• Journal of the korean Society of Automotive Engineers
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• v.7 no.1
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• pp.12-17
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• 1985

주위기체와 다른 기체를 간헐적으로 또는 단발로 분사한 경우, 분류내의 분사체의 농도는 시간에 따라 급격히 변화한다. 수ms인 전자식기체 채취밸브를 이용해서 기체를 채취하고, 가스마토그 라프 등에 의해 가스분석을 행하는 방법이 있고 주로 피스톤식 내연기관의 연소실내 농도의 측 정에 이용되고 있다. 이 방법은 밸브 열립시간을 단축시켜도 약 1ms가 한도이고 시간분해능력도 1ms정도가 최단시간이다. 또 동일한 장소에서 농도의 시간경과를 얻는 데에는 각각의 시간에 대해서 기체의 채취와 분석을 행하지 않으면 안되어 실제시간의 농도측정이 불가능하다는 결점이 있다. 최근 레이저 응용기술의 진보에 의해 라만산란, 레리산란, CARS법 등의 농도순간측정이 가능해지고 있고, 점차 현실화되어가고 있다. 이들의 방법은 국소의 순간농도뿐만 아니라 온도의 동시측정도 가능하게 하는 특징을 갖고있다. 그러나 레이저에 의한 측정장치는 현시정에서는 아직 가격이 고가이고 광학계의 설치 등, 실험상의 조작이 복잡한 것 등의 결점을 갖고 있다. 본 고에서는 최근 진전이 현저하고 실용화에 대한 확신을 갖고 있는 열선농도Probe에 의한 순간농 도의 측정방법을 소개하고자 한다.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.215.2-215.2
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• 2013

본 연구에서는 흑연(graphite)과 티타늄(titanum; Ti) 타겟이 양쪽에 부착되어 있는 비대칭 마그네트론 스퍼터링 장치를 이용하여 Ti이 도핑되어진 다이아몬드상 탄소박막(Ti doped Diamond-like carbon, DLC:Ti)을 증착하였다. 흑연과 티타늄 타겟의 파워는 고정하고 기판에 음의 DC 바이어스를 인가하여 DC 바이어스 변화에 따른 DLC:Ti 박막을 증착하였다. 증착되어진 박막의 음의 DC 바이어스의 변화에 따라 변화되어지는 경도와 마찰계수, 표면의 거칠기, 접촉각 등의 트라이볼로지 특성들을 분석하였으며, XPS와 라만등의 분석법을 이용하여 박막의 구조적 특성과 트라이볼로지 특성과의 관계를 고찰하였다.

• Journal of the Korean GEO-environmental Society
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• v.5 no.2
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• pp.23-31
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• 2004

Trichloroethylene(TCE), Cr(VI), and nitrate removal efficiency of a novel reactive barrier were experimented, and the types of corrosion species that form on the surface of the iron and bentonite as a result of reaction were investigated with Raman spectrophotometer. The reactive barrier is composed of bentonite and zero valent iron(ZVI), and this can substitute conventional geosynthetic clay liners for landfill leachate. Tests were performed in batch reactors for various ZVI content (0, 3, 6, 10, 13, 16, 20, 30, 100 w/w %) and pH. The reduction rates and removal efficiencies of TCE, Cr(VI) and nitrate increase at pH 7 buffered solution. As ZVI content increases, TCE, Cr(VI) and nitrate removal efficiencies increase. From the result of analysis with Raman spectrophotometer, Fe-oxides were observed, which are strong adsorbers of cantaminants. Magnetite can be also beneficial to the long term performance of the iron metal.

• Journal of the Korean Chemical Society
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• v.47 no.5
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• pp.439-446
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• 2003

Surface-enhanced Raman(SER) spectroscopy was utilized to investigate the adorption orientation of the 4-biphenylcarboxylic acid(BPCA) derivatives, such as 4'-cyano-BPCA(c-BPCA), 4'-mercapto-BPCA(m-BPCA), and 4'-amino-BPCA(a-BPCA), which were adsorbed on Au and Ag colloid monolayers. For the systematic approach, information regarding the adsorption behavior of benzoic acid, biphenyl, and BPCA was applied to the target molecules. From the spectral behaviors of benzene ring, C-H stretching, carboxylate anion, and the other finger printing vibrational modes, it was concluded that only the m-BPCA was adsorbed tilt with thiol group being adsorbed on Au surface, whereas the other molecules were adsorbed flat on both Au and Ag surfaces.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.2
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• pp.260-266
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• 2002

DLC films were deposited on Si wafer by RF plasma assisted CVD using CH4 gas. Tribological tests were conducted using rotating type ball on disk friction tester in dry air. Four kinds of mating balls were used. The mating balls were made with stainless steel but apply different annealing conditions to achieve different hardness conditions. Testing results in all load conditions showed that the harder the mating materials, the lower the friction coefficient among the three kind of martensite mating balls. In case of austenite balls, the friction coefficients were lower than fully annealed martensite ball. The high friction coefficient in soft martensite balls seems to be caused by the larger contact area between DLC film and ball. The wear tracks of DLC films and mating balls could have proven that effect. Measuring the wear track of both DLC films and mating balls have similar tendency comparing to the results of friction coefficients. Wear rate of austenite balls were also smaller than that of fully annealed martensite ball. The results of effect of applying load showed, the friction coefficients were become decrease when the applying loads exceed critical load conditions. The wear track of mating balls showed that some material transfer occurs from DLC film to mating ball during the high friction process. Raman spectra analysis showed that transferred material was a kind of graphite and contact surface of DLC film seems to undergo phase transition from carbon to graphite during the high friction process.

• Composites Research
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• v.29 no.4
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• pp.156-160
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• 2016

Glassy carbon can be utilized in a variety of harsh environment due to exceptional thermal stability and chemically impermeability along with scalability and low electrical resistance. In this work, we studied effects of electron(e)-beam irradiation on thermoelectric properties of the glassy carbon film. E-beam irradiation triggered local crystallization and/or amorphization of glassy carbon thin films, which was determined by a Raman spectroscopy. The structural change by e-beam irradiation leads to the change in the doping level of the glassy carbon, which can be inferred from the change of a Seebeck coefficient and an electric conductivity. The optimal power factor we obtained for the irradiated glassy carbon film was ~200% higher than that of the non-irradiated sample.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.75-75
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• 2010

단일벽 탄소나노튜브(SWNT)는 뛰어난 물리적 성질과 화학적 안정성을 가지고 있어서 다양한 분야의 응용이 기대되어 폭넓은 연구가 진행 되고 있다. 특히 SWNT의 전기적 및 기계적 특성들은 SWNT의 직경 및 뒤틀림도(chirality)에 의해 크게 좌우되기 때문에, 합성하는 단계에서 직경 또는 chirality를 제어에 관한 많은 이론적 연구가 진행되어 왔으며, 최근에는 초기 SWNT의 핵생성 단계에서의 촉매의 거동 및 상호 연관성 등에 관한 실험적인 연구결과들이 속속 보고되고 있는 실정이다. 하지만, 아직도 이에 관한 더욱 다양하고 활발한 연구 접근 및 결과들이 필요한 시점이다. 상기 배경을 바탕으로 본 연구에서는 균일한 직경을 갖는 SWNT의 합성을 위한 기초연구로서 SWNT의 직경과 촉매나노입자의 크기의 상호 연관성에 대해 체계적으로 조사하였다. 우선 SWNT합성을 위한 촉매나노입자를 얻기 위해 페리틴(ferritin)용액의 농도 및 스핀코팅 조건을 변화시킴으로써 기판 위에 분산농도를 제어한 후, 대기 열처리를 통하여 촉매나노입자의 농도를 제어하였다. 나노입자의 평균직경은 4 nm 정도로 비교적 균일하였으며, 고농도의 촉매입자는 SWNT의 다발화(bundling)를 유발하였다. 따라서, SWNT와 나노입자 직경의 상호연관성을 조사하기 위해서는 단분산(monodispersed) 된 나노입자를 이용하였으며, 아르곤 분위기에서 추가적으로 고온($900^{\circ}C$) 열처리를 실시함으로써 나노입자의 크기감소를 도모하였다. 실험결과, 열처리 시간의 증가에 따라 입자크기가 감소함을 확인하였으며, 이는 나노입자의 증발에 의한 것으로 예상된다. 다음으로는 열처리를 통하여 직경이 제어된 나노입자를 이용하여 SWNT를 합성한 후 SWNT와 촉매크기 사이의 크기 관계를 조사하였다. SWNT의 합성은 메탄을 원료가스로 열화학증기증착법을 이용하였고, 합성기판으로는 산화실리콘웨이퍼와 퀄츠기판을 이용하였다. 성장한 SWNT의 직경은 AFM을 이용하여 측정하였으며, 퀄츠기판에 수평배향 성장시킨 SWNT를 3차원 구조의 기판으로 전사(transfer)하여, 라만분석이 용이하도록 하였다.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.1
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• pp.114-120
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• 2020

In this study, we analyzed the structural characteristics of soot, which is one of the anticipated regulatory substances of the IMO, and used a novel classification method to distinguish between exhaust soot and engine soot in marine engines. As an extension of a recent study on exhaust soot recycling, annealing was performed at 2,000 ℃ on engine soot to determine whether it could be recycled. Soot samples before and after annealing were analyzed using HR-TEM and Raman spectroscopy. The HR-TEM results showed that exhaust soot and engine soot had similar nanostructures; the exhaust soot has a spherical primary particle with a chain-like structure, whereas engine soot particles have amorphous structures. The Raman spectroscopy showed a D-peak and a G-peak for both exhaust soot and engine soot. However, the G/D ratio indicated that the value of exhaust soot was relatively higher than that of engine soot, which implies that the exhaust soot has a more graphitized structure. The analysis of annealed engine soot confirmed that graphitization proceeded without any problems, similar to the exhaust soot. This confirmed that both exhaust soot and engine soot generated by marine diesel engines could be recycled as graphite materials.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.8
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• pp.3597-3601
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• 2013

In this study, a wet cleaning process, P II, using aqua-regia and sulfuric acid mixture with oxidant agent ($K_2S_2O_8$, $P_2O_5$, $KMnO_4$, $H_2O_2$ etc) is proposed to remove the metastable phase of graphite such as graphene and DLC for high quality synthetic diamonds. The process employed the conventional acid cleaning process (P I) as well as P I+P II to remove the graphite related impurities from the 200um-diamond powders synthesized at 7GPa-$1500^{\circ}C$-5minutes. The degree of cleaning after P I and P I+P II has been observed by naked-eye, optical microscopy, micro-Raman spectroscopy, and TGA-DTA. After P I+P II, the color of diamond became more vividly yellow with enhanced saturation with naked eye and optical microscopy analysis. Moreover, the disappearance of diamond-like-carbon (DLC) peak ($1440cm^{-1}$) observed by Raman spectroscopy confirmed the decrease in amount of remaining impurities. TGA-DTA results showed that the graphite impurities first started to dissolve at $770.91^{\circ}C$ after PI process. However, the pyrolysis started at $892.18^{\circ}C$ after P I+P II process because of the dissolution of pure diamonds. This result proved the effective dissolution of the metastable phase of graphite. We expect that the proposed P II process may enhance the quality of diamonds through effective removal of surface impurities.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.761-764
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• 2009

Ag-Doped bioactive ceramic composites were prepared by colloidal silver solution. The physical properties of colloidal silver solution and Ag-Doped bioactive ceramic composites were characterized by Scanning electron microscopy(SEM), X-Ray Diffractometer(XRD) and Raman spectrophotometer respectively. According to XRD, we have identified that the chloride ion was chemically attached silver nano particles. SEM studies showed that silver chloride phases were homogeneously distributed on the Ag-Doped bioactive ceramic composites surface. Finally, we concluded that the silver chloride phase on the Ag-Doped bioactive ceramic composites surface was strongly prevent formation of Ag-hydroxyapatite.