• Title/Summary/Keyword: 라만분석

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Asymmetry of the 1.54${\mu}m$ forward and backward raman gain in methane (라만매질 $CH_4$의 전후방 1.54${\mu}m$ 유도라만 산란광의 비대칭적 발생)

  • 최영수;고해석;강응철
    • Korean Journal of Optics and Photonics
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    • v.10 no.2
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    • pp.89-94
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    • 1999
  • The 1.54 ${\mu}{\textrm}{m}$ forward and backward stimulated Raman scattering (SRS) have been studied in CH$_4$pumped by 1.06 ${\mu}{\textrm}{m}$ Nd:YAG laser. The forward and backward SRS output energy in a single pass were measured at dufferent CH$_4$pressures. Under steady state conditions, the pump input threshold energies and Raman gains in forward and backward directions were for Raman conversion at various CH$_4$pressures for a tight focusing geometry. The forward and backward slope efficiency for Raman conversion were 18% and 34% respectively. The pump input threshold energy of the backward SRS was lower than that of the forward. In backward SRS, the experimental input laser threshold and Raman gain values were in good agreement with the calculated values at different pressures of CH$_4$. The retio of the backward to the forward SRS gain was appoximately 1.4 times above 1200 psi. We obtained that the backward Raman gain coefficient was 0.32 cm/GW, and the forward Raman gain coefficient 0.23cm/GW at 1400 psi. Asymmetry of the forward and backward Raman gain is caused by the interaction between different pump intensities of each direction duting the amplification of the Stokers. The backward Raman gain is proportional to the average pump intensity. However, the forward SRS output grows by depleting the local pump intensity.

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Rapid bacterial identification using Raman spectroscopy (라만 분광법을 활용한 세균 검측 기술)

  • No, Jee Hyun;Lee, Tae Kwon
    • Korean Journal of Microbiology
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    • v.53 no.2
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    • pp.71-78
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    • 2017
  • Raman microspectroscopy is a promising tool for microbial analysis at single cell level since it can rapidly measure the cell materials including lipids, nucleic acids, and proteins by measuring the inelastic scattering of a molecule irradiated by monochromatic lights. Using Raman spectra provides high specificity and sensitivity in classification of bacteria at the strain level. In addition, a Raman approach coupled with stabled isotope such as $^{13}C$ and $^2H$ is able to detect and quantify general metabolic activity at single cell level. After bacterial detection process by Raman microspectroscopy, interested unculturable cell sorting and single cell genomics can be accomplished by combination with optical tweezer and microfluidic devices. In this review, the characteristics and applications of Raman microspectroscopy were reviewed and summarized in order to provide a better understanding of microbial analysis using Raman spectroscopy.

Ex Vivo Raman Spectroscopy Measurement of a Mouse Model of Alzheimer's Disease (라만 기반 치매 모델의 뇌조직 분광 특성 측정)

  • Ko, Kwanhwi;Seo, Younghee;Im, Seongmin;Lee, Hongki;Park, Ji Young;Chang, Won Seok;Kim, Donghyun
    • Korean Journal of Optics and Photonics
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    • v.33 no.6
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    • pp.331-337
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    • 2022
  • Raman spectroscopy is an optical technique that can identify molecules in a label-free manner, and is therefore heavily investigated in various areas ranging from biomedical engineering to materials science. Probe-based Raman spectroscopy can perform minimally invasive chemical analysis, and thus has potential as a real-time diagnostic tool during surgery. In this study, Raman experimentation was calibrated by examining the Raman shifts with respect to the concentrations of chemical substances. Raman signal characteristics, targeted for normal mice and cerebral tissues of the 5xFAD dementia mutant model with accumulated amyloid beta plaques, were measured and analyzed to explore the possibility of diagnosis of Alzheimer's disease. The application to the diagnosis of dementia was cross-validated by measuring Raman signals of amyloid beta. The results suggest the potential of Raman spectroscopy as a diagnostic tool that may be useful in various areas of application.

Qualitative and Quantitative Analysis of Space Minerals using Laser-Induced Breakdown Spectroscopy and Raman Spectroscopy (레이저 유도 분해 분광법과 라만 분광법을 이용한 우주 광물의 정성 및 정량 분석 기법)

  • Kim, Dongyoung;Yoh, Jack J.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.6
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    • pp.519-526
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    • 2018
  • In order to analyze space resources, it had to be brought to earth. However, using laser-induced breakdown spectroscopy(LIBS) and Raman spectroscopy, it is possible to analyze qualitative and quantitative analysis of space minerals in real time. LIBS is a spectroscopic method in which a high energy laser is concentrated on a material surface to generate a plasma, and the emitted light is acquired through a spectroscope to analyze the atomic composition. Raman spectroscopy is a spectroscopic method that analyzes the molecular structure by measuring scattered light. These two spectroscopic methods are complementary spectroscopic methods for analyzing the atoms and molecules of unknown minerals and have an advantage as space payloads. In this study, data were analyzed qualitatively by using principal component analysis(PCA). In addition, a mixture of two minerals was prepared and a quantitative analysis was performed to predict the concentration of the material.

Stimulated Raman scattering at 1.54${\mu}m$ and Brillouin scattering at 1.06${\mu}m$ in $CH_4$ under 5 Hz repetition rate (반복률과 라만매질 압력에 따른 1.54 ${\mu}m$ 전방, 후방 유도라만 및 1.06${\mu}m$ Brillouin 산란광의 출력특성)

  • 최영수;전용근;김재기
    • Korean Journal of Optics and Photonics
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    • v.10 no.2
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    • pp.95-101
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    • 1999
  • We have studied the 1.54$\mu\textrm{m}$ forward and backward stimulated Raman scattering (SRS) and stimulated Brillouin scattering (SRS) for various $CH_4$pressures by 1.06$\mu\textrm{m}$ Q-switched Nd:YAG laser pumping under a repetition rate of Hz in single pass. We obtained that the output of backward SRS was more efficient than that of the forward SRS. The output energy and conversion efficiency of forward and backward SRS were higher than those of SBS since SRS is a steady state, but SBS is a transient state. In a $CH_4$gas uncirculating system, the output energy of the backward SRS and SBS were reduced the about 47% due to a thermal heating of $CH_4$medium in a focusing region for a repetition rate of 5 Hz. But, the output energy of forward SRS was slightly enhanced by about 8.5% due to the increase of the undepleted pump beam in the backward SRS generation. Inthe Raman half resonator using a dichromatic focusing lens, the conversion efficiency of SRS was more than 37% for a input pump laser energy of 40 mJ.

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Maeasurement and analysis of anti-Stokes Raman spectroscopic singnals (코헤런트 반 스톡스 라만 분광 신호 측정 및 분석)

  • 한재원;박승남;이은성;김형식;이충희
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.07a
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    • pp.9-14
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    • 1991
  • 질소 기체의 코헤런트 반 스톡스 신호를 상자형 위상전합 방식으로 측정하였으며, 이 신호로부터 온도 및 밀도를 구하기 질소 기체의 코헤런트 라만 신호를 섭동이론을 이용하여 계산하였다.

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The Study of Two-dimensional Chemical Distribution about Soil using Laser Spectroscopy (레이저 분광법을 활용한 토양 2차원 화학적 분포도 검출 연구)

  • Yang, Jun-Ho;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.45 no.6
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    • pp.523-530
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    • 2017
  • Laser-Induced Breakdown Spectroscopy (LIBS) which a plasma is irradiated at a specific wavelength depending on the material when a high-energy laser is irradiated, and a Raman spectroscopy which measures rotation and vibration in molecules as light-scattering phenomenon occurs, are attracting attention as a space exploration technology because of the advantages of high accuracy and real-time analysis, and the ability to perform long-range detection. In this study, the tendency of the laser spectrum according to the change of the soil component was analyzed by laser spectroscopy and the two - dimensional chemical distribution was conducted based on the trend of laser spectrum. We have also established the environment of Mars (4-7 torr) and lunar atmosphere (<1 torr) in experimental setup, to prove that it is possible to measure by difference of soil chemical composition using LIBS and Raman spectroscopy even in artificial space environment.

Surface Enhanced Raman Scattering at Ag-Pyridine Interface by Use of Long Range Surface Plasmon (장거리 표면 프라즈몬을 이용한 은-피리딘계에서의 표면증강 라만산란)

  • 백문구;고의관;고도경;이해형;장준성
    • Korean Journal of Optics and Photonics
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    • v.1 no.2
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    • pp.142-148
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    • 1990
  • Surface-enhanced Raman scattering (SERS) experiment of pyridine (CsHsN) has been performed at silverpyridine interface by use of long range surface plasmon (LRSP) which is generated in the Sarid-type attenuated total reflection (A TR) structure consisting of prism. dielectric. metal and dielectric media. Generation of LRSP has ben confirmed by observing the propagation of the LRSP. Raman signal of pyridine adsorbed on a silver surface in the above layered structure has been observed and compared with the bulk Raman signal and SERS signal from the chemically adsorbed pyridine. SERS experiment by use of LRSP has not yet reported to the best of our knowledge.wledge.

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Wide Field Imaging Analysis of Graphene (그래핀의 대면적 이미지 특성 분석)

  • Kwon, Kanghyuk;Kim, Nayoung;Havener, Robin W.;Won, Donggwan;Cho, Seungmin;Park, Jiwoong
    • Korean Journal of Optics and Photonics
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    • v.24 no.3
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    • pp.143-147
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    • 2013
  • A Raman spectrometer is essential for analyzing the characteristics of graphene. The commercial micro-Raman spectrometer is useful for measuring small areas, but due to the small measuring area, it has limited use in industry, as a sampling measure. This paper suggests a Raman spectrometer able to get a large area image of graphene. By using this image, we can get information on defects and on the presence of graphene. Therefore, this equipment can be used for quality assessment for production of graphene.

초광대역 광증폭기에 대한 연구

  • 박남규;박종한;이한석;김나영
    • Information and Communications Magazine
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    • v.19 no.10
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    • pp.78-92
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    • 2002
  • 고용량 파장다중분할(WDM) 전송 시스템의 수요가 폭발적으로 증가함에 따라 기존의 erbium-doped fiber amplifiers(EDFA)가 제공하는 이득 대역을 넘어서는 대역폭의 광증폭기의 개발이 촉진되고 있다. 에르븀 이외의 새로운 회토류 첨가물을 사용한 증폭기와 광섬유 내에서의 비선형 현상인 라만 산란에 의한 라만 증폭기에 집중적인 연구가 그 예라 하겠다. 최근 몇 년간의 집중적인 연구를 통하여 현재의 광대역 광 증폭기는 기존의 EDFA(C 벤드 EDFA)가 제공하는 광이득대역의 4∼5배 정도를 쉽게 제공할 수 있다. 이러한 목적을 가지고 통신시장에서 사용될 수 있는 1500nm 근처 대역의 증폭에 대한 세가지의 증폭 기술이 연구되고 있다. 우선, S+밴드(1450-1480nm)와 S밴드(1480-1530nm)의 증폭을 위한 thulium-doped fluoride fiber amplifiers(TDFFA), C 밴드(1530-1560nm)와 L 밴드(1570-1610nm)를 위한 EDFA, 그리고 마지막으로 100nm 이상의 이득대역과 S+에서 L밴드까지 증폭파장대역의 선택이 자유로운 라만 증폭기가 있다. 또한 위의 세 기술을 직렬 또는 병렬로 조합하여 사용하는 증폭기가 있다. 이러한 증폭기 모두에 대해서 실험적인 보고는 많이 있었으나, 내부의 에너지 준위가 복잡하여 증폭 기제가 복잡하고, 실험 파라미터를 측정하기가 어려워서 광대역증폭기의 성능을 예측하기 어려운 점이 있었다. 게다가 이러한 상황에서 광대역증폭기에 대한 해석적이거나 수치해석적인 심도깊은 연구가 부족하여 앞으로 증폭기를 다양하게 응용하기 위한 성능의 예측이 어려울 것으로 보인다. 이는 광대역 증폭기 기반의 전송 시스템을 성공적으로 적용하는데 제한을 줄 것이다. 따라서 본 논문에서는 광대역 증폭기(C/L밴드 EDFA, 라만 증폭기, TDFA)에 대한 실험적인 분석뿐만 아니라 해석적, 수치해석적인 분석 방법까지 그 응용의 예와 함께 소개할 것이다.