 성과의 통계에 대하여 훑어보고 X-선 산란과 광전자분광을 이용한 구조, 성분 및 물성분석, 그리고 이미징 등의 분야에서 나온 탁월한 연구 결과를 살펴본다. 앞으로 건설될 신규 빔라인과 빔라인의 향후 운영 방향을 소개한다. 마지막으로 지금 포항가속기연구소에서 건설 중인 제4세대 가속기(X-선 자유전자레이저) 프로젝트의 개요 및 건설 현황과 함께 앞으로 기대되는 새로운 과학에 대하여도 소개하고자 한다.

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Rapid bacterial identification using Raman spectroscopy (라만 분광법을 활용한 세균 검측 기술)

  • No, Jee Hyun;Lee, Tae Kwon
    • Korean Journal of Microbiology
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    • v.53 no.2
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    • pp.71-78
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    • 2017
  • Raman microspectroscopy is a promising tool for microbial analysis at single cell level since it can rapidly measure the cell materials including lipids, nucleic acids, and proteins by measuring the inelastic scattering of a molecule irradiated by monochromatic lights. Using Raman spectra provides high specificity and sensitivity in classification of bacteria at the strain level. In addition, a Raman approach coupled with stabled isotope such as $^{13}C$ and $^2H$ is able to detect and quantify general metabolic activity at single cell level. After bacterial detection process by Raman microspectroscopy, interested unculturable cell sorting and single cell genomics can be accomplished by combination with optical tweezer and microfluidic devices. In this review, the characteristics and applications of Raman microspectroscopy were reviewed and summarized in order to provide a better understanding of microbial analysis using Raman spectroscopy.

Design of a customizable fluorescence detection system for fluorescently labeled tumor cells (형광 발현 암세포 탐지를 위한 맞춤형 검출시스템 개발)

  • Cho, Kyoungrae;Seo, Jeong-hyeok;Choe, Se-woon
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.23 no.3
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    • pp.261-266
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    • 2019
  • Flow cytometry is an electrical detection system that provides precise and diverse optical properties to cells and micro particles. Flow cytometry, which provides multidimensional information including cell size and granularity through light scattering and fluorescence emission generated by the induction of light of a specific wavelength to the fluorescently treated cells or micro particles, plays an important role in biomedical and biophysical fields. However, it has some drawbacks such as high cost, size of the instrument and limitation in selecting fluorescent dyes. Therefore, in this paper, a low cost compact fluorescent detection system is developed using light-emitting diode and microcontroller. The proposed fluorescence detection system has a replaceable the light source/fluorescence filter/photodetector and constructed by 3D printer, so that the user can design a customized system according to the selected fluorescent dyes. The fluorescence intensity was measured by varying the number of fluorescently labeled cells, and the measured intensities showed a high linearity within the tested concentration ranges.

In-situ Deposition Rate Measurement System to Improve the Accuracy of the Film Formation Process (성막 공정 정밀도 향상을 위한 실시간 성막 속도 측정 시스템)

  • Somi Park;Seung-Yo Baek;Hyun-Bin Kim;Jonghee Lee;Jae-Hyun Lee
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.383-387
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    • 2023
  • The quartz crystal microbalance (QCM), commonly used in high vacuum deposition, becomes difficult to use when a thick film is deposited on the quartz, affecting the crystal's inherent vibration. In this study, a non-destructive optical measurement method was developed to measure the film's deposition rate during the in-situ film deposition process. By measuring the scattered laser intensity caused by the dimer in the parylene gas passing through the gas flow path, it was successfully confirmed that the ratio of the dimer in the parylene gas increases as the pyrolysis temperature decreases. Additionally, it was noted that the film's thickness and haze increase as the pyrolysis temperature decreases by confirming the characteristics of the visible parylene films. Through the research results, we aim to utilize the stable in-situ film deposition rate measurement system to control the precise film deposition rate of parylene films.

A Study on the Security of Infrastructure using fiber Optic Scattering Sensors (광섬유 산란형 센서를 이용한 사회기반시설물의 보안에 관한 연구)

  • Kwon, Il-Bum;Yoon, Dong-Jin;Lee, Seung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.24 no.5
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    • pp.499-507
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    • 2004
  • We have studied tile detection techniques, which can determine the location and the weight of an intruder into infrastructure, by using fiber-optic ROTDR (Rayleigh optical time domain reflectometry) sensor and fiber-optic BOTDA (Brillouin Optical time domain analysis) sensor, which can use an optical fiber longer than that of ROTDR sensor Fiber-optic sensing plates of ROTDR sensor, which arc buried in sand, were prepared to respond the intruder effects. The signal of ROTDR was analyzed to confirm the detection performance. The constructed ROTDR could be used up to 10km at the pulse width of 30ns. The location error was less than 2 m and the weight could be detected as 4 grades, such as 20kgf, 40kgf, 60kgf and 80kgf. Also, fiber optic BOTDA sensor was developed to be able to detect intrusion effect through an optical fiber of tells of kilometers longer than ROTDR sensor. fiber-optic BOTDA sensor was constructed with 1 laser diode and 2 electro-optic modulators. The intrusion detection experiment was peformed by the strain inducing set-up installed on an optical table to simulate all intrusion effect. In the result of this experiment, the intrusion effort was well detected as the distance resolution of 3m through the fiber length of about 4.81km during 1.5 seconds.